FINAL JEE–MAIN EXAMINATION – JUNE, 2022

(Held On Friday 24 June, 2022)

th
TIME : 9 : 00 AM to 12 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A Official Ans. by NTA (B)
1. If a rocket runs on a fuel (C15 H30) and liquid Allen Ans. (B)
oxygen, the weight of oxygen required and CO2 Sol. Based on “n + l” rule only (B) has pair of electron in
released for every litre of fuel respectively are: degenerate orbitals
(Given: density of the fuel is 0.756 g/mL)
(A) 1188 g and 1296 g (B) 2376 g and 2592 g
3. Match List – I with List - II
(C) 2592g and 2376 g (D) 3429 g and 3142 g
Official Ans. by NTA (C) List – I List – II
Allen Ans. (C) sp3d
(A)  PtCl 4
2
(I)
45
Sol. C15 H30 + O2 15CO2 + 15H2O (B) BrF5 (II) d2sp3
2
Mass of fuel = 0.756 × 1000 g

No. of moles of fuel =

0.756  1000
210
EN (C)

(D)
PCl5

Co  NH 3  
3
(III)

(IV)
dsp2

sp3d2
 6
0.756  1000 45
Wt. of oxygen =   32 =2592g (A) (A)(II), (B)(IV), (C)(I), (D)(III)
210 2
0.756  1000
LL
(B) (A)(III), (B)(IV), (C)(I), (D)(II)
Wt of CO2 =  15  44 = 2376 g
210
(C) (A)(III), (B)(I), (C)(IV), (D)(II)

2. Consider the following pairs of electrons (D) (A)(II), (B)(I), (C)(IV), (D)(III)
1
Official Ans. by NTA (B)
A

(A) (a) n = 3, 1 = 1, m1 = 1, ms = +
2
1 Allen Ans. (B)
(b) n = 3, 1 = 2, m1 = 1, ms = +
2 Sol. Answer (B)
1
(B) (a) n = 3, 1 = 2, m1 = – 2, ms = – List – I List – II
2
1 (A)  PtCl  2
(III) dsp2
(b) n = 3, 1 = 2, m1 = –1, ms = – 4
2
1 (B) BrF5 (IV) sp3d2
(C) (a) n = 4, 1 = 2, m1 = 2, ms = +
2
(C) PCl5 (I) sp3d
1
(b) n = 3, 1 = 2, m1 = 2, ms = +
2
(D) Co  NH 3  
3 (II) d2sp3
The pairs of electron present in degenerate orbitals  6

is/are:
(A) Only A
(B) Only B
(C) Only C
(D) (B) and (C)

1
4. For a reaction at equilibrium 1
P 2  PB
1 K  c
A(g) B(g)  C(g) PA
2
3 1
the relation between dissociation constant (K),  2 p2
K 1
degree of dissociation () and equilibrium pressure
 2    2 1   
(p) is given by :
5. Given below are two statements :
1 3
 p 2 2 Statement I : Emulsions of oil in water are unstable
(A) K  1
 3  and sometimes they separate into two layers on
1   
2
 1  2 
standing.
3 1 Statement II :For stabilisation of an emulsion,
 2 p2
(B) K  1 excess of electrolyte is added.
 2    2 1    In the light of the above statements, choose the
3
most appropriate answer from the options
( p) 2
(C) K  1 given below :
 3 2
 1  2  1    EN (A) Both Statement I and Statement II are correct.

3
(B) Both Statement I and Statement II are incorrect.
( p) 2
(C) Statement I is correct but Statement II is
(D) K  1
1   1    2 incorrect.

Official Ans. by NTA (B ) (D) Statement I is incorrect but Statement II is

correct.
LL
Allen Ans. (B)
1 Official Ans. by NTA (C)
Sol. A(g) B(g) + C (g)
2 Allen Ans. (C)
Initial : Pi 0 0 Sol. Statement I : Fact
A

 Statement II: The principle emulsifying agents for

At eq.: Pi (1  ) Pi . Pi
2 O/W emulsions are proteins, gums natural and
Now, equilibrium pressure (p) , synthetic soaps etc…

  6. Given below are the oxides:

P = Pi ×  1  
 2 Na 2 O,As2 O3 ,N2 O, NO and Cl2O7
  Number of amphoteric oxides is:
 1  
 PA   P (A) 0 (B) 1

1 
 2 (C) 2 (D) 3
Official Ans. by NTA (B)
 
   Allen Ans. (B)
PB   P

 1   Sol. Na2O = Basic As2O3 = Amphoteric
 2
N2O = Neutral NO = Neutral
  
Cl2O7 = Acidic
 
PC   2  P

1 
 2

2
7. Match List – I with List – II Choose the most appropriate answer from the
List - I List - II options given below:
(A) Sphalerite (I) FeCO3 (A) (A) and (C) only (B) (A), (C) and (D) only
(B) Calamine (II) PbS (C) (B) and (C) only (D) (A) and (C) only
(C) Galena (III) ZnCO3 Official Ans. by NTA (A)
(D) Siderite (IV) ZnS Allen Ans. (A)
Choose the most appropriate answer from the Sol. (A) Both LiCl and MgCl2 are soluble in ethanol
options given below: (B) Li and Mg do not form superoxide
(A) (A) - (IV), (B) – (III), (C) – (II), (D) – (I) (C) LiF has high lattice energy
(B) (A) - (IV), (B) – (I), (C) – (II), (D) – (III) (D) Li2O is least soluble in water than other alkali
(C) (A) - (II), (B) – (III), (C) – (I), (D) – (IV) metal oxides
(D) (A) - (III), (B) – (IV), (C) – (II), (D) – (I) 10. Identify the correct statement for B2H6 from those
Official Ans. by NTA (A) given below.
Allen Ans. (A) (A) In B2H6, all B-H bonds are equivalent.
Sol. (B) In B2H6 there are four 3-centre-2-electron

(A)
List - I
Sphalerite (IV) ZnS
List - II
EN bonds.
(C) B2H6 is a Lewis acid.
(D) B2H6 can be synthesized form both BF3 and
(B) Calamine (III) ZnCO3 NaBH4.
(C) Galena (II) PbS (E) B2H6 is a planar molecule.
(D) Siderite (I) FeCO3 Choose the most appropriate answer from the
LL
options given below :
(A) (A) and (E) only (B) (B), (C) and (E) only
8. The highest industrial consumption of molecular (C) (C) and (D) only (D) (C) and (E) only
hydrogen is to produce compounds of element: Official Ans. by NTA (C)
(A) Carbon (B) Nitrogen Allen Ans. (C)
A

(C) Oxygen (D) Chlorine

Official Ans. by NTA (B)
Allen Ans. (B)
Sol. (A) (B)
Sol. Nitrogen . Around 55% of hydrogen around would
Two 3 centre – 2 – electron bonds
goes to ammonia production
(C) B2 H6 is e– deficient species
(E) B2H6 is non – Planar molecule
9. Which of the following statements are correct ?
(D) BF3 + LiAlH4 2B2H6 + 3LiF + 3AlF3
(A) Both LiCl and MgCl2 are soluble in ethanol.
NaBH4 + I2 B2H6 + 2NaI + H2
(B) The oxides Li2O and MgO combine with
11. The most stable trihalide of nitrogen is:
excess of oxygen to give superoxide.
(A) NF3 (B) NCl3
(C) LiF is less soluble in water than other alkali
(C) NBr3 (D) NI3
metal fluorides. Official Ans. by NTA (A)
(D) Li2O is more soluble in water than other alkali Allen Ans. (A)
metal oxides.

3
Sol. Order of stability: - Statement II : The solubility of monocarboxylic
NF3  NCl3  NBr3  NI3 acids in water decreases with increase in molar
mass.
12. Which one of the following elemental forms is not
Choose the most appropriate option:
present in the enamel of the teeth?
(A) Both Statement I and Statement II are correct.
(A) Ca2+ (B) P3+
(B) Both Statement I and Statement II are incorrect.
(C) F– (D) P5+ (C) Statement I is correct but Statement II is
incorrect.
Official Ans. by NTA (B )
(D) Statement I is incorrect but Statement II is
Allen Ans. (B) correct.
Official Ans. by NTA (A)
Sol. Calcium and phosphate are the major
Allen Ans. (A)
components of teeth enamel
Sol. I . Better packing efficiency of monocarboxylic
13. In the given reactions sequence, the major product
acids with even number of carbon atoms results in
„C‟ is :
higher M.P
II. As molar mass increases hydrophobic part size
increase hence solubility decreases.
(A) (B)
EN 15. Which of the following is an example of
conjugated diketone?
(C) (D)
Official Ans. by NTA (B)
(A)
LL
Allen Ans. (B)
Sol. C8 H10 DU = 9 –5 = 4
Br CH3
CH3 CH3
HNO3 Br2
(B)
A

H2SO4  B
NO2
NO2

A alc. KOH (C)

CH2

C
NO2
(D)

14. Two statements are given below :

Official Ans. by NTA (C)
Statement I: The melting point of monocarboxylic
acid with even number of carbon atoms
Allen Ans. (C)
is higher than that of with odd number of carbon
atoms acid immediately Sol. is a conjugated diketone
below and above it in the series.

4
16. Sol. Factual
18. A polysaccharide 'X' on boiling with dil H2SO4 at
393 K under 2-3 atm pressure yields 'Y'.
'Y' on treatment with bromine water gives gluconic
acid. 'X' contains -glycosidic linkages only.

The major product of the above reaction is Compound 'X' is :

(A) starch (B) cellulose
(C) amylose (D) amylopectin
Official Ans. by NTA (B)
(A) (B)
Allen Ans. (B)
Sol. Cellulose contains  – glycosidic linkages only
19. Which of the following is not a broad spectrum
antibiotic?
(A) Vancomycin (B) Ampicillin
(C) Ofloxacin (D) Penicillin G
(C) (D) Official Ans. by NTA ( D)
EN Allen Ans. (D)
Sol. Penicillin G following is a narrow spectrum
Official Ans. by NTA (D) antibiotic
Allen Ans. (D) 20. During the qualitative analysis of salt with cation
y2+ , addition of a reagent (X) to alkaline solution
Sol.
LL
of the salt gives a bright red precipitate. The
CH3 CH3 CH3
O O
-
O
reagent (X) and the cation (y2+) present
NaCN OH
O respectively are:
(A) Dimethylglyoxime and Ni2+
HC
Br CN CN
(B) Dimethylglyoxime and Co2+
A

(C) Nessler‟s reagent and Hg2+

(D) Nessler‟s reagent and Ni2+
CH 3
CH3 O
O Official Ans. by NTA (A)
H2 /Ni Allen Ans. (A)
NH2 CN
Sol. Ni2+ + DMG– [Ni (DMG)2]
O
OH (Bright red precipitate)
17. Which of the following is an example of polyester? SECTION-B
(A) Butadiene-styrene copolymer 1. Atoms of element X form hcp lattice and those of
(B) Melamine polymer 2
element Y occupy of its tetrahedral voids. The
(C) Neoprene 3
(D) Poly--hydroxybutyrate-co--hydroxy valerate percentage of element X in the lattice is_________
Official Ans. by NTA (D) (Nearest integer)
Allen Ans. (D) Official Ans. by NTA (43 )
Allen Ans. (43)

5
 2 is 0.576 V at 298 K. The pH of the solution is ___.
Sol. X6 Y 268
3 (Nearest integer)
6 Official Ans. by NTA (5 )
%X=  100 = 42.8 43%
14
Allen Ans. (5 )
2. 2O3 (g) 3O2 (g)
Anode : H 2  2H   2e –
At 300 K, ozone is fifty percent dissociated. The Sol. Cathode : Cu2   2e   Cu
standard free energy change at this
temperature and 1 atm pressure is (–) __J mol –1 Cu2   H 2  2H   Cu
(Nearest integer) 2
0.06 H  
[Given: ln 1.35 = 0.3 and R = 8.3 J K–1 mol–1] Ecell = E 0
cell  log  2
Official Ans. by NTA (747 ) 2 Cu 
Allen Ans. ( 747)
 H   2 
0.06  
Sol. 2O3 3O2 (g) 0.576 = 0.34 – log    
2   0.01

2 3

5 5 
+ 3.93 – log(H )  log0.1  pH  4.93 ~ 5
PO32
kp  EN 5. The rate constants for decomposition of
PO23
acetaldehyde have been measured over the
k p  1.35 temperature range 700 –1000 K. The data has been
G  –RT ln k p 10 3
analysed by plotting In k vs graph.The value of
T
 –8.3  300  ln 1.35
activation energy for the reaction is___ kJ mol–1.
LL

= –747 J/mol
(Nearest integer) (Given : R = 8.31 J K–1 mol–1)
3. The osmotic pressure of blood is 7.47 bar at 300 K.
To inject glucose to a patient intravenously, it has
to be isotonic with blood. The concentration of
A

glucose solution in gL–1 is _____(Molar mass of

glucose = 180 g mol–1
R = 0.083 L bar K–1 mol–1) (Nearest integer) Official Ans. by NTA (154 )
Official Ans. by NTA (54 ) Allen Ans. (154 )
Allen Ans. (54 )
Sol.   C.R.T Ea 3
 Ea 
Sol. ln k = ln A – 3
 103  nA  10   103 RT 
7.47= C × 0.083 × 300 10 RT T  

C = 0.3 M From the graph

= 0.3 ×180 gL–1  Ea
 18.5
= 54 gL–1 10 3  R

4. The cell potential for the following cell Ea = 153.735 kJ/mol

~154
Pt | H2 (g) | H (aq) || Cu 2 (0.01M) | Cu(s)
6. The difference in oxidation state of chromium in
chromate and dichromate salts is _______

6
 Official Ans. by NTA (0 ) Official Ans. by NTA (3)
Allen Ans. (0 ) Allen Ans. (3)
6 6 Sol.
Sol. Cr O24 ,Cr 2 O27 difference is zero

7. In the cobalt-carbonyl complex: [Co2(CO)8],

number of Co-Co bonds is "X" and terminal
CO ligands is "Y". X + Y =____

Official Ans. by NTA ( 7)

Allen Ans. (7 )
10. The major product 'A' of the following given
Sol.
reaction has _____ sp2 hybridized carbon atoms.
2,7 – Dimethyl1 – 2, 6 – octadiene


H
 A
Mojor Pr oduct

X=1
Official Ans. by NTA (2)
Y=6
8. A 0.166 g sample of an organic compound was
EN Allen Ans. (2)
Sol. Answer (2)
digested with cone. H2SO4 and then distilled
with NaOH. The ammonia gas evolved was passed
+
through 50.0 mL of 0.5 N H2SO4. The H
LL

used acid required 30.0 mL of 0.25 N NaOH for

+
complete neutralization. The mass percentage
Internal
of nitrogen in the organic compound is____. attack

Official Ans. by NTA ( 63) Me

A

H C
Allen Ans. (Bonus) Me
Me Me
Sol. meq of NaOH used = 30 ×0.25 +
–H
meq of H2SO4 taken = 50 × 0.5
meq of H2SO4 used Me
C
 = 50 × 0.25 ×30 ×0.25 = 17.5 m mol of NH3 Me
17.5  10 3  14 Me Me
%N=  100  147.59%
0.166
(Not possible)
9. Number of electrophilic centre in the given
compound is ____

7
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Friday 24th June, 2022) TIME : 3 : 00 PM to 6 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A 3. The correct order of bound orders of C2– 2–
2 , N 2 and

1. 120 of an organic compound that contains only O2–

2 is, respectively.

carbon and hydrogen gives 330g of CO2 and 270g

2  N2  O2
(A) C2– 2  N 2  C2
2– 2–
(B) O2– 2– 2–

of water on complete combustion. The percentage

2  O2  N 2
(C) C2– 2  C2  O2
2– 2–
of carbon and hydrogen, respectively are. (D) N2– 2– 2–

(A) 25 and 75 (B) 40 and 60 Official Ans. by NTA (B)

(C) 60 and 40 (D) 75 and 25 Allen Ans. (B)
Official Ans. by NTA (D) Sol. Species Bond order
Allen Ans. (D) C2– 3
2
Sol. Given mass of organic compound = 120
N2–
2 2
mass of CO2(g) = 330 g
O2– 1
mass of H2O () = 270 g EN 2

mass of carbon = n CO2  12 4. At 25°C and 1 atm pressure, the enthalpies of

combustion are as given below:
330
=  12  90g
44 Substance H2 C(graphite) C2H6(g)
90 C H –286.0 –394.0 –1560.0
% of carbon =  100  75%
LL
120
kJmol –1
mass of hydrogen = n H2 O  2
The enthalpy of formation of ethane is
270 (A) +54.0 kJ mol–1 (B) –68.0 kJ mol–1
=  2  30g
18 (C) –86.0 kJ mol –1
(D) +97.0 kJ mol–1
A

Official Ans. by NTA (C)

30
% of hydrogen =  100  25% Allen Ans. (C)
120
7
2. The energy of one mole of photons of radiation of Sol. C2 H 6 (g)  O2 (g)  2CO2 (g)  3H 2 O( )
2
wavelength 300 nm is
CH(C2H6) = 2fH CO2(g) + 3fH(H2O,)
(Given : h = 6.63 × 10–34 Js, NA = 6.02 × 1023mol–1,
c = 3 × 108 ms–1) – fH(C2H6,g)
–1560 = 2(–394) + 3 (–286) – fH(C2H6,g)
(A) 235 kJ mol–1 (B) 325 kJ mol–1
fH(C2H6,g) = –86 kJ/mole
(C) 399 kJ mol–1 (D) 435 kJ mol–1
5. For a first order reaction, the time required for
Official Ans. by NTA (C)
completion of 90% reaction is 'x' times the half life
Allen Ans. (C)
of the reaction. The value of 'x' is
hc
Sol. Energy of one mole of photons =  NA (Given: ln 10 = 2.303 and log 2 = 0.3010)

(A) 1.12 (B) 2.43
6.63  10 –34  3  108
  6.02  10 23 (C) 3.32 (D) 33.31
300  10 –9
Official Ans. by NTA (C)
= 399.13 × 103 Joule/mole
Allen Ans. (C)
= 399 kJ / mole

1
Sol. Given t0.90 = t 0.90  xt1/2 Sol. Sodium hydroxide is generally prepared

First order rate constant commercially by electrolysis of sodium chloride in

ln 2 1 A0 castner Kellner cell.

K  ln
t1/2 xt1/2 A – A  90 at cathode : Na  e – 
Hg
 Na – amalgum
0 0
100
1
ln 2 ln10 Anode : Cl – 
 Cl2  e –
 2
t1/2 xt1/2
The Na–amalgam is treated with water to give
ln10 2.303
x   3.32 sodium hydroxide and hydrogen gas :
ln 2 2.303  0.3010

6. Metals generally melt at very high temperature. 2Na (amalgam) + H2O  2NaOH + H2 + 2Hg
Amongst the following, the metal with the highest 9. Which one of the following compounds is used as
melting point will be
a chemical in certain type of fire extinguishers?
(A) Hg (B) Ag
(A) Baking Soda (B) Soda ash
(C) Ga (D) Cs
(C) Washing Soda (D) Caustic Soda
Official Ans. by NTA (B) EN
Allen Ans. (B) Official Ans. by NTA (A)

Sol. Hg, Ga, Cs are liquid near room temperature But Allen Ans. (A)
Ag(silver) is solid.
Sol. Sodium hydrogencarbonate (Baking soda),
7. Which of the following chemical reactions NaHCO3 is used in the fire extinguishers.
LL
represents Hall-Heroult Process?
10. PCl5 is well known. but NCl5 is not. Because.
(A) Cr2O3 + 2Al  Al2O3 + 2Cr
(A) nitrogen is less reactive than phosphorous.
(B) 2Al2O3 + 3C  4Al + 3CO2
(B) nitrogen doesn't have d-orbitals in its valence
(C) FeO + CO  Fe + CO2
A

shell.
(D) 2 Au  CN 2   Zn(s)  2Au(s)  Zn  CN4  2–
–

 aq 
(C) catenation tendency is weaker in nitrogen than
Official Ans. by NTA (B)
phosphorous.
Allen Ans. (B)
Sol. Hall Heroult process is the major industrial process (D) size of phosphorous is larger than nitrogen.

for extraction of aluminium. Official Ans. by NTA (B)

8. In the industrial production of which of the Allen Ans. (B)

following, molecular hydrogen is obtained as a
Sol. PCl5 forms five bonds by using the d–orbitals to
byproduct?
"expand the octet". But NCl5 does not exist
(A) NaOH (B) NaCl
because there are no d–orbitals in the valence shell
(C)Na metal (D) Na2CO3
(2nd shell). Therefore there is no way to expand the
Official Ans. by NTA (A)
octet.
Allen Ans. (A)

2
11. Transition metal complex with highest value of Sol. Carbocation is stabilised by resonance with lone

crystal field splitting (0) will be pairs on oxygen atom and +H effect of 2a

3 3
(A) Cr  H 2 O 6  (B)  Mo  H 2 O 6  hydrogens
O
H H
3 3
(C)  Fe  H 2 O 6  (D) Os  H 2 O 6 
B>A>C

Official Ans. by NTA (D)

14. Given below are two statements.
Allen Ans. (D)
Statement I : The presence of weaker - bonds
Sol. CFSE of octahedral complexes with water is make alkenes less stable than alkanes.
greater for 5d series metal centre ion as compared Statement II : The strength of the double bond is
to 3d and 4d series metal centre. greater than that of carbon-carbon single bond.
In the light of the above statements, choose the
12. Some gases are responsible for heating of correct answer from the options given below.
atmosphere (green house effect). Identify from the (A) Both Statement I and Statement II are correct.
following the gaseous species which does not
cause it.
EN (B) Both Statement I and Statement II are
incorrect.
(C) Statement I is correct but Statement II is
(A) CH4 (B) O3
incorrect.
(C) H2O (D)N2
(D) Statement I is incorrect but Statement II is
LL

Official Ans. by NTA (D) correct.

Allen Ans. (D) Official Ans. by NTA (A)

Allen Ans. (A)
Sol. CH4, O3 and H2O causes global warming in
A

Tropospheric level.
15. Which of the following reagents/ reactions will
N2 does not cause global warming.
convert 'A' to 'B'?
13. Arrange the following carbocations in decreasing CH2 CHO
order of stability.

 O O H3C H3C
 (A) (B)
 (A) PCC oxidation
A B C
(B) Ozonolysis
(A) A > C > B (B) A > B > C (C) BH3,H2O2 / –OH followed by PCC oxidation
(C) C > B > A (D) C > A > B (D)HBr, hydrolysis followed by oxidation by
Official Ans. by NTA (A) K2Cr2O7 .

Allen Ans. (A) Official Ans. by NTA (C)

Allen Ans. (C)

3
Sol. BH3, H2O2/–OH followed by PCC oxidation. Sol.

CH3–CH2–CH2–OH CH3–CH2–CH2–CH2NH2
CH2 CH2–OH Propanol
BH3,H2O2/OH
– n-Butanamine
Hydroboration SOCl2
oxidation H2/Ni, Hg/C2H5OH
Antimarkonikov PCC CH3–CH2–CH2–Cl KCN CH3–CH2–CH2–CN
addtion oxidation
CHO
18. Which of the following is not an example of a
condensation polymer?
16. Hex-4-ene-2-ol on treatment with PCC gives 'A'. (A) Nylon 6,6 (B) Decron
'A' on reaction with sodium hypoiodite gives 'B',
(C) Buna-N (D) Silicone
which on further heating with soda lime gives 'C'.
Official Ans. by NTA (C)
The compound 'C' is
Allen Ans. (C)
(A) 2- pentene (B) proponaldehyde
Sol. Buna-N is an addition copolymer of 1,3-butadiene
(C) 2-butene (D) 4-methylpent-2-ene
EN and acrylonitrile.
Official Ans. by NTA (C) CH2=CH–CH=CH2 + CH2=CH
Allen Ans. (C) CN
[–CH3–CH=CH–CH2–CH2–CH–]n
CH3–CH=CH–CH2–CH–CH3 Buna-N
Sol. CN
OH
PCC
LL

19. The structure shown below is of which

CH3–CH=CH–CH2–CH–CH3 (A)
well-known drug molecule?
NaOI O
H
CH3–CH=CH–CH2–COOH + CHI3 CN
A

(B) N
N
NaOH+CaO –CO2
N S
CH3–CH=CH–CH3 N NHCH3
H
(C)
But-2-ene (A) Ranitidine (B) Seldane

17. The conversion of propan-1-ol to n-butylamine (C) Cimetidine (D) Codeine

involves the sequential addition of reagents. The Official Ans. by NTA (C)

correct sequential order of reagents is. Allen Ans. (C)

20. In the flame test of a mixture of salts, a green
(A)(i) SOCl2 (ii) KCN (iii) H2/Ni,Na(Hg)/C2H5OH
flame with blue centre was observed. Which one of
(B) (i) HCl (ii) H2/Ni, Na(Hg)/C2H5OH
the following cations may be present?
(C) (i) SOCl2 (ii) KCN (iii) CH3NH2 (A) Cu2+ (B) Sr2+
(D) (i) HCl (ii) CH3NH2 (C) Ba2+ (D) Ca2+

Official Ans. by NTA (A) Official Ans. by NTA (A)

Allen Ans. (A)
Allen Ans. (A)
4
Sol. Ion Colour of the flame P  K H X CO2
+2
(A) Cu green flame with blue centre n CO2
(B) Sr 2+
Crimson Red 0.835 = 1.67 × 103 ×
n CO2  n H2 O
2+
(C) Ba Apple green w CO2 / 44
0.835 = 1.67 × 103 ×
SECTION-B 1000
1. At 300 K, a sample of 3.0 g of gas A occupies the 18
same volume as 0.2 g of hydrogen at 200 K at the w CO2 = 1.2222g = 1222.2 × 10–3g
same pressure. The molar mass of gas A is____ g
3. PCl5 dissociates as
mol–1 (nearest integer) Assume that the behaviour
of gases as ideal. (Given: The molar mass of PCl 5  g  PCl3  g   Cl 2  g 
hydrogen (H2) gas is 2.0 g mol–1)
5 moles of PCl5 are placed in a 200 litre vessel
Official Ans. by NTA (45) which contains 2 moles of N2 and is maintained at
Allen Ans. ( 45) 600 K. The equilibrium pressure is 2.46 atm. The
Sol. Given : Ideal gas A and H2 gas at same pressure equilibrium constant Kp for the dissociation of PCl5
is_____ × 10–3. (nearest integer)
and volume.
(Given: R = 0.082 L atm K–1 mol–1 : Assume ideal
From ideal gas equation pv = nRT
n1T1 = n2T2
EN gas behaviour)

3 0.2 Official Ans. by NTA (1107)

 300   200
GMMof A 2
Allen Ans. (1107 )
GMM of A = 45 g/mole Sol. Given : 2 mole of N2 gas was present as inert gas.
LL

2. A company dissolves 'X' amount of CO2 at 298 K Equilibrium pressure = 2.46 atm
in 1 litre of water to prepare soda water PCl 5 (g) PCl3  g   C 2 (g)
–3
X =____ × 10 g. (nearest integer) t=0 5 0 0
m
(Given: partial pressure of CO2 at 298 K= 0.835 t = Eq 5–x x x
A

bar. from ideal gas equation

PV = nRT
Henry's law constant for CO2 at 298 K = 1.67 kbar.
2.46 × 200 = (5 – x + x + x + 2) × 0.082 × 600
Atomic mass of H,C and O is 1, 12 and 6 g mol–1, x=3
respectively) n PCl3  n Cl2 P 
KP    total 
Official Ans. by NTA (1221) n PCl5  n total 
Allen Ans. (1222 & 1223) 3  3 2.46
  1.107  1107  10 –3
Sol. From Henry law 2 10
P  K H X CO2 4. The resistance of conductivity cell containing

w CO2 / 44 0.01 M KCl solution at 298 K is 1750 . If the

0.835 = 1.67 × 103 × 1.67  10 3 
w CO2 1000 conductively of 0.01 M KCl solution at 298 K is

44 18 0.152 × 10–3 S cm–1, then the cell constant of the
w CO2  1.2228g  1222.8  10 –3 g conductivity cell is_______× 10–3 cm–1.

Or Official Ans. by NTA (266)

Allen Ans. (266 )

5
 
4  3H 
 2MnO4–  MnO2  2H2 O
1 3MnO2–
Sol. K  cell cons tan t
R
O.S. of Mn in MnO4– = +7
1
0.152 × 10–3 = cell constant O.S. of Mn in MnO2 = +4
1750
cell constant = 266 × 10–3 difference = 3

5. When 200 mL of 0.2 M acetic acid is shaken with 8. 0.2 g of an organic compound was subjected to

0.6 g of wood charcoal, the final concentration of estimation of nitrogen by Dumas method in which

acetic after adsorption is 0.1 M. The mass of acetic volume of N2 evolved (at STP) was found to be

acid adsorbed per garm of carbon is_____ g. 22.400 mL. The percentage of nitrogen in the

Official Ans. by NTA (2) compound is____.[nearest integer]

Allen Ans. (2 ) (Given: Molar mass of N2 is 28 mol–1. Molar

Sol. weight of wood charcoal = 0.6 g volume of N2 at STP : 22.4 L)

M1V1 – M 2 V2 Official Ans. by NTA (14)

Mass of acetic acid adsorbed =  60
1000 Allen Ans. (14 )
Sol. weight of organic compound = 0.2g
0.2  200 – 0.1  200
=  60 22.4  10 –3
1000 EN mass of N2(g) evolved =  28
22.4
= 1.2 g
= 28 × 10–3g
Mass of acetic acid adsorbed per gram of 28  10 –3
% of N   100  14
1.2 0.2
carbon = 2
0.6 Cl
6. (a) Baryte, (b) Galena, (c) Zinc blende and
LL
9.
(d) Copper pyrites. How many of these minerals NaOH P
are sulphide based? H2O (Major Product)
Official Ans. by NTA (3)
Consider the above reaction. The number of 
Allen Ans. (3)
A

electrons present in the product 'P' is____.

Sol.
Official Ans. by NTA (2)
(1) Baryte : BaSO4
Allen Ans. (2)
(2) Galena : PbS
Sol. Number of  electron = 2
(3) Zinc blende : ZnS sulphide (S2–) Cl OH
ores NaOH
(4) Copper pyrite : CuFeS2
H2O

7. Manganese (VI) has ability to disproportionate in

acidic solution. The difference in oxidation states 10. In alanylglycylleucylalanylvaline, the number of
peptide linkages is______.
of two ions it forms in acidic solution is______
Official Ans. by NTA (4)
Official Ans. by NTA (3) Allen Ans. (4)
Sol. There are Five amino acids and four peptide
Allen Ans. (3) linkages.
Sol. MnO2–
4 disproportionates in a neutral or acidic

solution to give MnO4– and Mn+4

6
 Final JEE-Main Exam June, 2022/25-06-2022/Morning Session

FINAL JEE–MAIN EXAMINATION – JUNE, 2022

(Held On Saturday 25th June, 2022) TIME : 9 : 00 AM to 12 : 00 PM
CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 4. Leaching of gold with dilute aqueous solution of
1. Bonding in which of the following diatomic NaCN in presence of oxygen gives complex [A],
molecule(s) become(s) stronger, on the basis of which on reaction with zinc forms the elemental
MO Theory, by removal of an electron ? gold and another complex [B]. [A] and [B],
(A) NO (B) N2 respectively are :-
(C) O2 (D) C2 (A) [Au(CN)4]– and [Zn(CN)2(OH)2]2–
(E) B2 (B) [Au(CN)2]– and [Zn(OH)4]2–
Choose the most appropriate answer from the (C) [Au(CN)2]– and [Zn(CN)4]2–
options given below :- (D) [Au(CN)4]2– and [Zn(CN)6]4–
(A) (A), (B), (C) only (B) (B), (C), (E) only Ans. (C)
(C) (A), (C) only (D) (D) only Sol. Au + NaCN ® Na[Au(CN)2]
Ans. (C)
Sol. Bond strength µ Bond order

2.
removal of electron from antibonding MO
increases B.O.
NO & O2 has valence e in p *orbital.
_
EN
Incorrect statement for Tyndall effect is :-
5.
Zn + Na[Au(CN)2] ® Na2[Zn(CN)4] + Au
Number of electron deficient molecules among
the following
PH3, B2H6, CCl4, NH3, LiH and BCl3 is
(A) 0
(C) 2
(B) 1
(D) 3
(A) The refractive indices of the dispersed phase Ans. (C)
and the dispersion medium differ greatly Sol. Electron deficient species have less than 8
LL
in magnitude. electrons (or two electrons for H) in their
(B) The diameter of the dispersed particles is valence (incomplete octet)
much smaller than the wavelength of the B2H6, BCl3 have incomplete octet.
light used.
6. Which one of the following alkaline earth metal
(C) During projection of movies in the cinemas ions has the highest ionic mobility in its
hall, Tyndall effect is noticed. aqueous solution?
(D) It is used to distinguish a true solution from
A

(A) Be2+ (B) Mg2+

a colloidal solution.
(C) Ca2+ (D) Sr2+
Ans. (B)
Ans. (D)
Sol. The diameter of dispersed particle should be
Sol. Highest ionic mobility corresponds to lowest
somewhat below or near the wavelength of
extent of hydration and highest size of
light.
gaseous ion.
3. The pair, in which ions are isoelectronic with Al3+
Hence Sr 2+ has the highest ionic mobility
is :-
in its aqueous solution
(A) Br– and Be2+ (B) Cl– and Li+
7. White precipitate of AgCl dissolves in aqueous
(C) S2– and K+ (D) O2– and Mg2+ ammonia solution due to formation of :
Ans. (D) (A) [Ag(NH3)4]Cl2 (B) [Ag(Cl)2(NH3)2]
Sol. Isoelectronic species have same no. of electrons (C) [Ag(NH3)2]Cl (D) [Ag(NH3)Cl]Cl
Al , O , Mg all have 10 electrons.
+3 2- +2
Ans. ( C )
Sol. AgCl + 2NH3 ® [Ag(NH3)2]+Cl–

1
Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
soluble Sol.
8. Cerium (IV) has a noble gas configuration. : OH: OH:
Which of the following is correct statement OH NO2
about it? dil +
(A) It will not prefer to undergo redox HNO3
reactions.
NO2
( B ) It will prefer to gain electron and act as (ortho) (para)
an oxidizing agent
Para product has higher boiling point than
( C ) It will prefer to give away an electron
ortho as intermolecular H-bond is possible
and behave as reducing agent
in former, where as intramolecular H-bond
( D )It acts as both, oxidizing and reducing
agent. is possible in ortho product.

Ans. (B) Steam distillation can separate them as ortho

Sol. Cerium exists in two different oxidation state product is steam volatile.
+3, +4
12.

9.
Ce +4 + e – ® Ce 3+
Ce +3 + 3e – ® Ce

& accepts electron.

Among the following, which is the strongest
oxidizing agent ?
(A) Mn3+ (B) Fe3+
EN
E 0 = + 1.61 V
E 0 = –2.336 V
It shows Ce+4 acts as a strong oxidising agent
In the following structures, which one is having
staggered conformation with maximum dihedral
angle?

H
CH3
CH3
CH3 H

(C) Ti3+ (D) Cr3+ (A) H H (B)

LL
H H
Ans. (A) H CH3
H
Sol. Strongest oxidising agent have highest
reduction potential value

E 0Mn +3
/ Mn +2
= 1.51V (highest) CH3
CH3 CH
H H 3
10. The eutrophication of water body results in :
(A) loss of Biodiversity
A

(C) H H (D)
(B) breakdown of organic matter H H
(C) increase in biodiversity CH3 H H
(D) decrease in BOD.
Ans. (A) Ans. (C)
Sol. Eutrophication of water body results in loss of
Biodiversity. S o l . Dihedral angle : It’s the angle b/w 2
specified groups (–CH 3 here)
11. Phenol on reaction with dilute nitric acid, gives
two products. Which method will be most
Staggered form is Given in option (C) &
effective for large scale separation ?
the angle is 1800
(A) Chromatographic separation
13. The products formed in the following reaction.
(B) Fractional Crystallisation
(C) Steam distillation
(D) Sublimation
Ans. ( C )
2
 Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
CH 3
CH3 H

– –
C=CH2+H–C–CH3 ? is :
–
CH3 –
CH3 CH3
CH 3 + –
CH3– C – Cl + K O – C – CH3 ? is
(A) CH3 CH–CH –CH –CH CH3 CH3 CH3
CH3 2 2
CH3
(A) t-Butyl ethyl ether
CH3 (B) 2,2-Dimethyl butane
(B) CH 3
CH 3 C–CH2–C–CH3 (C) 2-Methyl pent-1-ene
H CH3 (D) 2-Methyl prop-1-ene
Ans. (D)
CH3
(C) CH3–CH–CH–CH Sol. We have been given a bulky base, hence
CH3
CH3 CH3 elimination will take place & not substitution.

CH3 CH3 CH3 CH3

_

Ans. (B)

Sol.
(D) CH3– C – C – CH3
CH3 CH3

+ H+ ¾¾
® +
EN 16.
CH3 C

CH2 H
Cl + t-BuO CH3 C

The intermediate X, in the reaction

OH
2-methyl
prop-1-ene
[D]
CH2

+ CHCl3+Aq.NaOH + [X]
+
LL
+ (1) NaOH
+
(2) H
+ H + OH
+ +
CHO is :
14. The IUPAC name of ethylidene chloride is :-
(A) 1-Chloroethene
OH OH
A

(B) 1-Chloroethyne CCl3 CHCl2

(A) (B)
(C) 1,2-Dichloroethane
(D) 1,1-Dichloroethane
Ans. (D)
– + – +
Cl O Na O Na
Sol. CHCl2 CCl3
(C) (D)
Cl

“1, 1-Dichloroethane is Ethylidene chloride”

15. The major product in the reaction Ans. (C)
Sol. It’s a classic Reimer-Tiemann reaction.

3
Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
_ +
O Na 18. The reaction of R–C– NH2 with bromine and KOH
CHCl2 O
gives RNH2 as the end product. Which one of the
following is the intermediate product formed in
Will be the intermediate formed. this reaction ?
17. In the following reaction :
(A) R–C– NH–Br (B) R–NH–Br
CH3 CH3 H3C CH3
CH C–O–O–H O
+
H (C) R–N=C=O (D) R–C– NBr2
+ O2
H2O
A and B
O
The compounds A and B respectively are :-
NTA Offical Ans. (C)
CH3
Ans. A & C
(A) , CH3COOH Sol. The given reaction is Hoffmann-Bromide
degradation method.
OH

(B)

(C)

(D)
OH

OH
OH
, CH3COOH

, CH3COCH3

OH
EN R
O

O
H

H
_
+ OH ƒ R
O

O
_
NH

Br Br

, CH3COCH3 _
Br .. Br
ƒ R ƒ R N
LL
N
Ans. (C) H _
Sol. Given reaction is cumene-Peroxide method for the
OH
preparation of phenol.
In this reaction
_
+
O-O-H O-OH 2 O :+ OH _ +
R-N=C-OH R-N=C=O R-N-C=O
_
¾¾
®
A

H+
¾¾® O

Proton transfer
H2O
H + H
O: O O
H _
OH
O R N C O RNH2 + CO2
+

Acetone Phenol

4
 Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
19. Using very little soap while washing clothes, does
4 ´ 58.5
not serve the purpose of cleaning of clothes = g
NA
because
(A) soap particles remain floating in water as ions m m
d unit cell = =
(B) the hydrophobic part of soap is not able to V a3
take away grease 4 ´ 58.5
(C) the micelles are not formed due to Þ = 43.1
NA × a 3
concentration of soap, below its CMC value
(D) colloidal structure of soap in water is Þ a 3 = 9.02 ´ 10-24 cm3
completely disturbed.
Ans. (C) Þ a = 2.08 ´ 10-8 cm
Sol. Micelle formation only takes place above CMC.
Þ a = 2.08 ´ 10-10 m
20. Which one of the following is an example of
artificial sweetner ? Also a = 2 ( rNa + rCl
+ - )
(A) Bithional (B) Alitame
(C) Salvarsan
Ans. (B)
EN
(D) Lactose

Sol. Alitame is a second generation dipeptide sweetner

that is 200 times sweeter than sucrose.

SECTION-B
3.
Þ rNa + rCl = 1.04 ´ 10 -10 m
+

\ The answer is 1
-

The longest wavelength of light that can be used

for the ionisation of lithium atom (Li) in its ground
state is x × 10 –8 m. The value of x is
____________. (Nearest Integer)
1. The number of N atoms is 681 g of C7H5N3O6 is (Given : Energy of the electron in the first
x × 1021. The value of x is _____ (NA = 6.02 × shell of the hydrogen atom is –2.2 × 10–18 J;
LL
1023 mol–1) (Nearest Integer) h = 6.63 × 10–34 Js and c = 3 × 108 ms–1)
Ans. 5418
NTA Offical Ans. (4)
Sol. M.M. of C7H5N3O6 is 84 + 5 + 42 + 96 = 227
Allen Ans. (Bonus)
681
nC H N O = =3 Sol. We can not calculate I.E. of lithium atom.
7 5 3 6
227
681 4. The standard entropy change for the reaction
nN = ´ 3 = 9 mol
A

227 4Fe(s) + 3O2(g) ® 2Fe 2O3(s) is –550 JK –1 at

298 K.
no. of N atoms = 9 ´ 6.02 ´ 1023
[Given : The standard enthalpy change for the
= 5418 ´ 10 21 reaction is –165 kJ mol–1]. The temperature in K
at which the reaction attains equilibrium is
\ The answer is 5418.
_________. (Nearest Integer)
2. The distance between Na+ and Cl– ions in solid
Ans. 300
NaCl of density 43.1 g cm–3 is ________ ×
10–10m. (Nearest Integer) Sol. DG = DH - TDS = 0 at equilibrium
(Given : NA = 6.02 × 1023 mol–1) Þ -165 ´ 103 - T ´ ( -505 ) = 0
Ans. 1
Þ T = 300K
Sol. Unit cell formula – Na4Cl4
The answer is 300
Z ´ M.M.
Mass per unit cell = g
NA

5
Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
5. 1 L aqueous solution of H2SO4 contains 0.02 m spontaneous reaction in the cell is x × 10–2V 298
mol H2SO4. 50% of this solution is diluted with K. The value of x is __________ (Nearest
deionized water to give 1 L solution (A). In solution
Integer)
(A), 0.01 m mol of H2SO4 are added. Total m
mols of H 2 SO 4 in the final solution is Ans. 23
____________ × 103 m mols.
NTA Offical Ans. (15) Sol. Fe +3 + I - ¾¾
® I 2 + Fe +2
Cathode anode

Allen Ans. (0)

E 0Cell = E 0cathode - E anode
0
Sol. n H SO in Soln A = 50% of original solution
2 4

= 0.01 m mol. =0.77–0.54

n H SO in Final solution = 0.01 + 0.01
2 4
=0.23
= 0.02 mmol = 23 ´ 10-2 V
= 0.00002 ´ 103 mmol
8. For a given chemical reaction
The answer 0
6.
dissociation of N2O4 into NO2 at 27°C and 1

_________. (Nearest Integer)

EN
The standard free energy change (DG°) for 50%

atm pressure is –x J mol–1. The value of x is

[Given : R = 8.31 J K–1 mol–1, log 1.33 = 0.1239

ln 10 = 2.3]
Ans. 710
g1A + g 2 B ® g 3C + g 4 D

Concentration of C changes from 10 mmol

dm–3 to 20 mmol dm–3 in 10 seconds. Rate of
appearance of D is 1.5 times the rate of
disappearance of B which is twice the rate of
disappearance A. The rate of appearance of D
Sol. N 2O4 ƒ 2NO 2 has been experimentally determined to be 9 mmol
LL
t=0 1 mol dm –3 s –1 . Therefore the rate of reaction is
t=t (1-0.5) mol 0.5 ´ 2 mol ________mmol dm–3 s–1. (Nearest Integer)
= 0.5 mol 1 mol Ans. 1

æ 1 ö
2
Sol. g1A + g 2 B ¾¾
® g 3C + g 4 D
ç 1.5 ´ 1÷
kP = è ø = 1 = 100
æ 0 .5 ö 0.75 75 d [D] -3 d [ B ]
Given : + =
A

ç 1.5 ´ 1÷ dt 2 dt
è ø
= 1.33
-1 d [ B ] + 1 d [ D ]
Þ =
DG 0 = -RTlnk P 2 dt 3 dt

= -8.31 ´ 300 ´ ln (1.33) = -710.45 J / mol d [ B] d [A] 1 d [ B] -d ( A )

- = -2 Þ- =
dt dt 2 dt dt
= –710 J/mol.

7. In a cell, the following reactions take place d [ B]

+ = 9 mmoldm -3s -1
dt
Fe 2+ ® Fe3+ e - E oFe3+ /Fe2+ = 0.77 V
+d [ C] 20 - 10
= = 1mmoldm -3s -1
-
2I ® I 2 + 2e - E oI /I- = 0.54 V dt 10
2

The standard electrode potential for the + d [ C] 1 +d [ D ]

= ´
dt 9 dt
6
 Final JEE-Main Exam June, 2022/25-06-2022/Morning Session

1 10. Number of grams of bromine that will completely

1A + 2B ¾¾
® C + 3D react with 5.0g of pent-1-ene is _______ ×
3
10–2g. (Atomic mass of Br = 80 g/mol) [Nearest
Þ 3A + 6B ¾¾
® C + 9D Integer)
NTA Official Ans. 1136
+d [ C] Allen Ans. 1143
Rate of reaction = = 1 mmol dm -3 s -1
dt
Br
9. If [Cu(H2O)4]2+ absorbs a light of wavelength 600
nm for d–d transition, then the value of octahedral Sol. +Br2 ¾¾
®
crystal field splitting energy for [Cu(H2O)6]2+ will (C5 H10 ) (C5H 10 Br2)
Br
be___________× 10–21 J. (Nearest Integer)
(Given : h = 6.63 × 10–34Js moles of Br2 = moles of C5H10

and c = 3.08 × 108 ms–1) w 5

Þ =
NTA Official Ans. 745 160 70

Ans. 766

Sol. Dt =

=
hc 6.63 ´ 10-34 ´ 3.08 ´ 108
l
=
600 ´ 10-9

6.63 ´ 3.08 ´ 10-17

600
EN Þw=
5 ´ 160

= 11.428 g
70
g

= 1142.8 ´ 10-2 g » 1143 ´ 10-2 g

= 0.034034 ´ 10-17
LL
= 340.34 ´ 10-21 J

9
D0 = Dt
4

9
= ´ 340.34 ´ 10-21
A

= 765.765 ´ 10-21 J

» 766 ´ 10-21 J
Answer = 766

7
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Saturday 25 June, 2022) th
TIME : 3 : 00 PM to 6 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A Official Ans. by NTA (D)
1. The minimum energy that must be possessed by Allen Ans. (D)
photons in order to produce the photoelectric effect Sol. T = i kf  m
with platinum metal is: 0.7 1000
0.2 = i × 1.86 × 
[Given: The threshold frequency of platinum is 1.3 93 42
× 1015 s-1 and h = 6.6 × 10-34 J s.] 0.2  93  6
i=
(A) 3.21 × 10 -14
J (B) 6.24 × 10 -16
J 1.86 100

(C) 8.58 × 10 -19

J (D) 9.76 × 10 -20
J i = 0.60

Official Ans. by NTA (C) 2A A2

Allen Ans. (C) 

Sol. W = hv

2.
= 6.6 × 10–34 × 1.3 × 1015
= 8.58 × 10–19 J
At 25C and 1 atm pressure, the enthalpy of
combustion of benzene (1) and acetylene (g) are
EN 1–α

i=1–α+

i  1

1


2

 0.60
2

2

–3268 kJ mol–1 and –1300 kJ mol-1, respectively. 2

LL
The change in enthalpy for the reaction 
1 – 0.60 =
3 C2H2(g)  C6H6(l), is 2
(A) + 324 kJ mol-1 (B) +632 kJ mol–1 α = 0.80
(C) – 632 kJ mol–1 (D) – 732 kJ mol–1 4. The Ksp for bismuth sulphide (Bi2S3) is
–73 –1
Official Ans. by NTA (C) 1.08 × 10 . The solubility of Bi2S3 in mol L at
Allen Ans. (C) 298 K is
A

Sol. H =HCombustion (Reactant) - HCombustion (A) 1.0 × 10–15 (B) 2.7 × 10–12
(Product) (C) 3.2 × 10–10 (D) 4.2 × 10–8
= 3 × (–1300) – [–3268] Official Ans. by NTA (A)
= – 632 kJ mol–1 Allen Ans. (A)
3. Solute A associates in water. When 0.7 g of solute Sol. Bi 2S3 2Bi 3  3S2
A is dissolved in 42.0 g of water, it depresses the 2s 3s
ksp = (2s)2 (3s)3
freezing point by 0.2°C. The percentage
= 4s2 × 27 (s)3
association of solute A in water, is
–1
= 108 (s)5
[Given : Molar mass of A = 93 g mol . Molal
1.08 1073
depression constant of water is 1.86 K kg mol–1] (s)5 
108
(A) 50 % (B) 60 %
 s = 10–15
(C) 70 % (D) 80 %

1
5. Match List I with List II. In the light of the above statements, choose the
List I List II correct answer from the options given below.
A. Zymase I. Stomach (A) Both Statement I and Statement II are true.
B. Diastase II. Yeast (B) Both Statement I and Statement II are false.
C. Urease III. Malt (C) Statement I is true but Statement II is false.
D. Pepsin IV. Soyabean (D) Statement I is false but Statement II is true.
Choose the correct answer from the options given Official Ans. by NTA (A)
below: Allen Ans. (A)
(A) A-II, B-III, C-I, D-IV Sol. In the electro-refining, impure metal (here blister
(B) A-II, B-III, C-IV, D-I copper) is used as an anode while precious metal
(C) A-III, B-II, C-IV, D-I like Au, Pt get deposited as anode mud.
(D) A-III, B-II, C-I, D-IV 8. Given below are two statements one is labelled as
Official Ans. by NTA (B) Assertion A and the other is labelled as Reason R:
Allen Ans. (B) Assertion A : The amphoteric nature of water is
Sol. Zymase naturally occurs in yeast.

Diastase is found in malt.

Urease is found in soyabean

Pepsin is found in stomach

EN explained by using Lewis acid/base concept.
Reason R : Water acts as an acid with NH3 and as
a base with H2S.
In the light of the above statements choose the
correct answer from the options given below :
(A) Both A and R are true and R is the correct
6. The correct order of electron gain enthalpies of Cl, explanation of A.
LL
F, Te and Po is (B) Both A and R are true but R is NOT the correct
(A) F < Cl < Te < Po (B) Po < Te < F < Cl explanation of A.
(C) Te < Po < Cl < F (D) Cl < F < Te < Po (C) A is true but R is false.
Official Ans. by NTA (B) (D) A is false but R is true.
Allen Ans. (D) Official Ans. by NTA (D)
Sol. As Cl has maximum electron affinity among all Allen Ans. (D)
A

elements. Sol. H 2S H 2O H3O  HS

Acid Base
Element egH (kJ/mol)
F –328 H 2O NH 3 NH 4OH
Acid Base
Cl –349
9. The correct order of reduction potentials of the
Te –190
following pairs is
Po –174
A. Cl2/Cl–
7. Given below are two statements.
B. I2/I–
Statement I: During electrolytic refining, blister
C. Ag+/Ag
copper deposits precious metals
D. Na+/Na
Statement II: In the process of obtaining pure
E. Li+/Li
copper by electrolysis method, copper blister is
Choose the correct answer from the options given
used to make the anode.
below.

2
 (A) A > C > B > D > E Ni2+ : 1s2 2s2 2p6 3s2 3p6 3d8
(B) A > B > C > D > E (3d) (unpaired e– = 2)
(C) A > C > B > E > D Cr2+ : 1s2 2s2 2p6 3s2 3p6 3d4
(D) A > B > C > E > D
(3d) (unpaired e– = 4)
Official Ans. by NTA (A)
Fe2+ : 1s2 2s2 2p6 3s2 3p6 3d6
Allen Ans. (A)
(3d) (unpaired e– = 4)
Sol. ECl /Cl–  1.36V
2
12. Given below are two statements: one is labelled as

E I2 /I –
 0.54 V Assertion A and the other is labelled as Reason R
Assertion A: Polluted water may have a value of
EAg /Ag  0.80V
BOD of the order of 17 ppm.

E Na  /Na
 –2.71V Reason R: BOD is a measure of oxygen required
to oxidise both the biodegradable and non-
ELi /Li  –3.05V
biodegradable organic material in water.
10. The number of bridged oxygen atoms present in
compound B formed from the following reactions
is
Pb(NO3 )2 

A 
B
673 K
 A  PbO  O2
Dimerise
EN In the light of the above statements, choose the
most appropriate answer from the options given
below.
(A) Both A and R are correct and R is the correct
explanation of A.
(A) 0 (B) 1 (B) Both A and R are correct but R is NOT the
LL
(C) 2 (D) 3 correct explanation of A.
Official Ans. by NTA (A) (C) A is correct but R is not correct.
Allen Ans. (A) (D) A is not correct but R is correct.

Pb(NO3 ) 2 
 PbO  NO 2  O 2 Official Ans. by NTA (C)
Sol. 673 K
Allen Ans. (C)
(A)
Sol. Clean water have BOD less than 5 ppm while
2NO2 
Dimerise
 N 2O 4
A

A B highly polluted water has BOD greater or equal to

17 ppm. So, assertion is correct.
BOD is measure of oxygen required to oxidise
only bio-degradable organic matter. So, reason is
(no bridged oxygen) false.
11. The metal ion (in gaseous state) with lowest spin- 13. Given below are two statements: one is labelled as
only magnetic moment value is Assertion A and the other is labelled as Reason R.
2+ 2+
(A) V (B) Ni Assertion A: A mixture contains benzoic acid and
(C) Cr2+ (D) Fe2+
napthalene. The pure benzoic acid can be separated
Official Ans. by NTA (B)
out by the use of benzene.
Allen Ans. (B)
Reason R: Benzoic acid is soluble in hot water.
Sol. V2+ : 1s2 2s2 2p6 3s2 3p6 3d3

(3d) (unpaired e– = 3)

3
 In the light of the above statements, choose the OCH3

most appropriate answer from the options given

below. (C) O Br
OCH3
(A) Both A and R are true and R is the correct
explanation of A.
Br
(B) Both A and R are true but R is NOT the correct (D) O

explanation of A. Official Ans. by NTA (A)

(C) A is true but R is false. Allen Ans. (A)

(D) A is false but R is true. Sol.

Official Ans. by NTA (D)

Allen Ans. (D)
Sol. Benzoic acid and Napthalene can be effectively
separated by crystallization. Benzoic acid is
soluble in hot water whereas Napthalene is 16. In the given reaction

14.
insoluble.

EN
Hence assertion is incorrect but reason is correct

During halogen test, sodium fusion extract is

boiled with concentrated HNO3 to
(A) remove unreacted sodium
2A
(i) 2 M g, THF
(ii) Methyl benzoate
(iii) H 2 O/H

‘A’ can be
+
OH

(B) decompose cyanide or sulphide of sodium (A) benzyl bromide (B) bromobenzene
LL
(C) extract halogen from organic compound (C) cyclohexyl bromide (D) methyl bromide
(D) maintain the pH of extract Official Ans. by NTA (B)
Official Ans. by NTA (B) Allen Ans. (B)
Allen Ans. (B) Sol.
Sol. Sodium fusion extract is boiled with concentrated Br

2Mg/THF
HNO3 to remove sodium cyanide and sodium 2 2PhMgBr
A

sulphide Now O –  O— O
–

––
––

Ph Mg Br
15. Amongst the following, the major product of the Ph – C – O – CH 3 Ph – C – O – CH3 Ph – C – Ph
–

Ph
given chemical reaction is – 
Ph Mg Br
OH O— Mg + Br
H2 O/H +
–

Br2 Ph – C – Ph
Major Product C
–

CH 3OH Ph
O

(A)
Br

(B) O OCH3

4
17. Which of the following conditions or reaction
O
sequence will NOT give acetophenone as the
major product ? (A) O

(A) (a) C6H5 H + CH 3MgBr (b) Na Cr O , H+ (B) O OH

2 2 7

O O

(B) (a) H3 C H + C6H5MgBr (b) PCC, DCM (C) O H

C6H5 OC2H 5 + 2CH3MgBr

(C) (D) O O
O
Official Ans. by NTA (D)
C6H5 Cl + CH3MgBr + CdCl2 Allen Ans. (D)
(D)
Official Ans. by NTA (C) Sol.

Sol.
Allen Ans. (C)

EN H+
H ..
HO
..

O
H

—H
LL
O
O –  OH O
C6H5 MgBr PCC,DCM 19. Which of the following ketone will NOT give
–
––

––

(B) H3 C– C – H H3 C – C – H H3 C – C – Ph
–

C6H5 (Acetophenone)
enamine on treatment with secondary amines?
O –  O—
[where t-Bu is –C(CH3)3]
–
––

(C) C6H5 – C – O – C 2H 5 CH3 MgBr C6H5 – C – O – C 2H5

–

CH3 O O
A

C C2H5 C CH3
OH –  O (A) C2H5 (B) C2H5
CH3 MgBr
–

––

C6H5 – C – CH 3 C6H5 – C – CH 3 O
O
–

CH3
O O C
(CH3) 2Cd (C) t-Bu t-Bu (D)
––
––

(D) C6H5 – C – Cl + CH3 MgBr + CdCl 2 C6H5 – C – CH 3 No

(Acetophenone) reaction

(CH3) 2Cd
Official Ans. by NTA (C)
Allen Ans. (C)
18. The major product formed in the following
Sol. Enamine formation is an example of nucleophilic
reaction, is
addition elimination reaction
+ O CH3
H H3 C
OH + Since in ketone C
C
C CH3 Carbonyl
O H3 C CH3
CH3

Group is highly sterically hindered hence attack of

nucleophile will not be possible.
5
20. An antiseptic dettol is a mixture of two compounds P1 P2
Sol. 
‘A’ and 'B' where A has 6 electrons and B has 2 T1 T2

electrons. What is ‘B’? 30 P

 2
(A) Bithionol 300 318

(B) Terpineol 30
P2   318
300
(C) Chloroxylenol
1
(D) Chloramphenicol =  318
10
Official Ans. by NTA (B)
= 32
Allen Ans. (B)
23. Amongst BeF2, BF3, H2O, NH3, CCl4 and HCl, the
Sol. Dettol is mixture of
OH CH3 number of molecules with non-zero net dipole
moment is __________.
and
H3 C CH3 Official Ans. by NTA (3)
Cl H3 C C OH
Allen Ans. (3)

21.
Chloroxylenol
(Compound A)
It has 6e—

Hence compound ‘B’ is Terpineol.

SECTION-B
CH3

Terpineol
(Compound B)
It has 2e—

A protein ‘A’ contains 0.30% of glycine

EN Sol. BeF2, BF3 and CCl4  µnet = 0

24.
H2O, NH3 and HCl  µnet  0

At 345 K, the half life for the decomposition of a

sample of a gaseous compound initially at 55.5 kPa
was 340 s. When the pressure was 27.8 kPa, the
(molecular weight 75). The minimum molar mass half life was fund to be 170 s. The order of the
LL
of the protein ‘A’ is________ × 10 g mol 3 –1 reaction is________. [integer answer]
[nearest integer] Official Ans. by NTA (0)
Official Ans. by NTA (25) Allen Ans. (0)
Allen Ans. (25) 1
Sol. t1/2 
Sol. 0.30 % glycine is equal to 75 [P0 ]n 1
A

75 t1 (P2 )n 1
1 % 
 
0.30 t 2 (P1 )n 1
75 n 1
100 % 
  100 340  27.8 
0.30  
170  55.5 
= 25000 g 1
 2
22. A rigid nitrogen tank stored inside a laboratory has (2) n 1
n=0
a pressure of 30 atm at 06:00 am when the 25. A solution of Fe2(SO4)3 is electrolyzed for 'x' min
temperature is 27 °C. At 03:00 pm, when the with a current of 1.5 A to deposit 0.3482 g of Fe.
temperature is 45°C, the pressure in the tank will The value of x is______. [nearest integer]
be ____________atm. [nearest integer] Given : 1 F = 96500 C mol–1
Official Ans. by NTA (32) Atomic mass of Fe = 56 g mol–1
Allen Ans. (32) Official Ans. by NTA (20)
Allen Ans. (20)
6
Sol. Fe3+ + 3e– 
 Fe More 0  smaller value of absorbed 
K3 [Fe(CN)6 ] : Fe3+ : 3d5 4s0 4p 0
3F 
 1 mole Fe is deposited

For 56 g 
 3 × 96500 (required charge) 1 unpaired e– d2 sp3

3  96500 Spin only magnetic moment (µ) = 3 BM

For 1g 
 (required charge)
56 = 1.732 BM
3  96500 Rounding off  2
For 0.3482 g 
  0.3482
56 28. The Novolac polymer has mass of 963 g. The
= 1800.06 number of monomer units present in it are
Official Ans. by NTA (9)
Q = it
Allen Ans. (9)
1800.06 = 1.5 t OH

t = 20 min CH2OH

26. Consider the following reactions : Sol. Monomer unit of Novolac is its
PCl3 + H2O 
 A + HCl

A + H2O 
 B + HCl

number of ionisable protons present in the product

B________.

Official Ans. by NTA (2)

EN molecular mass is 124 amu.
Upon considering molecular weight of polymer
as 963 amu (In question its given as 963 gram)
Now if during formation of Novolac, (n–1) unit
of water are removed then
n 124  963  18   n 1
n=9
Allen Ans. (2)
29. How many of the given compounds will give a
LL
Sol. PCl3+H2O 
Partial
hydrolysis
 PCl2(OH) (or) PCl(OH)2 + positive Biuret test ______ ? Glycine,
Glycylalanine, Tripeptide, Biuret
HCl
Official Ans. by NTA (2)
Allen Ans. (2)
Sol. Biuret test is given by all proteins and peptides
having atleast two peptide linkages.
Hence positive test must be given by tripeptide and
A

no. of ionisable protons in B = 2

Biuret.
27. Amongst FeCl3.3H2O, K3[Fe(CN)6] and 30. The neutralization occurs when 10 mL of 0.1 M
[Co(NH3)6]Cl3, the spin-only magnetic moment acid ‘A’ is allowed to react with 30 mL of 0.05 M
base M(OH)2. The basicity of the acid 'A'
value of the inner-orbital complex that absorbs
is______. [M is a metal]
light at shortest wavelength is________ B.M.
Official Ans. by NTA (3)
[nearest integer] Allen Ans. (3)
Official Ans. by NTA (2) Sol. Acid + Base 
 Salt + H2O
0.1 M M(OH)2
Allen Ans. (2)
10ml 0.05 M
Sol. [Fe(H 2O)3 Cl3 ], K 3[Fe(CN)6 ], [Co(NH3 )6 ]Cl3 30 ml
inner orbital complexes
at equivalence point
K3[Fe(CN)6] has more value of 0 than that of equivalent of acid = equivalent of base
[Co(NH3)6]Cl3; as CN is stronger ligand. 0.1 × 10 × n = 30 × 0.05 × 2
n=3

7
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Sunday 26th June, 2022) TIME : 9 : 00 AM to 12 : 00 AM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A 3. If the radius of the 3rd Bohr's orbit of hydrogen
1. A commercially sold conc. HCl is 35% HCl by atom is r3 and the radius of 4th Bohr's orbit is r4.
mass. If the density of this commercial acid is 1.46 Then :
g/mL, the molarity of this solution is : 9 16
(A) r4  r3 (B) r4  r3
(Atomic mass : Cl = 35.5 amu, H = 1 amu) 16 9
(A) 10.2 M (B) 12.5 M 3 4
(C) r4  r3 (D) r4  r3
(C) 14.0 M (D) 18.2 M 4 3
Official Ans. by NTA (C) Official Ans. by NTA (B)
Allen Ans. (C) Allen Ans. (B)
Sol. Let total volume = 1000 mL = 1L n2
Sol. r = 0.529  Å
total mass of solution = 1460 g z
35 32
mass of HCl = 1460 EN r3 = 0.529 ×
100 1
35  1460 42
moles of HCl = r4 = 0.529 ×
100  36.5 1
2
r4 4 16
35  1460 = =
So molarity = = 14M r3 32 9
100  36.5
LL

2. An evacuated glass vessel weighs 40.0 g when 16r3

r4 =
empty, 135.0 g when filled with a liquid of density 9
0.95 g mL–1 and 40.5 g when filled with an ideal 4. Consider the ions/molecule
gas at 0.82 atm at 250 K. The molar mass of the
O 2 , O 2 , O 2– , O2–
2
gas in g mol–1 is :
A

(Given : R = 0.082 L atm K–1 mol–1) For increasing bond order the correct option is :
(A) 35 (B) 50 (A) O2– – 
2 < O2 < O2 < O2
(C) 75 (D) 125

(B) O 2– < O2–
2 < O2 < O2
Official Ans. by NTA (D)

Allen Ans. (D) (C) O 2– < O2–
2 < O2 < O2

Sol. Mass of liquid = 135 – 40 = 95 g (D) O 2– < O 2 < O2–

2 < O2

mass 95 Official Ans. by NTA (A)

Volume of liquid = = mL
density .95 Allen Ans. (D)
= 100 mL = 0.1 L Sol.
mass of ideal gas = 40.5 – 40 g = 0.5 g ion/molecule Number Number of e¯ Bond
PV = nRT of e¯ in in ABMO order
BMO
 0.5  O2+ 10 5 2.5
0.82 × 0.1 =   × 0.082 × 250 O2 10 6 2
M O2– 10 7 1.5
M = 125 O22– 10 8 1

1
 Bond order O22– < O2– < O2 < O2+ (B) Both Statement I and Statement II are
incorrect.
 E 
5. The    of different types of half cells are as (C) Statement I is correct but Statement II is
 T  P
incorrect.
follows :
(D) Statement I is incorrect but Statement II is
A B C D correct.
–4 –4 –4 Official Ans. by NTA (D)
1 × 10 2 × 10 0.1 × 10 0.2 × 10–4 Allen Ans. (D)
(Where E is the electromotive force) Sol. Metal oxide with lower G° is more stable

Which of the above half cells would be preferred Statement II is correct

8. Consider the following reaction :
to be used as reference electrode ?
2HSO4–  aq  
 1 Electrolysis 
 2 Hydrolysis  2HSO4  2H  A
–
(A) A (B) B
(C) C (D) D The dihedral angle in product A in its solid phase
Official Ans. by NTA (C) at 110 K is :
(A) 104° (B) 111.5°
Allen Ans. (C) (C) 90.2° (D) 111.0°
Sol. A cell with less variation in EMF with temperature Official Ans. by NTA (C)
Allen Ans. (C)
is preferred as reference electrode because it can be EN (1) Electrolysis
used for wider range of temperature without much Sol. 2HSO4¯(aq.) 2HSO4¯+2H+ +H2O2
(2) Hydrolysis (A)
derivation from standard value so a cell with less
 E 
  is preferred. H
 T P
O–O 90.2° Solid phase.
6. Choose the correct stability order of group 13
LL
H
elements in their +1 oxidation state.
(A) Al < Ga < In < Tl (B) Tl < In < Ga < Al
9. The correct order of melting point is :
(C) Al < Ga < Tl < In (D) Al < Tl < Ga < In
Official Ans. by NTA (A) (A) Be > Mg > Ca > Sr (B) Sr > Ca > Mg > Be
Allen Ans. (A) (C) Be > Ca > Mg > Sr (D) Be > Ca > Sr > Mg
A

Sol. Moving down the group stability of lower Official Ans. by NTA (D)
oxidation state increases Allen Ans. (D)
Al < Ga < In < Tl
Sol. M.P
7. Given below are two statements :
Be 1560 K
Statement I : According to the Ellingham
Mg 924 K
diagram, any metal oxide with higher G° is more
stable than the one with lower G°. Ca 1124 K
Statement II : The metal involved in the Sr 1062 K
formation of oxide placed lower in the Ellingham 10. The correct order of melting points of hydrides of
diagram can reduce the oxide of a metal placed
higher in the diagram. group 16 elements is :
In the light of the above statements, choose the
(A) H2S < H2Se < H2Te < H2O
most appropriate answer from the options given
(B) H2O < H2S < H2Se < H2Te
below :
(A) Both Statement I and Statement II are (C) H2S < H2Te < H2Se < H2O
correct. (D) H2Se < H2S < H2Te < H2O

2
 Official Ans. by NTA (A) (C) Statement I is correct but Statement II is
Allen Ans. (A) incorrect.

(D) Statement I is incorrect but Statement II is

11. Consider the following reaction : correct.
A + alkali  B (Major Product) Official Ans. by NTA (A)
If B is an oxoacid of phosphorus with no P–H Allen Ans. (A)
bond, then A is :
Sol. Both statement I & statement II are correct.
(A) White P4 (B) Red P4


(C) P2O3 (D) H3PO3 14.  C 7 H 5O2 2 

h
  X   2 C 6 H 5  2CO 2

Official Ans. by NTA (B) Consider the above reaction and identify the
Allen Ans. (B) intermediate 'X'
12. Polar stratospheric clouds facilitate the formation
O O
of : 
(A) C6H5–C (B) C6H5–C–O
(A) CIONO2 (B) HOCl
(C) ClO
Official Ans. by NTA (B)
(D) CH4
EN (C) C6H5–C–O
O
(D) C6H5–C–O
O

Allen Ans. (B) Official Ans. by NTA (D)

Sol. Polar stratospheric clouds provide surface on Allen Ans. (D)
which hydrolysis of ClONO2 takes place to form O O
LL

HOCl (Hypochlorous acid) Sol. C O O C

ClONO2 (g) + H2O(g) HOCl(g) + HNO3(g) h
O
13. Given below are two statements :
C O
A

Statement I : In 'Lassaigne's Test, when both

[X]
nitrogen and sulphur are present in an organic
compound, sodium thiocyanate is formed.
+ CO2
Statement II : If both nitrogen and sulphur are
present in an organic compound, then the excess of
sodium used in sodium fusion will decompose the
sodium thiocyanate formed to give NaCN and
Na2S.
In the light of the above statements, choose the
most appropriate answer from the options given
below :

(A) Both Statement I and Statement II are

correct.

(B) Both Statement I and Statement II are

incorrect.

3
15. 16. Which will have the highest enol content ?

MgBr O O O O
+ CH3–C–CH2–C–CH3
H2O O
'A' 'B'
Major Product (A) (B)
MgBr
O
Consider the above reaction sequence and identify
the product B. O O

OH (C) (D)
OH O O
(A) CH3 (B) O
HO
CH3
OH Official Ans. by NTA (C)

Allen Ans. (C)

OH
H3C O O
(C) (D) O OH
H3C OH H3C CH3
EN Sol. is tautomer of
O O HO OH
Official Ans. by NTA (A)

Allen Ans. (A) , Which is aromatic in nature.

Sol. Although Acetyl Acetone predominantly gives 17. Among the following structures, which will show
Acid base reaction with G.R due to Active the most stable enamine formation ?
LL

methylene group but according to given option ans (Where Me is –CH3)

should be based on nucleophilic addition reaction
(NAR). N COOH
(A)
A


Me
CH3 O mgBr OMe

CH3 C
MgBr CH2 N COOH
 O C
(B) OMe
+ CH2 CH2 Me

MgBr  O C CH2
CH3 N COOH
OmgBr (C)
CH3 Me
H2O OMe
OH
(D) N COOH
MeO
Me
Official Ans. by NTA (C)
OH
Allen Ans. (C)

4
Sol. All these enamines are interconvertible through 20. Which statement is not true with respect to nitrate
their resonating structures. So most stable form is ion test ?
‘C’ due to steric factor. (A) A dark brown ring is formed at the junction of
18. Which of the following sets are correct regarding two solutions.
polymer ?
(B) Ring is formed due to nitroferrous sulphate
(A) Copolymer : Buna–S
complex.
(B) Condensation polymer : Nylon–6,6
(C) The brown complex is [Fe(H2O)5 (NO)]SO4.
(C) Fibre : Nylon–6,6
(D) Thermosetting polymer : Terylene (D) Heating the nitrate salt with conc. H2SO4, light
(E) Homopolymer : Buna–N brown fumes are evolved.
Choose the correct answer from given options Official Ans. by NTA (B)
below: Allen Ans. (B)
(A) (A), (B) and (C) are correct
Sol. Ring is formed due to formation of nitrosoferrous
(B) (B), (C) and (D) are correct
sulphate
(C) (A), (C) and (E) are correct
(D) (A), (B) and (D) are correct
Official Ans. by NTA (A)
EN SECTION–B

Allen Ans. (A,B,C) 1. For complete combustion of methanol

Sol. Which of the following set are correct regarding 3
CH3OH  l   O2  g   CO2  g   2H 2 O  l 
polymer. 2
LL

Bona - 5 is copolymer of butadiene + styrene the amount of heat produced as measured by bomb
Nylon 6.6 is condensation polymer of adipic Acid calorimeter is 726 kJ mol–1 at 27°C. The enthalpy
and hexanediamine. of combustion for the reaction is –x kJ mol–1,
Nylon 6.6 is fiber where x is ______. (Nearest integer)
A

Terylene is fiber not themosetting polymer

(Given : R = 8.3 JK–1 mol–1)
Buna-N is copolymer nol Homopolymer
Official Ans. by NTA (727)
19. A chemical which stimulates the secretion of
Allen Ans. (727)
pepsin is :
Sol. U = –726 KJ/mol
(A) Anti histamine (B) Cimetidine
–1
(C) Histamine (D) Zantac  ng = 1–3/2 =
2
Official Ans. by NTA (C)
 H = U + ngRT
Allen Ans. (C) 1 8.3  300
=–726 – ×
Sol. Histamine (It is use for secretion of pepsin & HCl 2 1000
in stomach) = –727.245

5
2. A 0.5 percent solution of potassium chloride was log 3 = 0.48
found to freeze at –0.24°C. The percentage
dissociation of potassium chloride is ________. log 5 = 0.69
(Nearest integer)
log 7 = 0.84
(Molal depression constant for water is 1.80 K kg
mol–1 and molar mass of KCl is 74.6 g mol–1) log 11 = 1.04
Official Ans. by NTA (99 or 98)
Official Ans. by NTA (476)
Allen Ans. (99 or 98)
Sol. 0.5% solution of KCl Allen Ans. (476)

0.5 1 Sol. Moles of CH3COOH = 5 m mole

So m = 
74.6 0.1 moles of NaOH = 2.5 m mole
 Tf = i × mf NaOH + CH3COOH CH3COONa + H2O

0.5 1.80 2.5 m mole 2.5 m mole

  
74.6 0.1 0 2.5 m mole 2.5 m mole
so buffer is formed
0.24  74.6
i=  0.1
0.5 1.80  2.5 / 75 
pH = pKa + log   = pKa
= 1.989 EN  2.5 / 75 
1.989 = 1 + (n–1) pH = 4.76
1.989 = 1 +  = 476 × 10–2
  = .989 4. A flask is filled with equal moles of A and B. The
%  = 98.9% half lives of A and B are 100 s and 50 s
LL

Ans 99% respectively and are independent of the initial

If mass of H2O = 99.5 concentration. The time required for the
0.5 1 concentration of A to be four times that of B is
m= 
74.5 .0995 ________s.
A

0.24  74.6  .0995 (Given : ln 2 = 0.693)

i=
.5 1.80
Official Ans. by NTA (200)
= 1.979
Allen Ans. (200)
1.979 = 1 +  (n–1)
1.979 = 1 +  ln 2 ln 2
Sol. kA = ; kB =
100 50
 = .979
%  = 97.9 % At  A0  e–k At

 – ln 2 
Ans 98%  t 
A t  A0  e  100 
3. 50 mL of 0.1 M CH3COOH is being titrated
 – ln 2 
against 0.1 M NaOH. When 25 mL of NaOH has  t 
B t  B0  e  50 
been added, the pH of the solution will be
________ × 10–2. (Nearest integer) A0 = B0
& At = 4Bt
(Given : pKa (CH3COOH) = 4.76)
ln 2 ln 2
– t – t
log 2 = 0.30 e 100
=4× e 50

6
 ln 2
t Sol. CoCl3. 4NH3 [Co(NH3)4 Cl2]Cl
e 100 = 4
NiCl2.6H2O Ni(H2O)6Cl2
ln 2
t
e 100
4 PtCl4 . 2HCl H2[PtCl6]

[Ni(H2O)6]Cl2  2AgCl  + [Ni(H2O)6](NO3)2

2AgNO
ln 2 3

 t  ln 4  2ln 2
100
t = 200 sec

5. 2.0 g of H2 gas is adsorbed on 2.5 g of platinum

powder at 300 K and 1 bar pressure. The volume
= 2  2  2  B.M = 2.84 BM 
of the gas adsorbed per gram of the adsorbent is
________ mL. 8. On complete combustion 0.30 g of an organic
–1
(Given : R = 0.083 L bar K mol ) –1 compound gave 0.20 g of carbon dioxide and
0.10 g of water. The percentage of carbon in the
Official Ans. by NTA (9960)
given organic compound is ________ (Nearest
Allen Ans. (9960)
Integer)
nRT 2 0.083  300
Sol. Volume of H2 =
p
= 
2 1
EN Official Ans. by NTA (18)

Allen Ans. (18)

= 24.92
= 24900 mL  y z y
Sol. CxHyOz +  x  –  O2 xCO2 + H2O
24900  4 2 2
So 'g platinum adsorb =
LL
mLH 2
2.5 0.3g 0.2g .1g

= 9960 n CO x 0.2 / 44
2
 
nH O y / 2 .1/ 18
6. The spin–only magnetic moment value of the most 2

basic oxide of vanadium among V2O3, V2O4 and 2x 36 9

A

 
V2O5 is ________ B.M. (Nearest Integer) y 44 11
Official Ans. by NTA (3) 9y
x=
Allen Ans. (3) 22

Sol. Most basic oxide is V2O3 nC H O 1

x y z

V+3 [Ar] 3d2 nCO2 x
0.3 44 1
= 2  2  2  = 2.84 BM 3 × =
12x  y  16z 0.2 x
7. The spin–only magnetic moment value of an 66x = 12 x + y + 16 z
octahedral complex among CoCl3.4NH3,
54x = y + 16 z
NiCl2.6H2O and PtCl4.2HCl, which upon reaction
with excess of AgNO3 gives 2 moles of AgCl is 54  9y
– y = 16 z
________ B.M. (Nearest Integer) 22
Official Ans. by NTA (3)
464y
Allen Ans. (3) =16z
22
7
 29y 10. The number of oxygens present in a nucleotide
z=
22 formed from a base, that is present only in RNA is
CxHyOz = CxHyOz ________.
C 9y H yO 29y Official Ans. by NTA (9)
22 22

C9 H22 O29 Allen Ans. (9)

12  9 108 Sol. Uracil is the base which only present is RNA.

% of C = × 100 =  100
12  9  22  29 16 594 O
O
18.18% N
NH O
O–P–O–CH2 O N
9. Compound 'P' on nitration with dil. HNO3 yields N O
O O
two isomers (A) and (B). These isomers can be H
separated by steam distillation. Isomers (A) and Uracil
H
(B) show the intramolecular and intermolecular OH OH
hydrogen bonding respectively. Compound (P) on
Structure of nucleotides number of 0-9.
reaction with conc. HNO3 yields a yellow EN
compound 'C', a strong acid. The number of
oxygen atoms is present in compound 'C'
________.

Official Ans. by NTA (7)

LL

Allen Ans. (7)

Cl OH OH
NO2
Sol. Dil.HNO3 +
A

Intramolecular NO2
H-bonding Intermolecular
H-bonding

OH OH
O2H NO2
Conc.HNO
Picric acid
NO2
Strong acid
(yellow compound)

8
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Sunday 26th June, 2022) TIME : 3 : 00 AM to 6 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A 4. The role of depressants in Troth Floation method*
1. The number of radial and angular nodes in 4d is to
orbital are. respectively (1) selectively prevent one component of the ore
(1) 1 and 2 (2) 3 and 2 from coming to the froth.
(3) 1 and 0 (4) 2 and 1 (2) reduce the consumption of oil for froth
Official Ans. by NTA (1) formation.
Allen Ans. (1)
(3) stabilize the froth.
Sol. Radial node = n – l – 1
(4) enhance non-wettability of the mineral
=4–2–1
=1 particles.
Angular node (l) = 2 Official Ans. by NTA (1) (Page No. 154)
2. Match List I with List II. Allen Ans. (1)
List I
Enzyme
A. Invertase
B. Zymase
C. Diastase
List II
Conversion of
I. Starch into maltose
II. Maltose into glucose
EN
III. Glucose into ethanol
Sol. refer NCERT (Page No. 154)
5. Boiling of hard water is helpful in removing the
temporary hardness by converting calcium
hydrogen carbonate and magnesium hydrogen
carbonate to
(1) CaCO3 and Mg(OH)2
(2) CaCO3 and M2CO3
D. Maltase IV. Cane sugar into glucose
(3) Ca(OH)2 and MgCO3
LL
Choose the most appropriate answer from the
(4) Ca(OH)2 and Mg(OH)2
options given below :
Official Ans. by NTA (1)
(1) A-III, B-IV. C-II. D-I
Allen Ans. (1)
(2) A-III. B-II. C-I. D-IV
Sol. Mg(HCO3)2   Mg(OH)2 + 2CO2
Boil

(3) A-IV, B-IIL C-I. D-II

Ca(HCO3)2   CaCO3 + H2O + CO2
Boil

(4) A-IV, B-II. C-III. D-I

6. s-block element which cannot be qualitatively
A

Official Ans. by NTA (3)

confirmed by the flame test is
Allen Ans. (3) (1) Li (2) Na (3) Rb (4) Be
Sol. Invertase : Cane sugar  Glucose and fructose Official Ans. by NTA (4)
Zymase : Glucose  Ethanol and CO2 Allen Ans. (4)
Sol. refer NCERT (Page No. 300)
Diastase : Starch  Maltose
7. The oxide which contains an odd electron at the
Maltase : Maltose  Glucose
nitrogen atom is
3. Which of the following elements in considered as a (1) N2O (2) NO2 (3) N2O3 (4) N2O5
metalloid? Official Ans. by NTA (2)
(1) Sc (2) Pb (3) Bi (4) Te Allen Ans. (2)
Official Ans. by NTA (4) Sol. NO2  7 + 2 × 8 = 23 electron (odd)

Allen Ans. (4)

N=O
Sol. Te (Metalloid) refer NCERT (Page No. 83)
O

1
8. Which one of the following is an example of Allen Ans. (4)
disproportionation reaction? Sol. Nucleophilicity  electro density on donor atom
2 
(1) 3MnO  4H  2MnO  MnO2  2H2O
4

4
 size of donor atom (in gas)
1
2  
(2) MnO4  4H  4e  MnO2  2H2O 
( for period)
EN of atom
   2 12. Oxidation of toluene to Benzaldehyde can be easily
(3) 10I  2MnO4  16H  2Mn  8H2O  5I2
carried out with which of the following reagents?
 2 2 
(4) 8MnO4  3S2O3  H2O  8MnO2  6SO4  2OH (1) CrO3/acetic acid, H3O+
(2) CrO3/acetic anhydride, H3O+
Official Ans. by NTA (1)
(3) KMnO4/HCl, H3O+
Allen Ans. (1) (4) CO/HCl, anhydrous AlCl3
Sol. 3MnO42– + 4H+  2MnO4– + MnO2 + 2H2O Official Ans. by NTA (2)
Allen Ans. (2)
+6 +7 +4
Sol.
So, it is disproportionation reaction. O

9. The most common oxidation state of Lanthanoid O – C – CH3

CH3 HC CHO
O – C – CH3

deviate easily from +3 oxidation state?

(1) Ce (At. No. 58)
(3) Lu (At. No. 71)
Official Ans. by NTA (1)
Allen Ans. (1)
EN
elements is +3. Which of the following is likely to

(2) La (At. No. 57)

(4) Gd (At. No. 64) 13.
CrO3/Acetic an hydride

The major product in the following reaction

O

 i Hg OAc 

 ii NaBH4 ?
2 2 ,H O
H2O/H+

Hydrolysis
+ 2 CH3COOH

Sol. Ce = [Xe] 4f1 5d1 6s2

(1) (2)
LL
Ce3+ = [Xe] 4f1 5d0 OH O
+4 0 0
Ce = [Xe] 4f 5d (Noble gas configuration) OH
10. The measured BOD values for four different water (3) (4)
OH
samples (A-D) are as follows:
Official Ans. by NTA (1)
A = 3 ppm: B=18 ppm: C-21 ppm: D=4 ppm. The
Allen Ans. (1)
water samples which can be called as highly
A

( 1) H g (O A2c ) ,2 H O
H
polluted with organic wastes, are Sol. (2) NaBH4

(1) A and B (2) A and D OH

Oxymercuration – Demercuration
(3) B and C (4) B and D
Addition of H2O
Official Ans. by NTA (3) Markovnikov’s addition without rearrangement
Allen Ans. (3) 14. Halogenation of which one of the following will
yield m-substituted product with respect to methyl
Sol. BOD for clean water < 5 ppm
group as a major product?
CH3
CH 3
11. The correct order of nucleophilicity is NO2

  H2 O  OH
(1) F  OH (2) (1) CHO (2)

R OH  RO 
(3) (4) NH2  NH3
Official Ans. by NTA (4)

2
 CH3 CH3 CH3 – CH = C – CN
OH
(2) CH3

OH
(3) (4) NO2
CH3 – CH – C – COOH

(3) CH3
Official Ans. by NTA (3)
CH3 – CH = C – CONH2
Allen Ans. (3)
Sol. Electrophile will attack at ortho and para position (4) CH3

with respect to better electron releasing group Official Ans. by NTA (1)

(ERG) Allen Ans. (1)

Sol.
ERG : – OH > – CH3 O CN
CH3 CH3CH2 – C – CH3 HCN CH3CH2 – C – CH3 95% H2SO4
Heat
OH OH
CH3
CH3 –CH = C – COOH

15.
Para position with respect to – OH (+R) group and
it will be meta position with respect to – CH3
group.
The reagent, from the following, which converts
benzoic acid to benzaldehyde in one step is
EN 17. Which statement is NOT correct for p-toluenesulphonyl
chloride?
(1) It is known as Hinsberg’s reagent.
(2) It is used to distinguish primary and secondary
amines.
(3) On treatment with secondary amine, it leads to
CHO a product, that is soluble in alkali.
LL
COOH (4) It doesn’t react with tertiary amines.
Official Ans. by NTA (3)
Allen Ans. (3)
(1) LiAlH4 (2) KMnO4 Sol.
(3) MnO (4) NaBH4 CH3
Official Ans. by NTA (3)
Allen Ans. (3)
A

Sol.
SO2 Cl
Hinsberg's reagent
O O O
MnO O
C 6H 5 – C – OH + HO – C – C 6H5 C 6H 5 – C – C 6 H5 + CO2 + H2 O
O O O H3 C S – Cl + 1° Amine Soluble in alkali
MnO
C 6H 5 – C – OH + HO – C – H C 6H 5 – C – H + CO 2 + H2 O O

16. The final product ‘A’ in the following reaction

O
sequence
HCN 95% H2 SO4 H3 C S – Cl + 2° Amine insoluble in alkali
CH3 CH2 – C – CH3 ? A
Heat O
O O
CH3 H3 C S – Cl + 3° Amine No reaction

(1) CH3 – CH = C – COOH O

3
18. The final product ‘C’ is the following series series Official Ans. by NTA (2)
of reactions Allen Ans. (2)
NO2 Sol. Refer NCERT (Page No. 452)
 Naphthol

Sn/HCl
A 
NaNO2
 B  C
HCl NaOH is
20. Which one of the following is a water soluble
vitamin, that is not excreted easily?
(1) Vitamin B2 (2) Vitamin B1
N=N
(3) Vitamin B6 (4) Vitamin B12
OH
(1) Official Ans. by NTA (4)
OH
Allen Ans. (4)
Sol. Refer NCERT (Page No. 426)
N=N SECTION-B
(2)
1. CNG is an important transportation fuel. When 100
OH

(3)
N=N

N=N
OH
EN g CNG is mixed with 208 oxygen in vehicles, it
leads to the formation of CO2 and H2O and
produces large quantity of heat during this
combustion, then the amount of carbon dioxide,
produced in grams is________. [nearest integer]
[Assume CNG to be methane]
(4)
Official Ans. by NTA (143)
LL
Official Ans. by NTA (3)
Allen Ans. (3) Allen Ans. (143)
NO 2 NH 2 N2 Cl Sol. CH4 + 2O2  CO2 + 2H2O

Sn/HCl NaNO2 100 208

Sol. HCl Mole 16 32
Diazonium salt
= 6.25 = 6.5
A

OH
N2 Cl OH Mole 6.25 6.5
N=N–  3.25
Stoi. Coeff. 1 2
–napthol NaOH
Diazonium salt So, O2 is limiting reagent
19. Which of the following is NOT an example of Mole – Mole analysis
synthetic detergent? n O2 n co2

2 1
– +
CH3 – (CH2)11 SO3 Na
(1) 6.5
 nco2
(2) CH3 – (CH2)16 –COO– Na+
2
+ 6.5
CH3 Mass of CO2 = × 44 = 143 gm
2
CH3 – (CH2)15 – N – CH3 –
Br 2. In a solid AB. A atoms are in ccp arrangement and
CH3 B atoms occupy all the octahedral sites. If two
(3)
atoms from the opposite faces are removed, then
(4) CH3(CH2)16COO(CH2CH2O)nCH2CH2OH

4
 the resultant stoichiometry of the compound is mass 60 kg mol–1 in 200 mL of water at 27°C is
AxBy. The value of x is_______. [nearest integer] _______ Pa. [integer value]

Official Ans. by NTA (3) (use R = 0.083 L bar mol–1 K–1)

Allen Ans. (3) Official Ans. by NTA (415)

Sol. A  4 –  2  1  = 3 Allen Ans. (415)

 2 Sol.  = iCRT
B  12 × 1 + 1 × 1 = 4 1 2
4 =  0.083  300
60000  0.2
So, Compound is A3B4 = 0.00415 bar ( 1 bar = 105 Pa)
The value of x is 3.
So, 0.00415 × 105 Pa = 415 Pa
3. Amongst SF4, XeF4, CF4 and H2O, the number of
6. 40° of HI undergoes decomposition to H2 and I2 at
species with two lone pairs of electrons ______ .
300 K. G for this decompostion reaction at one
Official Ans. by NTA (3)
atmosphere pressure is________ J mol–1. [nearest

4.
Allen Ans. (2)

EN
Sol. Number of lone pair on central atom for H2O and
XeF4 is equal to 2.
A fish swimming in water body when taken out
from the water body is covered with a film of
integer]
(Use R = 8.31 J K–1 mol–1; log 2 = 0.3010. In 10 =
2.3, log 3 = 0.477)

Official Ans. by NTA (2735)

Allen Ans. (2735)
water of weight 36 g. When it is subjected to
1 1
LL
cooking at 100°C, then the internal energy for Sol. HI H2 + I2
2 2
vaporization in kJ mol–1 is ________. [nearest
ti 1
integer]
0.4 0.4
[Assume steam to be an ideal gas. Given AvapH teq 1 – 0.4 
 2  2
for water at 373 K and 1 bar is 41.1 kJ mol–1 ; R = 1 1
(0.2) 2 (0.2) 2 0.2 1
 
A

8.31 JK–1mol–1] Kp =
1  0.4 0.6 3
Official Ans. by NTA (38) G  G  RT ln K  0
Allen Ans. (38) 1
G  RT ln K  8.31 300  2.3  log  
Sol. H2O (l)  H2O(g) 3
= 2735 J/mol
36
n= = 2 mol 7. Cu(s) + Sn2+ (0.001M)  Cu2+ (0.01M) + Sn(s)
18
U = H – ng RT The Gibbs free energy change for the above
reaction at 298 K is x × 10–1 kJ mol–1;
1 8.31 373
= 41.1 – kJ / mol The value of x is______. [nearest integer]
1000
Given : E Cu2 /Cu  0.34V; E Sn2 /Sn  0.14V; F  96500C mol –1 
= 38 kJ/mol
Official Ans. by NTA (983)
5. The osmotic pressure exerted by a solution
Allen Ans. (983)
prepared by dissolving 2.0 g of protein of molar
Sol. Cu(s) + Sn2+ (0.001 M)  Cu2+ (0.01 M) + Sn(s)
E°cell = E°cathode – E°anode
5
 = – 0.14 – (0.34) 
= – 0.48 V
Low spin complex
0.059 [Cu2 ]
Ecell  Ecell  log Co3+  3d6 4s0
2 [Sn 2 ]
0.059 0.01  t2g6 eg0
 0.48 – log
2 0.001 Total number electrons = 6
 0.509
10. The moles of methane required to produce 81 g of
G = – nF Ecell
water after complete combustion is ______ × 10–2
= – 2 × 96500 × (–0.5095)
mol. [nearest integer]
= 98333.5 J/mol
Official Ans. by NTA (225)
= 98.335 kJ/mol
= 983.35 × 10–1 kJ/mol Allen Ans. (225)

Nearest Integer : 983 Sol. CH4 + 2O2  CO2 + 2H2O

8. Catalyst A reduces the activation energy for a POAC on H atom

reaction by 10 kJ mol–1 at 300 K. The ratio of rate nCH4 × 4 = nH2O × 2

constants,
k
k
T,Catalysed
T, Uncatalysed is ex. The value of x is

_______. [nearest integer]

[Assume theat the pre-exponential factor is same in
both the cases.
EN nCH4 
81
18
nCH4  2.25

= 225 ×10–2
1 81
2 
4 36

Nearest Integers = 225

Given R = 8.31 J K–1 mol–1]

LL
Official Ans. by NTA (4)
Allen Ans. (4)
Sol.
 Ea
K  Ae RT
Ea1 Ea
 
A

K cat  Ae RT
, K uncat.  Ae RT

1
Ea  Ea 101000
K cat
 e RT  e 8.31300  e 4.009  e x
K uncat.
 x4

9. Reaction of [Co(H2O)6]2+ with excess ammonia

and in the presence of oxygen results into a
diamagnetic product. Number of electrons present
in t2g–orbitals of the product is _______ .

Official Ans. by NTA (6)

Allen Ans. (6)
Sol. [Co(H2O)6]2+ +NH3(excess)  [Co(NH3)6]3+ +
6H2O
Diamagnetic
6
 A

7
LL
EN
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Monday 27th June, 2022) TIME : 9 : 00 AM to 12 : 00 PM
PM
CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A (A) (A) – I, (B) – (II), (C) – (III), (D) – (IV)
1. Given below are two statements : one is labelled as (B) (A) – (III), (B) – (IV), (C) – (I), (D) – (II)
Assertion (A) and the other is labelled as Reason (C) (A) – (III), (B) – (IV), (C) – (II), (D) – (I)
(R) (D) (A) – (IV), (B) – (III), (C) – (I), (D) – (II)
Assertion (A) : At 10°C, the density of a 5M Official Ans. by NTA (B)
solution of KCl [atomic masses of K and Cl are 39 Allen Ans. (B)
-1
& 35.5 g mol . The solution is cooled to -21°C. Sol. T-shaped ClF3 sp3d, 2lp
The molality of the solution will remain Trigonal planar BF3 sp2, 0lp
unchanged. Square planar XeF4 sp3d2, 2lp
Reason (R) : The molality of a solution does not See-saw SF4 sp3d, 1lp
change with temperature
unaffected with temperature.
as

In the light of the above statements, choose the

correct answer from the options given below:
EN
mass

(A) Both (A) and (R) are true and (R) is the correct
remains 3. Match List-I with List-II

(A)
(B)
List-I
Spontaneous process
List-II
H < 0
Process with P = 0, GT,P < 0
T = 0
explanation of (A)
(C) Hreaction (III) Isothermal and
LL
(B) Both (A) and (R) are true but (R) is not the
isobaric process
correct explanation of (A)
(D) Exothermic process (IV) [Bond energies of
(C) (A) is true but (R) is false
molecules in reactants] -
(D) (A) is false but (R) is true
[Bond energies of
Official Ans. by NTA (A)
product molecules
Allen Ans. (A) Choose the correct answer from the options given below:
A

Sol. Molality is independent of temperature and hence (A) (A) – (III), (B) – (II), (C) – (IV), (D) – (I)
both assertion and reason are true. (B) (A) – (II), (B) – (III), (C) – (IV), (D) – (I)
2. Based upon VSEPR theory, match the shape (C) (A) – (II), (B) – (III), (C) – (I), (D) – (IV)
(geometry) of the molecules in List-I with the (D) (A) – (II), (B) – (I), (C) – (III), (D) – (IV)
molecules in List-II and select the most appropriate Official Ans. by NTA (B)
option Allen Ans. (B)
List-I List-II Sol. (A) For a spontaneous process GT,P < 0
(Shape) (Molecules)
(B) P = 0  Isobaric process
(A) T-shaped (I) XeF4
T = 0  Isothermal process
(B) Trigonal planar (II) SF4
(C) Hreaction = (Bond energies of reactants) -
(C) Square planar (III) ClF3
(bond energies of products)
(D) See-saw (IV) BF3
(D) H < 0 is for exothermic reaction

1
4. Match List-I with List-II Official Ans. by NTA (D)
List-I List-II Allen Ans. (D)
(A) Lyophilic colloid (I) Liquid-liquid colloid Sol. Ionic radius of O2- is more than that of Mg2+
(B) Emulsion (II) protective colloid Both O2- and Mg2+ are isoelectronic with 10
(C) Positively charged (III) FeCl3 + NaOH electrons
(D) Negatively charged (IV) FeCl3 + hot water 6. Match List-I with List-II
colloid List-I List-II
Choose the correct answer from the options given (A) Concentration of (I) Aniline
below: gold ore
(A) (A) – (II), (B) – (I), (C) – (IV), (D) – (III) (B) Leaching of alumina (II) NaOH
(B) (A) – (III), (B) – (I), (C) – (IV), (D) – (II) (C) Froth stabiliser (III) SO2
(C) (A) – (II), (B) – (I), (C) – (III), (D) – (IV) (D) Blister copper (IV) NaCN
(D) (A) – (III), (B) – (II), (C) – (I), (D) – (IV) Choose the correct answer from the options given
Official Ans. by NTA (A) below.
Allen Ans. (A)
Sol. (A) Protective colloids are lyophilic colloids
(B) Emulsions are liquid in liquid colloidal
solutions
(C) FeCl3 + hot water forms positively charged
EN (A) (A) – (IV), (B) – (III), (C) – (II), (D) – (I)
(B) (A) – (IV), (B) – (II), (C) – (I), (D) – (III)
(C) (A) – (III), (B) – (II), (C) – (I), (D) – (IV)
(D) (A) – (II), (B) – (IV), (C) – (III), (D) – (I)
Official Ans. by NTA (B)
colloidal solution of hydrated ferric oxide. Allen Ans. (B)
LL
(D) FeCl3 + NaOH forms negatively charged Sol. Gold is concentrated by cyanidation
colloidal solution due to preferential adsorption of Leaching of alumina is done by NaOH
OH- ions Froth stabiliser is aniline
5. Given below are two statements: one is labelled as Blister copper has condensed SO2 on the surface
Assertion (A) and the other is labelled as 7. Addition of H2SO4 to BaO2 produces:
Reason(R) (A) BaO, SO2 and H2O (B)BaHSO4 and O2
A

2- 2+
Assertion (A): The ionic radii of O and Mg are (C) BaSO4, H2 and O2 (D) BaSO4 and H2O2
same. Official Ans. by NTA (D)
2-
Reason (R) : Both O and Mg 2+
are isoelectronic Allen Ans. (D)
species Sol. BaO2 + H2SO4  BaSO4 + H2O2
In the light of the above statements, choose the This is a common method to prepare hydrogen
correct answer from the options given below peroxide
(A) Both (A) and (R) are true and (R) is the correct 8. BeCl2 reacts with LiAlH4 to give
explanation of (A) (A) Be + Li[AlCl4] + H2
(B) Both (A) and (R) are true but (R) is not the (B) Be + AlH3 + LiCl + HCl
correct explanation of (A) (C) BeH2 + LiCl + AlCl3
(C) (A) is true but (R) is false (D) BeH2 + Li[AlCl4]
(D) (A) is false but (R) is true Official Ans. by NTA (C)
Allen Ans. (C)
2
Sol. 2BeCl2 + LiAlH4 2 BeH2 + LiCl + AlCl3 12. Given below are two statements:
This is the method to prepare BeH2 Statement I: Classical smog occurs in cool humid
9. Match List-I with List-II climate. It is a reducing mixture of smoke, fog and
List-I List-II sulphur dioxide
(Si-Compounds) (Si-Polymeric/other Statement II: Photochemical smog has
products) components, ozone, nitric oxide, acrolein,
(A) (CH3)4Si (I) Chain silicone formaldehyde, PAN etc.
(B) (CH3)Si(OH)3 (II) Dimeric silicone In the light of above statements, choose the most
(C) (CH3)2Si(OH)2 (III) Silane appropriate answer from the options give below
(D) (CH3)3Si(OH) (IV) 2D – Silicone (A) Both Statement I and Statement II are correct
Choose the correct answer from the options given (B) Both Statement I and Statement II are
below: incorrect
(A) (A) – (III), (B) – (II), (C) – (I), (D) – (IV) (C) Statement I is correct but statement II is
(B) (A) – (IV), (B) – (I), (C) – (II), (D) – (III) incorrect

Official Ans. by NTA (D)

Allen Ans. (D)
Sol. (CH3)4Si is a silane
EN
(C) (A) – (II), (B) – (I), (C) – (IV), (D) – (III)
(D) (A) – (III), (B) – (IV), (C) – (I), (D) – (II)
(D) Statement I is incorrect but Statement II is
correct
Official Ans. by NTA (A)
Allen Ans. (A)
Sol. Classical smog occurs in cool humid climate. It is a
(CH3)Si(OH)3 polymerise to form 2D silicone reducing mixture of smoke, fog and sulphur
LL
(CH3)2Si(OH)2 polymerise to form chain silicone dioxide
(CH3)3Si(OH) form dimer (CH3)3Si-O-Si(CH3)3 Photochemical smog has components, ozone, nitric
10. Heating white phosphorus with conc. NaOH oxide, acrolein, formaldehyde, PAN etc.
solution gives mainly CH4 + O3  HCHO + H2O + CH2 = CH – CHO +
(A) Na3P and H2O (B) H3PO and NaH O
(C) P(OH)3 and NaH2PO4 (D) PH3 and NaH2PO2 H3C
A

O ONO2 (PAN - peroxyacetyl nitrate)

Official Ans. by NTA (D)
Allen Ans. (D)
Sol. P4 + 3NaOH + 3H2O  3NaH2PO2 + PH3
11. Which of the following will have maximum
stabilization due to crystal fild?
(A) [Ti(H2O)6]3+ (B) [Co(H2O)6]2+
(C) [Co(CN)6]3- (D) [Cu(NH3)4]2+
Official Ans. by NTA (C)
Allen Ans. (C)
Sol. Co3+ has maximum effective nuclear charge and
CN- is the strongest ligand in the given options

3
13. Which of the following is structure of a separating 15. The major product of the following reaction is:
funnel?

(A) (B)
(A) (B)

(C) (D)
Official Ans. by NTA (A)

14.
Allen Ans. (A)

immiscible with different densities

‘A’ and ‘B’ respectively are:
A (1)O3
( 2) Zn H O
2
 Ethane-1,2-dicarbaldehyde
EN
Sol. It is used to separate liquid-liquid mixture which is

+ Glyoxal/Oxaldehyde
(C) (D)

B   5-oxohexanal
LL
(1)O3
( 2) Zn H O
2

(A) 1-methylcyclohex-1, 3-diene & cyclopentene

(B) Cyclohex-1, 3-diene & cyclopentene
(C) 1-methylcyclohex-1,4-diene
& 1-methylcyclopent-1-ene Official Ans. by NTA (A)

(D) Cyclohex-1,3-diene Allen Ans. (A)

A

& 1-methylcyclopent-1-ene Sol.

Official Ans. by NTA (D) H3C H3C

Allen Ans. (D)

I SPh
Sol.
F   F
CHO

1.O3
2. Zn H O
2
+ OHC CHO 
PhSNa
DMF
CHO (glyoxal)
ethane-1, 2-dicarbaldehyde NO2 NO2

CH3
CH3
It is bimolecular nucleophilic substitution (SN2)
O which occur at benzylic carbon by inversion in

1.O3
2. Zn H O
2 CHO
contiguration. This reaction cannot undergo
5-oxohexanal substitution at benzene ring

4
16. Which of the following reactions will yield 17. Given below are two statements:
benzaldehyde as a product? Statements-I : In Hofmann degradation reaction,
COOH the migration of only an alkyl group takes place
 
(i) SOCl2 Quinoline
(ii)H /Pd/BaSO
 from carbonyl carbon of the amide to the nitrogen
2 4
(A) atom.
CH2 OH
Statement-II : The group is migrated in Hofmann
degradation reaction to electron deficient atom.


CrO3/H2SO4
In the light of the above statement, choose the
(B)
most appropriate answer from the options given
O
below:
C OCH3
(A)Both Statement-I and Statement-II are correct

(i) NaBH4
(ii) PCC

(C) (B) Both Statement-I and Statement-II are
CH3 incorrect
(C) Statement-I is correct but Statement-II is

(D)
(A) (B) and (C)
(C) (A) and (D)
Official Ans. by NTA (C)
Allen Ans. (C)

(i) CrO3 , (CH3CO)2 O

(ii) H3O , 


(B) (C) and (D)

(D) (A) and (C)
EN incorrect
(D) Statement-I is incorrect but Statement-II is
correct
Official Ans. by NTA (D)
Allen Ans. (D)
Sol. R – CO – NH2 + Br2 + NaOH 
Sol.
LL
R – NH2 + Na2CO3 + NaBr + H2O
 
COOH COCl
CHO R – CO – NH2 + O H  R – CO - N H 
Br2

 
  R – CO – NH – Br 
OH
 R – CO - N  Br
SOCl2
Quinoline 
H2|Pd|BaSO4
(R osenmund Reduction)


(Benzaldehyde)  

CH2OH COOH 

migration of R
 R – NCO 
2 OH
 RNH2 + CO32
A

In this reaction of alkyl as well as aryl group can


CrO3 |H2SO4
(oxidation)
 migrate to electron deficient nitrogen atom.
18. Match List-I with List-II
COOCH3
List-I List-II
(Polymer) (Used in)

NaBH4
No Reduction occurs
(A) Bakelite (I) Radio and television

CH3 CHO Cabinets

CH(OCOCH3)2
(B) Glyptal (II) Electrical switches

CrO3 ,(CH3CO)2 O 
(C) PVC (III) Paints and Lacquers

H3O

(Benzaldehyde) (D) Polystyrene (IV) Water pipes
Choose the correct answer from the options given
below:

5
 (A) (A) – (II), (B) – (III), (C) – (IV), (D) – (I) Sol.
(B) (A) – (I), (B) – (II), (C) – (III), (D) – (IV) H O
COOH
(C) (A) – (IV), (B) – (III), (C) – (II), (D) – (I) HO H
HO H
(D) (A) – (II), (B) – (III), (C) – (I), (D) – (IV) HO H

Br2|H2O
HO H
Official Ans. by NTA (A) OH
OH
Allen Ans. (A) L-isomer optically active
Sol. Bakelite- It is thermosetting polymer used for
H O
making electrical switches. COOH

Glyptal – manufacture of paints and lacquers HO H HO H

HO H 
con.HNO3
 HO H
PVC – manufacture of water pipes, rain coats,
COOH
hand bags OH
optically inactive
Polystyrene – manufacture of radio and television L-isomer
cabinets 20. Match List-I with List-II
19. L-isomer of a compound ‘A’ (C4H8O4) gives a

Compound ‘A’ produces an optically active

EN
positive test with [Ag(NH3)2]+. Treatment of ‘A’
with acetic anhydride yield triacetate derivative.

compound (B) and an optically inactive compound

(C) on treatment with bromine water and HNO3
List-I
(A)

CH3
CH3 (CH2 )15 - N - CH3
CH3
+

Br-

respectively, compound (A) is:

LL
(A) (B) CH 3 - (CH2)11 SO3 Na 
(B)
CHO CHO
(C) C17 H35COO Na   Na 2CO3  Rosinate
HO H H OH

HO H HO H (D) CH3(CH2)16COO(CH2CH2O)nCH2CH2OH

CH2OH CH2OH List-II

(I) Dishwashing powder
A

(C) (D)
(II) Toothpaste
CHO CHO
(III) Laundry soap
H OH OH H
(IV) Hair conditioner
H OH H OH
(A) (A) – (III), (B) – (II), (C) – (IV), (D) – (I)
CH2OH CH2OH
(B) (A) – (IV), (B) – (II), (C) – (III), (D) – (I)
Official Ans. by NTA (A) (C) (A) – (IV), (B) – (III), (C) – (II), (D) – (I)
Allen Ans. (A) (D) (A) – (III), (B) – (IV), (C) – (I), (D) – (II)
Official Ans. by NTA (B)
Allen Ans. (B)

6
Sol. (A) CH3 (CH2 )15  N(CH3 )3  Br 
 h
 mV.x 
4
is cationic detergents used in hair conditioner
6.626  10 34
 m  2.4  10 26  10 7 
 4 
CH3 (CH 2 )11 SO3 Na
6.626
(B) m  101
9.6  
Is anionic detergent used in tooth pastes
m = 0.02198 kg
(C) C17 H35COO Na   Na 2CO3  Rosin ate is m = 21.98 gm
used as laundary soap nearest integer = 22
(D) CH3 (CH2 )16 COO(CH2CH2O)N CH2CH2OH 3. 2g of a non-volatile non-electrolyte solute is
is non-ionic detergents formed from stearic acid dissolved in 200 g of two different solvents A and
and poly ethylene glycol used as liquid B whose ebullioscopic constants are in the ratio of
dishwashing detergents 1 : 8. The elevation in boiling points of A and B
SECTION-B x
1. Metal deficiency defect is shown by Fe0.93O. In the
crystal, some Fe2+ cations are missing and loss of
positive charge is compensated by the presence of
Fe 3+
ions. The percentage of Fe
Fe0.93O crystals is _________ . (Nearest integer)
2+
EN
ions in the
are in the ratio

Allen Ans. (8)

Sol. Given :
(K b )A 1

y
is_________ (Nearest integer)

Official Ans. by NTA (8)

(x : y). The value of y

Official Ans. by NTA (85) (K b )B 8

LL
Allen Ans. (85) (TB )A (K b )A .m 1 x
   
Sol. In Fe0.93O for every 93 Fe ions 14 are Fe+3 and (93 (TB )B (K b )B .m 8 y

– 14) = 79 are Fe+2 ions x 1


y 8
79
 % Fe+2 =  100 = 84.9%
93  y  8 (nearest integer)
  nearest integer = 85%
A

4. 2NOCl(g) 2NO(g) + Cl2(g)

2. If the uncertainty in velocity and position of a In an experiment, 2.0 moles of NOCl was placed in
minute particle in space are, 2.4 × 10-26 (ms-1) and a one-litre flask and the concentration of NO after
10-7(m) respectively. The mass of the particle of g equilibrium established, was found to be 0.4
is _________ (Nearest integer) mol/L. The equilibrium constant at 30°C is ______
-34
(Given : h = 6.626 × 10 Js) × 10-4.
Official Ans. by NTA (22) Official Ans. by NTA (125)
Allen Ans. (22) Allen Ans. (125)
-26 -1
Sol. V = 2.4 × 10 ms Sol. 2NOCl(g) 2NO(g) + Cl2(g)
-7
x = 10 m t=0 2M - -
h x
p. x  t=teq (2-x)M xM M
4 2

7
 x  0.4 M EA
Sol. ln k = ln A 
RT
 [NOCl]eq = 1.6 M
[NO]eq = 0.4 M 2.0  10 4
Given: ln k = 33.24 
T
[Cl2]eq = 0.2 M
EA
[NO]2[Cl2 ] [0.4]2[0.2]  on comparing = 2.0 × 104
 Kc   R
[NOCl]2 [1.6]2
 EA = 2.0 × 104 × R
32
Kc   103  EA = 2.0 × 104 × 8.3 J
2.56
Kc = 12.5 × 10-3  EA = 16.6 × 104J = 166 kJ

Kc = 125 × 10-4 7. The number of statement(s) correct from the

Integer answer is 125 following for copper (at no. 29) is/are ______

5. The limiting molar conductivities of NaI, NaNO3 (A) Cu(II) complexes are always paramagnetic
and AgNO3 are 12.7, 12.0 and 13.3 mS m2 mol-1, (B) Cu(I) complexes are generally colourless

Official Ans. by NTA (14)

Allen Ans. (14)
Sol. Given
EN
respectively (all at 25°C). The limiting molar
conductivity of AgI at this temperature is _____
mS m2 mol-1
(C) Cu(I) is easily oxidized
(D) In Fehling solution, the active reagent has
Cu(I)

Official Ans. by NTA (3)

Allen Ans. (3)
Sol. A,B,C are correct and D is incorrect because
(1)  m (NaI) = 12.7 mS m2 mol-1
LL
Fehling solution has Cu(II)
(2)  m (NaNO3) = 12.0 mS m2 mol-1 8. Acidified potassium permanganate solution

(3)  m (AgNO3) = 13.3 mS m2 mol-1 oxidises oxalic acid. The spin-only magnetic
moment of the manganese product formed from
 m (Ag I) = (1) + (3) - (2)
the above reaction is ______ B.M. (Nearest
= 12.7 + 13.3 – 12.0 Integer)
A

= 26.0 – 12.0
Official Ans. by NTA (6)
 m (Ag I) = 14.0
Allen Ans. (6)
6. The rate constant for a first order reaction is given Sol. 2KMnO4 + 5H2C2O4 + 3H2SO4  K2SO4
by the following equation: + 2MnSO4 + 10CO2 + 8H2O
2.0  10 K
4 Mn2+ has 5 unpaired electrons therefore the
ln k = 33.24 -
T magnetic moment is 35 BM
The Activation energy for the reaction is given by
______ kJ mol-1. (In Nearest integer)
(Given: R = 8.3 J K-1 mol-1)

Official Ans. by NTA (166)

Allen Ans. (166)

8
9. Two elements A and B which form 0.15 moles of CH3
A2B and AB3 type compounds. If both A2B and
AB3 weigh equally, then the atomic weight of A is
_____ times of atomic weight of B.
CH3
Official Ans. by NTA (2) 1,3-dimethylcyclopentane
will show stereo isomerism, Its stereo isomers are
Allen Ans. (2)
Sol. Given : Molar mass of A2B = AB3 CH3 CH3

 A  Atomic wt.of A 
 (2A + B) = (A + 3B)  
=
 B  Atomic wt.of B  (identical)
 A = 2B CH3 CH3
 atomic wt. of A is 2 times of atomic wt. of B
CH3
Integer answer is 2 CH3

10. Total number of

dimethyl cyclopentane is ___________

Official Ans. by NTA (5)

Allen Ans. (6)
Sol. Dimethyl cyclopentane
EN
possible stereoisomers of
CH3
(enantiomers)
CH3
LL
CH3
H3C

1,1-dimethylcyclopentane
no stereoisomer
CH3
A

CH3
1,2-dimethylcyclopentane
will show stereo isomerism, Its stereo isomers are
CH3
CH3
CH3
CH3
=
(identical)

CH3 CH3

CH3 CH3

(enantiomers)

9
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Monday 27th June, 2022) TIME : 3 : 00 PM to 6 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTIONS

SECTION-A 2. Identify the incorrect statement for PCl5 from the
1. Which amongst the given plots is the correct plot following.
for pressure (p) vs density (d) for an ideal gas ? (A) In this molecule, orbitals of phosphorous are
(A) assumed to undergo sp3d hybridization.
(B) The geometry of PCl5 is trigonal bipyramidal.
(C) PCl5 has two axial bonds stronger than three
equatorial bonds.
(D) The three equatorial bonds of PCl5 lie in a
plane.
(B)
Official Ans. by NTA (C)

(C)
EN 3.
Allen Ans. (C)
Sol. In PCl5, axial bonds are weaker than equatorial.

Statement I : Leaching of gold with cyanide ion

in absence of air / O2 leads to cyano complex of
Au(III).
LL
Statement II : Zinc is oxidized during the
displacement reaction carried out for gold
extraction.
(D) In the light of the above statements, choose the
correct answer from the options given below.
(A) Both Statement I and Statement II are correct
A

(B) Both Statement I and Statement II are incorrect

(C) Statement I is correct but Statement II is
incorrect
Official Ans. by NTA (B)
Allen Ans. (B) (D) Statement I is incorrect but Statement II is
Sol. P vs d : correct
 RT  Official Ans. by NTA (D)
P=   d
 M
Allen Ans. (D)
Sol. Statement-1 : wrong, Au+ is correct, not Au+3
Statement-2 : correct

T3 > T2 > T1

1
4. The correct order of increasing intermolecular 7. Given below are two statements: one is labelled as
hydrogen bond strength is Assertion A and the other is labelled as Reason R.
Assertion A : Flourine forms one oxoacid.
(A) HCN < H2O < NH3
Reason R : Flourine has smallest size amongst all
(B) HCN < CH4 < NH3
halogens and is highly electronegative
(C) CH4 < HCN < NH3 In the light of the above statements, choose the
(D) CH4 < NH3 < HCN most appropriate answer from the options given
below.
Official Ans. by NTA (C)
(A) Both A and R are correct and R is the correct
Allen Ans. (C) explanation of A.
Sol. Order of H-Bonding (B) Both A and R are correct but R is NOT the

CH4 < HCN < NH3 correct explanation of A.

(C) A is correct but R is not correct.
NCH . . . NCH
(D) A is not correct but R is correct

5.
H2NH . . . NH3

The correct order of increasing ionic radii is

2+ + –
(A) Mg < Na < F < O < N

(B) N3– < O2– < F– < Na+ < Mg2+

(C) F– < Na+ < O2– < Mg2+ < N3–

2– 3–
EN Official Ans. by NTA (A)
Allen Ans. (A)
Sol. Both A and R are correct and R is the correct
explanation of A.

8. In 3d series, the metal having the highest M2+/M

LL
(D) Na+ < F– < Mg2+ < O2– < N3– standard electrode potential is
(A) Cr (B) Fe
Official Ans. by NTA (A)
(C) Cu (D) Zn
Allen Ans. (A) Official Ans. by NTA (C)
–3 –2 – + +2
Sol. N > O > F > Na > Mg (Radii) Allen Ans. (C)
(Isoelectronic species) Sol. Cr+2/Cr  –0.90 V
A

Fe+2/Fe  –0.44 V
6. The gas produced by treating an aqueous solution
Cu+2/Cu  +0.34 V
of ammonium chloride with sodium nitrite is
Zn+2/Zn  –0.76 V
(A) NH3 (B) N2 So Ans. Cu+2/Cu
9. The ‘f’ orbitals are half and completely filled,
(C) N2O (D) Cl2
respectively in lanthanide ions
Official Ans. by NTA (B) (Given: Atomic no. Eu, 63; Sm, 62; Tm, 69; Tb,
Allen Ans. (B) 65; Yb, 70; Dy, 66]
(A) Eu2+ and Tm2+ (B) Sm2+ and Tm3+
Sol. NH4Cl + NaNO2  NH4NO2 + NaCl
(C) Tb4+ and Yb2+ (D) Dy3+ and Yb3+

Official Ans. by NTA (C)
  Allen Ans. (C)

2
Sol. Tb  4f 9 6s2 11. On the surface of polar stratospheric clouds,
hydrolysis of chlorine nitrate gives A and B while
Tb4  4f 7
its reaction with HCl produces B and C. A, B and
Yb  4f 14 6s2
C are, respectively
Yb2  4f14 (A) HOCl, HNO3, Cl2
10. Arrange the following coordination compounds in (B) Cl2, HNO3, HOCl
the increasing order of magnetic moments. (C) HClO2, HNO2, HOCl
(Atomic numbers: Mn = 25; Fe = 26) (D) HOCl, HNO2, Cl2O
(A) [FeF6]3– Official Ans. by NTA (A)
3–
(B) [Fe(CN)6] Allen Ans. (A)
(C) [MnCl6]3– (high spin)
(D) [Mn(CN)6]3–
Sol.
(A) A < B < D < C (B) B < D < C < A
(C) A < C < D < B (D) B < D < A < C
Official Ans. by NTA (B)
Allen Ans. (B)
Sol. (A) [FeF6]3–
+3
Fe  3d 4s
n=5
5 0
EN 12. Which of the following is most stable?

(A)

(B) [Fe(CN)6]3– (B)

LL
(C)
+3 5 0
Fe  3d 4s
n=1
(C) [MnCl6]3– (D)
A

Official Ans. by NTA (A)

Mn+3  3d4 4s0 Allen Ans. (A)

n=4
(D) [Mn(CN)6]3–
Sol. is most stable as it is aromatic.

Mn+3  3d4 4s0

n=2
A>C>D>B
3
13. What will be the major product of following 14. Product ‘A’ of following sequence of reactions is

sequence of reactions?
(a) Br2 .Fe
Ethylbenzene 
(b) Cl2 , 
'A'(Major product)
(c) alc. KOH

(i) n  BuLi, (A)

n  C5 H11Cl
n  Bu  
(ii) Lindlar cat, H 2

(A)
(B)

(B)

(C)

(C)

(D)
EN (D)
LL
Official Ans. by NTA (C)
Official Ans. by NTA (D)
Allen Ans. (C) Allen Ans. (D)
Sol.
A

nBuLi
Sol. n  Bu  C  CH   Br , Fe
(acid base
reaction)
2
EAS reaction


n  Bu  C  C– Li 

n – C5H11Cl (SN reaction)

Cl , 
2
benzylic

halogenation
H
 2
Lindlar 's
 n  Bu  C  C – C5H11
Catalyst

alc. KOH

(elimination

reaction)

4
15. Match List I with List II (C)
List I List II
A. I. Br2 in CS2

(D)
B. II. Na2Cr2O7/H2SO4

C. III. Zn
16. Decarboxylation of all six possible forms of
diaminobenzoic acids C6H3(NH2)2COOH yields
three products A, B and C. Three acids give a

D.
EN
IV. CHCl3/NaOH
product ‘A’, two acids gives a product ‘B’ and one
acid give a product ‘C’. The melting point of
product ‘C’ is
(A) 63ºC
(C) 104ºC
Official Ans. by NTA (D)
(B) 90ºC
(D) 142ºC
Choose the correct answer from the options given
Allen Ans. (D)
LL
below:
(A) A-IV, B-III, C-II, D-I Sol.
(B) A-IV, B-III, C-I, D-II
(C) A-II, B-III, C-I, D-IV
(D) A-IV, B-II, C-III, D-I
Official Ans. by NTA (A)
A

M.P. 142ºC
Allen Ans. (A)
Sol. (A)
17. Which is true about Buna-N?
(A) It is a linear polymer of 1, 3-butadiene.
(B) It is obtained by copolymerization of 1, 3-
butadiene and styrene.
(B) (C) It is obtained by copolymerization of 1, 3-
butadiene and acrylonitrile.
(D) The suffix N in Buna-N stands for its natural
occurrence
Official Ans. by NTA (C)
Allen Ans. (C)

5
Sol. It is copolymerization of 1, 3-butadiene and Sol.
acrylonitrile. A. Antipyretic Reduces fever
18. Given below are two statements. B. Analgesic Reduces pain
Statments I: Maltose has two -D-glucose units C. Tranquilizer Reduces stress
linked at C1 and C4 and is a reducing sugar. D. Antacid Reduces acidity (Stomach)
Statement II: Maltose has two monosaccharides:
-D-glucose and -D-glucose linked at C1 and C6 20. Match List I with List II
and it is a non-reducing sugar. List I List II
In the light of the above statements, choose the (Anion) (Gas evolved on reaction with dil.
correct answer from the options given below. H2SO4)
(A) Both Statement I and Statement II are true A. CO3 2-
I. Colourless gas which turns lead
(B) Both Statement I and Statement II are false acetate paper black
(C) Statement I is true but Statement II is false B. S2-
II. Colourless gas which turns

Sol.
Official Ans. by NTA (C)
Allen Ans. (C) EN
(D) Statement I is false but Statement II is true

C. SO32-

D. NO2 –
acidified potassium dichromate
solution green.
III. Brown fumes which turns
acidified KI solution containing
starch blue.
IV. Colourless gas evolved with
brisk effervescence, which turns
LL
lime water milky.
Choose the correct answer from the options given
below:
19. Match List I with List Ii (A) A-III, B-I, C-II, D-IV
List I List II (B) A-II, B-I, C-IV, D-III
A. Antipyretic I. Reduces pain
A

(C) A-IV, B-I, C-III, D-II

B. Analgesic II. Reduces stress (D) A-IV, B-I, C-II, D-III
C. Tranquilizer III. Reduces fever Official Ans. by NTA (D)
D. Antacid IV. Reduces acidity Allen Ans. (D)
(Stomach) Sol. CO32- will give CO2(g) which will turns lime water
Choose the correct answer from the options given milky.
below: S2- will give H2S (g), will turns lead acetate paper
(A) A-III, B-I, C-II, D-IV black
(B) A-III, B-I, C-IV, D-II SO32- will give SO2 (g), which will turns acidified
(C) A-I, B-IV, C-II, D-III potassium dichromate solution green.
(D) A-I, B-III, C-II, D-IV NO2– will give brown NO2(g) will turn KI solution
Official Ans. by NTA (A) blue.
Allen Ans. (A)

6
 SECTION-B 3. BeO reacts with HF in presence of ammonia to
1. 116 g of a substance upon dissociation reaction, give [A] which on thermal decomposition produces
yields 7.5 g of hydrogen, 60g of oxygen and 48.5 g [B] and ammonium fluoride. Oxidation state of Be
of carbon. Given that the atomic masses of H, O in [A] is_______
and C are 1, 16 and 12 respectively. The data Official Ans. by NTA (2)
agrees with how many formulae of the following? Allen Ans. (2)
(A) CH3COOH (B) HCHO Sol.
(C) CH3OOCH3 (D) CH3CHO
Official Ans. by NTA (2)
Allen Ans. (2)
7.5
Sol. %H   100  6.5
116
60 84. When 5 moles of He gas expand isothermally and
%O   100  51.7
116 reversibly at 300 K from 10 litre to 20 litre, the

%C 
48.5
116
 100  41.8

Relative atomicities = H  6.5

O
51.7
16
41.8
EN
 3.25
magnitude of the maximum work obtained is ____
J. [nearest integer] (Given: R = 8.3 J K-1mol-1 and
log 2 = 0.3010)
Official Ans. by NTA (8630)
Allen Ans. (8630)
C  3.5 Sol. n = 5 mol
12
LL
T = 300 K
Emperically formula is approx.. CH2O
V1 = 10 L
(A) C2H4O2 (B) CH2O relate to this formula.
V2 = 20 L
2. Consider the following set of quantum numbers
V2
n l ml w  –nRT n
V1
A. 3 3 -3
20
B. 3 2 -2  –5  8.3  300  n
A

10
C. 2 1 +1
= –8630.38 J
D. 2 2 +2
5. A solution containing 2.5 × 10-3 kg of a solute
The number of correct sets of quantum numbers is
dissolved in 75 × 10–3 kg of water boils at 373.535
_______
K. The molar mass of the solute is ______ g mol–1.
Official Ans. by NTA (2)
[nearest integer] (Given: Kb (H2O) = 0.52 K Kg
Allen Ans. (2)
mol–1 , boiling point of water = 373.15K)
Sol. Quantum no. of set (B) and (C) can be correct.
Official Ans. by NTA (45)
(A) and (D) are wrong as n =  is not possible.
Allen Ans. (45)
Sol. w = 2.5 g Kb = 0.52
wsolvent = 75 g M = Mol. Wt. of solute
T'B  373.535 K

7
 TBo  373.15 K 0.3  2.303  8.3  300  309
Ea 
9
TB = 0.385 = Kb molality
= 59065.04 J
 2.5 1000 
0.385  0.52     Ea = 59.06 kJ
M 75 
M = 45 g mol–1
9.
6. pH value of 0.001 M NaOH solution is______.
Official Ans. by NTA (11)
Allen Ans. (11)
Sol. 0.001 M NaOH
[OH–] = 10–3
pOH = 3
pH = 11
7. For the reaction taking place in the cell: If the initial pressure of a gas is 0.03 atm, the mass

Eo
Cell
+

= +0.5332 V.
+
Pt(s) | H2(g) | H (aq) || Ag (aq) | Ag(s)

EN
The value of fG0 is ________ kJ mol–1. (in nearest
integer)
Official Ans. by NTA (51)
Allen Ans. (51 or 103)
Sol.
of the gas adsorbed per gram of the adsorbent is
______ × 10–2g.
Official Ans. by NTA (12)
Allen Ans. (12)

x
m
 kP n
1

1 x 1
H  Ag   H   Ag
LL
Sol. log  log k  log P
2 2 m n
G° = – nE° F From graph
= –1 × 0.5332 × 96500 J 1
Slope   1 n  1
= –51.35 kJ n
Intercept = log k = 0.602
(n = 2 for H2  2Ag  2H   2Ag )
k=4
A

1
8. It has been found that for a chemical reaction with x
 4  (0.03)1
m
rise in temperature by 9K the rate constant gets
x
doubled. Assuming a reaction to be occurring at  12  10 –2
m
300 K, the value of activation energy is found to be
______ kJ mol–1. [nearest integer]
10. 0.25 g of an organic compound containing chlorine
(Given ln 10 = 2.3, R = 8.3 JK–1mol–1, log2 = 0.30)
gave 0.40 g of silver chloride in Carius estimation.
Official Ans. by NTA (59)
The percentage of chlorine present in the
Allen Ans. (59)
compound is ______. [in nearest integer]
K Ea  1 1 
Sol. log10 2   –  (Given: Molar mass of Ag is 108 g mol–1 and that
K1 2.303R 300 309 
of Cl is 35.5 g mol–1)
Ea  9 
0.3   
2.303  8.3 300  309 

8
 Official Ans. by NTA (40)
Allen Ans. (40)
Sol. wt. of organic compound = 0.25 g
35.5
mass of Cl   0.4g
143.5
mass % of Cl in the organic compound
35.5  0.4
  100
143.5  0.25
= 39.58%

EN
LL
A

9
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Tuesday 28th June, 2022) TIME : 9 : 00 AM to 12 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A Sol. E  [Ar] 3d10 4s2 4p4
1. The incorrect statement about the imperfections in Element above E  [Ne] 3s2 3p4
solids is : 4. Given are two statements one is labelled as
Assertion A and other is labelled as Reason R.
(A) Schottky defect decreases the density of the
Assertion A :Magnesium can reduce Al2O3 at a
substance. temperature below 1350°C, while above 1350°C
aluminium can reduce MgO.
(B) Interstitial defect increases the density of the
Reason R : The melting and boiling points of
substance. magnesium are lower than those of aluminium.
In light of the above statements. choose most
(C) Frenkel defect does not alter the density of the
appropriate answer from the options given below:
substance. (A) Both A and R are correct. and R is correct
explanation of A.
(D) Vacancy defect increases the density of the
substance.
Official Ans. by NTA (D)
Allen Ans. (D)
EN
Sol. Due to vacancy defect density of the substance will
decrease.
.
(B) Both A and R are correct. but R is NOT the
correct explanation of A.
(C) A is correct R is not correct.
(D) A is not correct. R is correct.
Official Ans. by NTA (B)
Allen Ans. (B)
Sol. From Ellingham diagram given in NCERT, it can
2. The Zeta potential is related to which property of be seen that Mg, MgO line crosses Al, Al2O3 line
LL
colloids” after 1350ºC hence assertion is true.
(A) Colour Yes, Mg have lower MP and BP than aluminium
(B) Tyndall effect but it does not explain the above fact.
(C) Charge on the surface of colloidal particles 5. Dihydrogen reacts with CuO to give
(D) Brownian movement (A) CuH2
(B) Cu
Official Ans. by NTA (C) (C) Cu2O
A

Allen Ans. (C) (D) Cu(OH)2

Official Ans. by NTA (B)
Sol. The potential difference between the fixed and
Allen Ans. (B)
diffused layer of charges in a colloidal particle is Sol. CuO + H2  Cu + H2O (under hot conditions)
called zeta potential 6. Nitrogen gas is obtained by thermal decomposition
3. Element "E" belongs to the period 4 and group 16 of
(A) Ba(NO3)2 (B) Ba(N3) 2
of the periodic table. The valence shell electron (C) NaNO2 (D) NaNO3
configuration of the element, which is just above Official Ans. by NTA (B)
‘E’ in the group is Allen Ans. (B)
2
(A) 3s . 3p 4 10 2
(B) 3d . 4s , 4p 4 Sol. Ba(N3)2  Ba + 3N2
(C) 4d10. 5s2, 5p4 (D) 2s2, p4
Official Ans. by NTA (A)
Allen Ans. (A)

1
7. Given below are two statements : Sol. [Ni(CN)4]2– : d8 configuration, SFL, sq. planar
Statement -I :The pentavalent oxide of group- 15
splitting (dsp2), diamagnetic.
element. E2O5. is less acidic than trivalent oxide.
E2O3. of the same element. [Ni(CO)4] : d10 config (after excitation), SFL,
Statement -II :The acidic character of trivalent
tetrahedral splitting (sp3), diamagnetic.
oxide of group 15 elements. E2O3. decreases down
the group. [NiCl4]2– : d8 config, WFL, tetrahedral
In light of the above statements. choose most splitting (sp3), paramagnetic(2 unpaired e–).
appropriate answer from the options given below: 10. Which amongst the following is not a pesticide ?
(A) Both Statement I and Statement II are true. (A) DDT
(B) Both Statement I and Statement II are false. (B) Organophosphates
(C) Statement I true. but statement II is false. (C) Dieldrin
(D) Statement I is false but statement II is true. (D) Sodium arsenite
Official Ans. by NTA (D) Official Ans. by NTA (D)
Allen Ans. (D) Allen Ans. (D)
Sol. As +ve oxidation state increases, EN of element 11. Which one of the following techniques is not used
increases hence acidic character increases. Down to spot components of a mixture separated on thin
layer chromatographic plate?
the group, non-metallic character decreases, acidic (A) I2 (Solid)

8.
character decreases.
Acidic character : E2O5 > E2O3
Down the group, acidic character of E2O3
decreases
EN
Which one of the lanthanoids given below is the
most stable in divalent form?
(A) Ce (Atomic Number 58)
12.
(B) U.V. Light
(C) Visualisation agent as a component of mobile
phase
(D) Spraying of an appropriate reagent
Official Ans. by NTA (C)
Allen Ans. (C)
Which of the following structures are aromatic in
nature?
(B) Sm (Atomic Number 62)
(C) Eu (Atomic Number 63)
LL
(D) Yb (Atomic Number 70)
Official Ans. by NTA (C)
Allen Ans. (C) (A) A,B,C and D
Eu Yb (B) Only A and B
Sol. E oM3 /M 2  (C) Only A and C
– 0.35 –1.05 (D) Only B, C and D
Official Ans. by NTA (B)
Hence, due to more reduction potential in Eu as
Allen Ans. (B)
A

compared to Yb, it can concluded that Eu2+ is more Sol. A, B aromatic

stable than Yb2+.
C,D is nonaromatic
9. Given below are two statements :
Statement I : [Ni(CN)4]2- is square planar and 13. The major product (P) in the reaction
diamagnetic complex. with dsp2 hybridization for HBr  ? P
Ni but [Ni(CO)4] is tetrahedral. paramagnetic and   
with sp3-hybridication for Ni. [Ph is – C6H5] is
Statement II: [NiCl4] 2- and [Ni(CO)4] both have
same d-electron configuration have same geometry
and are paramagnetic. (A)
In light the above statements. choose the correct
answer form the options given below:
(A) Both Statement I and Statement II are true.
(B) Both Statement I and Statement II are false.
(C) Statement I is correct but statement II is false. (B)
(D) Statement I is incorrect but statement II is true.
Official Ans. by NTA (B)
Allen Ans. (B)
2
 15. Which one of the following compounds is inactive
towards SN1 reaction?
(C)

(A)
(D)
(B)
Official Ans. by NTA (C)
Allen Ans. (C)
Sol.
Ph Br HBr Ph Br
(C)

Br

Ph Br

(D)

14.

 Ph is  C6 H5 
NaOD
PhCHO  Ph  CHO 
in D2 O
Br

A 
EN
The correct structure of product ‘A’ formed in the
following reaction.
O
||
Ph  C O 
Sol.

16.
Official Ans. by NTA (C)
Allen Ans. (C)
Sol. The carbocation fromed is very unstable.

So it is inactive towards SN1

Identify the major product formed in the following

sequence of reactions :
LL
(A)

(A)
A

(B)

(C) (B)

(D)
(C)
Official Ans. by NTA (A)
Allen Ans. (A)
Sol. PhCH = O + PhCH = O
OD/D2O
 PhCH2OD+PhCO2–
(D)
Official Ans. by NTA (C)

3
 Allen Ans. (C) 20. The formula of the purple colour formed in
NH2 NH2 Laissaigne’s test for sulphur using sodium
Br Br
Br2 nitroprusside is
+H2O (A) NaFe[Fe(CN)6] (B) Na[Cr(NH3)2(NCS)4]
Br

NaNO2 + HCl (C) Na2[Fe(CN)5(NO)] (D) Na4[Fe(CN)5(NOS)]

Official Ans. by NTA (D)
N2Cl–
Br Br Allen Ans. (D)
Sol. Na2S + Na2[Fe(CN)5NO]  Na4[Fe(CN)5NO5]

SECTION-B
Br
1. A 2.0 g sample containing MnO2 is treated with
H3PO2
HCl liberating Cl2. The Cl2 gas is passed into a
Br Br
solution of KI and 60.0 mL of 0.1 M Na2S2O3 is

Sol.

17.
Br
EN
A primary aliphatic amine on reaction with nitrous
acid in cold (273 K) and there after raising
temperature of reaction mixture to room
temperature (298 K). Gives a/an
required to titrate the liberated iodine. The
percentage of MnO2 in the sample is __________.
(Nearest integer)
[Atomic masses (in u) Mn = 55; Cl = 35.5; O = 16,
I = 127, Na = 23, K = 39, S = 32]

(A) nitrile (B) alcohol Official Ans. by NTA (13)

(C) diazonium salt (D) secondary amine
LL
Allen Ans. (13)
Official Ans. by NTA (B)
Allen Ans. (B)
 Cl 2  Mn 2
MnO 2  HCl 
 R – N 2 
NaNO2
Sol. R–NH 2   R   R–OH Sol. 6 meq 6 meq
 HCl H O 2
 3m mol
18. Which one of the following is NOT a copolymer ?  Cl   I 2
Cl 2  KI 
(A) Buna-S (B) Neoprene 6 meq 6 meq
A

(C) PHBV (D) Butadiene-styrene I 2  Na 2S2O3 

 I –  Na 2S4O6
Official Ans. by NTA (B) 6 meq 6 m mol
Allen Ans. (B)  6 meq
3  10 –3  87
Sol. Buna-S, PHBr and Butadiene-styrene are %MnO2   100
copolymer. Only neoprene is namopolymer. 2
= 13.05%
19. Stability of  - Helix structure of proteins depends Ans. 13
2. If the work function of a metal is 6.63 × 10–19 J, the
upon
maximum wavelength of the photon required to
(A) dipolar interaction
remove a photoelectron from the metal is _______
(B) H-bonding interaction
nm. (Nearest integer)
(C) van der Waals forces
(D)  -stacking interaction [Given : h = 6.63 × 10–34 J s, and c = 3 × 108 m s–1]

Official Ans. by NTA (B) Official Ans. by NTA (300)

Allen Ans. (B) Allen Ans. (300)
4
 hc 6.63  10 –34  3  10 8 Official Ans. by NTA (3)
Sol.  = 6.63 × 10–19J = 
  Allen Ans. (3)
–7
  = 3 × 10 m = 300 nm
3
3. The hybridization of P exhibited in PF5 is spxdy. A2 X3s 2A aq   3X–2aq 
The value of y is __________. so lub ility  sM 2s 3s
(2s) (3s) = 1.1 × 10–23
2 3

Official Ans. by NTA (1)

108 s5  1.110 –23
Allen Ans. (1) mol mol
s 10 –5 M  10 –5  0.01 3
Sol. PF5  sp3d hybridisation L m
 k k
(5 sigma bonds, zero lone pair on central atom) Now  m  m  
m s
Value of y = 1  3  10 –5
 m   3  10 –3 S-m2/mol
4. 4.0 L of an ideal gas is allowed to expand 0.01
Ans. 3
isothermally into vacuum until the total volume is 7. The quantity of electricity in Faraday needed to
20 L. The amount of heat absorbed in this
reduce 1 mol of Cr2 O27 to Cr 3 is _________.
expansion is ___________ L atm.

Official Ans. by NTA (0)

Allen Ans. (0)
Sol. For free expansion:

Ans. 0
EN
Pext = 0 , w = 0
q = 0 , U = 0
Sol.
Official Ans. by NTA (6)
Allen Ans. (6)

1mol 6mol
 2Cr 3
Cr2O7–2  6e – 

 number of faradays = moles of electrons

=6

5. The vapour pressures of two volatile liquids A and

LL
8. For a first order reaction A  B , the rate constant,
B at 25°C are 50 Torr and 100 Torr, respectively.
If the liquid mixture contains 0.3 mole fraction of k  5.5 1014 s1 . The time required for 67%

A, then the mole fraction of liquid B in the vapour completion of reaction is x × 10–1 times the half
life of reaction. The value of x is ________
x
phase is . The value of x is ________.
17 (Nearest integer)
A

Official Ans. by NTA (14) (Given : log 3 = 0.4771)

Allen Ans. (14) Official Ans. by NTA (16)

yB Po  X B  Allen Ans. (16)

Sol.  Bo  
1 – y B PA  1 – X B   
1  1  t1/2  1 
y 100  0.7  14 Sol. t 67%  ln    ln  
 B  
1 – y B 50  0.3  3 k  1 – 0.67  ln 2 1– 2 
 3
14
  y B   t1/2 t1/2  0.4771
17 t 67%   log3 
 Ans. 14 log 2 0.301
6. The solubility product of a sparingly soluble salt  t67% = 1.585 × t1/2
X × 10–1 = 1.585
A2X3 is 1.1 × 10–23. If specific conductance of the  X = 15.85
solution is 3 × 10–5 S m–1, the limiting molar Ans.16

conductivity of the solution is x × 10–3 S m2 mol–1.

The value of x is __________.

5
9. Number of complexes which will exhibit synergic
bonding amongst, [Cr(CO)6], [Mn(CO)5] and
[Mn2(CO)10] is ________.

Official Ans. by NTA (3)

Allen Ans. (3)
Sol. Carbonyl complex compounds have tendency to
show synergic bonding.
10. In the estimation of bromine, 0.5 g of an organic
compound gave 0.40 g of silver bromide. The
percentage of bromine in the given compound is
_________% (nearest integer)
(Relative atomic masses of Ag and Br are 108u
and 80u, respectively).

Sol
Official Ans. by NTA (34)
Allen Ans. (34)

O.C 
0.5g
 AgBr
0.4 g

0.4
EN
mol of Br = mol of AgBr =
188
LL
0.4
 80
% Br = %Br  188  100
0.5
= 34.04%
A

6
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Tuesday 28th June, 2022) TIME : 3 : 00 PM to 6 : 00
PM
CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A (D) ±1/2 are the two possible orientations of
1. Compound A contains 8.7% Hydrogen, 74% electron spin.
Carbon and 17.3% Nitrogen. The molecular (E) For l = 5, there will be a total of 9 orbital.
formula of the compound is, Which of the above statements are correct?
Given : Atomic masses of C, H and N are 12, 1 and (A) (A), (B) and (C)
14 amu respectively.
(B) (A), (C), (D) and (E)
The molar mass of the compound A is 162 g mol–1.
(C) (A), (C) and (D)
(A) C4H6N2 (B) C2H3N
(D) (A), (B), (C) and (D)
(C) C5H7N (D) C10H14N2

Sol.
Official Ans. by NTA (D)

Allen Ans. (D)

C 74%
74
12
 6.16
6.16
1.23
5
EN Official Ans. by NTA (C)

Allen Ans. (C)

Sol. (A) Number of values of n = 1, 2, 3 … 

(B) Number of values of  = 0 to (n – 1)

(C.) Number of values of m = –  to + 

17.3 1.23
N 17.3%  1.23 1
LL
14 1.23 Total values = 2 + 1
8.7 8.7
H 8.7%  8.7 7 1
1 1.23 (D) Values of spin = 
2
Emperical formula = C5NH7
(E) For  = 5 number of orbitals = 2+ 1= 11
Emperical weight = 81
162 3. In the structure of SF4, the lone pair of electrons on
Multiplying factor = 2
A

81
S is in.
Molecular formula = C10N2H14
(A) equatorial position and there are two lone pair-
2. Consider the following statements : bond pair repulsions at 90°
(A) The principal quantum number „n‟ is a positive
(B) equatorial position and there are three lone
integer with values of „n‟ = 1, 2, 3, ….
pair-bond pair repulsions at 90°
(B) The azimuthal quantum number „l‟ for a given
(C) axial position and there are three lone pair –
„n‟ (principal quantum number) can have values as
bond pair repulsion at 90°.
„l‟ = 0, 1, 2, …. n
(D) axial position and there are two lone pair –
(C) Magnetic orbital quantum number „ml‟ for a
bond pair repulsion at 90°.
particular „l‟ (azimuthal quantum number) has (2l
+ 1) values. Official Ans. by NTA (A)

Allen Ans. (A)

1
Sol. Choose the correct answer from the options given
F below :
F
(A) (A) – (II), (B) – (III), (C) – (IV), (D) – (I)
S (B) (A) – (II), (B) – (I), (C) – (III), (D) – (IV)
(C) (A) – (II), (B) – (III), (C) – (I), (D) – (IV)
F
F (D) (A) – (I), (B) – (III), (C) – (II), (D) – (IV)
sp3d, See-Saw Official Ans. by NTA (C)
Allen Ans. (C)
4. A student needs to prepare a buffer solution of
Sol. Negative charged sol = CdS (II)
propanoic acid and its sodium salt with pH 4. The
Macromolecular colloid = starch (III)

[CH3CH 2 COO ] Positively charged sol = Fe2O3.xH2O (I)
ratio of required to make buffer
[CH3CH 2 COOH] Cheese = gel (IV)
is ………. 6. Match List-I with List-II.

Given : Ka(CH3CH2COOH) = 1.3 × 10–5 List-I (Oxide) List-II (Nature)

(A) 0.03

(C) 0.23

Official Ans. by NTA (B)

Allen Ans. (B)

(B) 0.13

(D) 0.33
EN (A) Cl2O7
(B)
(C)
(D) N2O
Na2O
Al2O3
(I)
(II)
(III)
Amphoteric
Basic
Neutral
(IV) Acidic
Choose the correct answer from the options given
below :
Salt  (A) (A) – (IV), (B) – (III), (C) – (I), (D) – (II)
Sol. pH  pK a  log 
LL
Acid  (B) (A) – (IV), (B) – (II), (C) – (I), (D) – (III)
(C) (A) – (II), (B) – (IV), (C) – (III), (D) – (I)
CH3CH2COO 
4  5  log1.3  log  (D) (A) – (I), (B) – (II), (C) – (IIII), (D) – (IV)
CH3CH2COOH
Official Ans. by NTA (B)
CH3CH2COO  
1.3 Allen Ans. (B)
log   log1.3  1  log
CH3CH2COOH 10 Sol. Cl2O7 Acidic
A

Na2O Basic
CH3CH2COO  Al2O3 Amphoteric
 0.13
CH3CH2COOH N2O Neutral
7. In the metallurgical extraction of copper, following
5. Match List-I with List-II.
reaction is used :
List-I List-II
FeO + SiO2  FeSiO3
(A) Negatively (I) Fe2O3·xH2O FeO and FeSiO3 respectively are.
charged sol (A) gangue and flux (B) flux and slag
(B) Macromolecular (II) CdS sol (C) slag and flux (D) gangue and slag
colloid Official Ans. by NTA (D)
(C) Positively (III) Starch Allen Ans. (D)
charged sol Sol. FeO = Gangue

(D) Cheese (IV) a gel FeSiO3 = Slag

2
8. Hydrogen has three isotopes : protium (1H), Sol.
deuterium (2H or D) and tritium (3H or T). They S (–2) O O
have nearly same chemical properties but different +6 +5
O S OH HO S S +5 OH
physical properties. They differ in
(A) number of protons OH O O
H2S2O3 H2S2O6
(B) atomic number
(C) electronic configuration O O O O
(D) atomic mass HO S
+6
O S+6 OH HO S
+6
O O S+6 OH
Official Ans. by NTA (D)
O O O O
Allen Ans. (D) H2S2O7 H2S2O8
Sol. They have different neutrons and mass number
9. Among the following basic oxide is : 12. Correct statement about photo-chemical smog is :
(A) SO3 (B) SiO2 (A) It occurs in humid climate.
(C) CaO (D) Al2O3
(B) It is a mixture of smoke, fog and SO2
Official Ans. by NTA (C)
Allen Ans. (C) (C) It is reducing smog.
Sol. SO3, SiO2 = Acidic

10.
CaO = Basic
Al2O3 = Amphoteric EN
Among the given oxides of nitrogen; N2O, N2O3,
N2O4 and N2O5, the number of compound/(s)
having N–N bond is :
(D) It results from reaction of unsaturated
hydrocarbons.

Official Ans. by NTA (D)

Allen Ans. (D)

Sol. Photo chemical smog results from the action of

(A) 1 (B) 2 sunlight on unsaturated hydro carbons and nitrogen
LL
(C) 3 (D) 4 oxide

Official Ans. by NTA (C) 13. The correct IUPAC name of the following
compound is :
Allen Ans. (C)
Sol.
O O O O
A

+
N  N– O –
N–N N–N
O O O (A) 4-methyl-2-nitro-5-oxohept-3-enal
N2O N2O3 N2O4
(B) 4-methyl-5-oxo-2-nitrohept-3-enal
O O
N –O– N (C) 4-methyl-6-nitro-3-oxohept-4-enal
O O (D) 6-formyl-4-methyl-2-nitrohex-3-enal
N2O5
Official Ans. by NTA (C)
11. Which of the following oxoacids of sulphur
contains “S” in two different oxidation states? Allen Ans. (C)

(A) H2S2O3 (B) H2S2O6 Sol.

(C) H2S2O7 (D) H2S2O8

Official Ans. by NTA (A)
Allen Ans. (A)
4-Methyl-6-nitro-3-oxohept-4-enal

3
14. The major product (P) of the given reaction is CH3 CH2–Cl
(where, Me is –CH3) Cl2 / CN

Br Br

CH2–CN CH2–COOH
H3O+
(A)
Br Br
16. Isobutyraldehyde on reaction with formaldehyde
(B)
and K2CO3 gives compound „A‟. Compound „A‟
reacts with KCN and yields compound „B‟, which
(C) on hydrolysis gives a stable compound „C‟. The
compound „C‟ is :

Sol.

Me
(D)
Official Ans. by NTA (C)
Allen Ans. (C)

OH Me OH2
EN (A)

(B)

Me H
+
Me
LL
Me Me H2 O
(C)
Me Me Me Me Me O
H3 C
Me
1,2-Methyl shift H+
Me Me
Me H3 C O
(i) Cl2 , 
15. A    4-Bromophenyl acetic acid. (D) HO
(ii) CN
(iii) H 2O/H  Official Ans. by NTA (C)
A

In the above reaction „A‟ is Allen Ans. (C)

Sol.

O
CH3 O H3C O
K 2CO3 H–C –H
(A) (B) CH3–CH–C–H Base CH3 – C – C – H

H3C O H3C O–
(C) (D) CH3 – C – C – H
KCN
CH3 – C – CH – CN
Official Ans. by NTA (C) CH2–OH CH2–OH
Allen Ans. (C) O
HO H3C OH
Sol. H3C H3 O+
O CH3 – C – CH – COOH
H3C CH2–OH
Stable product

4
17. With respect to the following reaction, consider the 19. When sugar „X‟ is boiled with dilute H2SO4 in
given statements : alcoholic solution, two isomers „A‟ and „B‟ are
formed. „A‟ on oxidation with HNO3 yields
HNO saccharic acid where as „B‟ is laevorotatory. The
 3
H SO , 288k
 products compound „X‟ is :
2 4

(A) o-Nitroaniline and p-nitroaniline are the (A) Maltose (B) Sucrose
predominant products
(C) Lactose (D) Strach
(B) p-Nitroaniline and m-nitroaniline are the
predominant products Official Ans. by NTA (B)
(C) HNO3 acts as an acid Allen Ans. (B)
(D) H2SO4 acts as an acid H
Sol. C12H22O11  H2O  
+
C6H12O6  C6H12O6
(A) (A) and (C) are correct statements.
[] = 66.6° D-Glucose D-Fructose
(B) (A) and (D) are correct statements. [] = +52.7° [] = –92.2°
(C) (B) and (D) are correct statements. (A) (B)
(D) (B) and (C) are correct statements. CHO COOH
Official Ans. by NTA (C) H OH H OH
Allen Ans. (C) HO H HO H
HNO

Sol.
NH2
HNO3
H 2SO4

HNO3  H2SO4  NO2

Base Acid
NH2

2%
NO2
+
NH2

47%
EN
+
NO2
NH2

NO2
51%
20.
H
H
CH2OH
OH
OH

The drug tegamet is :

3
H
H
OH
OH
COOH
Sachharic acid

18. Given below are two statements, one is Assertion

(A) and other is Reason (R).
LL
Assertion (A) : Natural rubber is a linear polymer (A)
of isoprene called cis-polyisoprene with elastic CH(NO2 )
properties. NMe2 S
Reason (R) : The cis-polyisoprene molecules O N NHMe
(B) H
consist of various chains held together by strong
polar interactions with coiled structure.
In the light of the above statements, choose the
A

correct one from the options given below :

(A) Both (A) and (R) are true and (R) is the correct (C)
explanation of (A)
(B) Both (A) and (R) are true but (R) is not the
correct explanation of (A).
(C) (A) is true but (R) is false.
(D) (A) is false but (R) is true.
Official Ans. by NTA (C)
(D)
Allen Ans. (C)
Official Ans. by NTA (C)
Sol. Natural rubber is linear polymer of isoprene (2-
methyl-1,3-butadiene) and is also called cis-1,4- Allen Ans. (C)
polyisoprene. The cis-polyisoprene molecules Sol. Tegamet is the brand name of Cimetidine
consists of various chains held together by weak N CH3 CN
Vander Waal‟s interactions and has a coiled N
structure
N S N
H NHCH3

5
 SECTION-B 4. For the given reactions
1. 100 g of an ideal gas is kept in a cylinder of 416 L Sn2+ + 2e–  Sn
volume at 27°C under 1.5 bar pressure. The molar
mass of the gas is ______ g mol–1. (Nearest Sn4+ + 4e–  Sn
integer) (Given : R = 0.083 L bar K–1 mol–1)
o
The electrode potentials are; ESn 2 = –0.140 V
Official Ans. by NTA (4) /Sn
o
Allen Ans. (4) and ESn 4
/Sn
= 0.010 V. The magnitude of
100 standard electrode potential for Sn4+/Sn2+ i.e.
Sol. 1.5  416   0.083  300
M o
ESn is ______ × 10–2 V. (Nearest integer)
4
M = 3.99 /Sn 2 

Ans. 4 Official Ans. by NTA (16)

2. For combustion of one mole of magnesium in an Allen Ans. (16)
open container at 300 K and 1 bar pressure, C HΘ
= –601.70 kJ mol–1, the magnitude of change in Sol. Sn2  2e  Sn G10  2  0.140  F
internal energy for the reaction is _____ kJ. Sn4  4e  Sn G02  4  0.01  F
(Nearest integer)
_____________________________________
(Given : R = 8.3 J K–1 mol–1)
Sn4  2e  Sn2 G30  2  E0Sn 4 /Sn 2  F

Sol.
Official Ans. by NTA (600)
Allen Ans. (600)
1
Mg(s)  O2 (g)  MgO(s)
2
H  U  ng RT
1
601.70  103  U 
2
 8.3  300
EN 5.
G30  G02  G10
–2 × E0 × F = –(0.04 + 0.28) × F
E0 = 0.16 volt = 16 × 10–2 V
Ans 16
A radioactive element has a half life of 200 days.
The percentage of original activity remaining after
601.70kJ  U  1.245kJ
83 days is ______. (Nearest integer)
LL
U  600.455kJ
(Given : antilog 0.125 = 1.333, antilog 0.693 =
Ans. 600 4.93)
3. 2.5 g of protein containing only glycine (C2H5NO2)
is dissolved in water to make 500 mL of solution. Official Ans. by NTA (75)
The osmotic pressure of this solution at 300 K is Allen Ans. (75)
found to be 5.03 × 10–3 bar. The total number of
glycine units present in the protein is ____ t1/2 A 0
t log
A

–1 –1 Sol.
(Given : R = 0.083 L bar K mol ) 0.3 A t
Official Ans. by NTA (330)
200 A 0
Allen Ans. (330) 83  log
0.3 A t
Sol.   CRT
A 0
5.03 103  C  0.083  300 0.125  log
A t
C  0.202 103 M
A 0 4
Moles of protein = 0.202 × 10–3 × 0.5  1.333 
= 10–4 × 1.01 A t 3

2.5 A t 3

1.01  104    100   100  75%
M A 0 4
M(molar mass of protein) = 24752
Ans. 75
24752
 No. of glycine units =  330.03
75

6
6. [Fe(CN)6]4– Official Ans. by NTA (46)
[Fe(CN)6]3– Allen Ans. (46)
3–
[Ti(CN)6] 0.793
Sol. Mole of CO2 = Moles of C =
[Ni(CN)4] 2– 44

[Co(CN)6]3– 0.793
Weight of „C‟ =  12  0.216 gm
44
Among the given complexes, number of
paramagnetic complexes is _____. 0.442
Moles of „H‟ = 2
18
Official Ans. by NTA (2)
0.442
Allen Ans. (2) Weight of „H‟ =  2  1  0.049 gm
18
Sol. [Fe(CN)6]4– Diamagnetic
 Weight of „O‟=0.492–0.216–0.049= 0.227 gm
3–
[Fe(CN)6] Paramagnetic (1 unpaired electron)
0.227
[Ti(CN)6]3– Paramagnetic (1 unpaired electron) % of ' O'   100  46.13%
0.492
[Ni(CN)4]2– Diamagnetic Ans. 46
3–
[Co(CN)6] Diamagnetic
Ans. 2
7. (a) CoCl3·4 NH3
(b) CoCl3·5NH3
(c) CoCl3·.6NH3 and
(d) CoCl(NO3)2·5NH3
EN 9. The major product of the following reaction
contains _______ bromine atom(s).

Number of complex(es) which will exist in cis- Official Ans. by NTA (1)
LL
trans is/are Allen Ans. (1)
Sol.
Official Ans. by NTA (1)
Br
Allen Ans. (1)
Sol. (a) CoCl3·4 NH3 = [Co(NH3)4 Cl2]Cl
Can exhibit G.I. cc
(b) CoCl3·5NH3 = [Co(NH3)5 Cl]Cl2
A

O
Can‟t exhibit G.I.
No. of Br atoms = 1
(c) CoCl3·.6NH3 = [Co(NH3)6]Cl3 10. 0.01 M KMnO4 solution was added to 20.0 mL of
Can‟t exhibit G.I. 0.05 M Mohr‟s salt solution through a burette. The
(d) CoCl(NO3)2·5NH3 = [Co(NH3)5 Cl](NO3)2 initial reading of 50 mL burette is zero. The
OR volume of KMnO4 solution left in the burette after
the end point is _______ mL. (nearest integer)
= [Co(NH3)5 (NO3)]Cl(NO3)
Official Ans. by NTA (30)
Both can‟t exhibit G.I.
Allen Ans. (30)
8. The complete combustion of 0.492 g of an organic
Sol. N1 V1  N2 V2
compound containing „C‟, „H‟ and „O‟ gives
0.01 × 5 × V1 = 0.05 × 1 × 20
0.793g of CO2 and 0.442 g of H2O. The percentage
V1 = 20 ml used
of oxygen composition in the organic compound is
 Volume left = 50 – 20 = 30 ml
____________. (nearest integer)

7
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Wednesday 29th June, 2022) TIME : 9 : 00 AM to 12 : 00 PM

CHEMISTRY TEST PAPER WITH ANSWER

SECTION-A (C) (A) and (C) only
1. Question ID: 101731 (D) (A), (B) and (C) only
Production of iron in blast furnace follows the Official Ans. by NTA (D)
following equation Allen Ans. (D)
Fe3O4(s) + 4CO(g) 3Fe(l) + 4CO2(g) Sol. (A) Cr = [Ar]3d5 4s1
when 4.640 kg of Fe3O4 and 2.520 kg of CO are (B) m = – to +
allowed to react then the amount of iron (in g)
(C) According to Aufbau principle, orbitals are
produced is :
filled in order of their increasing energies.
[Given : Molar Atomic mass (g mol –1): Fe = 56
Molar Atomic mass (g mol –1) : 0 = 16 (D) Total nodes = n – 1

Molar Atomic mass (g mol –1): = C = 12

(A) 1400
(C) 3360
Official Ans. by NTA (C)
Allen Ans. (C)
(B) 2200
(D) 4200
EN 3. Question ID: 101733
Arrange the following in the decreasing order of
their covalent character :
(A) LiCl
(B) NaCl
(C) KCl
4.640  103
Sol. Moles of Fe3O4   20
LL
232 (D) CsCl

2.52  103 Question: Choose the most appropriate answer

Moles of CO   90
28 from the options given below :
So limiting Reagent = Fe3O4 (A) (A)> (C) > (B)> (D)
So moles of Fe formed = 60 (B) (B) > (A) > (C) > (D)
Weight of Fe = 60 × 56 = 3360 gms (C) (A) > (B) > (C) > (D)
A

2. Question ID: 101732 (D) (A) > (B) > (D) > (C)
Which of the following statements are correct ? Official Ans. by NTA (C)
(A) The electronic configuration of Cr is [Ar] 3d 5 Allen Ans. (C)
4s1. Sol. LiCl > NaCl > KCl > CsCl (Covalent character)
(B) The magnetic quantum number may have a
negative value. 4. Question ID: 101734
(C) In the ground state of an atom, the orbitals are The solubility of AgCl will be maximum in which
filled in order of their increasing energies. of the following ?
(D) The total number of nodes are given by n – 2 . (A) 0.01 M KCl
Choose the most appropriate answer from the (B) 0.01 M HC1
options given below : (C) 0.01 M AgNO3
(A) (A), (C) and (D) only (D) Deionised water
(B) (A) and (B) only Official Ans. by NTA (D)
1
 Allen Ans. (D) Sol. For ZnS, KCN is used as depressant.
Sol. In deionized water no common ion effect will take For Gold and silver  leaching [Cyanide process]
place so maximum solubility 8. Question ID: 101738
5. Question ID:101735 Which one of the following reactions indicates the
Which of the following is a correct statement ? reducing ability of hydrogen peroxide in basic
(A) Brownian motion destabilises sols. medium ?
(B) Any amount of dispersed phase can be added (A) HOCl + H2O2  H3O+ + Cl– + O2
to emulsion without destabilising it. (B) PbS + 4H2O2 PbSO4 + 4H2O
(C) Mixing two oppositely charged sols in equal (C) 2MnO4  3H2O2  2MnO2  3O2  2H2O  2OH
amount neutralises charges and stabilises colloids. (D) Mn2 + + H2O2 Mn4+ + 2OH–
(D) Presence of equal and similar charges on Official Ans. by NTA (C)
colloidal particles provides stability to the colloidal Allen Ans. (C)
solution. Sol. In option (A) and (C) reducing action of hydrogen
Official Ans. by NTA (D)

6.
Allen Ans. (D)

other, hence will never precipitate.

Question ID: 101736
EN
Sol. As equal & similar charge particle will repel each

The electronic configuration of Pt (atomic number

peroxide is shown.
In option (A) it is in acidic medium, in option (B)
it is in basic medium.
or
For reducing ability H2O2 changes to O2 , i.e.
oxidize , so in option 'A' & 'C' O2 is formed but 'A'
78) is: is in acidic medium so option - C correct.
LL
14 9 1
(A) [Xe] 4f 5d 6s 9. Question ID: 101739
(B) [Kr] 4f14 5d10 Match the List-I with List- II.
14 10
(C) [Xe] 4f 5d List-I List-II
(D) [Xe] 4f14 5d8 6s2 (Metal) (Emitted light
Official Ans. by NTA (A) wavelength (nm))
Allen Ans. (A)
A

(A) Li (I) 670.8

Sol. 78Pt = [Xe] 4f14 5d9 6s1 (Exceptional electronic
(B) Na (II) 589.2
configuration)
(C) Rb (III) 780.0
7. Question ID: 101737
(D) Cs (IV) 455.5
In isolation of which one of the following metals
from their ores, the use of cyanide salt is not
Choose the most appropriate answer from the
commonly involved ?
options given below:
(A) Zinc
(A) (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
(B) Gold
(B) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)
(C) Silver
(C) (A)-(III), (B)-( I), (C)-(II), (D)-(IV)
(D) Copper
(D) (A)-(IV), (B)-(II), (C)-(I), (D)-(III)
Official Ans. by NTA (D)
Official Ans. by NTA (A)
Allen Ans. (D)
Allen Ans. (A)

2
Sol. NCERT Table 10.1.5 (C) Pyrophosphorus acid
Metal Li Na K Rb Cs (D) Hypophosphoric acid
Official Ans. by NTA (B)
Colour Crimson Yellow Violet Red Blue
red Violet
Allen Ans. (B)

/nm 670.8 589.2 766.5 780.0 455.5 Sol. P4 + 3NaOH + 3H2O  PH3 + 3NaH2PO2
oxoacid = H3PO2 (hypo phosphorus acid) or

10. Question ID: 101740 (phosphinic acid)

Match the List-I with List- II. 12. Question ID: 101742

List-I List-II The acid that is believed to be mainly responsible

(Metal) Application for the damage of Taj Mahal is

(A) Cs (I) High temperature (A) Sulfuric acid (B) Hydrofluoric acid
(C) Phosphoric acid (D) Hydrochloric acid
thermometer
Official Ans. by NTA (A)
(B) Ga (II) Water repellent
Allen Ans. (A)

(C) B
(D) Si

option given below:

sprays

EN
(III) Photoelectric cells
(IV) Bullet proof vest
Choose the most appropriate answer from the

(A) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)

Sol. CaCO3 + H2SO4  CaSO4 + H2O + CO2
13. Question ID:101743
Two isomers 'A' and 'B' with molecular formula
C4H8 give different products on oxidation with
KMnO4 in acidic medium. Isomer 'A' on reaction
with KMnO4/H+ results in effervescence of a gas
LL
(B) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
and gives ketone. The compound 'A' is
(C) (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
(A) But-1-ene (B) cis-But-2-ene
(D) (A)-(I), (B)-(IV), (C)-(II), (D)-(III) (C) trans-But-2ene (D) 2-methyl propene
Official Ans. by NTA (A) Official Ans. by NTA (D)
Allen Ans. (A) Allen Ans. (D)
Sol. Caesium is used in devising photoelectric cells.
A

CH3 CH3
KMnO4/Hf
Boron fibres are used in making bullet–proof vest. Sol. C=CH2 C=O
CH3 CH3
Silicones being surrounded by non–polar alkyl
+CO2
groups are water repelling in nature.

Gallium is less toxic and has a very high boiling 14. Question ID:101744

point, so it is used in high temperature

thermometers.
11. Question ID: 101741
The oxoacid of phosphorus that is easily obtained In the given conversion the compound A is:
from a reaction of alkali and white phosphorus and
Li
has two P-H bonds, is :
(A) Phosphonic acid (A)
(B) Phosphinic acid
OH
3
 Li Official Ans. by NTA (A)

(B) Allen Ans. (A)

O O
OLi Sol.
R–OH + R–C–OH R–O–C–R
nucleophilic acyl substitution

(C)
electron with drawing group on carboxylic acid
will increase the rate of esterification
C(CH3)3 16. Question ID: 101746
NH2 NH2
(D)
Br2(excess) (i) (CH3CO)2O
OH H2O
A
Major Product (ii) Br2, CH3COOH
B
Major Product
(ii) HCl

Consider the above reaction, the product A and

Official Ans. by NTA (B)
product B respectively are
Allen Ans. (B)
Sol.

Br

O
H
RLi

O=C=O
Li

OLi
+ RBr

O
EN (A)

Br
NH2

Br
NH2
and

Br Br
NH2

Br
NH2
Br
C
–
O Li (B) and
LL
OLi
+
H3O Br Br
NH2 NH2
CO2H
Br Br

OLi (C) and

A

Br Br
NH2 NH2
Br Br
15. Question ID:101745
(D) and
Given below are two statements :
Statement I : The esterification of carboxylic acid Br Br
with an alcohol is a nucleophilic acyl substitution.
Official Ans. by NTA (C)
Statement II : Electron withdrawing groups in the
carboxylic acid will increase the rate of Allen Ans. (C)
esterification reaction. Sol.
Choose the most appropriate option :
(A) Both Statement I and Statement II are correct.
(B) Both Statement I and Statement II are incorrect.
(C) Statement I is correct but Statement II is incorrect.
(D) Statement I is incorrect but Statement II is correct.

4
 19. Question ID: 101749
NH2 NH2
Br Br Which of the following compound does not
Br2 (excess)
H2O
contain sulfur atom ?
(A) Cimetidine (B) Ranitidine
Br
(C) Histamine (D) Saccharin
Official Ans. by NTA (C)
O
Allen Ans. (C)
NH2 O O NH–C–CH3
N NH2
(i)CH3 – C– O–C–CH3
Sol. N
H Histamine
Br2|CH3COOH
O
NH2 NH–C–NH3 Histamine is nitrogenous compound it does not
contain sulpher.
HCl

17.
Br

Question ID: 101747

Br
EN
The polymer, which can be stretched and retains its
20. Question ID: 101750
Given below are two statements.
Statement I : Phenols are weakly acidic.
Statement II : Therefore they are freely soluble in
NaOH solution and are weaker acids than alcohols
and water.
original status on releasing the force is Choose the most appropriate option:
LL
(A) Bakelite (B) Nylon 6,6 (A) Both Statement I and Statement II are correct.
(C) Buna-N (D) Terylene (B) Both Statement I and Statement II are incorrect.
Official Ans. by NTA (C) (C) Statement I is correct but Statement II is
Allen Ans. (C) incorrect.
Buna – N is synthetic rubber which can be (D) Statement I is incorrect but Statement II is
stretched and retains its original status on releasing correct.
A

the force. Official Ans. by NTA (C)

18. Question ID: 101748 Allen Ans. (C)
Sugar moiety in DNA and RNA molecules Sol. Phenol are weakly acidic. Phenol is more acidic
respectively are than alcohol & H2O statement (I) is correct. (II) is
(A) -D-2-deoxyribose,  -D-deoxyribose incorrect.
(B) -D-2-deoxyribose,  -D-ribose SECTION-B
(C) -D-ribose,  -D-2-deoxyribose 1. Question ID: 101751
(D) -D-deoxyribose,  -D-2-deoxyribose Geraniol, a volatile organic compound, is a
Official Ans. by NTA (B) component of rose oil. The density of the vapour is
Allen Ans. (B) 0.46 gL–1 at 257°C and 100 mm Hg. The molar
Sol. DNA contains – D – 2 – deoxyribose mass of geraniol is ___________ (Nearest Integer)
RNA contains – D – ribose [Given R = 0.082 L atm K–1 mol–1]
5
 Official Ans. by NTA (152) A dilute solution of sulphuric acid is electrolysed
using a current of 0.10 A for 2 hours to produce
Allen Ans. (152)
hydrogen and oxygen gas. The total volume of
dRT gases produced at STP is ________ cm3. (Nearest
Sol. Assuming ideal behaviour P 
M integer) [Given : Faraday constant F = 96500 C
100 mo1–1 at STP, molar volume of an ideal gas is
P atm, T = 257 + 273 = 530 K
760 22.7 L mo1–1]
d = 0.46 gm/L Official Ans. by NTA (127)

0.46  0.082  530 Allen Ans. (127)

So M   760 Sol. At anode
100
2H2O  O2(g) + 4H+ + 4e–
= 151.93  152
At cathode
2. Question ID: 101752 2H+ + 2e– H2(g)
17.0 g of NH3 completely vapourises at – 33.42°C i t
Now number of gm eq. =
96500
and 1 bar pressure and the enthalpy change in the
0.1 2  60  60
process is 23.4 kJ mol–1. The enthalpy change for 

conditions is ________ kJ.

Official Ans. by NTA (117)
Allen Ans. (117)
EN
the vapourisation of 85 g of NH3 under the same

Sol. Given data is for 1 moles and asked for 5 moles so

VO2 

VH2 
96500
= 0.00746
0.00746
4
0.00746
2
 22.7  0.0423

 22.7  0.0846

VTotal  127 ml or cc
value is 23.4 × 5 = 117 kJ
LL
5. Question ID: 101755
3. Question ID: 101753
The activation energy of one of the reactions in a
1.2 mL of acetic acid is dissolved in water to make
2.0 L of solution. The depression in freezing point biochemical process is 532611 J mo1–1. When the
observed for this strength of acid is 0.0198°C. The temperature falls from 310 K to 300 K, the change
percentage of dissociation of the acid is ________ .
in rate constant observed is k300 = x  10–3 k310. The
(Nearest integer)
value of x is _________.
A

[Given : Density of acetic acid is 1.02 g mL–1

Molar mass of acetic acid is 60 g mol–1 [Given: 1n10 = 2.3

Kf (H2O) =1.85 K kg mo1–1] R=8.3 J K–1 mo1–1]

Official Ans. by NTA (5) Official Ans. by NTA (1)
Allen Ans. (5)
Allen Ans. (1)
Sol. M = d × V = 1.02 × 1.2 = 1.224 gm
Moles of acetic acid = 0.0204 moles in 2L K  E  1 1 
Sol. n 2   a   
So molality = 0.0102 mol/kg  K1  R  T1 T2 
Now Tf = i × Kf × M
 K  532611  10 
i = 1 +  for acetic acid n 2    
 1
K 8.3  310  300 
0.0198 = (1 + ) × 1.85 × 0.0102
 = 0.04928 where K2 is at 310 K & K1 is at 300 K
 K 
n  2   6.9
4. Question ID: 101754  K1 

6
 = 3×n10

K2
n  n10
K1
K2 = K1 × 103
K1 = K2 × 103
So K = 1
6. Question ID: 101756
The number of terminal oxygen atoms present in the
8. Question ID: 101758
product B obtained from the following reaction is
Kjeldahl's method was used for the estimation of
________.
nitrogen in an organic compound. The ammonia
FeCr2O4 + Na2CO3+ O2 A + Fe2O3 + CO2
evolved from 0.55 g of the compound neutralised
+ +
A + H B+ H2O + Na 12.5 mL of 1 M H2SO4 solution. The percentage of
Official Ans. by NTA (6)
Allen Ans. (6)
Sol. 4FeCr2O4 + 8Na2CO3 + 7O2  8Na2CrO4 +
2Fe2O3 + 8CO2
2Na2CrO4 + 2H+  Na 2 Cr2 O7 + 2Na+ + H2O
B
EN Sol.
nitrogen in the compound is _________. (Nearest
integer)
Official Ans. by NTA (64)
Allen Ans. (64)
Meq of H2SO4 used by NH3 = 12.5 × 1 × 2 = 25

25  10 –3 14 100
% of N in the compound = = 63.6
LL
2–
0.55
O O O
+ O Cr Cr O
2Na or
O O
Meq. of H2SO4 = Meq. of NH3
12. 5 × 1 × 2 = 25 meq. of NH3
7. Question ID: 101757
= 25 millimoles of NH3
An acidified manganate solution undergoes So Millimoles of 'N' = 25
A

disproportionation reaction. The spin-only Moles of 'N' = 25 × 10–3

magnetic moment value of the product having wt. of N = 14 × 25×10–3
manganese in higher oxidation state is _________ 14  25  103
%N   100
B.M. (Nearest integer) 0.55
Official Ans. by NTA (0) = 63.66
 64%
Allen Ans. (0)
7 4 9. Question ID: 101759

Sol. 4  4H 
3MnO2–  2 Mn O4–  Mn O2  2H 2O
Observe structures of the following compounds
7
Mn = no. of unpaired electrons is '0' NH2
OH
Cl OH
 = 0 B.M. H2N
OH
O
O

7
 The total number of structures/compounds which
possess asymmetric carbon atoms is __________.
Official Ans. by NTA (3)
Allen Ans. (3)

Cl NH2 *
OH
Sol. * * *
O * OH

Number of compounds containing asymmetric

carbons are three.
10. Question ID: 101760

C6 H12 O6 
Zymase
 A 
NaOI

 B  CHI3

Sol.
Official Ans. by NTA (1)
Allen Ans. (1)
EN
The number of carbon atoms present in the product
B is __________.
LL
A
Zymase
C6H12O6 CH3CH2OH + CO2
NaOI
O
+
CHI3 + H–C–O¯Na
B
A

no. of carbon atoms present in B is 1

8
 FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Wednesday 29th June, 2022) TIME : 3 : 00 PM to 06 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A 3. Consider the species CH4, NH4+ and BH4–. Choose
1. Using the rules for significant figures, the correct the correct option with respect to the there species:
0.02858  0.112 (A) They are isoelectronic and only two have
answer for the expression will be: tetrahedral structures
0.5702
(A) 0.005613 (B) 0.00561 (B) They are isoelectronic and all have tetrahedral
(C) 0.0056 (D) 0.006 structures
Official Ans. by NTA (B) (C) Only two are isoelectronic and all have
Allen Ans. (B) tetrahedral structures
Sol. Reported answer should not be more precise than (D) Only two are isoelectronic and only two have
least precise term in calculations, so there should tetrahedral structures
be three significant figures in reported answer. Official Ans. by NTA (B)
2.

(A)
2(r)
EN
Which of the following is the correct plot for the
probability density (r) as a function of distance
'r' of the electron form the nucleus for 2s orbital?
Sol.

4.
Allen Ans. (B)

H
H
C
H
H H
H
N
H
H H
H
B
H
H

All are tetrahedral and each have 10 electrons.

4.0 moles of argon and 5.0 moles of PCI5 are
introduced into an evacuated flask of 100 litre
capacity at 610 K. The system is allowed to
LL
r
equilibrate. At equilibrium, the total pressure of
2(r) mixture was found to be 6.0 atm. The Kp for the
(B) reaction is [Given : R = 0.082L atm K–1 mol–1]
(A) 2.25 (B) 6.24
(C) 12.13 (D) 15.24
r
Official Ans. by NTA (A)
A

 (r)
2 Allen Ans. (A)
Sol. PCl5 = 5 mole
(C)
Ar = 4 mole
r 9  0.82  610
PTotal   4.5atm
100
5  4.5 4  4.5
2(r) PPCl5   2.5 ; PAr  2
9 9
(D)
PCl5 PCl3 + Cl2
r 2.5 – P P P
Official Ans. by NTA (B) Ptotal = 2.5 – P + P + P + PAr = 6
Allen Ans. (B) P = 1.5
1.5  1.5
Kp   2.25
Sol. For 2s, number of radial nodes = 2 – 0 – 1 = 1 and 1
value of 2 is always positive.

1
5. A 42.12% (w/v) solution of NaCl causes 7. Match List I with List II.
precipitation of a certain sol in 10 hours. The List I Ore List II Composition

coagulating value of NaCl for the sol is A. Siderite I. Fe CO3

B. Malachite II. CuCO3.Cu(OH)2
[Given : Molar mass : Na = 23.0 g mol–1; Cl = 35.5
C. Sphalerite III. ZnS
g mol–1]
D. Calamine IV. ZnCO3
(A) 36 mmol L–1
Choose the correct answer from the options given
(B) 36 mol L–1
below:
–1
(C) 1440 mol L (A) A-I, B-II, C-III, D-IV
–1
(D) 1440 mmol L (B) A-III, B-IV, C-II, D-I
Official Ans. by NTA (D) (C) A-IV, B-III, C-I, D-II

Allen Ans. (Bonus) (D) A-I, B-II, C-IV, D-III

Official Ans. by NTA (A)
Sol. Data insufficient.
6.

EN
Given below are two statements. One is labelled as
Assertion A and the other is labelled as Reason R.
Assertion A : The first ionization enthalpy for
oxygen is lower than that of nitrogen.
Reason R : The four electrons in 2p orbitals of 8.
Allen Ans. (A)
Sol. Siderite – FeCO3
Malachite – CuCO3.Cu(OH)2
Calamine – ZnCO3
Sphalerite – ZnS
Given below are two statements .
oxygen experience more electron-electron Statement I : In CuSO4.5H2O, Cu–O bonds are
LL
repulsion. present.
Statement II : In CuSO4.5H2O, ligands
In the light of the above statements, choose the
coordinating with Cu(II) ion are O-and S-based
correct answer from the options given below.
ligands.
(A) Both A and R are correct and R is the correct
In the light of the above statements, choose the
explanation of A. correct answer from the options given below
A

(B) Both A and R are correct but R is NOT the (A) Both Statement I and Statement II are correct
correct explanation of A. (B) Both Statement I and Statement II are incorrect

(C) A is correct but R is not correct. (C) Statement I is correct but Statement II is
incorrect
(D) A is not correct but R is correct
(D) Statement I is incorrect but Statement II is
Official Ans. by NTA (A)
correct
Allen Ans. (A)
Official Ans. by NTA (C)
Sol. Ionisation energy = N > O.
Allen Ans. (C)
In oxygen atom, 2 of the 4 2p electrons must Sol. 2+
H H
O O
occupy the same 2p orbital resulting in an H H H O O
Cu O S
H O O H H O O
increased electron electron-repulsion.
H H

2
9. Amongst baking soda, caustic soda and washing 12. Sulphur dioxide is one of the components of
soda carbonate anion is present in : polluted air. SO2 is also a major contributor to acid
(A) washing soda only. rain. The correct and complete reaction to

(B) washing soda and caustic soda only. represent acid rain caused by SO2 is :

(C) washing soda and baking soda only. (A) 2 SO2 + O2  2 SO3

(D) baking soda, caustic soda and washing soda. (B) SO2 + O3  SO3 + O2

Official Ans. by NTA (A) (C) SO2 + H2O2  H2SO4

Allen Ans. (A) (D) 2 SO2 + O2 + 2 H2O  2 H2SO4

Official Ans. by NTA (D)
Sol. Baking soda  NaHCO3
Allen Ans. (D)
Washing soda  Na2CO3.10H2O
Sol. 2SO2 + O2 + 2H2O  2H2SO4 (Acid rain)
Caustic soda  NaOH
13. Which of the following carbocations is most stable
10. Number of lone pair (s) of electrons on central
:
atom and the shape of BrF3 molecule respectively,
are :
(A) 0, triangular planar.
(B) 1, pyramidal.
(C) 2, bent T-shape.
(D) 1, bent T-shape
EN (A)

(B)

(C)
OCH3

H3CO
OCH3

(D) H CO
Official Ans. by NTA (C) 3
LL
Allen Ans. (C) Official Ans. by NTA (D)

Sol. F Allen Ans. (D)

+
F Br
F
Sol. H3CO
Steric no. = 5 (sp3d), lone pair = 2
Is most stable carbocation
A

Bent T shape.
Anhydrous, AlCl3
11. Aqueous solution of which of the following boron 14. + CH3CH 2CH 2Cl 'A'
Major Product
compounds will be strongly basic in nature?
The stable carbocation formed in the above
(A) NaBH4 (B) LiBH4
reaction is :
(C) B2H6 (D) Na2B4O7  
(A) CH3CH 2 CH 2 (B) CH3 C H 2
Official Ans. by NTA (D)

Allen Ans. (D) (C) CH3 – C H – CH3 (D) CHCH2CH 3

Sol. Na2B4O7 gives H3BO3 and NaOH (strong base) in

water.
Official Ans. by NTA (C)
Allen Ans. (C)
+
Sol. CH3–CH–CH3 is formed in the above reaction

3
15. Two isomers (A) and (B) with Molar mass 184 16. In Friedel-Crafts alkylation of aniline, one gets :
g/mol and elemental composition C, 52.2%; H, (A) alkylated product with ortho and para
4.9% and Br 42.9% gave benzoic acid and p- substitution.
bromobenzoic acid, respectively on oxidation with (B) secondary amine after acidic treatment.
KMnO4. Isomer 'A' is optically active and gives a (C) an amide product.
pale yellow precipitate when warmed with
(D) positively charged nitrogen at benzene ring.
alcoholic AgNO3. Isomer 'A' and 'B' are,
Official Ans. by NTA (D)
respectively :
Allen Ans. (D)
CH2Br
..NH –
CH3 Sol. 2
+
NH2 – AlCl3
(A) H3C–CHBr–C6H5 and
Anhydrous AlCl 3
+ CH3 – Cl
CH2Br CH2CH 3
CH3
(B) and 17. Given below are two statements : one is labelled as

(C) H3C–CHBr–C6H5 and

CH2CH 3
Br
CH2CH 3

Br
EN Assertion A and the other is labelled as Reason R.
Assertion A: Dacron is an example of polyester
polymer.
Reason R: Dacron is made up of ethylene glycol
and terephthalic acid monomers.
In the light of the above statements, choose the
LL
(D) and H3C–CHBr–C6H5
most appropriate answer from the options given
Br below.
Official Ans. by NTA (C)
(A) Both A and B are correct and R is the correct
Allen Ans. (C)
explanation of A.
Sol. Br
(B) Both A and B are correct but R is NOT the
A

CH – CH3 COOH
correct explanation of A.
KMnO4 (C) A is correct but R is not correct.
(D) A is not correct but R is correct.
(A)
Optically Active Official Ans. by NTA (A)
Allen Ans. (A)
AgNO 3
Yellow ppt of AgBr
 O O
Sol. n CH2 – CH2
CH2 – CH3 COOH + n HO – C C – OH
OH OH
KMnO4 ethylene glycol Terephthalic acid

O O
Br Br – O – H2C– H2 C– O – C C–
n
Dacron

4
18. The structure of protein that is unaffected by SECTION-B
heating is : 1. A box contains 0.90 g of liquid water in equilibrium
(A) secondary structure (B) tertiary structure with water vapour at 27°C. The equilibrium vapour
(C) primary structure (D) quaternary structure pressure of water at 27°C 32.0 Torr. When the
Official Ans. by NTA (C) volume of the box is increased, some of the liquid
Allen Ans. (C) water evaporates to maintain the equilibrium
Sol. Primary structure of protein is unaffected by pressure. If all the liquid water evaporates, then the
physical 'or' chemical changes. volume of the box must be____ litre. [nearest
19. The mixture of chloroxylenol and terpineol is an integer]
example of : (Given: R = 0.082 L atm K–1 mol–1)
(A) antiseptic (B) pesticide (Ignore the volume of the liquid water and
(C) disinfectant (D) narcotic analgesic assume water vapours behave as an ideal gas.)
Official Ans. by NTA (A)
Official Ans. by NTA (29)
Allen Ans. (A)

20.
terpineol.
EN
Sol. Antiseptic Dettol is mixture of chloroxylenol and

A white precipitate was formed when BaCl2 was

added to water extract of an inorganic salt. Further,
a gas 'X' with characteristic odour was released
Sol.
Allen Ans. (29)

V
nRT 0.90  0.82  300  760
P

18  32
= 29.21

2. 2.2 g of nitrous oxide (N2O) gas is cooled at a

constant pressure of 1 atm from 310 K to 270 K
causing the compression of the gas from 217.1 mL to
when the formed white precipitate was dissolved in
167.75 mL. The change in internal energy of the
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dilute HCl. The anion present in the inorganic salt
process, U is '–x' J. The value of 'x' is __.
is :
(A) I– (B) SO32– [nearest integer]

(C) S2– (D) NO2– (Given: atomic mass of N = 14 g mol–1 and of O

Official Ans. by NTA (B) = 16 g mol–1.
Allen Ans. (B) Molar heat capacity of N2O is 100 JK–1 mol–1)
A

Sol. BaCl2  SO32  BaSO3  

dil.HCl
SO2  Official Ans. by NTA (195)
white burning sulphur like smell Allen Ans. (195)
2.2 1
Sol. N 2 O moles  
44 20
1
H  nCp T   100(40)  200J
20
U = qp + w
w = –Pext. V
(167.75  217.1)
W  1  101.3J
1000
w = +5J
U = –200 + 5 = –195J

5
3. Elevation in boiling point for 1.5 molal solution of Sol. K = Ae–Ea/RT = (6.5 × 1012 s–1) e–26000K/T
glucose in water is 4K. The depression in freezing Ea
 26000
point for 4.5 molal solution of glucose in water is 8.314
4K. The ratio of molal elevation constant to molal Ea = 216.164 kJ/mol.
depression constant (Kb/Kf) is____. 6. Spin only magnetic moment of [MnBr6]4– is____
Official Ans. by NTA (3) B.M. (round off to the closest integer)

Allen Ans. (3) Official Ans. by NTA (6)

Sol. Tb  iKb m Allen Ans. (6)

Tf = iKfm Sol. Mn2  t 2g111 eg11

4 K b1.5 s  35

4 K f 4.5
= 5.91
Kb
3 =6
Kf

4.

EN
The cell potential for the given cell at 298 K
Pt | H2(g,1 bar) | H+(aq) || Cu2+(aq) | Cu(s)
is 0.31V. The pH of the acidic solution is found to
be 3, whereas the concentration of Cu2+ is 10–x M.
The value of x is _____.
7.


For the reaction given below:

CoCl3 . xNH3 + AgNO3 (aq) 

If two equivalents of AgCl precipitate out, then the

value of x will be _____.

Official Ans. by NTA (5)

Allen Ans. (5)
2.303RT
(Given: ECu2 /Cu = 0.34 V and = 0.06V)
LL
F Sol. CoCl3.xNH3 + AgNO3  AgCl
2 mol
Official Ans. by NTA (7)
[Co(NH3)5Cl]Cl2 + AgNO3  AgCl
Allen Ans. (7)
2 mol
Sol. H2(g) + Cu2+(aq.) 2H+(aq.) + Cu(s)
x= 5
0.06 [H ]2
0.31  0.34  log 8. The number of chiral alcohol(s) with molecular
A

2 [Cu 2 ]
formula C4H10O is______.
[Cu2+] = 10–7 M
x=7 Official Ans. by NTA (1)

5. The equation Allen Ans. (2)

Sol. CH3 – CH2 –CH2–CH2 – OH
k = ( 6.5 × 1012 s–1) e–26000K/T
is followed for the decomposition of compound A. CH3 – CH – CH2 – CH3
The activation energy for the reaction is ____ kJ OH –
(+)

mol–1. [nearest integer] CH3

CH3 – CH – CH2 – OH
(Given: R = 8.314 J K–1 mol–1)
CH3
Official Ans. by NTA (216)
CH3 – C – CH3
Allen Ans. (216) OH
Out of which only two are chiral

6
9. In the given reaction 10. In the given reaction,

O
(i) K 2Cr2O7
–
(ii) C 6H5MgBr (i) OH ‘P’
HO ‘X’
(iii) H 2O (ii) heat Major Product
+ Major Product
(iv) H , heat
The number of  electrons present in the product
the number of sp2 hybridised carbon (s) in 'P' is _____.
compound 'X' is_____. Official Ans. by NTA (4s)
Official Ans. by NTA (8) Allen Ans. (4)
Allen Ans. (8) Sol. O O
K2 Cr2 O7 C6 H5 MgBr HO
Sol. HO O –
H2O C6 H5 (i) OH
(ii) Heat

C6H5
EN H+ Heat
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A