Introduction To Chemical Engineering CH 7
Introduction To Chemical Engineering CH 7
Gases are more compressible than liquids because the distance between the gas molecules is
much greater than the distance between molecules in a liquid.
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
The pressure at the bottom of a stagnant fluid is greater than at the top of the fluid. The
higher pressure at the bottom is due to the weight of the fluid above it.
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
a. Since mass is conserved and the density and area are constant, the average outlet velocity
out must be equal to the average inlet velocity. In equation form:
b. The pressure will drop as the fluid flows through the pipe due to friction losses.
c. The potential energy of the liquid increases as it is pumped up a hill. The numerical
value of the shaft work term (ws) will be positive. The pump performs work on the fluid
in order to increase the energy of the fluid.
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
The first drawback is that the pressure available at the bottom of the tank is a function of the
height of the fluid in the tank. Because the height is expected to vary with time, the resulting
flow rate would also vary with time.
The second drawback is that the pressure at the bottom of the tank may not be high enough to
provide the NaOH at the desired flow rate.
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
Neither the dishwasher nor the clothes washer require extremely high pressures. Therefore,
either type of pump is capable of supplying the desired pressure. The centrifugal pump has
the additional advantage of running safely even when the outlet line is completely plugged.
A centrifugal pump is the recommended type of pump (and is the type of pump typically
used).
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
The rupture disc provides a safety feature by which the pressure downstream of the pump
will not exceed a specified threshold pressure. Furthermore, when the threshold pressure is
reached, the rupture disc and enclosure ensure that a rupture will occur within the safe
enclosure rather than somewhere else where people or the environment may be adversely
affected.
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
a. Because the pressure-measuring device reads the atmospheric pressure as zero, all
pressures are read as gauge pressures, so
peak pressure:
mm Hg: P = 80 mm Hg (gauge)
1 atm
atm: P = 80 mm Hg = 0.11 atm
760 mm Hg
b. The absolute pressures will be the gauge pressure plus the atmospheric pressure, so
peak pressure:
The relationship for the gauge pressure of a stagnant liquid is: P = ρgh
Writing this equation twice, once for a depth of 8 ft and once for a depth of 48 ft:
Taking a ratio of these two equations and recognizing that the density of the water is the
same at both depths and that the acceleration due to gravity is also the same at both depths,
P48 ft ρ g(48 ft )
= =6
P8 ft ρ g(8 ft)
Solving for P48 ft,
P48 ft = 6 P8 ft = 6(3.5 psi) = 21 psi
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
Pressure = pg (absolute)
1 Gas
L1 Liquid 1 Density = !1
2
L2 Liquid 2 Density = !2
3
P2 – pg = ρ1gL1 (3)
and
P3 – P2 = ρ2gL2 (4)
Equation 7.8a is
⎛P 1 αv 2
⎞ ⎛P 1 αv 2
⎞
⎜ + avg + gz⎟ - ⎜ + avg + gz⎟ = w s - w f
⎝ρ 2
⎠2 ⎝ρ 2
⎠1
a. Converting to Btu/lbm:
P lb f in ⎛ 1 Btu ⎞ ⎛ 144 in 2 ⎞
2
⎜ Btu
: ⎜ ⎟ ⎟ ⇒
ρ lbm ft3 ⎝ 778.1 ft lb f ⎠ ⎝ ft 2 ⎠ lbm
⎛ ft ⎞ ⎛⎜ 1 s lb f ⎞ ⎛⎜ 1 Btu ⎞⎟
2 2
2 Btu
2 αv avg ⎟ ⇒
1
: ⎝ ⎠
s ⎝ 32.174 lb m ft ⎠ ⎝ 778.1 ft lb f ⎠ lb m
b. Converting to J/kg:
P N m2 ⎛ 1 J ⎞ J
: ⎜ ⎟ ⇒
ρ kg m 3 ⎝1 N m ⎠ kg
1 αv 2 ⎛ m ⎞2 ⎛ 1 N ⎞ ⎛ 1 J ⎞ J
avg : ⎜ ⎟ ⎜ ⎟⎜ ⎟ ⇒
2 ⎝ s ⎠ ⎝ 1 kg m s2 ⎠ ⎝ 1 N m ⎠ kg
⎛ 9.80 m ⎞ ⎛ 1N ⎞⎛ 1J ⎞ J
gz : ⎜ 2 ⎟ ( m) ⎜ 2⎟⎜ ⎟ ⇒
⎝ s ⎠ ⎝1 kg m s ⎠ ⎝ 1 N m ⎠ kg
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
tube
1
h
2
P2 - P1
ρ
+ 1
2 (α 2v 2,2 avg - α1v1,avg
2
) + g(z2 - z1) = 0
We now make the following substitutions:
α = 1 (which you are instructed to assume in this class unless told otherwise)
P2 − P1
P1 = P2 = Patm, so =0
ρ
v1,avg = 0
1 2
2 v 2,avg - gh = 0
v 2,avg = 2gh
101325 Pa
= 860 mm Hg = 114660 Pa
760 mm Hg
b. From Equation 7.9b (where friction and shaft work are considered negligible),
P2 - P1
ρ
+ 1
2 (α 2v 2,2 avg - α1v1,avg
2
) + g(z2 - z1) = 0
Assuming α1 = α2 ≈ 1, neglecting height changes, and rearranging
1
P2 = P1 − ρ v 2,avg
2
2
( 2
− v1,avg )
⎡ 2⎤
m ⎞⎟ ⎥⎛ 1Pa ⎞
⎛ 2
1⎜ kg ⎞⎟⎢⎛⎜ m ⎞⎟ ⎛⎜
= 114660Pa − 1060 ⎟⎢⎜ 4.50 ⎟ − ⎜0.50 ⎟ ⎥⎜ ⎟
2 ⎜⎝ s ⎠ ⎥⎦⎝1kg /m s2 ⎠
m 3 ⎠⎢⎣⎝ s⎠ ⎝
760 mm Hg
c. P2 = (104060 Pa −101325 Pa) = 20.5 mm Hg
101325 Pa
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
Homework Problem 7.7: Once again, we start with Equation 7.9b (since we are neglecting
friction and there are no moving parts).
P2 - P1
ρ
+ 1
2 (α 2v 2,2 avg - α1v1,avg
2
) + g(z2 - z1) = 0
Not only will we set the values of α to 1.0, but we also recognize that, for a horizontal
Venturi meter, z2 – z1 = 0. Therefore
P2 - P1
ρ
(
+ 12 v 2,2 avg -v 1,avg
2
)= 0
or
(2
P1 - P2 = 12 ρ v 2,avg
2
-v1,avg ) (1)
Finally, if Equation 1 or 3 is used with the units of density being lbm /ft3 and velocity being
ft/s, the units of the pressure difference will be
lbm ⎛ ft ⎞
2
lb
3 ⎜ ⎟ ⇒ m2
ft ⎝ s ⎠ ft s
To convert that result to psi (which is lbf /in2), the following strategy is needed
lbm ⎛⎜ 1 lb f s
2 ⎞ ⎛ 1 ft ⎞ 2 lb f
Pressure conversion: ⎟⎜ ⎟ ⇒
ft s2 ⎜⎝ 32.174 lbm ft ⎟⎠ ⎝12 in ⎠ in 2
The spreadsheet on the next page uses Equation(s) 2 to calculate velocities and then uses
Equation 1 to compute ∆P. It also uses the conversions described above to express the flow
rate in units of ft3/s and the pressure difference in units of psi. As shown by the lines drawn
on the graph, a pressure difference of 2.75 psi corresponds to a flow rate of approximately 72
gal/min.
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
120
100
Vol.
80
Flow (gal/ 60
min)
40
20
0
0.00
1.00
2.00
3.00
4.00
5.00
6.00
Pressure Change (psi)
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
b) For the vertical orientation with the outlet at the top, z2 –z1 =L, so
P2 − P1
+ gL = −w f
ρ
P2 –P1 =ρ(-wf –gL)
c) For the vertical orientation with the outlet at the bottom, z2 –z1 =-L, so
P2 − P1
− gL = −w f
ρ
P2 –P1 =ρ(-wf +gL)
P1 = P2 = Patm (since both the inlet and outlet steam jets are in the open atmosphere)
1
2 (v 2o -v i2 ) = ws
b. For the given values,
⎡ m⎞ ⎤⎛ 1 J ⎞
1 ⎢⎛126 m ⎞
2
⎛ 2
J
ws = 2 ⎜ ⎟ − ⎜ 317 ⎟ ⎥ ⎜ ⎟ = - 42,300
⎢⎣⎝ s⎠ ⎝ s ⎠ ⎥⎦ ⎝1 kg m s ⎠
2 kg
This number is negative, because ws is the amount of work done by the environment on
the fluid, but in this case, the fluid is doing work on its environment. Therefore, we want
the negative of ws, or
Homework Problem 7.10: Again, the first step is to select reference locations. In this case, we
select reference location #1 at the top of the water in the reservoir and location #2 at the inlet
to the treatment pipe.
⎛ ⎛ 1 s2 lb ⎞⎛ ⎞
ft ⎞ 1 hp hp s
g(z2 − z1 ) = ⎜ 32.174 2 ⎟(−2800 ft)⎜⎜ ⎟⎜
f
⎜ ⎟⎟ = −5.1
⎝ s ⎠ ⎟
⎝ 32.174 lbm ft ⎠⎝ 550 ft lb f s ⎠ lbm
Thus
ws = 1.9 - 5.1 + 4.9 = 1.7 hp s/lbm
But from Equation 7.11 (as suggested by the hint in the problem)
Power = ρV˙w s
Inserting the appropriate values
⎛ lb ⎞ ⎛ gal ⎞ ⎛⎜ 1 ft 3 ⎞⎟ ⎛⎜ hp s ⎞⎟
Power = ⎜ 62.4 m3 ⎟ ⎝ 63.5 1.7 = 900 hp
⎝ ft ⎠ s ⎠ ⎝ 7.48 gal ⎠ ⎝ lb m ⎠
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
Pressure
Patm
Location
The gradual decrease in pressure depicted for the horizontal sections of pipe is due to
friction. For the case where friction is neglected, the pressure would not change for those
horizontal sections. The steeper fall and rise is due to the change in height. The very
sharp rise in pressure, of course, is due to the pump.
b. As depicted on the drawing in part a., the lowest pressure will be at the top of the hill.
c. For this calculation, the most convenient locations are at the inlet to the system and at the
top of the hill, as depicted in the drawing above. This is because we want the pump to be
within the region we calculate (so we can find the amount of work) and we want to use
the information about the lowest pressure being equal to the vapor pressure (the lowest
pressure is at the top of the hill).
Once again, the governing equation is
P2 - P1
ρ
+ 1
2 (α 2v 2,2 avg - α1v1,avg
2
) + g(z2 - z1) = ws − w f
For this problem, the simplifications are
P1 = 0 (gauge)
α1 = α2 = 1.0 (our usual assumption)
v1 = v2 (because the pipe diameter is the same at both locations)
wf = 0 (we are told to neglect friction)
Thus, the equation becomes
P2
+ g(z2 - z1 ) = ws
ρ
Chapter 7 – Answer Key, Introduction to Chemical Engineering: Tools for Today and Tomorrow
Because we are working with gauge pressure, we need to convert the value of P2 into
gauge pressure, preferably psig.
Converting to psig (using the fact that 1 atm = 760 mm Hg = 14.7 psi)
14.7 psi
P2, gauge = −743 mm Hg (gauge) = − 14.4 psig
760 mm Hg
We also recognize that
z2 – z1 = 2500 ft
So,
P2
ws = + g(z2 - z1 )
ρ
−14.4 lb f in 2 ⎛ 32.2 lbm ft ⎞⎛ 12 in ⎞
2
⎛ ft ⎞ ft 2
= ⎜ ⎟⎜ ⎟ + ⎜ 32.174 ⎟(2500 ft) = 79400
62.4 lbm ft 3 ⎜⎝ s2 lb f ⎟⎠⎝ ft ⎠ ⎝ s2 ⎠ s2
or, in units of W,
But we want the power to operate the pump, which from Equation 7.12, is
Power delivered to the pump 70.5 kW
Power to operate the pump = = = 90.4 kW
Efficiency .78