Part B-Positive List of Compositions For Metallic Materials
Part B-Positive List of Compositions For Metallic Materials
16th Revision
16 December 2021
France, Germany, the Netherlands, the United Kingdom and Denmark work together in the
framework of the 4MSI Common Approach as laid down in the Declaration of Intent (January
2011). This common approach aims for convergence of the respective national approval
schemes for materials and products in contact with drinking water.
The 4MSI have adopted Part A of this document as a common basis for implementing the
concept of accepting metallic compositions. The document is subject to revisions agreed by
the 4MSI.
Part B of this document includes a Positive List of metallic compositions accepted in all of the
Member States of the 4MSI following the procedure described in Part A.
Part C includes the procedure and methods for accepting metallic products or components.
The structure of this document (Part A, B, C) follows the different implementing acts as
described in the new article 11 paragraph 2 (a), (b), (c) of the European Drinking Water
Directive.
Further information may be obtained from any of the competent authorities of the 4MSI.
Bundesministerium für Gesundheit (Deutschland)
Ministère du Travail, de l’Emploi et de la Santé (France)
Ministerie van Infrastructuur en Milieu (Nederland)
Department for Environment, Food and Rural Affairs (United Kingdom)
The Danish Transport, Construction and Housing Authority and Ministry of Environment
(Denmark)
Denmark joined the 4MSI after the development of this common approach, and has therefore
not assessed the content of the approach.
Acceptance of Metallic Materials Used for Products in Contact with Drinking Water
16th revision 16 December 2021
C 1%
1. Components of products of
product group B (e.g. the spindle
of a pump or the moving parts in
water meter in building
installations). The sum of the
surfaces in contact with drinking
water of all these components has
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to be less than 10% of the total
wetted surface of the product.
2. Fittings, ancillaries in water mains
and water treatment works with
permanent flow (e.g. pumps bodies,
valves bodies used in water supply
systems)
D Components of fittings and ancillaries in
water mains in water treatment works
(C2)
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I Copper alloys
Copper-zinc alloys
Category
Constituents (% (m/m)):
Cu Zn
≥ 57.0% Remainder
Impurities (% (m/m)):
Al Fe Ni Pb Sn
≤ 0.1% ≤ 0.5% ≤ 0.2% ≤ 0.2% ≤ 0.5%
Each other impurity < 0.02%
Product
Notation
Group
5
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1.3.2
Product
Notation
Group
1.3.3
Product
Notation
Group
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1.3.4
Product
Notation
Group
1.3.5
Product
Notation
Group
1.3.6
Product
Notation
Group
7
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1.3.7
Product
Notation
groups
1.3.8
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2 Copper-zinc-aluminum alloys
2.1 Category
Constituents (% (m/m)):
Cu Zn Al
≥ 57.0% Remainder 0.1% - 0.3%
Impurities (% (m/m)):
Fe Pb Sn
≤ 0.3% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
Impurities (% (m/m))
Fe Pb Sn
≤ 0.3% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
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3 Copper-zinc-aluminum-tin alloys
3.1 Category
Constituents (% (m/m)):
Cu Zn Al Sn
≥ 62.0% Remainder 0.5% - 2.0% 0.3% - 1.0%
Impurities (% (m/m)):
Fe Mn Ni Pb Si
≤ 0.5% ≤ 0.1% ≤ 0.3% ≤ 0.2% ≤ 0.2%
Each other impurity < 0.02%
Impurities (% (m/m))
Fe Mn Ni Pb Si
≤ 0.10% ≤ 0.10% ≤ 0.10% ≤ 0.2% ≤ 0.2%
Each other impurity < 0.02%
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4 Copper-zinc-aluminum-silicon-iron alloys
4.1 Category
Constituents (% (m/m)):
Cu Zn Al Si Fe
≥ 62.0% Rem. 0.5% - 0.9% 0.5% - 0.9% 0.04% - 0.2%
Impurities (% (m/m)):
Ni Pb Sn
≤ 0.1% ≤ 0.2% ≤ 0.1%
Each other impurity < 0.02%
Impurities (% (m/m)):
Ni Pb Sn
0.05% - 0.09% 0.09% - 0.15% ≤ 0.1%
Each other impurity < 0.02 %
CuZn35AlSiFe B-D
Constituents (% (m/m))
Cu Zn Al Si Fe
62.5% - 64.5% Rem. 0.5% - 0.85% 0.5% - 0.8% 0.04% - 0.1%
Impurities (% (m/m))
Ni Pb Sn
≤ 0.09% ≤ 0.15% ≤ 0.1%
Each other impurity < 0.02 %
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5 Copper-zinc-arsenic alloys
5.1 Category
Constituents (% (m/m)):
Cu Zn As
≥ 61.0% Remainder 0.02% - 0.15%
Impurities (% (m/m)):
Al Fe Mn Ni Pb Sn
≤ 0.1% ≤ 0.5% ≤ 0.1% ≤ 0.3% ≤ 0.2% ≤ 0.5%
Each other impurity < 0.02%
Constituents (% (m/m)):
Cu Zn As
61.5% - 63.5% Remainder 0.02% - 0.15%
Impurities (% (m/m)):
Al Fe Mn Ni Pb Sn
≤ 0.05% ≤ 0.1% ≤ 0.1% ≤ 0.3% ≤ 0.2% ≤ 0.1%
Each other impurity < 0.02%
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5.3.2
Constituents (% (m/m)):
Cu Zn As
69.0% - 71.0% Remainder 0.02% - 0.06%
Impurities (% (m/m)):
Fe Mn Pb Sn
≤ 0.05% ≤ 0.1% ≤ 0.07% ≤ 0.05%
Each other impurity < 0.02%
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6 Copper-zinc-arsenic-aluminium alloys
6.1 Category
Constituents (% (m/m)):
Cu Zn As Al
≥ 61.0% Remainder 0.02% - 0.15% 0.2% - 1.0%
Impurities (% (m/m)):
Fe Mn Pb Sn
≤ 0.5% ≤ 0.1% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
Impurities (% (m/m)):
Fe Mn Pb Sn
≤ 0.3% ≤ 0.1% 0.15% - 0.25% ≤ 0.3%
Each other impurity < 0.02%
Constituents (% (m/m)):
Cu Zn As Al
63.0% - 64.5% Remainder 0.04% - 0.14% 0.2% - 0.7%
Impurities (% (m/m)):
Fe Mn Pb Sn
≤ 0.3% ≤ 0.1% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
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7 Copper-zinc-arsenic-antimony-aluminum alloys
7.1 Category
Constituents (% (m/m)):
Cu Zn As Sb Al
≥ 60.0% Remainder 0.02% - 0.10% 0.02% - 0.10% 0.02% - 1.0%
Impurities (% (m/m)):
Fe Mn Ni Pb Sn
≤ 0.5% ≤ 0.1% ≤ 0.2% ≤ 0.2% ≤ 0.5%
Each other impurity < 0.02%
Constituents (% (m/m))
Cu Zn As Sb Al
62.0% - 65.0% Remainder 0.02% - 0.04% 0.02% - 0.05% 0.45% - 0,7%
Impurities (% (m/m))
Fe Mn Ni Pb Sn
≤ 0.2% ≤ 0.1% ≤ 0.20% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
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8 Copper-zinc-lead alloys
8.1 Category
Constituents (% (m/m)):
Cu Zn Pb
≥ 57.0% Remainder 0.2% - 3.5%
Impurities (% (m/m)):
Al Fe Ni Si Sn
≤ 0.3% ≤ 0.5% ≤ 0.2% ≤ 0.2% ≤ 0.5%
Each other impurity < 0.02%
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8.3.2
Product
Notation
groups
CW614N* (CuZn39Pb3)
C and D
CW603N* (CuZn36Pb3)
* Contents of certain elements are further restricted (see below)
Constituents (% (m/m)):
Cu Zn Pb
57.0% - 62.0% Remainder 2.5% - 3.5%
Impurities (% (m/m)):
Al Fe Ni* Si Sn
≤ 0.05% ≤ 0.3% ≤ 0.2% ≤ 0.03% ≤ 0.3%
Each other impurity < 0.02%
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9 Copper-zinc-lead-aluminium alloys
9.1 Category
Constituents (% (m/m)):
Cu Zn Pb Al
≥ 57.0% Remainder 0.2% - 1.5% 0.2% - 1.0%
Impurities (% (m/m)):
Fe Mn Ni Si Sn
≤ 0.3% ≤ 0.05% ≤ 0.2% ≤ 0.05% ≤ 0.5%
Each other impurity < 0.02%
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10 Copper-zinc-lead-arsenic-aluminium alloys
10.1 Category
Constituents (% (m/m)):
Cu Zn Pb As Al
≥ 61.0% Remainder 0.2% - 2.2% 0.02% - 0.15% 0.02% - 1.0%
Impurities (% (m/m)):
Fe Mn Ni Sn
≤ 0.5% ≤ 0.1% ≤ 0.2% ≤ 0.5%
Each other impurity < 0.02%
Constituents (% (m/m)):
Cu Zn Pb As Al
62.0% - 64.0% Remainder 0.2% - 1.6% 0.04% - 0.14% 0.5% - 0.7%
Impurities (% (m/m)):
Fe Mn Ni Sn
≤ 0.3% ≤ 0.1% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
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10.3.2
Product
Notation
groups
CW626N (CuZn33Pb1.5AlAs) B-D
Constituents (% (m/m)):
Cu Zn Pb As Al
64.0% - 66.0% Remainder 1.2% - 1.7% 0.02% - 0.15% 0.8% - 1.0%
Impurities (% (m/m)):
Fe Mn Ni Sn
≤ 0.3% ≤ 0.1% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
Constituents (% (m/m)):
Cu Zn Pb As Al
62.0% - 64.0% Remainder 1.2% - 1.6% 0.02% - 0.15% 0.5% - 0.7%
Impurities (% (m/m)):
Fe Mn Ni Sn
≤ 0.3% ≤ 0.1% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
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11 Copper-zinc-lead-arsenic-antimony-aluminum alloys
11.1 Category
Constituents (% (m/m)):
Cu Zn Pb As Sb Al
≥ 60.0% Remainder 0.2% - 1.1 % 0.02% - 0.10% 0.02% - 0.10% 0.02% - 1.0%
Impurities (% (m/m)):
Fe Mn Ni Sn
≤ 0.5% ≤ 0.1% ≤ 0.2% ≤ 0.5%
Each other impurity < 0.02%
Constituents (% (m/m))
Cu Zn Pb As Sb Al
62.0% - 65.0% Remainder 0.2% - 1.1% 0.02% - 0.04% 0.03% - 0.06% 0.45% - 0.7%
Impurities (% (m/m))
Fe Mn Ni Sn
≤ 0.2% ≤ 0.1% ≤ 0.2% ≤ 0.3%
Each other impurity < 0.02%
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12 Copper-zinc-lead-arsenic-aluminium-silicon alloys
12.1 Category
Constituents (% (m/m)):
Cu Zn Pb As Al Si
≥ 61.0% Remainder 0.2% - 1.0% 0.02% - 0.10% 0.02% - 1.0% 0.02% - 0.5%
Impurities (% (m/m)):
Fe Mn Ni Sn
≤ 0.5% ≤ 0.1% ≤ 0.2% ≤ 0.5%
Each other impurity < 0.02%
Impurities (% (m/m)):
Fe Mn Ni Sn
≤ 0.3% ≤ 0.1% 0.15% - 0.25% ≤ 0.3%
Each other impurity < 0.02%
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13 Copper-tin-zinc-lead-nickel alloys
13.1 Category
Constituents (% (m/m)):
Cu Sn Zn Pb Ni
Remainder 4.0% - 13.0% 4.0% - 6.5% 0.2% - 3.0% 0.1% - 0.6%
Impurities (% (m/m)):
Fe P S Sb
≤ 0.30% ≤ 0.04% ≤ 0.04% ≤ 0.10%
Each other impurity < 0.02%
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14 Copper-tin-zinc-phosphorus-sulphur alloys
14.1 Category
Constituents (% (m/m)):
Cu Sn Zn P S
Remainder 3.0% - 9.0% 1.0% - 5.0% 0.01% - 1.0% 0.2% - 0.7%
Impurities (% (m/m)):
Fe Ni Pb Sb
≤ 0.3% ≤ 0.3% ≤ 0.2% ≤ 0.1%
Each other impurity < 0.02%
Constituents (% (m/m)):
Cu Sn Zn P S
90.0% - 96.0% 3.0% - 5.0% 1.0% - 3.0% 0.01% - 0.1% 0.2% - 0.6%
Impurities (% (m/m)):
Fe Ni Pb Sb
≤ 0.3% ≤ 0.3% ≤ 0.2% ≤ 0.1%
Each other impurity < 0.02%
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15 Copper-zinc-silicon-phosphorus alloys
15.1 Category
Constituents (% (m/m)):
Cu Zn Si P
60.0% - 80.0% Remainder 0.5% - 5.5% 0.01% - 0.3%
Impurities (% (m/m)):
Al Fe Mn Ni Pb Sn
≤ 0.1% ≤ 0.5% ≤ 0.05% ≤ 0.2% ≤ 0.1% ≤ 0.5%
Each other impurity < 0.02%
Constituents (% (m/m)):
Cu Zn Si P
75.0% - 77.0% Remainder 2.7% - 3.5% 0.02% - 0.10%
Impurities (% (m/m)):
Al Fe Mn Ni Pb Sn
≤ 0.05% ≤ 0.3% ≤ 0.05% ≤ 0.2% ≤ 0.1% ≤ 0.3%
Each other impurity < 0.02%
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15.3.2
Product
Notation
groups
Constituents (% (m/m)):
Cu Zn Si P
75.0% - 77.0% Remainder 2.7% - 3.5% 0.02% - 0.10%
Impurities (% (m/m)):
Al Fe Mn Ni Pb Sn
≤ 0.05% ≤ 0.3% ≤ 0.05% ≤ 0.2% ≤ 0.1% ≤ 0.3%
Each other impurity < 0.02%
The content of boron and zirconium has to be less than 0.02%.
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16 Copper-silicon-zinc-manganese-phosphorus alloys
16.1 Category
Constituents (% (m/m)):
Cu Si Zn Mn P
≥ 80.0% 0.5% - 5.5% Remainder 0.01% - 0.2% 0.01% - 0.3%
Impurities (% (m/m)):
Al Fe Ni Pb Sn
≤ 0.3% ≤ 0.5% ≤ 0.1% ≤ 0.1% ≤ 0.5%
Each other impurity < 0.02%
Impurities (% (m/m)):
Al Fe Ni Pb Sn
≤ 0.3% ≤ 0.3% 0.06% - 0.10% 0.06% - 0.10% ≤ 0.3%
Each other impurity < 0.02%
Constituents (% (m/m)):
Cu Si Zn Mn P
Remainder 2.5% - 4.5% 1.0% - 7.0% 0.03% - 0.09% 0.05% - 0.15%
Impurities (% (m/m)):
Al Fe Ni Pb Sn
≤ 0.3% ≤ 0.3% ≤ 0.10% ≤ 0.10% ≤ 0.3%
Each other impurity < 0.02%
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16.3.2
Product
Notation
groups
CC246E (CuSi4Zn9MnP-C) B-D
Constituents (% (m/m)):
Cu Si Zn Mn P
Remainder 2.5% - 4.5% 7.0% - 11.0% 0.03% - 0.09% 0.05% - 0.15%
Impurities (% (m/m)):
Al Fe Ni Pb Sn
≤ 0.3% ≤ 0.3% ≤ 0.10% ≤ 0.10% ≤ 0.3%
Each other impurity < 0.02%
16.3.3
Product
Notation
groups
CuSi4Zn4MnP B-D
Constituents (% (m/m)):
Cu Si Zn Mn P
Remainder 2.5% - 4.5% 1.0% - 7.0% 0.01% - 0.09% 0.05% - 0.15%
Impurities (% (m/m)):
Al Fe Ni Pb Sn
≤ 0.3% ≤ 0.3% ≤ 0.10% ≤ 0.10% ≤ 0.3%
Each other impurity < 0.02%
16.3.4
Product
Notation
groups
CuSi4Zn9MnP B-D
Constituents (% (m/m)):
Cu Si Zn Mn P
Remainder 2.5% - 4.5% 7.0% - 11.0% 0.01% - 0.09% 0.05% - 0.15%
Impurities (% (m/m)):
Al Fe Ni Pb Sn
≤ 0.3% ≤ 0.3% ≤ 0.10% ≤ 0.10% ≤ 0.3%
Each other impurity < 0.02%
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17 Copper-tin-phosphorus alloys
17.1 Category
Constituents (% (m/m)):
Cu Sn P
Remainder 1.5% - 9.0% 0.02% - 0.4%
Impurities (% (m/m)):
Fe Ni Zn
≤ 0.1% ≤ 0.2% ≤ 0.2%
Each other impurity < 0.02%
Constituents (% (m/m))
Cu Sn P
Remainder 7.5% - 8.5% 0.02% - 0.4%
Impurities (% (m/m))
Fe Ni Zn
≤ 0.1% ≤ 0.2% ≤ 0.2%
Each other impurity < 0.02%
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18 Copper-tin-lead-phosphorus alloys
18.1 Category
Constituents (% (m/m)):
Cu Sn Pb P
Remainder 9.0% - 13.0% 0.2% - 1.0% 0.01% - 1.0%
Impurities (% (m/m)):
Fe Mn Ni S Sb Zn
≤ 0.2% ≤ 0.2% ≤ 0.2% ≤ 0.05% ≤ 0.1% ≤ 0.5%
Each other impurity < 0.02%
Constituents (% (m/m)):
Cu Sn Pb P
88.0% - 90.0% 9.0% - 11.0% 0.2% - 1.0% 0.01% - 0.2%
Impurities (% (m/m)):
Fe Mn Ni* S Sb* Zn
≤ 0.2% ≤ 0.10% ≤ 0.2% ≤ 0.05% ≤ 0.1% ≤ 0.5%
Each other impurity < 0.02%
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19 Copper alloys for product group D
In addition to the compositions listed for the Product Groups A, B and C for components of the
Product Group D further copper alloys can be used.
The copper alloys have to comply with:
Cu, Zn, Si, Sn, P: no restrictions
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II Coppers
1 Copper
1.1 Category
Constituents (% (m/m)):
Cu P
≥ 99.9% ≤ 0.04%
Impurities (% (m/m)):
Others total
≤ 0.1%
Each impurity < 0.02%
Constituents (% (m/m)):
Cu P
≥ 99.9% 0.015% - 0.04%
1.3.2
Notation Product group
Constituents (% (m/m)):
Cu O*
≥ 99.90% ≤ 0.040%
* Oxygen has a technological function in the composition, it is not possible to specify a minimum
content
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1.3.3
Notation Product groups
Constituents (% (m/m)):
Cu
≥ 99.95%
1.3.4
Notation Product groups
Constituents (% (m/m)):
Cu P
≥ 99.95% 0.001% - 0.006%
1.3.5
Notation Product groups
Constituents (% (m/m)):
Cu P
≥ 99.95% 0.002% - 0.007%
1.3.6
Notation Product groups
Constituents (% (m/m)):
Cu P
≥ 99.90% 0.005% - 0.013%
Basis for acceptance
UBA opinion (15 May 2017)
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Restrictions for the use of metallic materials with respect to water composition (health
based)
The formation of the copper compounds on the surface of copper pipes and consequently
the dissolution is strongly influenced by minor components of the water composition. In some
water compositions, the rate of leaching of copper may be unacceptably high. Member
States may need to offer guidance to the water industry and to suppliers and installers of
copper pipe on restrictions that may need to be introduced on use of copper pipe in water
compositions where excessive leaching of copper might occur.
Further research into the compatibility of copper with certain compositions of water needs to
be carried out using harmonised procedures for investigation and evaluation.
Basis for acceptance
Research results and practical experience in several Member States are needed to
characterise the conditions for safe use.
Note
The contamination of drinking water by copper pipes depends on several characteristics of
water composition. There is no consensus view on their combined action and interaction at
this time. In particular, there is inadequate information on the range of compositions of
drinking water where non-compliance with the DWD is likely to occur.
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2 Tinned copper pipes and tinned copper fittings
For tinned copper tubes and tinned copper fittings as base composition copper according to
1 is used. On this substrate composition a tin layer is deposited by different processes. By
diffusion of copper ions into the tin layer the formation of an increasing intermetallic phase
consisting of tin and copper (-phase = Cu6Sn5) is formed.
2.1 Category
Constituents of the tin layer (% (m/m)):
Sn + Cu
≥ 99.90%
Impurities of the tin layer (% (m/m)):
As Bi Cd Cr Ni Pb Sb
≤ 0.01% ≤ 0.01% ≤ 0.01% ≤ 0.01% ≤ 0.01% ≤ 0.01% ≤ 0.01%
Each other impurity < 0.02%
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Guidance on restrictions for the use of metallic compositions with respect to water
composition
The following formula is proposed as a means identifying water compositions where
corrosion rates for galvanised steel is acceptable.
pH 7.5 or free CO2 0.25 mmol/L
AND Alkalinity 1.5 mmol/L
AND S1 < 2 (definition of S1 below)
AND Calcium 0.5 mmol/L
AND Conductivity 600 µS/cm at 25 °C
AND S2 <1 or S2>3 (definition of S2 below)
c(Cl- ) + 2 c(SO42- )
S2 = concentrations in mmol/l
c(NO3- )
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Basis for acceptance
There are regulations with respect to water composition in France (DTU 60.1 / NF P 40-201)
and in Germany (DIN 50930-3). These limits are based on practical experience but are
expressed in different ways. The proposal covers mainly the same water compositions as
both regulations. The proposal takes into account available results from research in Germany
and co-normative research.
The proposal incorporates also the recommendations given EN 12502-3 with regard to the
risk of localised corrosion. This localised corrosion frequently leads to deterioration in water
quality as a result of corrosion products of iron.
The proposal is based on results that have been obtained with galvanised steel pipes with
lead concentrations between 1.0% and 0.6% in the zinc layer, assuming a similar behaviour
of pipes with lower lead concentrations.
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2 Carbon steel
Carbon Steel for pipes and tanks
Carbon steel without permanent protective layers is not suitable for use in contact with
drinking water.
Carbon Steel for ancillaries
Unprotected carbon steel can be used for specific applications (e.g. pumps, valves) and only
for small surface in contact with water.
2.1 Category
Not defined
2.2 Reference Material
Not defined
2.3 Accepted Alloys
Product
Notation
groups
Carbon Steel
according to EN 10025 C2
/ EN 10213 / EN 10222
Constituents (% (m/m)):
Fe C Cr Mo Mn Ni
0.02% - 0.02% - 0.02% - 0.02% - 0.02% -
0.25% 0.30% 0.12% 1.65% 0.50%
Impurities (% (m/m)):
Al Cu Nb P S Si Ti V
≤ 0.05% ≤ 0.55% ≤ 0.05% ≤ 0.03% ≤ 0.03% ≤ 0.6% ≤ 0.05% ≤ 0.12%
Each other impurity < 0.02%
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3 Cast iron
Cast iron for pipes and tanks
Cast iron without permanent protective layers is not suitable for pipes and fittings in contact
with drinking water.
Cast iron for ancillaries
Unprotected cast iron can be used for specific applications (e.g. pumps, valves) and only for
very small surface in contact with water. Their composition needs to be regulated.
3.1 Category
Not defined
3.2 Reference Material
Not defined
3.3 Accepted Alloys
Product
Notation
groups
Cast Iron according to
C2
EN 1561 / EN 1563
Constituents (% (m/m)):
Fe C Cu Cr Mo Mn Ni Si
0.02% - 0.02% - 0.02% - 0.02% - 0.02% - 0.02% - 1.5% -
4.0% 1.0% 1.0% 1.0% 1.0% 1.0%1 3.5%
Impurities (% (m/m)):
As Mg P S Sn V
≤ 0.05% ≤ 0.1% ≤ 0.15% ≤ 0.1% ≤ 0.1% ≤ 0.1%
Each other impurity < 0.02%
1
For some special products (e.g. pumps for the backwash of filters, pumps which draw raw
water in river with possible high rates of suspended matters, pumps for lime milk), if it is
justified, this content can be higher (up to max. 6.0% (m/m)) in order to resist the abrasion or
for some steps of water treatment
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4 Stainless steel
Stainless steels according to EN 10088 and EN 10283 can be applied for all product groups
(A-D)
Restrictions:
Some stainless steels show a higher probability of occurrence of local corrosion (e.g. pitting or
crevice corrosion) caused by the contact with certain drinking waters or in case of disinfection
with high chlorine concentrations. For this purpose EN 16056 can be used to compare the
passivity behaviour of the different stainless steel grades.
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IV Platings
1 Tin plating applied by a galvanic process on the external surface
Components made of copper alloys (Chapter I) corresponding to the European Positive List
can be plated galvanically with a layer composition of copper and tin.
Restrictions:
Bulk composition of components to be tinned:
o Copper alloys corresponding to the European Positive List: I Copper alloys
Layer composition: 1.) Cu 2.) Sn
applied process: galvanic tin plating
Purity of the used anodes: ≥ 99.90 %
Additional requirement:
For the respective production process it has to be proven that the manufactured products are
not contaminated with organic substances used in the galvanic process baths. This can be
demonstrated by a migration test according to EN 12873-1. The evidence can be provided in
the course of an approval/certification process of respective plated products. In this process
a test of the metal release is not required. Additionally, a quality assurance scheme for the
production process is required. In UK additional product tests might be necessary.
Basis for acceptance
UBA opinion (12 Aug 2015)
Anses opinion (6 July 2018)
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V Passive compositions
Category
Not defined
Reference Material
Not defined
Accepted Alloys
3.1
Product
Notation
groups
NiCr7030 B-D
Constituents (% (m/m)):
Ni Cr Si
≥ 60.0% 29.0% - 32.0% 0.50% - 2.0%
Impurities (% (m/m)):
Al C Co Cu Fe Mn P S
≤ 0.30% ≤ 0.10% ≤ 1.5% ≤ 0.50% ≤ 5.0% ≤ 1.00% ≤ 0.020% ≤ 0.015%
Each other impurity < 0.02%
Constituents (% (m/m)):
Ni Ti
54.0% - 56.0% Remainder
Each impurity < 0.02%
3.3
Product
Notation
groups
Titanium Grade 1
according to ASTM B-D
B265
Constituents (% (m/m)):
Ti
Remainder
Impurities (% (m/m)):
C O N H Fe
≤ 0.08% ≤ 0.18% ≤ 0.03% ≤ 0.015% ≤ 0.20%
Each other impurity < 0.1%, Other impurity in total < 0.4%
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Acceptance of Metallic Materials Used for Products in Contact with Drinking Water
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3.4
Product
Notation
groups
Titanium Grade 2
according to ASTM B-D
B265
Constituents (% (m/m)):
Ti
Remainder
Impurities (% (m/m)):
C O N H Fe
≤ 0.08% ≤ 0.25% ≤ 0.03% ≤ 0.015% ≤ 0.30%
Each other impurity < 0.1%
Other impurity in total < 0.4%
3.5
Product
Notation
groups
Titanium Grade 3
according to ASTM B-D
B265
Constituents (% (m/m)):
Ti
Remainder
Impurities (% (m/m)):
C O N H Fe
≤ 0.08% ≤ 0.35% ≤ 0.05% ≤ 0.015% ≤ 0.30%
Each other impurity < 0.1%
Other impurity in total < 0.4%
3.6
Product
Notation
groups
Titanium Grade 4
according to ASTM B-D
B265
Constituents (% (m/m)):
Ti
Remainder
Impurities (% (m/m)):
C O N H Fe
≤ 0.08% ≤ 0.40% ≤ 0.05% ≤ 0.015% ≤ 0.50%
Each other impurity < 0.1%
Other impurity in total < 0.4%
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Acceptance of Metallic Materials Used for Products in Contact with Drinking Water
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3.7
Product
Notation
groups
Titanium Grade 5
according to ASTM B-D
B265
Constituents (% (m/m)):
Ti Al V
Remainder 5.5% - 6.75% 3.5% - 4.5%
Impurities (% (m/m)):
C O N H Fe
≤ 0.08% ≤ 0.20% ≤ 0.05% ≤ 0.015% ≤ 0.4%
Each other impurity < 0.1%
Other impurity in total < 0.4%
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