Certi icate

of Analysis Certi ied

Reference
Metals in Soil
Material
Description
Product ID SQC001-30G
Lot LRAC6625
Expiration Date April 2024
Manufacturing Date April 2020
Storage Conditions ROOM TEMPERATURE
Solvent/Matrix LOAMY CLAY

Certi ied Values

1,4
Certi ied
Analyte Units
Value

Aluminum, Al mg/Kg 11450 ± 619

An mony, Sb mg/Kg 42.0 ± 4.1
Arsenic, As mg/Kg 43.1 ± 0.7
Barium, Ba mg/Kg 597 ± 9
Beryllium, Be mg/Kg 117 ± 2
Boron, B mg/Kg 230 ± 6
Cadmium, Cd mg/Kg 118 ± 2
Calcium, Ca mg/Kg 4272 ± 66
Chromium, Cr (total) mg/Kg 299 ± 4
Cobalt, Co mg/Kg 114 ± 2
Copper, Cu mg/Kg 330 ± 4
Iron, Fe mg/Kg 12923 ± 296
Lead, Pb mg/Kg 144 ± 2
Lithium, Li mg/Kg 103 ± 6
Magnesium, Mg mg/Kg 1827 ± 43
Manganese, Mn mg/Kg 1065 ± 19
Mercury, Hg mg/Kg 2.86 ± 0.10
Molybdenum, Mo mg/Kg 60.2 ± 1.4
Nickel, Ni mg/Kg 171 ± 3
PHOSPHORUS AS P, TOTAL mg/Kg 294 ± 26
Potassium, K mg/Kg 6087 ± 141
Selenium, Se mg/Kg 154 ± 3
Silver, Ag mg/Kg 73.5 ± 1.6
Sodium, Na mg/Kg 1417 ± 28
Stron um, Sr mg/Kg 369 ± 10
Thallium, Tl mg/Kg 43.3 ± 1.1

2931 Soldier Springs Rd. Laramie, Wyoming 82070 USA

800-325-5832
[email protected] www.sigma-aldrich.com
Page 1 of 3
Description
Lot LRAC6625
Expiration Date April 2024
Manufacturing Date April 2020
Storage Conditions ROOM TEMPERATURE
Solvent/Matrix LOAMY CLAY

Tin, Sn mg/Kg 215 ± 8

Titanium, Ti mg/Kg 75.4 ± 6.9
Vanadium, V mg/Kg 259 ± 4
Zinc, Zn mg/Kg 874 ± 11

Informational Values

Suggested Acceptance Standard

Analyte Units Windows Deviation
Aluminum, Al mg/Kg 0.00 to 23308 3964
An mony, Sb mg/Kg 0.00 to 126 27.3
Arsenic, As mg/Kg 27.3 to 58.8 5.26
Barium, Ba mg/Kg 390 to 797 67.9
Beryllium, Be mg/Kg 75.2 to 161 14.3
Boron, B mg/Kg 125 to 337 35.3
Cadmium, Cd mg/Kg 81.7 to 153 11.9
Calcium, Ca mg/Kg 3031 to 5542 418
Chromium, Cr (total) mg/Kg 202 to 391 31.4
Cobalt, Co mg/Kg 79.6 to 147 11.2
Copper, Cu mg/Kg 240 to 419 29.9
Iron, Fe mg/Kg 6994 to 18874 1980
Lead, Pb mg/Kg 99.1 to 187 14.6
Lithium, Li mg/Kg 25.0 to 189 27.3
Magnesium, Mg mg/Kg 1005 to 2680 279
Manganese, Mn mg/Kg 670 to 1456 131
Mercury, Hg mg/Kg 1.47 to 4.20 0.455
Molybdenum, Mo mg/Kg 31.2 to 89.5 9.72
Nickel, Ni mg/Kg 112 to 225 18.9
PHOSPHORUS AS P, TOTAL mg/Kg 0.00 to 589 98.3
Potassium, K mg/Kg 3285 to 8622 889
Selenium, Se mg/Kg 80.2 to 226 24.3
Silver, Ag mg/Kg 39.7 to 106 11.0
Sodium, Na mg/Kg 877 to 1972 182
Stron um, Sr mg/Kg 186 to 552 60.9
Thallium, Tl mg/Kg 20.1 to 66.5 7.73
Tin, Sn mg/Kg 96.5 to 337 40.1
Titanium, Ti mg/Kg 0.00 to 180 34.9
Vanadium, V mg/Kg 167 to 353 31.0
Zinc, Zn mg/Kg 625 to 1125 83.3

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Certi icate of Analysis Certi ied
Reference
Metals in Soil
Material
Description
Product ID SQC001-30G
Lot LRAC6625
Expiration Date April 2024
Manufacturing Date April 2020
Storage Conditions ROOM TEMPERATURE
Solvent/Matrix LOAMY CLAY

Additional Information:
DESCRIPTION
A total sample size of 30g is provided.
The sample has been heat sterilized.
This sample should be digested using USEPA method 3050, 3051 or equivilent methods.

SAMPLE PREPARATION
Perform the sample digestion on an appropriate amount of sample according to the selected digestion procedure. The
recommended minimum sampling size is 0.5 grams.
Determination of the percent moisture content of the material is required.
All results are reported on a dry weight basis.
It is recommended that approximately one gram of the soil be digested.

1 Metrological traceability: Traceable to the SI and higher order standards from NIST through an unbroken chain of comparisons. The balance used to weigh raw materials is accurate to +/-0.0001 g and
calibrated regularly using mass standards traceable to NIST. All dilutions were performed gravimetrically. Additionally, individual analytes are traceable to NIST SRMs where available and specified above.
4 Ucrm - Uncertainty values in this document are expressed as Expanded Uncertainty (Ucrm) corresponding to the 95% confidence interval. Ucrm is derived from the combined standard uncertainty multiplied by
the coverage factor k, which is obtained from a t-distribution and degrees of freedom. K=2 unless specified. The components of combined standard uncertainty include the uncertainties due to characterization,
homogeneity, long term stability, and short term stability (transport). The components due to stability are generally considered to be negligible unless otherwise indicated by stability studies. The mathematical
representation of the Ucrm calculation is as follows:

u CRM  2
u char  u hom
2
ogeneity  u stability
2

k: Coverage factor derived from a t-distribution table, based on the degrees of freedom of the data set. Assume 2.0 for a Confidence interval = 95%

Traceability: The standard was manufactured under an ISO/IEC 17025:2017 certified quality system. The balance used to weigh raw materials is accurate to +/- 0.0001g and
calibrated regularly using mass standards traceable to NIST. All dilutions were preformed gravimetrically. Additionally, individual analytes are traceable to NIST SRMs where
available and specified above.

Homogeneity: Homogeneity was assessed in accordance with ISO 17034:2016. Completed units were sampled using a random stratified sampling protocol. The results of chemical
analysis were then compared using a one-way analysis of variance approach as described by TNI EL-V3-2009 Appendix A.2. See Instructions for minimum sub-sample size.

Expiration is at end of month given on certificate and label.

MSDS reports for components comprising greater than 1.0% of the solution or 0.1% for components known to be carcinogens are available upon request.

THIS PRODUCT WAS DESIGNED, PRODUCED AND VERIFIED FOR ACCURACY AND STABILITY IN ACCORDANCE WITH ISO/IEC 17025:2017 (ANAB Cert AT-1467) and ISO
17034:2016 (ANAB Cert AR-1470).

Andy Ommen - QC Manager Mark Pooler - QA Supervisor

Certi ication Date April 01, 2021
Version 0-412021

2931 Soldier Springs Rd. Laramie, Wyoming 82070 USA

800-325-5832
[email protected] www.sigma-aldrich.com
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