33 ELECTROCHEMISTRY

PAGE NO.:
DATE:

conductors - substance which allow electric

i

current to pass through them majorly

they are of two types :(without undergoingauemparieth
Metallic conductors : These are metals which
Wanita
Kwa ant
current due
conduets werent
snit of e- also kras electronic conductent.
e
to moveme

Thein conductivity, mainlydepends

a on
Nature of업 metal at position in periodic table)
Total no. of ralance &
1

Temp. with a in temp. conductivity &

-

1) Electrolytie conductens: they heat — of also klas

electusłytes which shoues
condutivity due to flour safnsions. They're of
2 types: (on basis of extent of dissociat)
strong electrolyte - 'they shout soomplete dissociates
when dissolved in aqueous sol"
eq. uce, 1960.
H, a, MNOG
4MIND,, Nadu, KOH ete.
weak electrolytes whow incomplete dissociations
majorly they're weak acids the base
eg. CH₃COOH H₂PO4 , HON 2 A, B, ,, , NH4OH, C2H ),
ALOH), etc,

electuslytic conducth depends on:

Nature of electrolyte ertentun of a conductivity
ionizato

Nature of solvent - Mostly they dissolve in solar

solwent

CHEMISTRY BY
ABHISHEK SIR
(H20)
 J.P.
PAGE NO.:
DATE: &
Viscosity ofmedium .
extentof dilution (with Liin diluets conductivity 1)
Temp. t with rise in temp. aug. Kifit)with a
ionic mobility na with t in temp

electrolysis -,process of decomposition of an

electrolyte by passage of electricity

through—it's aqueous sol or mielten (gused)
nom

liniting molas conductivity (m):

Ëm molare conductie
-vity when conc. approaches to zero
Electwolytic cell: apparatus to bring electrolysis,
galvanic cell act as electrolytice cell when
Eext & Eiell, current flows in opp. direct of coooying
anode becomes (twe) cathode lowell as to
AG ZO out

non spontaneous
‫܂‬ Rons
sawib ja to
sno DC sariti uke cesed while measuring conductielty
cantanke
Do because its brings about electrolysis (change
composition of woun) , AC is used.

*oelectrolytic cell @ flows from cathode to anode

sunduhrough exti supply only cous floue in sol".
HO!!!

PÈCA) IM219)]Htlan) (mydiegen electrodes taken as anode

falso called reference half cell) to find emf.
Fiel@const is inconvenient to measure : electrolyte beperty nawe
ellait is determined by measuring Hu
I&A. the resistance
ofur.
the cell containing wol of knowen conductivity PAGE NO.:
DATE
eg.kce

Conductance of electrolytis tol":

να 1
by Ohm's law 4
VIR

RR = fl
S unit : ohm metre (2)
А

f resistivity / specific resistance 1

anxe
= conductivity (G)6 uniti deinen)/ whol az
mholar

f
1
condutivity (he) unit: 2mn
or opecific conductielly
cell const.
A

1 A
1

R
fd

cell const.

Gx cell consta
K EG
cg。
TA
l

equivalent & molar conductance :

conductance of all the ions produced by
1gram eq. of electrolyte in solm denoted by a
Λε KX1000
K->
condustrieety
c. C conc. (noumality) -

A + conductance
sl unit,& lcm e egon sm²eq 2

conductivity of different bllotrialytes in same luent diety

A

aut to charge and size of the lens in which they diselite CHEMISTRY BY
ABHISHEK SIR
conductance of the electrolytic colm Rept blue the electrodes
PAGE
fu.P.
a conductility'cell at unit dist; but havingovrea of DATE:(
cross secta large enough to accomodate
sufficient volume of sola Mat contains ont mole of electrolyte
Molau conductance
conductance all the ions
of
pusduced by 1 gram mole
of electrolyte in
the sol denoted by a
Am KT1000
molarity

SI unit, 2- in2 molt

CGS 21 cm 2 mol of

15m2 mol some mol

4
No 150
Q10. f 0.0027,65 2 cm' ; R = 1002

R 11
se
А
COOH
e n
R Ava

S (‫والی‬ (Some/mall
Kle
< joo 0.002765
0.2165 cm

(mol/L)/2
Olloh berus K x 1000 xl x1000 where
с R A 20
‫ܓ‬ NG 500 DE
2000
11 1 +0000

Wisata 25 A org

40 Scm² eq
Down
TIST
Qist
: RAE
e
5852x sita o osx oly
toooo
sel ooo
CHEMISTRY BY
ABHISHEK SIR
 J.P.
PAGE NO.:

DATE:

de
f 5.5 5 * 15.7
-
87.135 2cm

condutivoitly 0.011476 sony

‫طر‬ 87. 135

ли K X 1000 2 x 1000
R A で
ad
20D
0.11416 41000 Bb 1000000 t
+000
X
0.05 5557 SA4Xorsors
1:57
0108
4444
229.52 Sem?/mol Ans vis.ro graph
fot strong electrolyte
Am = RACł at e = 1 A =v 4000000
its 7 intercept = in
i im ķy slope = -A

B condustijoites Molare conductricity

Variation
Calconc.
with temore
const
→
depending times
her
on nature of eltetuolyte
= im
Im - Ava பார் தயாராக
with increase in dilution the
no of ions per
unit vol & which further decreases
conductivity or specific. conductance of electrolyte
dilution

however ebuurved that Molar conducte

conductivity
ou
equivalent conductivity with 1 in

dilution, nouwer it showes variat for

a

the type of electrolyte used for

Fød string electrolytes with dilut inter onic
email which is conie mobility resulting
& a

himp mun
forces
in minore ased value
value of, molar" conductance
1
In case
dilut
of weak electrolyte the extent of
causes lange increase in molar
conductance las extent of diesocial is
. very
small & with dilut dissociat t) but
(no. of ions with dilution),