SULIT 4541/1 (PP) 4541/1 (PP) Chemistry Kertas 1 Peraturan Pemarkahan November 2021 MAKTAB RENDAH SAINS MARA PEPERIKSAAN AKHIR SIJIL PENDIDIKAN MRSM 2021 CHEMISTRY Kertas 1 Peraturan Pemarkahan a Untuk kegunaan pemeriksa sahaja Peraturan pemarkahan ini mengandungi 3 halaman bercetak [Lihat halaman sebelah 4541/1(PP) © Hak cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerTable of Specification SPMRSM 2021 No. Construct Topic Type Of Item Key 1 Remembering F4LA2 M. Choice D 2 Remembering F4LA3 M. Choice Cc 3 Remembering F4LA4___|M. Choice c 4 Remembering F4LAS5 M. Choice A 5 Remembering F4LA6 _|M. Choice D 6 Remembering F4LA6 | M. Choice B 7 Remembering F4LA7 M. Choice D 8 Remembering F4LA8 M. Choice A 9 Remembering FSLAQ M. Choice A 10 ‘Remembering F5LA9 | M. Choice D 11 Remembering FSLAI0 | M. Choice B 12 Remembering FSLAIO M. Choice A 13 Remembering FSLAI M. Choice D 14 Remembering FSLAI2 M. Choice A 15. Remembering FSLAI3 M. Choice B 16 Understanding F4LA2 _|M. Choice € 17 Understanding F4LA2 _ | M. Choice B 18 Understanding F4LA3 M. Choice A 19 Understanding F4LA4 M. Choice A 20 Understanding F4LA4 __[M, Choice B 21 Understanding F4LA5__| M. Choice Cc 22 Understanding F4LA6 __|M. Choice A 23 Understanding F4LA7___|M. Choice A 24 Understanding F4LAT __|M.Choice D 25 Understanding F4LA8 M. Choice B 26 ‘Understanding F5LA9__| M. Choice D oT Understanding F5LAI0 | M. Completion Cc 28 Understanding FSLAI | M. Choice c 29 Understanding FSLAI2 M. Choice D 30 Understanding F5LAI3__[M. Choice B 31 ‘Applying F4LA3__|M. Choice B 32 Applying F4LA5__|M. Choice Cc 33 Applying F4LA6 __|M. Choice é 34 ‘Applying F4LA7___|M. Choice B 35 ‘Applying F5LA9__|M. Choice D 36 ‘Applying F5LA9__| M. Completion A 37 Applying FSLAI M. Choice & 38 Applying F5LA10 | M. Choice B 39 Analyzing F4LA6 _ | M. Choice Cc 40 ‘Analyzing F5LA9 | M. Completion D 4541/1(PP) © Hak cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT 4541/2(PP) 4541/2 (PP) Chemistry Kertas 2 November 2021 MAKTAB RENDAH SAINS MARA Be PEPERIKSAAN AKHIR SIJIL PENDIDIKAN MRSM 2021 CHEMISTRY Kertas 2 Peraturan Pemarkahan Leen EEE Untuk Kegunaan Pemeriksa Sahaja —— Peraturan Pemarkahan ini mengandungi 21 halaman bercetak (Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSECTION A No. Mark Scheme Sub | Total Mark | Mark T]@] © | [Able to state the name of positively charged subatomic particle in the atom correctly] Answer: Proton [e: symbol] 1 (Gi) | [Able to state the number of neutrons found in the nucleus of carbon-12 atom correctly] Answer: 6 (iii) | [Able to state the difference between carbon-14 and carbon-12 correctly) 3n vS 6n Answer: Number of neutrons Nucleon ho (© | @ | (Able to write the standard representation of atom Z correctly] Answer: wz Be ay (i) | [Able to write the electron arrangement of Z ion correctly] Answer: 2 1 1 Total| 5 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScanner4541/2(PP) SULIT 4 Sub | Total No. Mark Scheme Mark | Mark 2 | @ [Able to name the component in substance A and B correctly] Answer: Clay // Kaolin Tanah liat (b) [Able to state two basic properties of A and B correctly] Sample answer: T temp One High thermel resistant // Breaks eastly // Chemically 1 Inert // Electrical insulator // Hard and strong // Heat 1 2 insulator 7 BALL, - Choose any two properties © [Able to state one difference for both A and B correctly] Sample answer: A B Traditional ceramic Advanced ceramic : 1 Contain Made by clay/kaolin | xi des/carbides/nitrides Lower resistant to heat | Higher resistant to heat compared to B compared to A Less chemically inert | More chemically inert No superconductivity |” Has superconductivity properties properties Choose any one comparison @ [Able to state another usage of substance A correctly] Sample answer: Cookware/ tiles 1 1 Accept any suitable answer Total| 5 Scanned with CamScannerSULIT Is LA 4541(PP) Mark Scheme Sub Mark Total Mark [Able to state the meaning of cosmetics\correctly] Answer: Cosmetics are materials or products that are used externally to cleanse, protect or enhance one’s appearances () [Able fo state one example of the harmful chemical in cosmetic that can cause redness and peeling skin correctly] Answer: Tretinoin © | @ hee it 15 died [Able fo give one example of traditional medicine can be used and describe briefly how it is used correctly] Sample answer: -turmen © PI. Aloe vera maa P2. (Apply) the gel/juice/liquid and rub onto affected skin // Rub the aloe vera gel/juice/liquid onto the affected skin Gi) [Able to explain the different of efficacy level between modern and traditional medicine correctly] Sample answer: P1. Traditional medicine may not undergo clinical trials // may not have data to authenticate the effectiveness 2. Hard to determine the correct dosage / amount OR Any correct statements about modern medicine Total [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahogian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT No. Mark Scheme [Able to state the colour of chlorine gas correctly} Answer: Greenish yellow Sub Mark 4541/2(PP) | Total | Mark Gi) [Able to write a chemical ‘equation for the reaction between chlorine gas and iron wool correctly] PI. Correct formulae of reactants and product P2. Balanced equation Answer: 2Fe + 3Ch — 2FeCls Gi [Able to calculate the mass of the product formed correctly] . af ad i) P1. Mole ratio P2. Mass of FeCls with correct unit Sample answer: Pl. 2 mole of Fe produces 2 mol of FeCls 0.1 mole of Fe produces 0.1 mol of FeCls P2. Mass of FeCls = 0.1 x [5643 x 35.5)] = 16.25g e) [Able to explain why bromine is less reactive than chlorine towards hot iron wool correctly] Sample answer: ze of bromine is bigger than chlorine U the ance between nucleus and the valence shell in bromine atom is further than chlorine atom P2, Forces of attraction between nucleus and valence electron is weaker in bromine atom than chlorine atom. // Nuclear attraction force is weaker in bromine atom than chlorine atom. P3. Harder for bromine atom to receive/attract electrons. Max 2 Total 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT ¢ 7 4541(PP) # Sub | Total No. 0. Mark Scheme Mark | Mark 5 |(@) |G) | TAble to state the meaning of hydrogen bond correctly] Answer: Attraction forces between hydrogen atom, H that has bonded with an atom of high electronegativity (such as F, O, N) with N, O or F atom in another 1 1 molecule, Gi) | [Able to state the name of the element in cellulose that can form hydrogen bond with water molecules correctly} Answer: Oxygen // 1 1 hydrogen in hydroxyl group/-OH ® [Able to state to explain why cotton clothes take longer time to dry compared to synthetic clothes correctly] Sample answer: P1. Cotton clothes absorb water more readily than synthetic fibre clothes 1 P2. Hydrogen bond will hold the water to cellulose in cotton 1 2 OR P1. Synthetic fibre clothes allow water to evaporate easily. 2, No formation of hydrogen bond [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Babagian Pendidikan Menengah MARA SULIT Scanned with CamScanner—hepain Po SULIT 4541/2(PP) rivyveleen ly > [Able to explain the difference of boiling point between ethanol and ethane correctly} Answer: P1. Ethanol has higher boiling point compared to ethane. P2. Hydrogen bonds formed between ethanol molecules P3. Require more heat to overcome the forces of attraction Vice versa Max — @ [Able fo draw the dative bond in the ammonium ion correctly] P1. Correct diagram with correct charge P2. Lone pair of electrons shared with H atom Answer: ra Total 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT 9 4541(PP) Sub Total No. Mark Scheme Mark | Mark © | @] @ | [Able to state the conditions for the effective collision to happen correctly] Answer: P1: Reactant molecules/particles collide in a correct orientation 1 P2: Achieved/overcome activation energy 1 2 (b) | (i) | [Able to write a chemical equation for the reaction between magnesium carbonate and hydrochloric cid correctly] P1. Correct formulae of reactants and products 1 P2, Balanced equation 1 2 Answer: MgCO; + 2HC1 MgCh + CO2 + H20 Gi) | [Able to explain which set of experiment used the highest concentration of hydrochloric acid correctly] Answer: PL. Set! 1 2, Has the steepest curve/gradient 1 a volume 64 Coz d_Con gat [Able to calculate the maximum yolunté of carbon dioxide gas released at room condition correctly] PI. Number of mole of HCI 1 P2. Mole ratio 1 P3. Volume of CO> with correct unit = @ Sample answer: P1: Number of mole of HCI: (0.5 x 50) / 1000 = 0.025 mol P2: 2 mol of HCI produce 1 mol of COz 0,025 mol of HCI produce 0.0125 mol of CO2 P3: Volume of CO2 = 0.0125 x 24 = 0.3 dm*/300 em? Total a [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT 10 4541/2(Pp) No. Mark Scheme Sub Mark Total Mark i [Abie fo state the meaning of redox reaction correctly] Answer: Chemical reaction where oxidation and reduction occur simultaneously/ at the same time &) | @ [Able to state the strongest reducing agent correctly] Answer: Mg // Magnesium (ii) [Able to calculate the oxidation number for chromium in Cr207* correctly] Answer: 2x +7(-2) +6 ©} @ [Able to state the observation in Beaker A after 30 minutes correctl D pa’ blue Answer: yi Yu becom? blue Ker Intanetiy of bus colour Hocreises PE Electrode becomes thicker. @) [Able to state and explain which electrode will undergo oxidation in terms of standard electrode potential correctly] Answer: PI. Sn/Tin P2, Standard electrode potential value for Sn/tin is ‘more negative/less positive than Cweopper // Standard electrode potential value for Cu/eopper is more positive/less negative than Sn/tin Note * P| — wrony P2- no-merk 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT i 4541@2P) Gi) | [Able fo write the cell notation for the voltaic cell in Diagram 7 and calculate the cell voltage correctly} Answer: PL. Sn(s) | Sn®*(aq) || Cu?*(aq) | Cu(s) 1 P2, Bean = E cathode E anode = (40.34)- (0.14) = +0.48 V 1 2 (@) | [Able to describe how to increase the cell voltage of the two half-cells based on answer in 7(c)(i correctly} Sample answer: P1. Replace Sn with Mg 1 P2. Replace tin({) nitrate solution with magnesium nitrate solution, 1 2 OR PI. Replace Cu with Ag P2, Replace copper(I!) nitrate solution with silver nitrate solution. Total 10 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA. SULIT Scanned with CamScannerSULIT 12 454120@p) Mark Scheme Sub Mark ‘Total | Mark [Able fo suggest metal Q correctly] Answer: Zn/Zine Gi) [Able to calculate the change in temperature correctly] P1. Number of mole of Pb?”Pb displaced P2. Ratio of the heat release P3, Temperature with correct unit Sample answer: PIL. Number of moles of Pb”*/Pb displaced MvV/1000 0.5 x 100/1000 =0.05 mol P2. 1 mol of Pb displaced releases 112000 J of heat 0.05 mol of Pb displaced releases 5600 J of heat HW Q=nx aH = 0.05 mol x 112000 J molt = 56003 P3. Heat given out = mc® 5600 J = (100)(4.2)() O=13.3°C ) |@ [Able to identify acid R and acid S correctly] Answer: R : Ethanoic acid // any weak acids $ : Hydrochloric acid // any strong acids Accept formula of acids 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengoh MARA SULIT Scanned with CamScannerSULIT 1B 4541(PP) (i _| [Able to write the thermochemical equation for the reaction bdtween acid R and potassium hydroxide solution correctly] py Cet Grom bis ) P1. Correct formulae of reactants and products P2, JH with correct value and unit ; 2 Answer: kou CH\COOH+Ne@HSCH:COOMA+H:0 AH =-55 kI mol! Penalty P2 if no equation/P1 given * J Giiy | [Able to explain the difference in heat of neutralisation for both reactions correctly] Sample answer: PL. Ethanoic acid/ acid R ionizes partially in water and some remain as molecules (to produce low concentration of H' ions) while hydrochloric | acid/ acid S ionized completely in water (to produce high concentration of H” ions) I! Bthanoic acid/ acid R is a weak acid while hydrochloric acid acid S is a strong acid P: 8 . Some of the heat released during neutralisation is absorbed by ethanoic acid/ acid R molecules and used to completely ionises the weak acid 1 2 Note: mention molecules at least once Total| 10 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA. SULIT Scanned with CamScannerSULIT 14 SECTION 4541/20@p) Mark Scheme Sub Mark Total | Mark [Able to suggest substances that can be used to prepare the salt correctly] Answer: PL, Lead({1) oxide // Lead(I1) carbonate P2. Nitric acid Lead [a: formula} [Able to write the chemical equation for the decomposition of the salt correctly} P3. Correct formulae of reactants and products P4, Balanced equation Answer: 2Pb(NOs)2 > 2PbO + 4NO2+ O2 ) {Able to state the name of green solid P and aqueous solution R correctly] Answer: P1. Green solid P = Copper(I1) carbonate P2. Aqueous solution R = Copper(Il) chloride r: formula [Able to describe briefly how to confirm the presence of anion in aqueous solution R correctly] Sample answer: P3, Add (dilute) nitric acid/ HNOs / sulphuric acid/H2SO« P4, Add silver nitrate/AgNOs sob PS. White precipitate produced r: HCI for P3 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA. SULIT Scanned with CamScannerSULIT 15 4541(PP) () {Able to name the chemical reaction to produce compound J correctly] Answer: PI. Precipitation // Double decomposition [Able to identify compound L and gas M correctly] Answer: P2, Compound L=Calcium chloride Mt CaChe 3, Gas M = Carbon dioxide // COz @ [Able to calculate the value of X correctly with the correct unit] P1, Number of mole of NaOH P2. Mass of NaOH with the correct unit Sample answer: P1: Mol NaOH =MV/1000 = (0.5 x 50)/ 1000 = 0,025 mol P2:Mass NaOH = = mol x molar mass = 0.025 x 40 =lg [Able to calculate the volume of distilled water needed to form 0.1 mol dm sodium hydroxide correctly] P3. Final volume of solution with correct unit 4, Volume of distilled water needed with correct unit Sample answer: P3. MiVi = MaV2 Vo.= (0.5)(50) / 0.1 = 250 cm? P4, Volume distilled water = 250-50 = 200 cm* [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Behagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT late the pH value of the diluted T [Able to calcul lane ion correctly] 1 sodium hydroxide soluti PS, Value of pOH P6. pH value of solution Sample answer: PS, pOH =- log [0.1] =1 P6. pH = 14-1 =L [Able t&gxplain why does diluted sodium hydroxide has different pH value than the standard solution correctly] Answer: P7. Concentration of hydroxide ion, OH in diluted 1 solution is lower than that in the standard solution. 8. The lower the concentration of OH ion, the 1 2 lower the pH value. Total 20 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT 17 4541(PP) Sub | Total No. Mark Scheme Mark | Mark 10 | (@) [Able to compare the observation for synthetic polymer A and synthetic polymer B correctly] Answer: Synthetic polymer A_| Synthetic polymer B Melt and solidify when | Disintegrate / burn upon they are cooled heating 141 {Able to explain the difference in the observation for synthetic polymer A and synthetic polymer B correctly] 4 Answer: Synthetic polymer A_| Synthetic polymer B Thermoplastic polymers | Thermosetting polymers i Can be repeatedly Cannot be remoulded 1 remoulded upon heating | after heating resi Can be recycled Cannot be recycled 1 5 ® [Able to state the meaning of polymer correctly] Answer; Pl, Long chain molecule that is made from a combination | 1 of many repeating units/ monomer. [Able to compare both polymerisation reaction correctly] Sample answer: Terylene Vinyl chloride Condensation polimerisation | Addition polymerisation | Made up from two different | Made up from same 1 monomers monomers 4 Monomers must have Monomers consist of atleast | jouble bond between C two functional groups atoms Produce polymer and simple ee Produce polymer only Choose any two comparisons for P2 & P3 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT 18 4541/2(0PP) [Able to suggest other polymer that ean be produced for each type of polymerisation correctly] Sample answer: P4. Example of condensation polymer: Nylon/ Cellulose// Starch PS, Example of addition polymer: Polycthene// Polypropene// Polystyrene © |@ [Able to suggest the name of suitable coagulant to speed up the coagulation of latex and able to describe briefly the process involved correctly] Sample answer: P1. Any named acid P2. Hydrogen ions, H* in acid neutralise the negatively charged protein membrane of the rubber particles. P3. The (neutral) rubber particles collide with one another and break the protein membrane, P4. The rubber polymers combine/clump with one another. Gi) [Able to suggest and justify the most suitable situation to be used for the delivery of the latex correctly] Sample answer: PL. Situation B P2. Anticoagulant contains hydroxide ions, OH P3. Hydroxide ions neutralise the hydrogen ions from lactic acid produced by the bacteria. P4, The protein membrane of rubber particles remains negatively-charged P5. Rubber particles repel one another P6, Latex remains in liquid form Note : accept any justification for P2 to P6 on rejection on Situation A Total 20 4541/2 (PP) © Hok Cipta Bahagien Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT 19 4541(@P) SECTION C Sub | Total No. Mark Scheme ‘mark | Meee Tl@ [Able to state the homologous series of hydrocarbon A correctly] Answer: PI. Alkane 1 [Able to draw and name two isomers of butane correctly] Answer: PQ. HH HH HH C-C-6-0-H Tra t 1 HHA H P3. 1 Pa, H-C-H i | HoG-C-C-H HHH PS. Tmethylpropane 1} os Gi | TAble to compare and contrast compound B and compound C correctly] Sample answer: Similarities: : Norrydrocatbon freanie compound ) 1 * Miscible in water Las ¢ pluble I * Low boiling point 2 Accept any two answers for P1 &P2 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA. SULIT Scanned with CamScannerMOM AAPP) 20 sULIT | Differences ound C Compound B . re Fase to {with base | Can rea aowcacion | produce stand water —— | //no reaction ___ Cannot react with Can react with metal/ metal metal/metal carbonate | Carhonate J/no reaction : = a Lower boiling point Higher boiling pot (compared to C) (compared to B) " pHneutral//pH=7 _| pH below 7 Purple colour of ‘No changes on purple acidified potassium colour of acidified i manganate(VI) potassium manganate(VI) solution tums colourless | solution 1 5 Functional group: Funetional group: -OH/hyticoxyl grpup | -COOH/carboxyl group viml ae Accept any three relevant answers for P3, P4 & PS b) [Able to describe the preparation of pentyl ethanoate by using named materials correctly] Answer: Guept P1, Pentan-1-ol : 2. Ethanoie acid fondonetd formla Note: P1 & P2 can be deduce from procedure r: pentanol Sample answer: Procedure: P3. Pour [2-4] cm? of glacial/pure ethanoic acid and [2-4] cm? of pure pentan-1-ol into boiling tube and mix well, 4, Add slowly/a few drops of concentrated sulphuric acid into the mixture. PS, Heat gently/warm the mixture, P6, Pour the mixture into a beaker containing water. OR 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScannerSULIT a 4541(@PP) [reflux method] : a P3. Pour [25-50] om? of glacial/pure ethanoie acid and [25-50] cm of pure pentan-1-ol into the round bottom flask P4. Add [3-5] om? of concentrate into the mixture. PS. Heat under reflux. oo P6. Collect the product formed by using distillation method. .d sulphuric acid 7. CH;COOH + CsHiOH > CHsCOOCsHu + 0 (©) [Able to choose the hand sanitiser and able to justify correctly] Sample answer: PL. Sanitiser M P2. Percentage of alcohol is higher P3. Can kill germs/bacteria better OR P1. Sanitiser N P2. Percentage of alcchol is lower P3. Less irritate the skin // less harm to skin OR PL. Sanitiser M P2, Percentage of alcchol in N is lower P3. Sanitiser N has less irritation on skin/ less harm to skin OR PI. Sanitiser N P2, Percentage of alcohol in M is higher P3. Sanitiser M can kill germs/bacteria better Total 20 END OF MARK SCHEME [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT Scanned with CamScanner