Thermodynamics

  (C) JEE Main 2021 (July) Chapter-wise Questions

Questions with Answer Keys MathonGo

Q1 (20 July 2021 Shift 1)

An average person needs about 10000 kJ energy per day. The amount of glucose (molar mass

= 180.0 g mol
−1
) needed to meet this energy requirement is ___ g.

( Use : Δ C
H( glucose ) = −2700 kJ mol
−1
)

Q2 (20 July 2021 Shift 2)

For a given chemical reaction A → B at 300 K the free energy change is −49.4 kJ mol −1
and the enthalpy of
reaction is 51.4 kJ mol −1
. The entropy change of the reaction is ___ JK −1
 mol
−1

Q3 (22 July 2021 Shift 1)

If the standard molar enthalpy change for combustion of graphite powder is −2.48 × 10 2
 kJ mol
−1
, the
amount of heat generated on combustion of 1 g

of graphite powder is _____ kJ. (Nearest integer)

Q4 (25 July 2021 Shift 1)

At 298.2 K the relationship between enthalpy of bond dissociation (in kJmol −1

) for hydrogen (E H) and its
isotope, deuterium (E ), is best described by:
D

(1) E H =
1

2
ED

(2) E H = ED

(3) E H = ED − 7.5

(4) E H = 2ED

Q5 (25 July 2021 Shift 1)

At 298 K, the enthalpy of fusion of a solid (X) is 2.8 kJ mol −1

and the enthalpy of vaporisation of the liquid
(X) is 98.2 kJ mol . The enthalpy of sublimation of the substance (X) in kJmol
−1 −1
is

(in nearest integer)

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Thermodynamics
  (C) JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

Q6 (25 July 2021 Shift 2)

A system does 200 J of work and at the same time absorbs 150 J of heat. The magnitude of the change in

internal energy is J. (Nearest integer)

Q7 (27 July 2021 Shift 1)

For water at 100 ∘

C and 1 bar,

Δvap  H − Δvap  U =

2
×10  J mol
−1

(Round off to the Nearest Integer)

[Use: R = 8.31 J mol
−1
 K
−1
]

[Assume volume of H 2 O(l) is much smaller than volume of H 2 O(g). Assume H 2 O(g) treated as an

ideal gas]

Q8 (27 July 2021 Shift 2)

When 400 mL of 0.2MH 2 SO4 solution is mixed

with 600 mL of 0.1MNaOH solution, the

increase in temperature of the final solution is −10 −2

 K . (Round off to the nearest integer).

[ Use : H +
(aq) + OH
−
(aq) → H2 O :

−1
Δγ H = −57.1 kJ mol ]

Specific heat of H 2
O = 4.18 J K
−1
 g
−1

density of H 2
O = 1.0 g cm
−3

Assume no change in volume of solution on mixing.

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Thermodynamics
  (C) JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

Answer Key

Q1 (667) Q2 (360) Q3 (21) Q4 (3)

Q5 (101) Q6 (50) Q7 (31) Q8 (2)

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Thermodynamics
  (C) JEE Main 2021 (July) Chapter-wise Questions
Hints and Solutions MathonGo

Q1

1 mole glucose give 2700 kJ energy so mole of glucose needed for 10 energy = moles

5 10000
 kJ = 370
2700

wt. of glucose = 3.10 × 180

= 666.666

≈ 667gm

0
YBenzene  P XB

YM.B
= 0
B
=
70×1

20×1
=
7

P XMB
MB

YBenzene  =
7

9
= 77.77 × 10
−2

−12
= 78 × 10

Q2

Given chemical reaction:

A ⟶ B[ΔG]P,T = −49.4 kJ/mol

T300 K

ΔHrxn = 51.4 kJ/mol

ΔSrxn =?

⇒ From the relation [ΔG] P,T = ΔH − TΔS

ΔHrxn − [ΔG]P,T
⇒ ΔSrxn =
T

[51.4 − (−49.4)] × 1000 J

=
300 molK

J
⇒ ΔSrxn = 336
molK

Q3

1 mol graphite = 12gmC

248
Ans. = 12
= 20.67 kJ/gm heat evolved

Q4

Enthalpy of bond dissociation (kJ/mole) at 298.2 K For, hydrogen = 435.88 For, Deuterium = 443.35
EH ≃ ED − 7.5

Q5

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Thermodynamics
  (C) JEE Main 2021 (July) Chapter-wise Questions
Hints and Solutions MathonGo

ΔHab = ΔHf is + ΔHvqp

= 2.8 + 98.2

= 101 kJ/mol

Q6

w = −200 J, q = +150 : ΔU = q + w

ΔU = 150 − 200 = −50 J : magnitude = 50 J = |ΔU|

Q7

H2 O(θ) ⇌ H2 O(v)

ΔH = ΔU + Δng RT

for 1 mole waters ;

Δng = 1

∴ Δng RT = 1 mol × 8.31 J/mol − k × 373 K

2
= 3099.63 J ≅ 31 × 10  J

Q8

400×0.2
nH+ = × 2 = 0.16
1000

nOH− =
600×0.1

1000
= 0.06

Now, heat liberated from reaction

= heat gained by solutions

or, 0.06 × 57.1 × 10

3

= (1000 × 1.0) × 4.18 × ΔT

∴ ΔT = 0.8196 K

−2 −2
= 81.96 × 10  K ≈ 82 × 10  K

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