Structure of The Atom
Structure of The Atom
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Q.3. Is it possible for the atom of an element to have one electron, one proton and
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no neutron? If so, name the element.
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Ans. Yes, it is true for hydrogen atom which is represented as 11H.
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Q. 4. Electron attributes negative charge, protons attribute positive charge. An
atom has both but why there is no charge?
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Ans. The positive and negative charges of protons and electrons are equal in
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Q.5. Write the electronic configuration of an element whose atomic number is 12.
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Ans. K, L, M
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2, 8, 2
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Ans. The state of an atom where all the electrons in the atom are in their lowest energy
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Q. 13. In the atom of an element X, 6 electrons are present in the outermost shell.
If it acquires noble gas configuration by accepting requisite number of electrons,
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then what would be the charge on the ion so formed?
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Ans. - 2.
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Q. 14. Give two important applications of radioactive isotopes. so
Ans. (i) An isotope of carbon-12, C14, is used in carbon dating.
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Ans. Among the three isotopes of hydrogen, deuterium (21 H) is found in heavy water.
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Q. 16. Chemical formula of a metal sulphate is MSO4. What will be the formula of
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its chloride?
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Ans. MCl2
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Q. 17. An element 'A' has valency +3, while another element 'B' has valency -2.
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Give the formula of their compound formed when 'A’ reacts with ‘B'.
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Q. 19. Will 35Cl and 37 Cl have different valencies? Justify your answer.
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Q. 20. The atomic number of calcium and argon are 20 and 18 respectively, but
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the mass number of both these elements is 40. What is the name given to such a
pair of elements?
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Ans. Isobars
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Q. 1. How do you know that nucleus is very small as compared to the size of
atom?
Ans. Rutherford observed that when α-particles were bombarded on a very thin foil they
bounced back. But the number of a-particles bouncing back got doubled when he
doubled the thickness of gold foil. Then he concluded that the area of nucleus is very
small in comparison to the total area of the atom.
Q. 2. Write two characteristics of the canal rays.
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Ans. (i) The canal rays are deflected by the magnetic fields in a direction opposite to
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that of the cathode rays.
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(ii) They consist of positively charged particles.
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Q.3. Write the electronic configuration of a positively charged sodium ion (Na+).
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Atomic number of sodium is 11.
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Ans. Number of electrons in Na atom = Atomic number = 11
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Q.5. The atomic number of Al and Cl are 13 and 17, respectively. What will be the
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Ans. Helium has two electrons in its energy shell, while argon and neon have 8
electrons in their valence shells. As these have maximum number of electrons in their
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valence shells, they do not have any tendency to combine with other elements. Hence,
they have a valency equal to zero.
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Q.9. Helium atom has 2 electrons in its valence shell but its valency is not 2.
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Explain.
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Ans. Helium atom has 2 electrons in its valence shell and its duplet is complete. Hence,
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Q. 10. Find out the valency of the atoms represented by the Figs. (a) and (b)
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Q.11. Identify the Na+ ion from the following figures. What is the valency of
sodium atom? Give reason.
Ans. Figure number (ii) is correct because sodium ion (Na+) is formed when one
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electron is lost.
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Na → Na + + le−
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(2,8,1) (2,8)
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The valency of sodium atom is one because stable (octet) electronic configuration is
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obtained after loss of one electron. so
Q. 12. Calculate the number of neutrons present in the nucleus of an element X
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which is represented as 𝟑𝟏
𝟏𝟓𝐗.
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= 31 – 15 = 16
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Ans. Isotopes have same atomic numbers and thus same number of electrons.
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Therefore, they have the same electronic configuration which provides them similar
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chemical properties.
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Q. 15. An element "Z' forms the following compound when it reacts with
hydrogen, chlorine, oxygen and phosphorous.
ZH3, ZCl3, Z203, and ZP
(a) What is the valency of element ‘Z'?
(b) Element 'Z' is metal or non-metal?
Ans. (a) The valency of ‘Z' is 3.
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(b) Element ‘Z’ is a metal because it is electropositive and is reacting with non-metals.
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2. Electrons present throughout the atom. 2. Electrons revolve in orbits.
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3. No space is empty. 3. Most of the space is empty.
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Q.2. In the gold foil experiment of Geiger and Marsden, that paved the way for
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Rutherford's model of an atom, ~1.00% of the a-particles were found to deflect at
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angles > 50°. If one mole of a-particles were bombarded on the gold foil, compute
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the number of a-particles that would deflect at angles less than 50°.
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99
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= × 6.022 × 1023
100
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596.178
= × 1023
100
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= 5.96 x 1023
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Ans. (a) If ‘X’ contains 6 electrons in 'M' shell as valence electrons, then the electronic
configuration of ‘X’ is K = 2, L = 8, M = 6
∴ Atomic number = 16
(b) ‘X' is a non-metal.
Q. 5. The atomic number of lithium is 3. Its mass number is 7.
(a) How many protons and neutrons are present in a lithium atom?
(b) Draw the diagram of a lithium atom.
Ans. (a) Number of neutrons = Mass number - atomic number
Number of neutrons = 7 - 3 = 4
Number of protons = atomic number
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∴ Number of protons = 3
(b) Structure of a lithium atom
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Q 6. Complete the table on the basis of information available in the symbols given
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below
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𝟖𝟏
(a) 𝟑𝟓
𝟏𝟕𝐂𝐈 (b) 𝟏𝟐𝟔𝐂 (c) 𝟑𝟓𝐁𝐫
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Element np nn
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Ans.
Element np nn
Cl 17 18
C 6 6
Br 35 46
Q.7. In the atom of an element 'Z', 5 electrons are present in the outermost shell .
It requires noble gas configuration by accepting requisite number of electrons,
then what would be the charge on the ion so formed? Write the formula of the
compound which will be formed when 'Z' reacts with Na atom.
Ans. Number of electrons in the outermost shell = 5
Number of electrons required to make noble gas configuration = 8 – 5 = 3
The charge on the ion so formed = Z + 3e-
= Z3-
The valency of Z = 3
Chemical formula of the compound:
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Q. 8. 𝟐𝟐𝟐 Rn is an isotope of noble gas, radon. How many protons, neutrons and
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𝟖𝟔
electrons are there in one atom of this radon isotope?
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Ans. Atomic number of radon = 86 so
The number of protons = 86
The number of electrons = Number of protons
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= 86
Number of neutrons = Atomic mass - Atomic number
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= 222 - 86
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= 136
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Q. 9. What information do you get from the figures about the atomic number,
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mass number and valency of atoms X, Y and Z? Give your answer in a tabular
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form.
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Ans.
Atomic No. Mass No. Valency
X 5 11 3
Y 8 18 2
Z 15 31 3, 5
Q. 10. Write the molecular formulae for the following compounds:
(a) Copper (II) bromide (b) Aluminium (III) nitrate
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Q. 11. Write the molecular formulae of all the compounds that can be formed by
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the combination of following ions
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𝟑−
Cu2+, Na+, Fe3+, Cl-,𝐒𝐎𝟐−
𝟒 , 𝐏𝐎𝟒
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Ans. CuCl2; CuSO4; Cu3 (PO4)2
NaCl; Na2SO4; Na3PO4
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FeCl3; Fe2(SO4)3; FePO4
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Q. 12. Write the formula of the compounds formed by the following ions.
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Mg2+ S2-
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Valencies 2 2
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the valency.
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(ii) Elements Atomic no. Electronic configuration Valency
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Chlorine 17 2, 8,7 -1
Sulphu 16 2, 8, 6 -2
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Aluminium 13 2, 8, 3 +3
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Q. 2. What is the gold foil experiment? Name the scientist who performed this
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experiment. Write the conclusions and shortcomings of Rutherford's model of
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atom.
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Ans. In 1911, Rutherford performed the gold foil experiment. He bombarded a stream of
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a-particles on a gold foil, a thin sheet which was 0.00006 cm thick in an evacuated
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(i) Most of the a-particles passed straight through the foil without any deflection. This
concluded that most of the space inside of an atom is empty.
(ii) A few α-particles were deflected through small angle aid few through larger angles.
This happened due to positive charge on particles and core (nucleus) of the atom. The
heavy positively charged 'core' was named as nucleus.
(iii) The number of a-particles which bounced back was very small. This concluded that
the volume of the nucleus is very small in comparison to the total volume of the atom.
On the basis of gold foil experiment, Rutherford concluded that an atom consists of
nucleus which has positive charge and it is surrounded with electrons which are moving
around the nucleus. The number of electrons and protons are equal and the entire mass
of the atom is concentrated at its nucleus.
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Drawbacks in the Rutherford's model
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(i) According to classical electro-magnetic theory, a
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moving charged particle, such as an electron under the
influence of attractive force loses energy continuously
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in the form of radiations. As a result of this, electron
should lose energy and therefore, should move in even
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smaller orbits ultimately falling into the nucleus. But the
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collapse does not occur. There is no explanation for this
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behavior.
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(ii) Rutherford did not specify the number of orbits and the number of electrons in each
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orbit.
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Thomson's atomic
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model?
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Ans. Rutherford proposed a model in which electrons revolve around the nucleus in
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well-defined orbits. There is a positively charged centre in an atom called the nucleus.
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He also proposed that the size of the nucleus is very small as compared to the size of
the atom and nearly all the mass of an atom is centred in the nucleus. Whereas,
Thomson proposed the model of an atom to be similar to a christmas pudding. The
electrons are studded like currants in a positively charged sphere like christmas pudding
and the mass of the atom was supposed to be uniformly distributed.
Q.4. What are the postulates of Bohr's model of an atom?
Ans. The postulates put forth by Neils Bohr's about the model of an atom:
(a) Only certain special orbits known as discrete orbits of electrons, are allowed inside
the atoms.
(b) While revolving in discrete orbits the electrons do not radiate energy. These orbits
are called energy levels. Energy levels in an atom are shown by circles.
These orbits are represented by the letters K, L, M, N, .... or the numbers n = 1,2, 3, 4,
….
Q. 5. The ratio of the radii of hydrogen atom and its nucleus is ~105. Assuming the
atom and the nucleus to be spherical, (i) what will be the ratio of their sizes? (ii) If
atom is represented by planet Earth 'Re’ = 6.4 x 106 m. Estimate the size of the
nucleus.
4
πr3
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Ans. (i) Volume of the sphere =
3
Let R be the radius of the atom and r be that of the nucleus.
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⇒ R = 105r
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4 4
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Volume of the atom = 𝜋R3 = 𝜋(105 r)3 (∴ R
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3 3
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= 105r)
so
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= 𝜋r3 × 1015
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3
4
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4
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×1015 ×πr3
3
Ratio of the size of atom to that of nucleus = = 1015
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4
πr3
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3
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(ii) If the atom is represented by the planet Earth (Re = 6.4 x 106m), then the radius of
the
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nucleus would be
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𝑅𝑒
rn =
105
6.4×106 𝑚
rn = = 6.4 x 10 m
105
= 64 m.
Q.6. Show diagrammatically the electron distribution in a sodium atom and a
sodium ion and also give their atomic number.
Ans.
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Since the atomic number of
sodium atom is 11, it has 11 electrons. A positively charged sodium ion (Na+) is formed
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by the removal of one electron from a sodium atom. So, a sodium ion has 11-1 = 10
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electrons in it. Thus, electron distribution of sodium ion will be 2, 8. The atomic number
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of an element is equal to the number of protons in its atom. Since, sodium atom and
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sodium ion contain the same number of protons, therefore, the atomic number of both is
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11.
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Q. 7. The given figure depicts the atomic structure of an atom of an element 'X’.
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'X’.
(a) Atomic number of ‘X’
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= 8 + 10 = 18 u
(c) Valence electrons = 6
(d) Valency of 'X' = 8 – 6 = 2
(e) 'X' should be non-metal because there are six valence electrons hence it will take
two more electrons to complete its outermost shell.
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X Y
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Protons 8 8
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Neutrons 8 10
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Give the mass number of ‘X’ and ‘Y’ What is the relationship between the two
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species?
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Ans. (i) Atomic mass of elements ‘X’ = Number of protons + Number of neutrons
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= 8 + 8 = 16 u
(ii) Atomic mass of element ‘Y’ = Number of neutrons + Number of protons
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= 10 + 8 = 18 u
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Relationship between X and Y: The atomic number of the elements is same but their
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atomic masses are different. Hence, they are isotopes of each other.
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Q. 3. An atom ‘M’ of an element reacts wit oxygen to from M2O3. Calculate the
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3
∴ Number of oxygen atoms combining with one atom of element ‘M’ = 2
3
Therefore, the valency of element ‘M’ = 2 × 2 = 3
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Q. 5. Explain why chlorine whether as the element or its compounds, always has
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relative atomic mass of about 35.5.
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Ans. The relative atomic mass is the average mass of one of the atoms and has to take
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into account the relative abundances of the various isotopes.
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3 1
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Natural chlorine always contains about 4 × 35 C1 and 4 × 37 C1.
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17 17
3 1
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35.5 u
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Q. 6. An element ‘X’ has mass number 4 and atomic number 2. Write the valency
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Ans. We know that only valence electrons take part in bond formation with different
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atoms. In the atom of ‘X’ element there are only two electrons. Since atomic number is
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2. Thus, K shell is fully filled for this atom. Hence, its valency is zero. It will not other
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ideas.
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Answer the following questions based on the above information:
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(𝒊) Name the scientific values associated with above anecdotes.
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(𝒊𝒊) Give any example from your life experiences so far which reflects display of
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such a value by you as an individual.
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(𝒊𝒊𝒊) In what way such a personal attribute is likely to help you?
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Ans. (𝑖) Intellectual honesty, open-mindedness, ability to accept failure.
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(𝑖𝑖) Any examples, say your perception about culture and traditions, your wrong
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2. An old man and a scientist were talking about a deserted house. The old man
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was sure that it was haunted by ghosts, but the scientist discarded the view
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saying no one had ever seen a ghost. The old man was annoyed and challenged
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the scientist about existence of atoms, sub-atomic particles which also could not
be seen.
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