BOHR MODEL

Q.1 Suppose that a hypothetical H-like atom gives a red Green, blue & violet line spectrum. Which jump
according to figure would give off the red spectral line.
n=4
n=3
n=2
n=1
(A) 3 – 1 (B) 2  1 (C) 4 – 1 (D)3  2 [D]
Q.2 The ratio of the radii of first orbits of H, He+ and Li2+ is -
(A) 1 : 2 : 3 (B) 6 : 3 : 2 (C) 1 : 4 : 9 (D) 9 : 4 : 1 [B]
–1
Q.3 The wave number of the limiting line in Lyman series of hydrogen is 109678 cm . The wave number of the
limiting line in Balmer series of He+ would be -
(A) 54839 cm–1 (B) 219356 cm–1 (C) 109678 cm–1 (D) 438712 cm–1 [C]
Q.4 The energy of an electron in the first orbit of H- atom is – 13.6 eV. The possible energy values of the
excited state for electron in Bohr orbits of Li2+ ions is/are –
(A) –3.4 eV (B) –30.6 eV (C) –13.6 eV (D) All of the above [D]

1
Q.5 A small particle of mass m moves in such a way that P.E. = – mkr2, where k is a constant and r is the
2
distance of the particle from origin. Assuming Bohr's model of quantization of angular moment and
circular orbit, r is directly proportional to -

(A) n2 (B) n (C) n (D) none of these [C]

Q.6 As we go away from the nucleus, the difference between the successive energy levels -
(A) increases (B) decreases (C) remains constant (D) first increases, then decreases [B]
Q.7 The ionization energy of hydrogen atom is 13.6 eV. What will be the ionization energy of He+ ?
(A) 13.6 eV (B) 54.4 eV (C) 122.4 eV (D) Zero [B]
Q.8 Ionisation potential of hydrogen atom is 13.6eV. If hydrogen atom in the ground state is excited by
monochromatic light of energy 12.1 eV, then the spectral lines emitted according to Bohr's theory will be -
(A) One (B) Two (C) Three (D) Four [C]
Q.9 Energy levels A, B, C of a certain atom correspond to increasing value of energy, i.e., E A < EB < EC. If 1,
2 & 3 are the wavelengths of radiations corresponding to the transitions C to B, B to A and C to A
respectively, which of the following statement is correct :
C
1
B

2 3
A
1  2
(A) 3 = 1 + 2 (B) 3 = (C) 1 + 2 + 3 = 0 (D) 23  21  22 [B]
1   2
Q.10 Calculate the wavelength of the spectral line when the electron in the hydrogen atom undergoes a transition
from fourth energy level to second energy level ?
(A) 4.86 nm (B) 486 nm (C) 48.6 nm (D) 4860 nm [B]
Q.11 The wave number of the first line of Balmer series of hydrogen is 15200 cm–1. The wave number of the
first Balmer line of Li2+ ion is
(A) 15200cm–1 (B) 60800 cm–1 (C) 76000 cm–1 (D) 136800 cm–1 [D]
Q.12 The frequency of one of the lines in Paschen series of a hydrogen atom is 2.34 x 1014Hz. The quantum
number, n2, which produces this transitions is
(A) three (B) four (C) six (D) five [D]
Q.13 In hydrogen spectrum, the series of lines appearing in ultra violet region of electromagnetic spectrum are
called
(A) Lyman lines (B) Balmer lines (C) Pfund lines (D) Brackett lines [A]
Q.14 Which of the following series of lines in the atomic spectrum of hydrogen appear in the visible region ?
(A) Lyman (B) Paschen (C) Brackett (D) Balmer [D]
Q.15 Which of the following is not correct according to Planck's quantum theory ?
(A) Energy is emitted or absorbed discontinuously
(B) Energy of a quantum is directly proportional to its frequency
(C) A photon is also a quantum of light
(D) Energy less than a quantum can also be emitted or absorbed. [D]
Q.16 To which electronic transition between Bohr orbits in hydrogen, the second line in the Balmer series
belongs ?
(A) 3  2 (B) 4  2 (C) 5  2 (D) 6  2 [B]
Q.17 The ratio of the radii of first three Bohr orbits is
(A) 1 : 05 : 033 (B) 1 : 2 : 3 (C) 1 : 4 : 9 (D) 1 : 8 : 27 [C]
Q.18 Bohr advanced the idea of
(A) stationary electrons (B)Stationary Nucleus (C) Stationary orbits (D)Elliptical orbits [C]
Q.19 The frequency of first line of Balmer series in hydrogen atom is 0. The frequency of corresponding line
emitted by singly ionised helium atom is
(A) 2v0 (B) 4v0 (C) v0/2 (D) v0/4 [B]
Q.20 Energy of third orbit of Bohr’s atom is
(A) – 13.6 Ev (B) – 3.4 eV (C) – 1.5 eV (D) None of the three [C]
Q.21 If the radius of first Bohr orbit be a0, then the radius of the third orbit would be
(A) 3 × a0 (B) 6 × a0 (C) 9 × a0 (D) 1/9 × a0 [C]
Q.22 In H–atom electron jumps from 3rd to 2nd energy level, the energy released is
(A) 3.03 × 10–19 J/atom (B) 1.03 × 10–19 J/atom
(C) 3.03 × 10–12 J/atom (D) 6.06 × 10–19 J/atom [A]
Q.23 The ratio of ionization energy of H and Be+3 is
(A) 1 : 1 (B) 1 : 3 (C) 1 : 9 (D) 1 : 16 [D]
Q.24 The ionization energy of hydrogen atom (in the ground state) is x kJ. The energy required for an electron to
jump from 2nd orbit to the 3rd orbit will be(A) x/6 (B) 5x (C) 7.2x (D) 5x/36 [D]
Q.25 In two H atoms X and Y the electrons move around the nucleus in circular orbits of radius r and 4r
respectively. The ratio of the times taken by them to complete one revolution is
(A) 1 : 4 (B) 1 : 2 (C) 1 : 8(D) 2 : 1 [C]
Q.26 Wave-number of the first line of Paschen Series is - (R = 109700 cm–1)
(A) [18750 Å]–1 (B) [2854 Å]–1 (C) [3452 Å]–1 (D) [6243 Å]–1 [A]
Q.27 A photon was absorbed by a hydrogen atom in its ground state and the electron was promoted to the fifth
orbit. When the excited atom returned to its ground state, visible quanta were emitted when electron made
transition - (A) 5  2 (B) 2  1 (C) 3  1 (D) 4  1 [A]
Q.28 What is the change in the orbit radius when the electron in the hydrogen atom (Bohr model) undergoes the
first Paschen transition?
(A)4.23 × 10–10 m (B) 0.35 × 10–10 m (C) 3.7 × 10–10 m (D) 1.587 × 10–10 m[C]
Q.29 If the shortest wavelength of H atom in Lyman series is x. then longest wavelength in Balmer series of He+
9x 36 x x 5x
is : (A) (B) (C) (C) [A]
5 5 4 9
Q.30 The dissociation energy of H2 is 430.53KJ mol–1. If H2 is dissociated by illuminating with the radiation of
wavelength 253.7 nm, the fraction of the radiant energy which will be converted into kinetic energy is
given by (A) 8.76 % (B) 12.33 % (C) 11.3 % (D) 100% [A]
Q.31 The energy difference between two electronic states is 46 .12 kcal /mole. What will be the frequency of the
light emitted when an electron drops from the higher to the lower energy state? (Planck' constant = 9.52 ×
10–14 kcal sec mole–1)
(A) 4.84 × 1015 cycles sec–1 (B) 4.84 × 10–5 cycles sec–1
(C) 4.84 × 10–12 cycles sec–1 (D) 4.84 × 1014 cycles sec–1 [D]
Q.32 The radii of two of the first four Bohr orbits of the hydrogen atom are in the ratio 1 : 4. The energy
difference between them may be :
(A) Either 12.09 eV or 3.4 eV (B) Either 2.55 eV or 10.2 eV
(C) Either 13.6 eV or 3.4 eV (D) Either 3.4 eV or 0.85 eV [B]
Q.33 Bohr’s model can explain-
(A) the spectrum of hydrogen atom only (B) spectrum of an atom or ion containing one electron only
(C) the spectrum of hydrogen molecule (D) the solar spectrum [B]
Q.34 The radius of an atomic nucleus is of the order of-
(A) 10–10 cm (B) 10–13 cm (C) 10–15 cm (D) 10–8 cm [B]
Q.35 Electromagnetic radiation with maximum wavelength is-
(A) ultra violet (B) radio wave (C) X-ray (D) infra-red [B]
Q.36 The ratio of the energy of a photon of 2000Å wavelength radiation to that of 4000Å radiation is-
(A) 1/4 (B) 4 (C)1/2 (D) 2 [D]
Q.37 The energy of an electron in the first Bohr orbit of H atom is –13.6 eV. The possible energy value (s) of the
excited state(s) for electrons in Bohr orbits of hydrogen is (are)
(A) –3.4 eV (B) –4.2 eV (C) –6.8 eV (D) +6.8 eV [A]
Q.38 The energy of the electron in the first orbit of He+ is - 871.6 x 10–20 J. The energy of the electron in the
first orbit of hydrogen would be
(A) –871.6 x 10–20 J (B) –435.8 x 10–20 J (C) –217.9 x 10–20 J (D)–108.9 x 10–20 J [C]
Q.39 Atomic radius is of the order of 10 cm and nuclear radius is of the order of 10–13 cm. Calculate what
–8

fraction of atom is occupied by nucleus ?

(A) 10–5 (B) 105 (C) 10–15 (D) 10–8 [C]
Q.40 The number of photons of light having wave number 'x' in 2J of energy source is -
hc 2 2x
(A) 2hcx (B) (C) (D) [C]
2x hcx hc
Q.41 Ionisation potential of hydrogen atom is 13.6eV. If hydrogen atom in the ground state is excited by
monochromatic light of energy 12.1 eV, then the spectral lines emitted according to Bohr's theory will be –
(A) One (B) Two (C) Three (D) Four [C]
Q.42 What is the wavelength of the radiation emitted producing a line in the Lyman series when an electron falls
from fourth stationary state in hydrogen atom ?(RH = 1.1 × 107 m–1) -
(A) 96.97 nm (B) 969.7 nm (C) 9.697 nm (D) None [A]
Q.43 The ionization energy of He+ is 19.6 × 10–18 J atom–1. Calculate the energy of the first stationary state of
Li2+.
(A) 19.6 × 10–18 J atom–1 (B) 4.41 × 10–18 J atom–1
(C) 19.6 × 10–19 J atom–1 (D) 4.41 × 10–17 J atom–1 [D]
Q.44 In an atom, two electrons move around the nucleus in circular orbits or radii R and 4R. The ratio of the time
taken by them to completes one revolution is
(A) 1 : 4 (B) 4 : 1 (C) 1 : 8 (D) 8 : 7 [C]
Q.45 The transitions from the state n = 4 to n = 3 in a H like atom results in UV radiation. The infra-red
radiations will be obtained in the transition :
(A) 2  1 (B) 3  2 (C) 4  2 (D) 5  4 [D]

Q.46 The number of spectral lines produced according to bohr's concept when one electron jumps from 5th to 2nd
shell are (A) 6 (B) 8 (C) 10 (D) 12 [A]
Q.47 Calculate the frequency of light emitted for an electron transition from the sixth to the second orbit of the
hydrogen atom.
(A) 7.31 × 1014Hz (B) 2.31 × 1014Hz (C) 3.21 × 1014Hz (D) 5.2 × 1014Hz [A]
Q.48 The ratio of the radii of the first three Bohr orbits in H atom is -
(A) 1 : 1/2:1/3 (B) 1 : 2 : 3 (C) 1 : 4 : 9 (D) 1 : 8 : 27 [C]
Q.49 For which of the following species, Bohr's theory is not applicable ?
(A) H (B) He2+ (C) Li2+ (D) Be3+ [B]
Q.50 The ionization energy of hydrogen atom is 13.6 eV. What will be the ionization energy of He+ ?
(A) 13.6 eV (B) 54.4 eV (C) 122.4 eV (D) Zero [B]
Q.51 How much energy should be absorbed by a hydrogen atom in ground state to reach excited state ?
(A) + 1.5 eV (B) 3.4 eV (C) 13.4 eV (D) 10.2 eV [D]
Q.52 Bohr's radius for the H-atom (n = 1) is approximately 0.53 Å. The radius of the first excited state (n = 2)
orbit is - (A) 0.13 Å (B) 1.06 Å (C) 4.77 Å (D) 2.12 Å [D]
Q.53 In hydrogen atom, energy of the first excited state is – 3.4 eV. Then find out the K.E. of the same orbit of
H-atoms. (A) + 3.4 eV (B) + 6.8 eV (C) – 13.6 eV (D) + 13.6 eV [A]
Q.54 If the velocity of electron in Bohr's first orbit of hydrogen atom is x, then the velocity of electron in the
x
third orbit is - (A) 3x (B) x (C) 9x (D) [D]
3
Q.55 Find the ratio of frequency of e– in 1st orbit of H atom to 3rd orbit of He+ ion.
27 4 54 27
(A) (B) (C) (D) [A]
4 27 4 8
Q.56 In an atom, two electrons move around the nucleus in circular orbits of radii R and 4R. The ratio of the time
taken by them to completes one revolution is
(A) 1 : 4 (B) 4 : 1 (C) 1 : 8 (D) 8 : 7 [C]
Q.57 Which state of Be3+ has the same orbit radius as that of the ground state of hydrogen atom.
(A) 3 (B) 2 (C) 4 (D) 5 [B]
Q.58 The kinetic and potential energy (in eV) of electron present in third Bohr's orbit of Hydrogen atom are
respectively-
(A) –1.51, –3.02 (B) 1.51, –3.02 (C) –3.02, 1.51 (D) 1.51, –1.51 [B]
Q.59 What is the separation energy (in eV) for Be3+ in the first excited state in eV ?
(A) 13.6 eV (B) 27.2 eV (C) 40.8 eV (D) 54.5 eV [D]
Q.60 The ratio of the difference in energy of electron between the first and second Bohr's orbits to that between
second and third Bohr's orbits is : (For Hydrogen)
1 27 9 4
(A) (B) (C) (D) [B]
3 5 4 9
Q.61 If each hydrogen atom is excited by giving 8.4 eV of energy, then the number of spectral lines emitted is
equal to : (A) None (B) Two (C) Three (D) Four [A]
Q.62 Imagine an atom made up of a proton and a hypothetical particle of double the mass of electron but having the
same charge as the electron . Apply the Bohr atom model and consider all possible transitions of this
hypothetical to the first excited level. The longest wavelength photon that will be emitted has wavelength
(given in terms of the Rydberg constant RH for the hydrogen atom ) equal to :
9 36 18 4
(A) (B) (C) (D) [C]
5R H 5R H 5R H RH
Q.63 O2 undergoes photochemical dissociation into 1 normal oxygen atom and 1 oxygen atom 1.967 eV more
energetic than normal. The dissociation of O2 into 2 normal oxygen atoms is known to require 498 kJ/mol
O2. What is the maximum wavelength effective for the photochemical dissociation of O2 :
(A) 240 Å (B) 174 nm (C) 174 Å (D) 200 Å [B]
Q.64 In a measurement of the quantum efficiency of photosynthesis in green plants, it was found that 8 quanta of
red light at 6850 Å ware needed to evolve 1 molecule of O2. The average energy storage in the
photosynthetic process is 112 K cal/mol O2 evolved. What is the energy conversion efficiency in this
experiment : (A) 33.5 % (B) 66.5 % (C) 64.5 % (D) 15 % [A]
Q.65 Imagine an atom made up of a proton and a hypothetical particle of double the mass of electron but having
the same charge as the electron. Apply the Bohr atom model and consider all possible transitions of this
hypothetical to the first excited level. The longest wavelength photon that will be emitted has wavelength
(given in terms of the Rydberg constant RH for the hydrogen atom ) equal to :
9 36 18 4
(A) (B) (C) (D) [C]
5R H 5R H 5R H RH
Q.67 For a hydrogenic ion kinetic energy of electron in its 3rd excited state is found to be 54.4 eV. Then series
1
limit   for Balmer series, for this ion, is -

(A) 109678 × 16 cm–1 (B) 109678/16 cm–1 (C) 109678 × 4 cm–1 (D) 109678 × 64 cm–1[A]
Q.68 The radius of the 4th Bohr orbit is 0.864 nm. The de Broglie wavelength of the electron in that orbit is -
(A) 13.297 Å (B) 1.3565 nm (C) 1.3291 pm (D) 0.1329 nm [B]
Q.69 The ionization energy of per mole of hydrogen atom in terms of Rydberg constant (RH) is given by the
expression(A) RHhc (B)RHc (C) 2 RH hc (D) RH NA hc [D]
Q.70 Which of the following is not correct ?
(A) Lyman spectral series of hydrogen atom lies in the UV region of electromagneticv rediation.
(B) Balmer spectral series of hydrogen atom lies in the visible region of electro magnetic radiation.
(C) Paschen spectral series of hydrogen atom is in the visible region of electromagnetic radiation.
(D) Brackett spectral series of hydrogen atom lies in the infrared region of electromagnetic radiation.
[C]
Q.71 The energy of an electron in the Ist orbit of H-atom is— 13.6 eV. The possible energy values of the excited
2+
state for electrons in Bohr orbits of Li ions is/are-
(A) –3.4 eV (B) –30.6 eV (C) –13.6 eV (D) Both B & C are correct [D]
2+
Q.72 What is the wave length emitted during the transition of electron in between two levels of Li whose sum
–1
is 4 and difference is 2 ? Given RH = 109678 cm :
(A) 0.1096 cm–1 (B) 0.101 × 10–6 cm–1 (C) 1.14 × 10–6 cm–1 (D) 109 Å [C]
Q.73 Supposing the ionization energy of hydrogen atom is 640 eV. Point out the main shell having energy equal
to – 40 eV - (A) n = 2 (B) n = 3 (C) n = 4 (D) n = 5 [C]
Q.74 A 1-kW radio transmitter operates at a frequency of 880 Hz. How many photons per second does it emit -
(A) 1.71 x 1021 (B) 1.71 x 1033 (C) 6.02 x 1023 (D) 2.85 x 1026 [B]
Q.75 On Bohr’s stationary orbits -[C]
(A) Electrons do not move (B) Electrons move emitting radiations
(C) Energy of the electron remains constant (D) Angular momentum of the electron is h/2
Q.76 The value of Bohr radius of hydrogen atom is -
(A) 0.529x 10–7cm (B) 0.529x 10-8cm (C) 0.529x 10-9cm (D) 0.529x 10–10 cm [B]
Q.77 On the basis of Bohr’s model, the radius of the 3rd orbit is -
(A) Equal to the radius of first orbit (B)Three times the radius of first orbit
(C) Five times the radius of first orbit (D) Nine time the radius of first orbit [D]
Q.78 The correct expression derived for the energy of an electron in the nth energy level is - [D]

2 2 me 4 2 2 me 4 2 2 me 2 2 2 me 4
(A) En = (B) En = – (C) En = – 2 2 (D) En= –
n 2h 2 nh 2 n h n 2h 2
Q.79 Ionization energy for hydrogen atom in ergs, Joules and eV respectively is -
(A) 21.8 x 10–12 , 218 x 10–20 , 13.6 (B) 13.6 x 218 x 10–20, 21.8 x 10–13
–20 –13
(C) 21.8 x 10 , 13.6 , 21.8 x 10 (D) 21.8 x 10–13, 13.6, 21.8 x 10–20 [A]
Q.80 The velocity of an electron in the third orbit of hydrogen atom -
(A) 7.28 x107 cm sec–1 (B) 7.08 x 107 cm sec –1 (C)7.38 x 107cm sec–1(D) 7.48 x107cm sec–1 [A]
Q.81 The ionization energy of a hydrogen atom is 13.6eV. The energy of the third-lowest electronic level in
doubly ionized lithium (Z = 3) is -
(A) –28.7 eV (B) –54.4 eV (C) –122.4 eV (D) –13.6 Ev [D]
Q.82 The momentum of a photon with energy 20 eV is -
(A) 10.66 x 10–27 Kg m sec–1 (B) 10.55 x 10–27 Kg m sec–1
(C) 10.60 x 10–27 Kg m sec–1 (D) 10.80 x 10–27 Kg m sec–1 [A]
Q.83 For ionising an excited hydrogen atom, the energy required in eV will be -
(A) 3.4 or less (B) More than 13.6 (C) Little less than 13.6 (D) 13.6 [A]
Q.84 A gas absorbs a photon of 300 nm and then re-emitts two photons. One photon has a wavelength 600 nm.
The wavelength of second photon is -
(A) 300 nm (B) 400 nm (C) 500 nm (D) 600 nm [D]
Q.85 For H– atom, the energy required for the removal of electron from various sub-shells is given as under–
[C]
3s
3p 3d
E1 n=
0
E2
0
E3
0
The order of the energies would be –
(A) E1 > E2 > E3 (B) E3 > E2 > E1 (C) E1 = E2 = E3 (D) None of these
Q.86 The wave number of the first line of Balmer series of hydrogen is 15200 cm–1. The wave number of the
first Balmer line of Li2+ ion is- [D]
(A) 15200cm–1 (B) 60800 cm–1 (C) 76000 cm–1 (D) 136800 cm–1
Q.87 The wavelength of the third line of the Balmer series for a hydrogen atom is -
21 100 21R H 21R H
(A) (B) (C) (D) [B]
100R H 21 R H 100 100
Q.88 Wave number of a spectral line for a given transition is x cm–1 for He+ , then its value for Be3+ for the
same transition is - (A) 4x cm–1 (B) x cm–1 (C) x/4 cm–1 (D) 2x cm–1 [D]
Q.89 A photon was absorbed by a hydrogen atom in its ground state and the electron was promoted to the fifth
orbit. When the excited atom returned to its ground state, visible and other quanta were emitted. Other
quanta are -(A) 2  1 (B) 5  2 (C) 3  1 (D) 4  1 [A]
Q.90 Wave-length of the first line of Paschen Series hydrogen spectrum is - (R = 109700 cm–1) -
(A) 18750 (Å) (B) 2854 (Å) (C) 3452 (Å) (D) 6243 (Å) [A]
Q.91 What is the change in the orbit radius when the electron in the hydrogen atom (Bohr model) undergoes the
first Paschen transition - [C]
(A) 4.23 x 10–10 m (B) 0.35 x 10–10 m (C) 3.7 x 10–10 m (D) 1.587 x 10–10 m
Q.92 If the shortest wavelength of H atom in Lyman series is x, then longest wavelength in Balmer series of He +
36 x x 5x
is - (A) 9x (B) (C) (D) [A]
5 5 4 9
Q.93 Which of the following expressions represents the spectrum of Balmer series(If n is the principal quantum
number of higher energy level) -
R (n – 1)(n  1) R (n – 2)(n  2)
(A) v  2
cm 1 (B) v  2
cm 1
n 4n
R (n – 2)(n  2) R (n – 1)(n  1)
(C) v  2
cm 1 (D) v  2
cm 1 [B]
n 4n
Q.94 If the I.P. of Li+2 is 122.4 eV. Find out 6th I.P. of carbon - [A]
(A) 122.4 × 4eV (B) 122.4 × 2eV (C) 122.4 × 3eV (D) 122.4 × 5eV
Q.95 The energy difference between two electronic states is 46 .12 kcal /mole. What will be the frequency of the
light emitted when an electron drops from the higher to the lower energy state
(Planck' constant = 9.52 x 10-14 kcal sec mole -1)
(A) 4.84 x 10 15 cycles sec -1 (B) 4.84 x 10 -5 cycles sec-1
(C) 4.84x 10-12 cycles sec-1 (D) 4.84 x 10 14 cycles sec-1 [D]
Q.96 I.P. of hydrogen atom is equal to 13.6 eV. What is the energy required for the process :
He+ + energy — He+2 + e–
(A) 2 × 13.6 eV (B) 1 × 13.6 Ev (C) 4 × 13.6 eV (D) None of these [C]
Q.97 In an atom two electron move around the nucleus in circular orbits of radii R and 4R. The ratio of the time
taken by them to complete one revolution -
(A) 1 : 4 (B) 4 : 1 (C) 1 : 8 (D) 8 : 7 [C]
Q.98 Bohr’s model can explain -
(A)The spectrum of only hydrogen atom (B)The spectrum of the atoms of all the elements
(C)The spectrum of only sodium atom (D)The spectrum of atomic or ionic species having one electron.[D]
Q.99 The energy required to separate an electron from the level n = 3 of an atom is 9.69 × 10–19 Joules. What
will be its energy in first excited state -

9  9.69  10 –19 4
(A) – 9 × 9.69 × 10–19 J (B) – J (C) × 9.69 × 10–19 J (D) None of these [B]
4 9
Q.100 If ionisation energy of hydrogen atom is 13.6 eV. I.E. of Li+2 will be -
(A) 13.6 eV (B) 10.4 eV (C) 40.8 eV (D) 122.4 eV [D]
Q.101 The wavelength of third lyman series of hydrogen atom is approximately -
(A) 1 × 10–7 m (B) 1 × 10–8 m (C) 1 × 10–6 m (D) 1 × 10–5 m[A]
Q.102 The number of waves made by a Bohr electron in one complete revolution in its 3rd orbit -
(A) 1 (B) 2 (C) 3 (D) 4 [C]
Q.103 If potential energy of an electron in hydrogen atom is –x eV, then its kinetic energy will be -
(A) x eV (B) –x eV (C) 2x eV (D) x/2 eV [D]
Q.104 Energy of H–atom in the ground state is –13.6 eV , Hence energy in the second excited state is –
(A) –6.8 eV (B) –3.4 eV (C) –1.51 eV (D) –4.3 eV [C]
Q.105 In Bohr series of lines of hydrogen spectrum, third line from the red end corresponds to where one of the
following inter-orbit jumps of electron for Bohr orbits in an atom of hydrogen.
(A) 4  1 (B) 2  5 (C) 3  2 (D) 5  2 [B]
Q.106 The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to stationary
state 1, would be (Rydberg constant = 1.097×107 m–1)
(A) 91 nm (B) 192 nm (C) 406 nm (D) 9.1×10–8 nm [A]
Q.107 The ionization enthalpy of hydrogen atom is 1.312 × 106 J mol–1. The energy required to excite the
electron in the atom from n = 1 to n = 2 is
(A) 6.56 × 105 J mol–1 (B) 7.56 × 105 J mol–1 (C) 9.84 × 105 J mol–1 (D)8.51×105Jmol–1[C]
Q.108 What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition n = 4
to n = 2 in the He+ spectrum ?
(A) n= 4 to n = 1 (B) n = 3 to n = 2 (C) n = 3 to n = 1 (D) n = 2 to n= 1[D]
Q.109 The energy of an electron in the first Bohr orbit of H atom is –13.6 eV. The possible energy value (s) of
the excited state(s) for electrons in Bohr orbits of hydrogen is (are)
(A) –3.4 eV (B) –4.2 eV (C) –6.8 eV (D) +6.8 eV [A]
Q.110 The energy of the electron in the first orbit of He+ is – 871.6 x 10–20 J. The energy of the
electron in the first orbit of hydrogen would be –
(A) –871.6 x 10–20 J (B) –435.8 x 10–20 J (C) –217.9 x 10–20 J (D)–108.9x10–20J [C]
Q.111 The work function of a metal is 4.0 eV. If the metal is irradiated with radiation of wavelength 200nm, then
the maximum kinetic energy of the photoelectrons would be about – [B]
(A) 6.4 × 10–19 J (B) 3.5 × 10–19 J (C) 1.0 × 10–18 J (D) 2.0 × 10–19 J
Q.112 According to Bohr’s theory the energy required for the transition of H-atom from n = 6 to n = 8 state is –
[C]
(A) Equal to the energy required for the transition from n = 5 to n = 6 state
(B) Larger than in (A)
(C) Less than in (A)
(D) Equal to the energy required for the transition from n = 7 to n = 9 state.
 hcR 
Q.113 For a hydrogen atom, what is the orbital degeneracy of the level that has energy = , where R is the
9
Rydberg constant for the hydrogen atom ? (A) 1 (B) 9 (C) 36 (D) 3 [B]
Q.114 Energy of the electron in H-atom is 1.50 times as much as energy as the minimum required for its escape
(13.6 eV) from the atom. Calculate the wavelength of the emitted electron. [A]
(A) 4.71 Å (B) 4.17 Å (C) 5.47 Å (D) 5.74 Å
 R 
Q.115 What is the degeneracy of level of H-atom that has the energy   H  ? [C]
 9 
(A) 3 (B) 6 (C) 9 (D) 36
Q.116 Infrared lamps are used in restaurants and cafeterias to keep food warm. The infrared radiation is strongly
absorbed by water raising its temperature and that of the food in which it is incorporated. How many
photons per second of infrared radiation are produced by an infrared lamp that consumes energy at the rate
of 100 watt (100 J s–1) and is 12% efficient in converting this energy to infrared radiation ? Assume that the
radiation has a wavelength of 1500 nm. [A]
(A) 9.06 × 1019 Photons s–1 (B) 9.06 × 1016 Photons s–1
(C) 9.06 × 1014 Photons s–1 (D) 9.06 × 1021 Photons s–1
Q.117 -particles of 6 MeV energy is scattered back from a silver foil. Calculate the maximum volume in which
the entire charge of the atom is supposed to be concentrated ? [D]
[Z for silver = 47]
(A) 3.6 × 10–28 m3 (B) 5.97 × 10–42 m3 (C) 6.55 × 10–71 m3 (D) 48 × 10–42 m3
Q.118 From The Rutherford’s -particle scattering, it can be concluded that
 1 1 
(A) N sin4 (B) N  4
(C) N  4
(D) N = sin
2 sin  sin  / 2 2
When N = Number of -particle scattered by an angle . [C]
Q.119 The line spectrum of two elements is not identical because [C]
(A) They donot have same number of neutrons
(B) They have dissimilar mass numbers
(C) They have different energy level schemes
(D) They have different number of valence electrons.
Q.120 What transition in the hydrogen spectrum would have the same wavelength as the Balmer
transition n = 4 to n = 2 of He+ spectrum ? [D]
(A) n1 = 3; n2 = 2 (B) n1 = 4; n2 = 2
(C) n1 = 3; n2 = 4 (D) n1 = 1; n2 = 2