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Theory of Quantitative Analysis

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59 views

Theory of Quantitative Analysis

Uploaded by

Sri Vanya
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© © All Rights Reserved
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Thcony of Quscltelne Onset y = x debersrinalliiy Of De Ptah Srbedudiin 7 Ovtartlilaliie Cray ial | Lt oO Lisiols elurnk (29) Ompoweels lation Cotunnbilalie orale _ A) lumabui analysin S)gpomucretas orale + Vebrmobise analypiss- 8 Unalteh Sebioe © A Shaton af Keowr thurgls (o conastalie a hal Rabileern” iS — | | a ee ——_ oF + Pllinaty Glinolarel Subrsenie 2 Cyn ete Ch. Cubelarty cwhote Gralate) Solultin Cn dae cay ppt“ ee ot Rubilina’ in 0 Kroc vais of hh gr Hata Ox (enahi onal) Ay + Bueno andad Sulina = Oo ukadert ae — clissth re Calle! Seconclety ubttarta oz Tt Catily | Ky 004 Gg Wel, Ha S0, , Kronos, , Kon, NaOH | | : _— : | ~A} Nonume tae AnaLisis | clyndiy orn | Type of -drenebiors ArMlelute in lela hy ate y ee Daal hates) &) orislelicn-Deducten 3) fSdigritalion’ “) ‘one Newbsabitalin o : : . forrnueo dibalivin 5 Punlons ee rr, ee D) Aris Age eaaliors CD iimaly on euidiay» Oe PO tiny 0 thralasy 2d Colalr GD Analimebs 2 In Abealimety , the guen sy using & Lanolurol olrale Solubioir’ Hau Toba snebah all volumilsi oebrrninalrins besoin Ln reebrolialn Swackosn : HY OW” <2 H,0 abicale xs Climbed Ay Baal Solubiwo x Climates of anol Sebuliin in bh (dileaain Uasx”- Chia Solalin wht Tp naling a Or pict ty neg ees OH called) on Snolicales” oA Salil + & Bulla cot Soon es ea 7+ ee eee | » onahealos Bocrld he Srndlly Ulaable oe wot Ghoul nob offal lhe cclsal Ormical Ssaslisa £36 Soul gis 0 plas caren Charge cals Ore GY “ga: dbfeunt caloes oxit notes Liye of Hore ' «© ene» a ohapt of st hae! te Mppcant prota He ay ne ee cones sich Gs On ea) ou ban Sbale es | () phenolprbraleine se ix colsailils in Curia! Colulior © pink in clnali Ysluben 2) methyl OIwNBeI 9 of, gollow «, alnals solelor ‘. © pink in, aio! Rabuleor s Choice OF ZInolcAToR Maline hty Of Aciea- base eneli'colite (vin ‘aude incall ix 2 Qubtlaran, Cohish Joe ore colour in Be | ie 5 ane! 0 completely dlifferent Coloes in lhe thanx amecliisrs- atisles oruadivn | astenald-theaays | > ecoteli eto thi Crtery, O17 includes in eiblas 6. Caen ofpanti ct Bo Ao J Compocne! vber GS elie ott pete? Jar crothy, Colour - : > the inclicalos (HIn) honises 22 follows + An = Ab tin 2 Cootown 1) [Peer eae ee ahaoie Leoty Le clotiivy Of phirolphtiolein am B righ otrge explain ot otiout 7 ee ec “oot clan pn capo at» eebanles J k Slag hilly ol foun At ions Ceolourlur) & ph” Zon Cri) + Pp tphtholen ss cuppreserdee! 08 Hph <> Nt +ph- Colousless> Pink) Case T Cp aeehs) en hie e rmaclecwidsé” Jorverg Hed is aaleled ten Lhe Anusate in Ht don Coruerbiatin Suppauia lhe olinossliin of phunalphlialein. ot chu to “tomrion ion effets the Cypuitilerivn Yidts Loasards Lf 2 De Svlulen Surnin “colourless” Cate -O Calxalin) : . bis. Rebate sa abn’ by ali jess aleope of Nao Me OH” sons Sunk ali, H* ions to form crionitis) wales srioleuls. Che obeeuate in Ht itn Contenlralron Ligh be eyuilibinn Totouds Sight”. un mote of plerolptinlin seni & Solectn ° recorner “pink” Cole lo plo ion). Mente, Ute initalos 4s Colocals in dhe ceili & pnw in lhe odraline \ ap x WOON = Ha? * aid © elon of ray ang = > Ne olyeni Compound & ch cr a Ceear hate”» ot Solunble sy cotails & series do Vey Small Ontent Meoh ——= Met + OH- Gelteco Pink Cate I Carielsi: meoliturn) - of te Slutuin is mak ariel, lun Lhe Ayobogen ions besnishol vay che atin! Combine eulilh ON” isne te fotm A Wrionied Corals role Cron He Cletrwate in 0 H~ in i Contenbubiin Bhigh, Lee Oytelerim Lousasels Sight - Bap Ae ii { Horn the &elubern Ceglrins @ pink —celeca cur te-Met sons Cats-T) Coubhaline Treelian)s- rs H te \} i} (2 ta oe i+ mre Gale by aeleligrsipettee Ven be Coneertaliny 0f Oo sreeante ~ The Srrcrante in lhe « conurbalen of ON" ions “Buys Lhe Aissoislion of « | rnellyl Charge = Vis Diz Ogeibbsinen Shige octards lhe ft | ok cud he Co ee ene aula | let Se ae iis oad thie ad lbs at Th) puseareid Letty bop Head — ate inca oe capable of entity in dase Lanter fe bergoid & Yt I wnt FF wivtensia Fosrm pte goto ate iit colts, gral De Sry is Ligpn » cot Dun opreronyed Gre of lhe. forrs 14 Uebls in, eetlie mmedliun & ober in alealin rudion | g coo t. oy o> oo i co Oe _ x6 eo, apsinencid fot” Bergeid foo a+ px ‘ % eles iy Rhable in celine rmedlisre 4 Blable An ouidlet mechivm - 6) Dadhayl Stopes ete cng Uoaoerani. ots Of Talis Charge : cH. = 4 3 a of fon > Uhl in cltaline medi > Yelboco colora = a tly 4s Cyn NN, | > gptinonad for: > Blake in cericlix meolium 7 pu colour re wee ENN se Sd geal rralicilou and cin PH sarge | ‘ of dibadion | orolicales pH ange Tait Tae A uid hing ben | phuslpilalen goa “10 ele feed | 5) nya he phunolpliilin gatio | Add bere } a Ceascusd by boy plerwlphtielss $-2—10 »Adtelire oe | | } 4)| cummed, Gloomy rally orange 3-4 Meali Gellert | _Mesalite of pH cling let syne of doetere ) 0) whalion ofa ory id eis Clieny ase i 7 Wa Nook Contiols Le Lihaliein of a5ml 1 ofo-In Heb Chong aud) to AL || gaint o-\N Noon (ebony dats) |S ‘ > he hate conbiruotuly ARO OE WAT hs E & . : xs pHvaloe > eypeal Lo 7» : we ——n, sub st how buen jourdlhot Bepn & Noleme of gaseemt) > ofulle Solan jt (aso. rusalinliv 2s 30° ero) aut ofl reialilisn 95 . pone ob) he snc coh Staite P¥ange bebatn 3409-5 On epistles LAE tibeadeer pe J y | @ | 5 conaaa te ialon of 26nd of orn abelai xis! Cuseavacid) cutith O-WN Naor (2bieng Heat) Fs peclei cui! each leds Noon Solulen te Jom Sediivn utel andatols > Sodium cuslal on i joins & ane Lhe Crofporint List at tee a8 Value Cchich 28 Mek Ban 0 > pli valvee— > De hase creamy old § he phe Bs tober se plat cpt Mies Volume 0f Lhe Pete- “chaly for Such ban PH ange Aalasan 1 do 96 a0" > nalghlialas’ hor pi Sarge 3) thabuin of eueok awe cits daa Cidepe none and 25mlof Hel > Nuon ouatts cuit He! be Jot Nid Se Hy 0 $ > Niel i oe e >the how ix , ach)" ] Be pH value of bie Solabur ob Plolled against dose: + Ye Crd point dis at Some pH vile whivr ix Le Lon qo Tibaliée af % Chew Beet ulth Sieory epede *~ a CHgcooti* NCH = Cu Coone H Hy . 19| A ' >No 2&3) 4 invlicator Shoals b. olecheo! ephich bas Aacbtun 809-8 & Suet Bs prey 2 nicl HHI? ouislt- NYLON wad est os wn + Ae nil Ql fa ohio sa ap sare semi aor 7 : poy Yruthyl clang Aas a pH sarge bebauar sto ng bent Sot Oe i ag etl: WO auliors Of cutenn oie! Ubilh Uleeh Bett *- > Consids be Litialion of ff 25m} Of ov IW AIMgOH Cupniah UG asm of oN Hy + ail Ate hase cs Continuoerly 4 aloe g Be ph value of Du . Solubieir x plolled ageivrat . | th Volum. of oie Aate alee: Ze > Prom hai cate ee su tat 2 in dhs Cae Dan a no harp js \ an dhe pH Value - 3 Volume “of base em) <4 | Charge, an dhe pi q { 1 Daw Lush dibalie ia rol posible pharst aca Aus pH darge (oto 95) ard brane ty ctting his snolicalios oppronémate deleminaliin of Lx Nuulraliialion point Con bemacde wd x —*— 55) oman Srevluetiin (Restor) eileaions :- +> Samal Sires - telain ean be atin by . ln” Suis 21 Bas bod idan oe Juolerclion Sachin occur Ungelhes ive, O70 aubelinte * enialie!’ @ corel xe Sucluetel- > Celli 5 sus of ert rte Cay, yo Raa = gun of 0 OD Tet ebetrons hy « Bubreline re —> pest +e (eridlalien) jee fesse colt em a cet Counlucliin) ceadous " sith “> Redon dus proceso! Cuil Gmultansons wots one Jor PEE among Da sslng aan 0 le Ras Seton Segi- fo cee > fee ce Reduction Coun of e) oniolising agent Coviula) > Ue Sabilarie hich gains e- Cie .j enalago Asaluclion) in Sutle alinkn colon age” gap Remon 1 Mocrnon Raaaing gent Clue) 3- —> te Subsbvin whir ous e- Cire, age a) 9 Quljhale Ereiog uns wns 6g: onli aus), fotrous ammeniion oha?sa salt “ype of Reales Lisabions :- @) peng pgecaliy 3 - éakinalirs chic Anitobues sm le Lose of poles polrangarele 2% called kero, dilate () Qoworndly - Eibimalrs cahtsh slat in de cae df polation — ~ didwivrnaik, ote Calle! Kyo, oy dialn(od clichsomaly” © rdemdye- sr ype of bain vily Liitaal Dole » ealimnales this +s echo Hrewn 08 Irolisect mulhoo! B) Toolirrudy - “om hs yp of has i ain f ‘all gee « Duclussig yen this celap unerarn cs ett enolesd ho) Sedlucuy int hy See | yf caivtivis ager Ay olandhsel | nudiosly ae alt af th ; Redhusclisnaly ‘anbatos of th ah en o Snaliilos fos Parle LeLialisss :- ©) 2h snabcalow 2- on Som caus oneg] De Searlarl in Le dibaben el as an Rett Kenny Clitin in hua) aga BaS0u Cl? | Conical plus) Lhe Aobalion of NOx Cox ouil) Jurrsis | Colousbee LL cle duatlion is complete. as boon O Aeaclion | Puerto any coburn Chele of te Creal isd ppsseard “empl exe i te olde psmanger | | an conical Have | a nd ih dap pride | Anat np ts Clay” le ln of cred fe | ~" pasemanganomelng’Cturh tehiolions ate ger) © Qe NO, HH BHQSOY sR KaSOmq | | | + amnso, + 34,04 ses : ‘gc siAs —+ loco, +540 Y eootl \ | | x 4 RAANS04 TIOCEa* SUQO « : ‘ QkmMMoy * 3HsSOy~ Fok —» ky Sey i ah 80814 + chs snolitalis te ond point - Sing, he Krome, (one of De Seedartt) itadp 1 axcling cu on inoliculer” Ati known ar ‘ely sneliculss” ex YS yan > Somelima Cor hoiisr Of Quhttance oulsiole ell, Suseien ‘he Saath 4 " sndicalel toy De eof pninluse Suh Sabotlors ta called a “Qichtrornel Bg” seit labs? feric_fol oO aon - axglie cendg] + 3FeS0q —> 5 ie Leech — pe F eARO Fearicganide bee ts eco, \y _ Beep P bive colooned comple @ gpett x & precende| — Fea gee ‘pols fenyoricl salad do th Fla ssi a ba tl obind ope big ogre ET” 2 OF Fesen ait : Fet @ sae Vn. Cig dy + GFeS0y FTN $4 = Brel) Nea (ios, . Ky §0,414,9 © ‘ / SN PN + prep, MIS Dupe 0.5 © Redlow ingen ’- Cohen farm Surviny ro ) S Pailog sndiealn is compoural cohish enclaye Didaliin ie aa v By ptagenin® oats 9 AG a tied an Fes, Ws) kK, 09204 oo eee > this snob cals, os ‘blue wiolet” colour 2” eye pein, Vials Colouslus” én, Creoluuted etm . een GSO rie Feo ), Ka ,04 ¥ Tr S04 + GPesOy —> KFS ane x —x— * an fi, of tenluin delral » (2) oaderaly me inhi, Lyps, op thle, only th ciel odin sa hima | this alse knw as snélitil mabhod.” i. > on dhavrrbod Lit Citdlising pnt do tro. Cebrnaledl as Leealesl ct.lh | | co es <= TAH 4 aan Barents, + A%S09 — | e Hae anaioabor 45 Usual” Refer J paackce janes! o| © 8) ads = cae > ie ee 2 Si dil Saduing agent ite Ne,6, 05 teclitun vuenife eb oye noe, $602, Wgig= ANaL + Na aa? ANd *293 tn eb wy pothrull deacon 3 .tagog SHKE TAN PBS” Sue dey ae 4 ae Naz $y ) Precipitation 1 TITRATIONS 6 ARGEN TOMETRY 7 inin Lebsabrors aledision oy W > yee tomeby ee Seley Milsal nikal librabent at preipilalie 7 “cohidh palpi of Caget- Agcnss cle) ix found Ay Agnios Sobibor | > ye of Agnes Lsaliois i (a) moh + moh sis method t- Cotaisiwn chromate knoli calos ) we on Suth bypes of aayentemelsy lhe Agens feet 4 3CNS” Fe Cen S)3 8 repr’ yt aq FOL wa cv Red colo md | > SS i rruthod Agel pot: poy ss ila. pllsad GA coaguteled 1 (2 Pagan’s Grtacton rielhid Celeplisn nelieais) + | wpm i Alain ci estos do ba cues) ore of Linbbatir | “elas (dy) + Ue erolpout * fy ce apapeatante Oa hay serie be HTP ey Ayes, Wah KO hkens axe prirary anda \ Ls. j ly lp i rie! Solan . | | | yee QU compiexome rey b Comnplexornnbis dibubirn on lbwte « cchich a malel ion Seach Cibo ligand ‘to fotre Solunble Comply. EDTA Celhylane liamire daha elite) Plerashadal OCH” . *aXy CMytoo™ N cn, Ca, NS = E iam. = goo’ Hc a _ 2 cy, C007 CAletaatontal) - Complomebis Sualies (80 ilar psbalal capa ft ebeniniihen of a mire 4 ee Ed1 As Sek ee abi appr « _ Sod AA ee joa Oy ee | ase Lael ling abe foarte compl. ” ot bot ‘eae pap * fa is po oon | ehechsen pin clones + uy abil f Entra pst Slowd tt a bone pats of Chebrors Jor be jn of ie at dd ol celicin matin EDT 0. Jemaclonll whieh > Epia a Le aatt calilly tad Comping et pang opi ep Beh, fescoleo® of mn (ml) + gee orl S mogl rule) sore Suck cil Cleeliom pis SIE lo fom - Oe abenet Qneais (61) bipansl +8 0” 40" 0 Covabat herd cuits a Calton i+®-, inde) eloen hy shovels & P&P rrulal “EDTA Cemplen MerAar TNDICATORS 8- + ondiestou Sach og CEiachiomne plave-t-Prsvuiciee, aabphanebant) forviie coloarsel corrgalen. ‘ith ole ‘tedceting, ralel to Ae llivmiad! + gorsaly, cps ov anid ox vaca an - tpdlicaben cohen acloleed clo Ble Sh enoally Pe og mis 2 rnold Solatain Patra 0-Cornpe us Vahl, Lan Wa 7 alias | Meid + Fraicaler > real | Compl) (bss ahh) mull ~Iredicalios xeon > mild Cora + li OM Ghable | compet (ck ear eat Cxichrome - Alaa t (EBT) . Mult +EGT —> Melal-Eor Coommplex) wine 26) Color hss Table metal 081 + EDTA —> mut -OrA + EBT : Complex, Glue M. Chae ate Slable comphe nals + End -powt * ce pane _ J debated pol ts pig 7 eo a the mele! EDIA TH IRATIONS &- 7" 0) Raed tehelsiys- Aharigh te rain bh tbal o. proalicenles 40 Aaathurs ton. Spec ts potshh saleby eat pape Anite PAS bhi. au oo Liat Cit Lert Suast Salis flatly cuit 0 r™ tik rl son wish fon CDi compe at on: nolicales olin M™bls Such os mg % Ca ara lib ian Dom 4 ‘ int Be 5 ela hs Pi Cont) te bs dative halal geet 7 rmagrativn Céampolx. EDTA: ne yr fe * semngt nee : elo Be colirn prrsent dus Be crmount mg kt free 5 fa Sealab, mela! Aroealet & oun be Aibaly cuits 0. thinolaw EDTA ee Crcraral Pini snylohtolingraume lays + the tonlenk ¥ gisen elrant @Ni0n ina. Cublunie A casallyd * D tonattos ios cote inky a7 “rtalushl conposed! Hh pully tal prsspilini Cabiod i pollaue torte Ge a ct C barninu| + ssvlaler! in Le a shabim) which i ezlathed, tahich Can be te ppsrtrigarbslion be Brought chocl thy ermical 9 pabrysital eg Bs follecstng ve toe tonne os githy ops Yoong prep sea ( at tama nals pstinilalin Blip of-arelysis) . Dadeelabin CA Some tne prcipllalne Bip “sm. precypilalin mili ofl adil of prep apart ibe Relalines af Ronis Urals analyst Deiare is tn snilenl srkachiors prin | Talote autclentin occuns «fs exe rutchi Pot don from Le Sabin “5 ming clan rad in te alloy tm degels Sree & e bhy, adelibvo of 77 Proleruls os 0 rreechan « former 044 \ wy : > chin a dubia Canbivs. ro'e. Salads Nay Uroubdl te praunt ob epeilly Me kolubivs 4 Laid ta be a i + nclalion procach pectin Ban posticl grosulh ein Le Sabin +s Ay’ Loprsalisale) 18° étull s- Sauyantion of ling pastiche rien Fon a less Safes Suburulid Salulivn 2ttcleales, ¢ Cou e { Fost a dance ibe gmc info clases mite Liaclabl partels® — y Pon pepo Sarg + precipilolen of Pubilanacr Cin Aget, aso, Alcon), Le | conalilion of precipilalicn x Ud lpoiy Saipecleie Aamie Pod. 0 Petal Cota! Dis eapeclaa Kelabilt pecludl- (loco gp pal \ ibh list etal. oF + Ty prccifdal) buy Glows cabolts cedpl tig | hat Labidion Y Pecepilliiy Saagerd ith Comlant Wry | of trial,» Lolabioin of prstipubiling Seager are antded Lilt pou 3 [Pe Oe conlaminalion + precy bs re vl cn Bt lbw abit, eo ua telco eat Prsipilelin- Coppeiidaion & pd paespTabn ening pin eld ti st formal tid. July chinidad pastel oy De otabechly Selon A gpa an ebebical : % ate Orruhy bphin Cusprertion Pvc oye canal by Be ins ef Arusne GD Cabins O7 Rate of i jpstiche for Og prodipilck Ane a evra B ardiete cur dens « As tapulad a Reedy lunes cess of me of oppose ane Le Bone, prsrwily carotid Tur ebedbscal lowble edger ii, Jorma! Arluien in Priliche & Labube’ gl ttl y hone + De riviemur Contnal of eulinlyt Fy eee en oe ohh Layer 4 called Ce Boceuali.” clue lo Coho Cogent > Conlaminaleen of pprreigaitale a of 2byre Oe pep g ott prcsplalior Deprun. > pruupillon of cry ebares Qaalants ete ove rH Pee Candler ae conclile'ns ty dhe reaping Cel +4 Ramen 08 pest: Grae a silage Rasoy on aol lzoirof Hers Bet, cot pris 4 604) > BasOny Ee . tate haa atl yplel, endorses bila se fon Bye by Ag Tce welale Pea: fg. Agc0oAg a Adsorhud Jr te Lat tolunble diay ridbuh i cle colle! tolaler ate previa rs fe eae allen of co- prstepilalic * iene eae 2 iy eam a nto tape Cr tpe Dae ings dtral iad “7 cual seni 8) pot prspilelin 2 Nee ea: Cabtcios cx Cubrium oxalate ipa of ng Ry > Ally he prcripilalns prmest Wie pli Cobar ~ Lips eg vith pineal eonlny peeps Bish phrwonnon a att usps” oli 34 — Pant | | Seth press lhe Ptecipclale a garsally diguled ty cil Auclirg & by alloy at Wen Avomslngraling for torre Presents Ain aig abit ronald peepee | ahtaining % glows qian precipilel whi, is Senalit, pMrdble form Pap mon pale , oie jack Filbate’, ra — Ch prasiprilals #2 Asolalid from Lhe rales Llbabery I Si pees Ee fame, 2 atin opel +e de duethe! sn otols th Mate, Ok pile PC be sald Ail Aol Se nde satashing a Cy) tlt “ ete coish ol ml as die pees ilh te usin “caida tlt kolaluors Seolun, Salubilily e cipilals Comey Jon ips Glulicis Cohich car teolace Be be tases coy tlce vie Aydrolpsa 6) Dairy Q rasta ae > te pigs » Jills bp sx cial hy rang ss of Bes chal os, sb tan bu-sloms ty at i oer 6) ech otter + sri pret iy leprae ofl compa dying Hla pop nites A mle tae ONE Sh yn tase preps kia 8280 Agel eh ag teoluerd! by cathen te be ey tas 05. spe on po Oat ile > brid fu ; j sprpn iilh ace at datin & Auant Syzoralel ofl, Aumeltng prey Gol pscrpilals os Cparatily bane os 8) caeayhiy 2 anal tie by prouiailel is lain out oe te thn cbs Cléighd actenaily Or0 erable hala

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