Thermodynamics (C) JEE Main 2021 (August) Chapter-wise Questions

 
Questions with Answer Keys MathonGo

Q1 2021 (01 Sep Shift 2)

For the reaction 2NO 2 ( g) ⇌ N2 O4 ( g) , when

ΔS = −176.0JK
−1
and ΔH = −57.8 kJ mol ,
−1

the magnitude of ΔG at 298 K for the reaction is ____ kJmol −1

. (Nearest integer)

Q2 2021 (31 Aug Shift 2)

The incorrect expression among the following is:

ΔGSystem 
(1) ΔSTotal 
= −T( at constant P)
∘ ∘
ΔH −TΔS
(2) ln K = RT

(3) K = e −ΔG /RT

Vf

(4) For isothermal process w revesible 

= −nRT ln
 Vi

Q3 2021 (31 Aug Shift 1)

According to the following figure, the magnitude of the enthalpy change of the reaction

A + B → M + N in kJ mol
−1

is equal to ____. (Integer answer)

Q4 2021 (27 Aug Shift 2)

Data given for the following reaction is as follows:

FeO(s) + C(graphite)  ⟶ Fe(s) + CO(g)

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Thermodynamics (C) JEE Main 2021 (August) Chapter-wise Questions
 
Questions with Answer Keys MathonGo

The minimum temperature in K at which the reaction becomes spontaneous is ____. (Integer answer)

Q5 2021 (27 Aug Shift 1)

200 mL of 0.2 M HCl is mixed with 300 mL of 0.1 M NaOH. The molar heat of neutralization of this
reaction is −57.1  kJ. The increase in temperature in ∘
C of the system on mixing is x × 10 . The value of x
−2

is ____. (Nearest integer)

[Given : Specific heat of water = 4.18 J g −1

 K
−1

Density of water = 1.00 g cm

−3
]

(Assume no volume change on mixing)

Q6 2021 (26 Aug Shift 2)

For water Δ vap  H = 41 kJ mol

−1
at 373 K and 1 bar pressure. Assuming that water vapour is an ideal gas that

occupies a much larger volume than liquid water, the internal energy change during evaporation of water is
____ kJmol
−1

[ Use : R = 8.3 J mol
−1
 K
−1
]

Q7 2021 (26 Aug Shift 1)

The Born-Haber cycle for KCl is evaluated with the following data :

Δf H
⊖
for KCl = −436.7 kJ mol
−1

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Thermodynamics (C) JEE Main 2021 (August) Chapter-wise Questions
 
Questions with Answer Keys MathonGo

Δsub H
⊖
for K = 89.2 kJ mol
−1

= −348.6 kJ mol
−1
; Δlond  H
∘
for Cl 2
= 243.0 kJ mol
−1

The magnitude of lattice enthalpy of KCl in kJmol −1

is ____.(Nearest integer)

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Thermodynamics (C) JEE Main 2021 (August) Chapter-wise Questions
 
Questions with Answer Keys MathonGo

Answer Key

Q1 (5) Q2 (2) Q3 (45) Q4 (964)

Q5 (82) Q6 (38) Q7 (718)

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Thermodynamics (C) JEE Main 2021 (August) Chapter-wise Questions
 
Hints and Solutions MathonGo

Q1 (5)

ΔG = ΔH − TΔS

298(−176)
ΔG = 57.8 −
1000

ΔG = −5.352 kJ/mole

∣ Nearest integer value ∣= 5

Q2 (2)

Option (2) is incorrect

∘
ΔG = −RTℓnK
∘ ∘
ΔH − TΔS = −RT ℓnK
∘ ∘
ΔH −ΔS
ℓnK = − [ ]
RT

Q3 (45)

ΔH = Eat − Eab

= 20 − 65

= −45KJ/mol

|ΔH| = 45KJ/mol

Q4 (964)

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Thermodynamics (C) JEE Main 2021 (August) Chapter-wise Questions
 
Hints and Solutions MathonGo

Δ H
Tmin = ( 0
)
Δ  S

0
Δ Hrxn = [Δ H(Fe) + Δ H(CO)] −
0

f
0

0
= [Δ H(FeO) + Δ H (C(graphite ) )]
f
0

= [0 − 110.5] − [−266.3 + 0]

= 155.8 kJ/mol

0 0
Δ  Srxn = [Δ  S(Fe) + Δ  S(CO)] −
0

0
[Δ  S(FeO) + Δ  S (C(graphite ) )]
0

= [27.28 + 197.6] − [57.49 + 5.74]

= 161.65 J/mol − K

3
155.8×10  J/mol
Tmin =
161.65 J/mol−K
= 963.8 K

≃ 964 k (nearest integer)

Q5 (82)

⇒ Millimoles of HCl = 200 × 0.2 = 40

⇒ Millimoles of NaOH = 300 × 0.1 = 30

⇒ Heat released = ( 1000

30
× 57.1 × 1000) = 1713 J

⇒ Mass of solution = 500ml × 1gm/ml = 500gm

q 1713 J
⇒ ΔT =
m×C
= J
= 0.8196 K

500 g×4.18
g−K

−2
= 81.96 × 10  K

Q6 (38)

Given equation is

kJ
H2 O(ℓ) ⟶ H2 O(g) : ΔH = 41
mol

⇒ From the relation : ΔH = ΔU + Δn g RT

⇒ 41
mol
kJ
= ΔU + (1) ×
8.3

1000
× 373

⇒ DU = 41 − 3.0959

= 38 kJ/mol

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Thermodynamics (C) JEE Main 2021 (August) Chapter-wise Questions
 
Hints and Solutions MathonGo

Q7 (718)

⊖ ⊖ Θ 1 Θ
Δf H = Δsub H + Δionization  H + Δbond  H
KCl (K) (K) 2 (Cl2 )

+Δclectron gain 
H
⊖

(Cl)
+ Δlattice  H
⊖

(KCl)

⇒ −436.7 = 89.2 + 419.0 +

1

2
(243.0) + {−348.6}

+Δlattice  H
⊖

(KCl)

⇒ Δlattice  H
⊖

(KCl)
= −717.8 kJ mol
−1

The magnitude of lattice enthalpy of KCl in kJmol −1

is 718 (Nearest integer).

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