Ollc)-

Csdiamanmetic ompolund
0

C2 12-: g2 oTs 2s2 T2e = Tz

opti Cc) carreck
2(6 An the malerulan ouitol diaamua rJ the malecula
ivaN2the o elecbremiin dlhe moleclon-
0dáuta is->

TT2P
2p2

T2p T12p

T2

N N
N N

C'2s
N2-
N2
 O2p contau1elechfon
Sa, for N
So 6)is_correct

he laaud ordeuCA oe fawad_Ak-

B:0 Nh-Na-
2

h h e baudiiug0toitnl
lh No. e
No No. e L a Hae autihoucdiug 0aitni.
B0 E CLO-5)5 2

Ca) ia corrert

Nh 10Na=6_
B:0 Nh- Na 10-6 Y
2 2

Nh 10 No
8-0 Nh-Na 10-7=3 al:5
2
2
Nh 10 Na =S
B.0zNb Na 10-5 S
2

Bo(O)KB:o (2) Qnd 9.0 (0) > B-o(0)_

 h O2 h a s a o u l0ad ordle taan O2,0 hosA
a higher dhaud ordeutthan O2
d)_ia_correct

6).Cisunatcorect
One o Uae short cOning& o malecdan auatal
-fhearyisits inalaility to hccouut Jon a iple
oaudun Lhe Jaitroge nadlecude Na iaat correst

8 6udnti.bcudiag_maleculan arhitails Qne podsuLe hs-

desrunliue dntducti»oatnale arbitals

9cThelu male.culanooital dlieoprams ane m0re

uunetsci.ccu lha ihose a homa nuelean dintomuc
alecules e nse

Nu)=> Ois2 OisS Osa 2sa Ozp TT2p TaP

B:0 0-4= 3

N (t3) = O2 OT 2 Os T P Tp Cp2

T
B:010-6 2

Sa,_uoind arde e NE S 2_aud baud Onder e

NQudN2is RS aud
 npainec e in N2=
ja Uupained. i n N2 2

Sa, no. aupaineel o in Njs 2 and, o, o npained

e- in Na and N ane O_ad 1espeetiusly
Aue levatuu oaud distaueeik iAuenkelupmpariaua
to laud ond en
Bawd orden Nz NT >N
B.ow distauoe => N2>NJ >N2

12 Bocd arden cot is 3:5 aMd bond orlee cO is 3

B0, CO niore Stable kord Hhcn CO. But Co moleoula
4 e 1aeatol in haiune Bol orde Cot depeudh enl
mJaulauidALsation o maleculeS0, Bond lougth o ot
AMAan bovud Jeaath o co
COodCo bond leugaone a 128 augstrom aud
1S Anqahrom

13(a) Siama naleculan OLbital may_neault rom 0vedap

p atdmic onlitall pexpeadicuda tohe malecl
u Side -on) false
15 Bond ordexKRr_iiapomimately auvnte the e
20 and_3r calacel_cack othe dut justlika ihe_
ond the 21T
Eleu) KTBY
K 4-
Brt

-125

-1. 24 S
2S S

H)

O2Pz
 OF(IR)> ois2 crd O2 Coga p TTe ex Tt2p TT2e TRA2
Na = No. e n autiboudiug oktal R
Nb= No. o e in boudiug oaitrl =10
Bauad oden R.ó Nh-NaLo-
sa, tae1erlisted ooud ardez OE 1
No. o uupained e in Of is"a
The aast_Lileelypasitiolufor addiuo Ht to OF" eu
ia F lea becse it is _Most wounalble to add Ht
Hae AAast eele aicla fien as Ht is e-deliciest

30

a
Gproup-
Atomic ovoital 10
0oltals
Moleeulan Orbita

18 AU nmolerulan Orhitals eKLept the hiahest eue194 Oane

Sietdt Silled qiuiug Q band oxden qL
CI uil aitrack HE_aast: becauze"it uil Jead to
foxmaicu Stabie HCL Conapouiad
 19)hepueuomeuon oS=P mixiug_OCcun2whea molerula stun
hesame summehiy ovmed om the_combination o -
and n atomid oraitala ane close euoughua euotgy_ta
uxheintonct uhica can lead to o chaage sthé ezpetiea
_Oudeu c auotala LA0ngie
The pakaitala o ¢ f ane higtae
fae 2p osaitala o RBecauseo tt f2 mly laaig -
,
eaAigle Sp miwiag uot Suiiiuat tn_chounge dae
CIA Pun ardeuiug .
B2 aleRule duille diamagneticuul0K 98-p niuu
opeHatie And Huads ules uat uinleked4 t l
Je diamnqnetic hecause_due to 2-p miui all e
pained

a) r XH ualeculeXd peajad oleututs

Caaidex the Be fa moleclea Be houu a is22s2 e conliqunah
Juita noupained eauailalble J bodiug Irann a
R Apectiue o uiag nly, atmit orkitalitn aeueate ti
sondiuug oaitnla Jud uauld couolude taat he malecule
Coud udt Bss siace. uo eeesaitala ouiestala eist a
Be to boud
Be hos s aud 2P oraitals_and it a in the naiddle
H os s_0foitals,thene ane RHatomå n the Outsic
JUJ inihaly_maka combinatio heHao mie-
Droibls dt up1euiously used to malee diatoms
hydoan D4cept_thene iho ovelap ie =S=o)
Tuee tombinatim ill_mic uulh tae s aud 2P
G Be as saau belou
H
 Be
Aconmbiaatiana uith approprlate
oHAOS Be A0s

heu uuo Con put Hae maleruda arhital didgrom-

toqetheh Staxting uit Hae olutside dauig _in
boadiag 0nboudiuag Aud uti baudiag M0g od
tte The boad orde ie.
auk bouduq orotals 8eH
o - loondiug ovotols
cOmblnaton3
- B e -H

bondiag Oialtals

H-A-H Mte
At labtratas diae decobw Hha actual Júnenn
oAe Re Ha aud he trul beud 4agleculo
Ha0

3Py3P7

3S

PBecause the boud in Awould be uonleen than

in2, Hae_Ar-Ar distauce uaauld be expected o
be loug en

RoNE = 106 a
Tae a0st ilee boud orde R NE .
 T4-54 eV
l742 eV

30
.

Nihroge NE fuoirlue

o h,S2, Cl2
Shmeuath= P2 >S2 >Cla
Rod peuia
shreugth_decueNie ac0s8 Hhe
As Boud
oitallou he ordeh Ps2 2Cl2

L)S S2, S
Bod Shreugth
Sa 2 S2a 2s2+
NOT
e) NO, NO NO NO>Mot
Baud sreug.th E2
 CHHeH or HeH2.
g(is)

H2 He

Atomic aHaital moleculan Atomuc

okoitals oroital

Ala. oe CheHa] =2
Mechronie cainiaundion LHe Ha 2 molecule

B-O 0

As Baudoden oHe HaZr ia

o, CHe H2 cau eisk

( aB3
az" te
d" (nou
Doudiny

LGOO
S MOde
hode-
 -Ha =
HaO = moleculan orotalW
HSALCs
qroup ovostals fo
b HQtovms
atomic
Oottat Ha

30y

32:3
(-32-3,

CNHa
LUM0
a+e
-10 S
P - HOMO

2s a -

H_
-dBfa oud
COS

RVe oiotuls
up 1o hore
HOMOS_ane F_
Moue pav

a9T aTFoz+02

B
Be e[PzTShcetud ar O)*
Ques O overtap Ustead
GeLPy CToVerlapP
al +e - - -

ar +e
Bs oS

O
jLUMO
HOMO
 TMS HDI EI BIPTT FPPI_

HOMO cliereut_peKible uoyauate Compouwd

-0:2/38
CHOMD (Ha) 0.247 -02OY -0-2v05 -0-2192-2-2035

LDMO drnk_pessible Boyauate comp0

-0.062?
0-0057,0:0289 -0-0233-00U33-01 058
kmo Ha)

-ODO

OOO

90 t-A-H He
molerul hape
BH Beub
8H Linea
iH2 =Be
uear
CH 9ackyloue caton
AlHA
H20 Beut (v-ghaped)