CARIBBEAN EXAMINATIONS COUNCIL ADVANCED PROFICIENCY EXAMINATION CHEMISTRY DATA BOOKLET DO NOT TAKE AWAY FROM THE EXAMINATION ROOM Revised February 2007 Scanned with CamScannerTABLE the Avogadro constant electronic charge the Faraday constant ionic product of water molar gas constant Molar volume of gas the Planck constant rest mass of electron, Se rest mass of neutron, 'n rest mass of proton, 1H Specific heat Capacity of water ‘Speed of light ina vacuum Kw Va Me ™ M = e 4: SOME IMPORTANT CONSTANTS -1 6.02 x 10°? mol 1.60 x 10°C 9.65 x 10°C mol * 1.00 x 107'4 mol@dm~> (at 298 kK) 8.31 JK” mol! 22.4 dm*mol” at s.t.p. 24 dm® mol under room conditions 6.63x 104 Js 9.11 x 103" kg 1.67 x 10°” kg 1.67 x 19°27 kg 4.18 kd kg"! 3.00 x 108m 57! Scanned with CamScannereo TABLE 2: IONISATION ENERGIES OF SELECTED ELEMENTS Element Proton Tonisation Energies (KJ mol’) frumiber First Second Third Fourth H 1 1310 - = = Ho 2 2370 5250 a - u 3 519 7300 11800 - Be 4 300 1760 14800 21000 B 5 799 2420 3660 25000 c 6 1090 2350 4610 6220 N 7 1400 2860 4590 7480 ° 8 1310 3390 5320 7450 F 9 1680 3370 6040 8410 Ne 10 2080 3950 6150 9290 Na 1 494 4560 6940 9540 Mg 12 736 1450 7740 10500 Al 13 877 1820 2740 11600 si 14 786 1580 3230 4360 P 15 1060 1900 2920 4960 s 16 1000 2260 3390 4540 cL "7 1260 2300 3850 5150 Ar 18 1520 2660 3950 5770 kK 19 418 3070 4600 5860 Ca 20 590 1150 4940 6480 Sc 21 632 1240 2390 7110 Ti 22 661 1310 2720 4170 v 23 648 1370 2870 4600 cr 24 653 1590 2990 4770 Mn 25 716 1510 3250 5190 Fe 26 762 1560 2960 5400 Co 27 787 1640 3290 5100 Ni 28 736 1750 3390 5400 cu 29 745 1960 3350 5690 Zn 30 908 1730 3828 5980 Ge 32 762 1540 3300 4390 Br 35 1140 2080 3460 4850 sr 38 548 1060 4120 440 Sn 50 707 1410 2940 3930 I 53 1010 1840 2040 4030 Ba 56 502 966 3390 7 Po 82 716 1450 3080 4080 Scanned with CamScanner(a) (b) () (d) (e) TABLE 3: ATOMIC AND IONIC RADII Group I! Metallic Group 1V single covalent metallic Group Vil single covalent Period 3 Metallic single covalent Van der Waals First row transition elements single covalent “4 OF SELECTED ELEMENTS atomio/nm ionic/nm Be 0.112 Be* 0.031 Mg 0.160 Mg* 0.065 Ca 0.197 Ca* 0.099 Sr 0.215 SPP 0.413 Ba 0.217 Ba* 0.15 Ra 0.220 Ra* 0.140 c 0.077 si 0.117 sit 0.041 Ge 0.122 Ge* 0.093 Sn 0.162 Sn* 0.112 Pb 0.175 Po* 0.120 5 0.072 F 0.136 ic 0.099 Ci" 0.481 Br O.114 Br 0.195 : 0.133 be 0.216 At 0.140 Na, 0.186 Nat 0.095 Mg 0.160 Mg 0.065 0.143 Am 0.050 - 0.117 si” o.0at - 0.110 p> 0.212 a 0.104 sé 0.184 0.099 cr 0.181 - 0.192 a 0.144 So” 0.081 7 0.132 Tie 0.090 & 0.122 ve 0.074 Mn 0117 cr 0.089 Fe 0.117 Mn 0,080 O116 Fe* 0.076 Co Fe 0.064 Ni O16 Co 0.078 ci 0.115 Ne 0.078 Ws 0.117 cue 0.069 0.125 zn 0.074 A Scanned with CamScannerBond (a) (b) 35 TABLE 4: SELECTED BOND ENERGIES Diatomic molecules H-H D-D N=N =O FF ci-cl Br—Br 1 a? H-Cl H—-Br Lad | Polyatomic molecules c—c ic CC (benzene) c-H c—cl c—Br co c—N c=N Energy/kJ mol 436 442 994 496 158 244 193 151 562 431 366 299 350 610 840 520 410 340 280 240 305 610 890 360 740 390 160 410 460 150 359 320 222 250 347 264 Scanned with CamScanner-6- RD ELECTRODE AND REDOX POTENTIALg TABLE 5: STANDAI — E Nolts Electrode reaction at 298 K(25°c) +0.80 Aghte <=> 49 - AP 430° <=> Al 4 Ba*+2e <== Ba aoe Br+2e <== 28F +1.07 Ca 2e° => Ca 2.87 Ch+2e° <=> 2017 +1.36 2HOCI+2H*+ 20° <=> Cl +2H,0 +1.64 Co" +20 <== Co ~0.28 Co* +e = Co* +1.82 [Co(NH,)\* +2e° <== Co+6NH, 0.43 z. +207 => Cr 0.91 CP +307 os 0.74 Chee SS oe Cr03°-+ 14H" + 6e™ > 2047.0 oa! ae ° 41.33 Cute Ss oy Cu 420 Gy 40.52 Cee 8 Gy +0.34 [Cu(NH:).)" +207 = yy aNH, 40.15 Fat2e an op- 0.05 Fe" +20 <= pe 42.87 Fo" de mk Fe ~0.44 Oe a eee => Fee 0.04 a - + SS root 40.77 Fe(OH) +o a Fe(OH). + on 40.38 2H’ +207 ow IH bez ~0.56 oe a 0.00 Kee os \ Uitte i 40.54 2.92 -3.04 Scanned with CamScanner7. TABL Electrode eaction E5 (Conrp) Mg" + 2e7 Mn** + 267 Mn** + @- MnO, + 4H* + 2e- MnO 4+ 6 MnO; + 4H* + 3e7 MnO, + 8H* + 5e7 NO} +2H*+e° NO; +3H* +207 NOj +10H* + Be Nat +e- Ni* 4 2e7 INi(NH)6}** + 267 H,02 + 2H? + 2e7 O2 + 4H" + 4e7 O2 + 2H20 + 4e7 O2 + 2H" + 2e7 2H, +207 Pb + 267 Pb* + 2e7 PbO, + 4H* + 267 SO?" + 4H* +267 S,0F +2e° 8,02" +207 Sn? + 267 Sn* +267 V4 26° ve em VO? + 2H* +e VO; +2H* +67 VO; + 4H" +67 Zn® +267 —_= —_> —_= —_= —_= —_= —_ SES = = = = = = = eS — = Mg Mn Mn? Mn? + 2H. Mno- MnO, +2H.0 Mn?* + 4H.0 NO. +H.0 HNO + H.0 NH; +3H,0 Na Ni Ni+ 6NH3 2H,0 2H.0 40H" H,02 Hz + 20H” Pb Pb* Pb + 2H,0 SO, + 2HzO 280% 28,05" sn Sn’ v vr vie HO vo +H:0 yor +2H:0 2 zn E” Wvolts at 298 K(25°c) 2.38 1.18 41.49 41.23 +0.56 41.67 41.52 40.81 40.94 40.87 -2.71 0.25 ~0.51 +177 41.23 40.40 40.68 0.83 0.13 +1.69 41.47 40.17 42.01 ++0.09 0.14 40.15 1.20 0.26 40.34 +1.00 +1.00 0.76 Scanned with CamScannerPa TABLE 6: SELECTED INFRARED ABSORPTION SPECTROSCOPIC DATA Characteristic absorption anges: (Wave number, cm’) Bond O-H ‘tree’ J 3580 to 3670 N-H primary amines - 3350 to 3500 O-H ‘hydrogen-bonded’ in alcohols, phenols 3230 to 3550 C-H alkanes, alkenes, arenes $ 2840 to 3095 O-H ‘hydrogen-bonded’ in acids F 2500 to 3300 c=N 2200 to 2280 c=c 2070 to 2250 c=0 aldehydes, ketones, acids, esters 1680 to 1750 _ 1610 to 1680 c-o alcohols, ethers, esters 1000 to 1. cer * due to stretching vibrations Scanned with CamScannera sequinu (ouiore) uoiosd ~ a joquts owore-x] x [on ssew quo ames |__ Scanned with CamScanner aaa ead Ol an we eg Pe) cee ef HO Se age ents seat | er oat eae | eos ee mae eee acme ede ee ap at el a mw ef ta] co] a] aft ala a | a alae | we | | es | | wo) | au | ca {| oo | cov | sox | cos | ost | cor | ese | os | - | ve | ive | ont | oct fr oye o | ww | ou 33] e] my yy ed] 35 w ag a fo fe] m | eg - doz zei | oor | oa | rer | tot zat i oe || ee us wo fom | a | on | a 1s out cor | i | - | 636 | ove Er) | ea rr rr oz) ja ° co | os | w | | A rw |» eee sze ees | oss | ers | ozs | 60s vor | ree 77) rT rT ay io] ¢ 4 's ow | oon gse | ree | ov | be eve | oe 8 a] Z| 9 5 5 a 4 o} N 2 a ea |on oe: | om | on | oz | oo ae 7 4 on wfafafm | ae dnoip, eiqes 91PoHed UL -6-