SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Ethanol
458600-25L
Version 1.5 Revision Date 21.07.2020

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name : Ethanol

SDS-number : 000000020236

Type of product : Mixture

Remarks : SDS according to Art. 31 of Regulation (EC) 1907/2006.

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the : Laboratory chemicals
Substance/Mixture

Uses advised against : none

1.3. Details of the supplier of the safety data sheet

Company : Honeywell Specialty Honeywell International, Inc.
Chemicals Seelze 115 Tabor Road
GmbH Morris Plains, NJ 07950-2546
Wunstorfer Straße 40 USA
30926 Seelze
Germany
Telephone : (49) 5137-999 0
Telefax : (49) 5137-999 123
For further information, : PMTEU Product Stewardship:
please contact: [email protected]

1.4. Emergency telephone number

Emergency telephone : +1-703-527-3887 (ChemTrec-Transport)

number +1-303-389-1414 (Medical)

Country based Poison : see chapter 15.1

Control Center

________________________________________________________________________________________________________________________
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

REGULATION (EC) No 1272/2008
Flammable liquids Category 2
H225 Highly flammable liquid and vapour.
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Eye irritation Category 2

H319 Causes serious eye irritation.
Specific target organ toxicity - single exposure Category 2
H371 May cause damage to organs.

2.2. Label elements

REGULATION (EC) No 1272/2008
Hazard pictograms :

Signal word : Danger

Hazard statements : H225 Highly flammable liquid and vapour.

H319 Causes serious eye irritation.
H371 May cause damage to organs.

Precautionary statements : P210 Keep away from heat, hot surfaces,

sparks, open flames and other ignition
sources. No smoking.
P243 Take precautionary measures against
static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/
vapours/ spray.
P280 Wear protective gloves/protective
clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact
lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical
advice/ attention.

Hazardous components : methanol

which must be listed on the
label

2.3. Other hazards

Vapours may form explosive mixtures with air.

SECTION 3: Composition/information on ingredients

3.1. Substance
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Version 1.5 Revision Date 21.07.2020

Not applicable

3.2. Mixture

CAS-No.
Index-No.
Classification
Chemical name REACH Registration Concentration Remarks
1272/2008
Number
EC-No.
methanol 67-56-1 Flam. Liq. 2; H225 >= 3 % - < 10 % 1*
603-001-00-X Acute Tox. 3; H331
01-2119433307-44 Acute Tox. 3; H311
200-659-6 Acute Tox. 3; H301
STOT SE 1; H370

ethanol; ethyl alcohol 64-17-5 Flam. Liq. 2; H225 >= 50 % - <= 100 1*
603-002-00-5 Eye Irrit. 2; H319 %
01-2119457610-43
200-578-6

1* - For specific concentration limits see Annexes of 1272/2008

Remaining components of this product are non-hazardous and/or are present at concentrations below
reportable limits.

Occupational Exposure Limit(s), if available, are listed in Section 8.

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice:
First aider needs to protect himself. Move out of dangerous area. Take off all contaminated clothing
immediately.

Inhalation:
Remove to fresh air. Call a physician immediately.

Skin contact:
After contact with skin, wash immediately with plenty of water. Call a physician if irritation develops or
persists.

Eye contact:
Rinse thoroughly with plenty of water, also under the eyelids. Protect unharmed eye. Call a physician
immediately.

Ingestion:

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Ethanol
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Version 1.5 Revision Date 21.07.2020

When swallowed, allow water to be drunk. Never give anything by mouth to an unconscious person.
Call a physician immediately.

4.2. Most important symptoms and effects, both acute and delayed

No data available

4.3. Indication of any immediate medical attention and special treatment needed

No data available

See Section 11 for more detailed information on health effects and symptoms. :

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media:

Water spray
Carbon dioxide (CO2)
Dry powder
Alcohol-resistant foam

Extinguishing media which shall not be used for safety reasons:

High volume water jet

5.2. Special hazards arising from the substance or mixture

Heating will cause pressure rise with risk of bursting and subsequent explosion
Burns with colourless flame.

5.3. Advice for firefighters

Wear self-contained breathing apparatus and protective suit.

Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation. Remove all sources of ignition. Keep people away from and upwind of
spill/leak.

6.2. Environmental precautions

Prevent further leakage or spillage if safe to do so. The product evaporates readily.
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6.3. Methods and materials for containment and cleaning up

Soak up with inert absorbent material.

Pick for disposal in tightly closed containers

6.4. Reference to other sections

For personal protection see section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling:
Exhaust ventilation at the object is necessary. Keep limited supplies at workplace.

Advice on protection against fire and explosion:

The product is easily combustible. Take measures to prevent the build up of electrostatic charge. Use
explosion-proof equipment. Vapours may form explosive mixtures with air.

Hygiene measures:
Keep working clothes separately. Ensure adequate ventilation, especially in confined areas.

7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions:

Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Do not
leave vessels/containers open Avoid product residues in/on containers.

Advice on common storage:

Do not store together with: Oxidizing agents

7.3. Specific end use(s)

no additional data available

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Ethanol
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Version 1.5 Revision Date 21.07.2020

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits:

Basis / Value / Exceeding

Components Remarks
Value type Form of exposure Factor

ethanol; ethyl alcohol EH40 WEL 1.920 mg/m3

TWA 1.000 ppm

methanol EH40 WEL 333 mg/m3

STEL 250 ppm

methanol EH40 WEL 266 mg/m3

TWA 200 ppm

methanol EH40 WEL Can be absorbed

SKIN_DES through the skin.
methanol EU ELV Can be absorbed
SKIN_DES through the skin.
methanol EU ELV 260 mg/m3 Indicative
TWA 200 ppm

TWA - Time weighted average

STEL - Short term exposure limit
SKIN_DES - Skin designation:

DNEL/ PNEC-Values
End-
Component Exposure duration Value Exposure routes Remarks
use/impact
ethanol; ethyl alcohol Workers / 1900 Inhalation
Acute local mg/m3
effects

ethanol; ethyl alcohol Workers / 343mg/kg Skin contact

Long-term bw/d
systemic
effects

ethanol; ethyl alcohol Workers / 950 mg/m3 Inhalation

Long-term
systemic
effects

ethanol; ethyl alcohol Consumers / 114 mg/m3 Inhalation

Long-term
systemic
effects

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Ethanol
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Version 1.5 Revision Date 21.07.2020

ethanol; ethyl alcohol Consumers / 950 mg/m3 Inhalation

Acute local
effects

ethanol; ethyl alcohol Consumers / 206mg/kg Skin contact

Long-term bw/d
systemic
effects

ethanol; ethyl alcohol Consumers / 87mg/kg Ingestion

Long-term bw/d
systemic
effects

methanol Consumers / 4mg/kg Skin contact

Acute bw/d
systemic
effects

methanol Workers / 20mg/kg Skin contact

Acute bw/d
systemic
effects

methanol Consumers / 4mg/kg Skin contact

Long-term bw/d
systemic
effects

methanol Workers / 20mg/kg Skin contact

Long-term bw/d
systemic
effects

methanol Consumers / 26 mg/m3 Inhalation

Acute local
effects

methanol Workers / 130 mg/m3 Inhalation

Acute local
effects

methanol Consumers / 26 mg/m3 Inhalation

Acute
systemic
effects

methanol Workers / 130 mg/m3 Inhalation

Acute
systemic
effects

methanol Consumers / 26 mg/m3 Inhalation

Long-term
local effects

methanol Workers / 130 mg/m3 Inhalation

Long-term
local effects
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Ethanol
458600-25L
Version 1.5 Revision Date 21.07.2020

methanol Consumers / 26 mg/m3 Inhalation

Long-term
systemic
effects

methanol Workers / 130 mg/m3 Inhalation

Long-term
systemic
effects

Environmental compartment /
Component Remarks
Value

ethanol; ethyl alcohol Fresh water: 0,96 mg/l

ethanol; ethyl alcohol Marine water: 0,79 mg/l

ethanol; ethyl alcohol Fresh water sediment: 3,6 mg/kg

ethanol; ethyl alcohol Soil: 0,63 mg/kg

methanol Sewage treatment plant: 100 mg/l

Assessment factor:
methanol Fresh water: 20,8 mg/l
10

Assessment factor:
methanol Marine water: 2,08 mg/l
100

methanol Fresh water sediment: 77 mg/kg

methanol Marine sediment: 7,7 mg/kg

Assessment factor:
methanol Soil: 100 mg/kg
100

8.2. Exposure controls

Occupational exposure controls

Do not breathe vapours/dust.

Take off all contaminated clothing immediately.
Recommended preventive skin protection
The Personal Protective Equipment must be in accordance with EN standards:respirator EN 136, 140,
149; safety glasses EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2; gloves EN 374, 511;
safety shoes EN-ISO 20345.

Personal protective equipment

Respiratory protection:
In the case of vapour formation use a respirator with an approved filter.

Hand protection:
Glove material: butyl-rubber
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Ethanol
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Break through time: > 480 min

Glove thickness: 0,7 mm
Butoject® 898
Gloves must be inspected prior to use.
Replace when worn.
Remarks:Supplementary note: The specifications are based on information and tests from similar
substances by analogy.
Due to varying conditions ( e.g.temperature or other strains) it must be considered that the usage of a
chemical protective glove in practice may be much shorter than the permeation time determined in
accordance with EN 374.
Since actual conditions of practical use often deviate from standardised conditions according EN 374
the glove manufacturer reccomends to use the chemical protective glove in practice not longer than
50% of the recomended permeation time.
Manufacturer´s directions for use should be observed because of great diversity of types .
Suitable gloves tested according EN 374 are supplied e.g. from KCL GmbH, D-36124 Eichenzell,
[email protected]

Eye protection:
Safety goggles

Skin and body protection:

Flame retardant antistatic protective clothing.
Working clothes must not consist of textiles, which show a dangerous melting behaviour in case of fire.

Environmental exposure controls

Handle in accordance with local environmental regulations and good industrial practices.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form : liquid

Colour : colourless

Odour : characteristic

molecular weight : 46 g/mol

Melting point/range : -144 °C

Boiling point/boiling range : 78 - 80 °C

Flash point : 14 °C
Method: closed cup

Auto-ignition temperature : 363 °C

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Ethanol
458600-25L
Version 1.5 Revision Date 21.07.2020

Lower explosion limit : 3,3 %(V)

Upper explosion limit : 19 %(V)

Vapour pressure : 59,5 hPa

at 20 °C

Density : ca. 0,78 g/cm3

Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

pH : Not applicable

Water solubility : completely soluble

Solubility in other solvents : Soluble in most organic solvents

Partition coefficient: n- : No data available

octanol/water

Relative vapour density : No data available

Evaporation rate : No data available

9.2 Other Information

no additional data available

SECTION 10: Stability and reactivity

10.1. Reactivity

Stable under normal conditions.

10.2. Chemical stability

At normal pressure may be distilled without decomposition.

Fire or intense heat may cause violent rupture of packages.

10.3. Possibility of hazardous reactions

None known.

10.4. Conditions to avoid

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Ethanol
458600-25L
Version 1.5 Revision Date 21.07.2020

Heat, flames and sparks.

Keep away from direct sunlight.

10.5. Incompatible materials

Reactions with alkali metals.

Evolution of inflammable gases/vapours easily.
Uncleaned empty vessels may contain product gases which can form explosive mixtures with air.
Explosive reactions with oxidising agents such as potassium chlorate and/or peroxides.

10.6. Hazardous decomposition products

None known.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute oral toxicity:
LD50
Species: Rat
Value: 10.470 mg/kg
Method: OECD Test Guideline 401
Information refers to the main component.

Acute dermal toxicity:

No data available

Acute inhalation toxicity:

LC50
Species: Rat
Value: 124,7 mg/l
Exposure time: 4 h
Method: OECD Test Guideline 403
Information refers to the main component.

Skin irritation:
Species: Rabbit
Result: No skin irritation
Method: OECD Test Guideline 404
Information refers to the main component.

Eye irritation:
Species: Rabbit
Result: Moderate eye irritation
Method: OECD Test Guideline 405
Information refers to the main component.

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Ethanol
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Respiratory or skin sensitisation:

Route of exposure: Skin contact
Species: Guinea pig
Result: Did not cause sensitisation on laboratory animals.
Method: OECD Test Guideline 406
Information refers to the main component.

Repeated dose toxicity:

Species: Rat, male
Application Route: Oral
Exposure time: 90 d
LOAEL: 3.156 mg/kg
Method: OECD 408
Note: Information refers to the main component.

Germ cell mutagenicity:

Test Method: Ames test
Result: negative
Method: OECD Test Guideline 471
Note: Information refers to the main component.

Test Method: In vitro gene mutation study in mammalian cells

Result: negative
Method: OECD Test Guideline 476
Note: Information refers to the main component.

Test Method: Chromosome aberration test

Method: OECD Test Guideline 478
Result: equivocal
Note: Information refers to the main component.

Reproductive toxicity:
Species: Rat
Developmental Toxicity: NOAEL: 5.200 mg/kg bw/d
Remarks: Information refers to the main component.

Aspiration hazard:
No data available

Other information:
Solvent removes skin oil from the skin.
Solvent vapours have a narcotic effect if inhaled in high concentrations.
Poisoning affects the central nervous system.

SECTION 12: Ecological information

12.1. Toxicity
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Toxicity to fish:
LC50
Species: Pimephales promelas (fathead minnow)
Value: 14.200 mg/l
Exposure time: 96 h
Information refers to the main component.
NOEC
semi-static test
Species: Danio rerio (zebra fish)
Value: 250 mg/l
Exposure time: 120 h
Method: OECD Test Guideline 212
Information refers to the main component.

Toxicity to aquatic plants:

EC50
Growth rate
Species: Chlorella vulgaris (Fresh water algae)
Value: 275 mg/l
Exposure time: 3 d
Method: OECD Test Guideline 201
Information refers to the main component.

EC50
Growth rate
Species: Chlorella vulgaris (Fresh water algae)
Value: 675 mg/l
Exposure time: 4 d
Method: OECD Test Guideline 201
Information refers to the main component.

EC50
Biomass
Species: Lemna gibba (gibbous duckweed)
Value: 5.967 mg/l
Exposure time: 7 d
Information refers to the main component.

NOEC
Biomass
Species: Lemna gibba (gibbous duckweed)
Value: 5.967 mg/l
Exposure time: 7 d
Information refers to the main component.

Toxicity to aquatic invertebrates:

LC50
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static test
Species: Ceriodaphnia dubia (water flea)
Value: 5.012 mg/l
Exposure time: 48 h
Information refers to the main component.

Chronic toxicity to aquatic invertebrates:

NOEC
semi-static test
Species: Ceriodaphnia dubia (water flea)
Value: 9,6 mg/l
Exposure time: 10 d
Information refers to the main component.

Chronic toxicity to aquatic invertebrates:

LC50
Reproduction Test
semi-static test
Species: Ceriodaphnia dubia (water flea)
Value: 1.806 mg/l
Exposure time: 10 d
Information refers to the main component.

Chronic toxicity to aquatic invertebrates:

NOEC
semi-static test
Species: Daphnia magna (Water flea)
Value: 9,6 mg/l
Exposure time: 9 d
Information refers to the main component.

Chronic toxicity to aquatic invertebrates:

LC50
Reproduction Test
semi-static test
Species: Daphnia magna (Water flea)
Value: 454 mg/l
Exposure time: 9 d
Information refers to the main component.

12.2. Persistence and degradability

Biodegradability:
aerobic
Biodegradation: 95 %
Exposure time: 15 d
Result: Readily biodegradable.
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Ethanol
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Information refers to the main component.

12.3. Bioaccumulative potential

No data available

12.4. Mobility in soil

No data available

12.5. Results of PBT and vPvB assessment

This substance is not considered to be very persistent and very bioaccumulating (vPvB).
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).

Remarks : Information refers to the main component.

12.6. Other adverse effects

No data available
SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product:
Dispose according to legal requirements.

Packaging:
Legal requirements are to be considered in regard of reuse or disposal of used packaging materials

Further information:
Provisions relating to waste:
EC Directive 2006/12/EC; 2008/98/EEC
Regulation No. 1013/2006

For personal protection see section 8.

SECTION 14: Transport information

ADR/RID
UN Number : 1987
Description of the goods : ALCOHOLS, N.O.S.
(ETHANOL, METHANOL)
Class : 3
Packaging group : II
Classification Code : F1
Hazard Identification : 33
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Ethanol
458600-25L
Version 1.5 Revision Date 21.07.2020

Number
ADR/RID-Labels : 3
Environmentally hazardous : no
Special Provision 640D

IATA
UN Number : 1987
Description of the goods : Alcohols, n.o.s.
(Ethanol, Methanol)
Class : 3
Packaging group : II
Hazard Labels : 3

IMDG
UN Number : 1987
Description of the goods : ALCOHOLS, N.O.S.
(ETHANOL, METHANOL)
Class : 3
Packaging group : II
Hazard Labels : 3
EmS Number : F-E, S-D
Marine pollutant : no

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture

Basis Value Remarks

Directive 2012/18/EC Amount 1: 5.000.000 kg
Listed in Regulation : P5c: FLAMMABLE Amount 2: 50.000.000 kg
LIQUIDS
Number in Regulation: 1.2.5.3

Basis Value Remarks

Regulation (EC) No. 1907/2006, Annex This product contains an ingredient
XVII according to Annex XVII of the
REACH Regulation1907/2006/EC.

Poison Control Center

Country Phone Number Country Phone Number

Austria +4314064343 Liechtenstein +41 442515151

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Belgium 070 245245 Lithuania +370532362052

Bulgaria (+)35929154233 Luxembourg 070245245; (+352)80002-5500

Croatia (+3851)23-48-342 Malta +356 2395 2000

Cyprus +357 2240 5611 Netherlands 030-2748888

Czech Republic +420224919293; +420224915402 Norway 22591300

Denmark 82121212 Poland +48 42 25 38 400

Estonia 16662; (+372)6269390 Portugal 808250143

Finland 9471977 Romania +40 21 318 3606

France +33(0)145425959 Slovakia (NTIC) +421 2 54 774 166

Greece +30 210 779 3777 Slovenia +386 1 400 6051

Hungary (+36-80)201-199 Spain +34915620420

112 (begär
Iceland 5432222 Sweden Giftinformation);+46104566786

Ireland +353(1)8092166 Switzerland 145

Italy 0382 24444 United Kingdom (+44) 844 892 0111

Berlin : 030/19240

Bonn : 0228/19240

Erfurt : 0361/730730

Freiburg : 0761/19240
Germany
Göttingen : 0551/19240

Homburg : 06841/19240

Mainz : 06131/19240

Munich : 089/19240
Latvia +37167042473

Other inventory information

US. Toxic Substances Control Act
On TSCA Inventory

Australia. Industrial Chemical (Notification and Assessment) Act

On the inventory, or in compliance with the inventory

Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL)
All components of this product are on the Canadian DSL

Japan. Kashin-Hou Law List

On the inventory, or in compliance with the inventory

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Ethanol
458600-25L
Version 1.5 Revision Date 21.07.2020

Korea. Toxic Chemical Control Law (TCCL) List

On the inventory, or in compliance with the inventory

Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act
On the inventory, or in compliance with the inventory

China. Inventory of Existing Chemical Substances (IECSC)

On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand

On the inventory, or in compliance with the inventory

15.2 Chemical safety assessment

A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

Text of H-statements referred to under heading 3

Methanol : H225 Highly flammable liquid and vapour.
H331 Toxic if inhaled.
H311 Toxic in contact with skin.
H301 Toxic if swallowed.
H370 Causes damage to organs.

Ethanol : H225 Highly flammable liquid and vapour.

H319 Causes serious eye irritation.

Further information
All directives and regulations refer to amended versions.
Vertical lines in the left hand margin indicate a relevant amendment from the previous version.

Abbreviations:
EC European Community
CAS Chemical Abstracts Service
DNEL Derived no effect level
PNEC Predicted no effect level
vPvB Very persistent and very biaccumulative substance
PBT Persistent, bioaccmulative und toxic substance

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
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Version 1.5 Revision Date 21.07.2020

material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. Final determination of suitability of any
material is the sole responsibility of the user.
This information should not constitute a guarantee for any specific product properties.

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