Home Work #2 - Thermodynamics - LIVE Short Duration

REVISION Course on NEETprep LIVE App

Contact Number: 9667591930 / 8527521718
1.
Determine enthalpy of formation for  H , using 4.
The standard heat of combustion of propane is –2220.1

2 O2 (l)

following enthalpies of reaction :

kJ mol–1. The standard heat of vaporisation of liquid
water is 44.0 kJ mol–1. What is enthalpy change of the
0
N H (l)+2H O (l)→ N (g)+4H O(l);   △ H
2 4 2 2 2 2 = −818
1

 kJ/mol
reaction of–

C3H8 (g) + 5O2 (g) → 3CO2 (g) + 4H2O(g)

0
N H (l)+O (g)→ N (g)+2H O(l);   △ H
2 4 2 2 2 = −622
2

 kJ/mol
1. – 2220.1 kJ

= −285 kJ /mol
2. – 2044.1 kJ

0
1
H (g)+ / O (g)→ H O(l);   △ H
2 2 2 2 3

1. -383 kJ/mol
3. – 2396.1 kJ

2. -187 kJ/mol
4. – 2176.1 kJ

3. -49 kJ/mol

4. None of the above

5.
Consider the following reaction,

S + O2 → SO2,  ΔH = – 298.2 kJ mole–1

2.
From the following bond energies : 
SO2 + 1/2 O2 →  SO3, ΔH = – 98.7kJ mole–1

H—H bond energy: 431.37 kJ mol-1 

C=C bond energy: 606.10 kJ mol-1 

SO3 + H2O → H2SO4 , ΔH = – 130.2 kJ mole–1

C—C bond energy: 336.49 kJ mol-1 

H2 + 1/2 O2 → H2O, ΔH = – 287.3 kJ mole–1

C—H bond energy: 410.50 kJ mol-1  the enthalpy of formation of H2SO4 at 298 K will be–

  1. – 814.4 kJ mole–1     

Enthalpy for the reaction, 

2. + 814.4 kJ mole–1

3. – 650.3 kJ mole–1     

4. – 433.7 kJ mole–1

6.
The standard enthalpy of combustion at  25 C   of
∘

  hydrogen, cyclohexene (C6H10), and cyclohexane

  (C6H12) are -241, -3800 and -3920 kJ mol-1, respectively.
will be
Calculate the standard enthalpy of hydrogenation of
 
cyclohexene.

1. 1523.6 kJ mol-1
1. -131 kJ mol-1

2. -243.6 kJ mol-1
2. -155 kJ mol-1

3. -120.0 kJ mol-1
3. -167 kJ mol-1

4. 553.0 kJ mol-1
4. -121 kJ mol-1

7.
ΔH   (298K) of methanol is given by the chemical
0

equation -

1. C(diamond)+ O +2H2→CH3OH

1
2
2
3.
Given that the bond energy of H—H and Cl-Cl is 430
2. CH4+ O →CH3OH

kJ mol-1 and 240 kJ mol-1 respectively and ΔHf for HCl is

2
2

3. CO+2H2→CH3OH

-90 kJ mol-1. Bond enthalpy of HCl is :

4. C(graphite)+ O +2H2→CH3OH

1
2
1. 290 kJ  mol
−1 2

2. 380 kJ  mol
−1

8.
When 4 g of iron is burnt to ferric oxide at constant
3. 425 kJ  mol
−1

pressure, 29.28 kJ of heat is evolved.

4. 245 kJ  mol

−1

The enthalpy of formation of ferric oxide will be -

(At. mass of Fe = 56) ?

1. −81.98 kJ

2. − 819.8 kJ

3. − 40.99 kJ

4.  +819.8 kJ

Page: 1
 Home Work #2 - Thermodynamics - LIVE Short Duration
REVISION Course on NEETprep LIVE App
Contact Number: 9667591930 / 8527521718
9.
Which of the following is not an endothermic reaction?
15.
Enthalpy of formation of 

1. Combustion of methane
CO ,   CO
(g)
,  N O  ,  and  N O
2(g)
 are

2 (g) 2 4(g)

2. Decomposition of water
–110 kJ  mol , – 393 kJ mol , 81 kJ  mol and 9.7 kJ 
−1 −1 −1,

3. Dehydrogenation of ethane or ethylene

mol respectively.

−1

4. Conversion of graphite to diamond

The value of Δ H for the reaction would be-

N O + 3 CO → N O + 3 CO

2 4(g) (g) 2 (g) 2(g)

10.
The enthalpy of combustion of methane, graphite, and −1

dihydrogen at 298 K are,

1.   − 777. 7  kJ   mol

–890.3 kJ mol-1  , –393.5 kJ mol-1,  and –285.8 kJ mol- 2.    + 777. 7  kJ   mol

−1

1 respectively.
3.    + 824. 9  kJ   mol
−1

The enthalpy of formation of CH4(g) is-

4.   −  345. 4  kJ   mol
−1

-1
1.  –74.8 kJ mol

16.
 
2.  –52.27 kJ mol-1

N   +  3 H   →  2 NH   Δ H   =   − 92. 4  kJ   mol

∘ −1

3.  +74.8 kJ mol-1

2 2 3 ; r

The standard enthalpy of formation of  NH   gas in the 3

4.  +52.26 kJ mol-1

above reaction would be-

1.   − 92. 4  J  mol

−1

11.
Enthalpy of combustion of carbon to CO2 is –393.5 kJ −1
2.    − 46. 2  kJ   mol

mol-1. The amount of heat released upon formation of 3.    +  46. 2 J  mol
−1

35.2 g of CO2 from carbon and dioxygen gas would be-

−1
4.   +  92. 4  kJ   mol
1. -393.5 kJ mol-1

2. -314.8 kJ mol-1
17.
The standard enthalpy of formation of CH3 OH(l)

3. +314.8 kJ mol-1
 from the following data is -

4. -320.5 kJ mol-1

3
CH3 OH ( l ) +   O2 (g)
  →  CO2 (g)
  +  2H2 O ( l ) ;
2

  Δr H°  =   − 726  kJ   mol

−1

12.
Assertion:  Combustion of all organic compounds is
C(s)  +  O2   →  CO2  ;  
an exothermic reaction.
(g) (g)

Reason:  The enthalpies of all elements in their standard Δc H°  =   − 393  kJ   mol
−1

state are zero.

1
H2   +   O2   →  H2 O ( l )  ;  
1.  Both assertion and reason are true and the reason is the (g)
2
(g)

correct explanation of assertion.

∘
Δf H   =   − 286  kJ   mol
−1

2.  Both assertion and reason are true and the reason is not 1.   − 239  kJ   mol
−1

the correct explanation of assertion.

−1
2.   +  239  kJ   mol
3.  Assertion is true but the reason is false.

−1
4.  Assertion is false but the reason is true.

3.   − 47  kJ   mol

4.   + 47  kJ   mol
−1

13.
The enthalpies of elements in their standard states are

taken as zero. The enthalpy of formation of a compound is 18.

-
−1
Δvap H° (CCl4 )  =  30. 5  kJ   mol

1. Generally negative

2. Always positive
Δf H° (CCl4 )  =   −  135. 5  kJ   mol
−1

3. Zero

4. Never negative
−1
Δa H° (C)  =  715. 0  kJ   mol

14.
Enthalpy of sublimation of a substance is equal to -
−1
Δa H° (Cl2 ) =  242  kJ   mol
1. Enthalpy of fusion + Enthalpy of vaporisation

2. Enthalpy of fusion
The enthalpy change for the reaction

3. Enthalpy of vaporisation
 CCl  (g)  →  C(g)  +  4 Cl  (g) would be -

4.  Twice the enthalpy of vaporisation

1.  326  kJ   mol
−1

−1
2.  1304  kJ   mol

−1
3.   − 328  kJ   mol

−1
4.   − 1304  kJ   mol

Page: 2
 Home Work #2 - Thermodynamics - LIVE Short Duration
REVISION Course on NEETprep LIVE App
Contact Number: 9667591930 / 8527521718
19.
At standard conditions, if the change in the enthalpy

for the following reaction is -109 kJ mol-1

H2(g)+Br2(g) →2HBr(g)

Given that bond energy of H2 and Br2 is 435 kJ mol-1 and

192 kJ mol-1, respectively, what is the bond energy (in kJ
mol-1) of HBr?

1. 368

2. 736

3. 518

4. 259

20.
Assertion: Combustion is an exothermic process.

Reason: Combustion is a spontaneous process.

1. Both Assertion & Reason are true and the reason is the
correct explanation of the assertion.

2. Both Assertion & Reason are true but the reason is not
the correct explanation of the assertion.

3. Assertion is true statement but Reason is false.

4. Both Assertion and Reason are false Statements. 

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