Mathongo
Mathongo
PART – A (PHYSICS)
1. Figure shown a DC voltage regulator circuit, with a Zener diode of breakdown voltage =
6V. If the unregulated input voltage varies between 10 V to 16 V, then what is the
maximum Zener current?
2. Three particles of masses 50 g, 100 g and 150 g are placed at the vertices of an
equilateral triangle of side 1 m (as shown in the figure). The (x, y) coordinates of the
centre of mass
will be :
3 7 7 3
(A) m, m (B) m, m
7 12 12 8
3 5 7 3
(C) m, m (D) m, m
4 12 12 4
3. The ratio of the weights of a body on the Earth's surface to that on the surface of a
1
planet is 9 : 4. The mass of the planet is th of that of the Earth. If 'R' is the radius of the
9
Earth, what is the radius of the planet ? (Take the planets to have the same mass
density)
R R
(A) (B)
3 4
R R
(C) (D)
9 2
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4. A block of mass 5 kg is (i) pushed in case (A) and (ii) pulled in case (B), by a force F =
20 N, making an angle of 30º with the horizontal, as shown in the figures. The coefficient
of friction between the block and floor is m = 0.2. The difference between the
accelerations of the block, in case (B) and case (A) will be : (g = 10 ms–2)
2
(A) 0.4 ms (B) 3.2 ms 2
(C) 0 ms 2 (D) 0.8 ms 2
6. A diatomic gas with rigid molecules does 10 J of work when expanded at constant
pressure. What would be the heat energy absorbed by the gas, in this process?
(A) 40 J (B) 30 J
(C) 35 J (D) 25 J
7. A Carnot engine has an efficiency of 1/6. When the temperature of the sink is reduced
by 62ºC, its efficiency is doubled. The temperatures of the source and the sink are,
respectively
(A) 62ºC, 124ºC (B) 99ºC, 37ºC
(C) 37ºC, 99ºC (D) 124ºC, 62ºC
8. Consider an electron in a hydrogen atom, revolving in its second excited state (having
radius 4.65 Å). The de-Broglie wavelength of this electron is :
(A) 12.9 Å (B) 9.7 Å
(C) 6.6 Å (D) 3.5 Å
9. A small speaker delivers 2 W of audio output. At what distance from the speaker will one
detect 120 dB intensity sound? [Given reference intensity of sound as 10–12W/m2]
(A) 30 cm (B) 10 cm
(C) 40 cm (D) 20 cm
10. A system of three polarizers P1, P2, P3 is set up such that the pass axis of P3 is crossed
with respect to that of P1. The pass axis of P2 is inclined at 60º to the pass axis of P3.
When a beam of unpolarized light of intensity I0 is incident on P1, the intensity of light
transmitted by the three polarizers is I. The ratio (I0/I) equals (nearly) :
(A) 10.67 (B) 1.80
(C) 5.33 (D) 16.00
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11. Let a total charge 2Q be distributed in a sphere of radius R, with the charge density
given by r(r) = kr, where r is the distance from the centre. Two charges A and B, of –Q
each, are placed on diametrically opposite points, at equal distance, a, from the centre. If
A and B do not experience any force, then :
3R 1
(A) a 1
(B) a 2 4 R
2 4
1
(C) a 8 4
R (D) a R/ 3
12. An electron, moving along the x-axis with an initial energy of 100 eV, enters a region of
magnetic field B 1.5 10 3 T kˆ at S (See figure). The field extends between x = 0 and
x = 2 cm. The electron is detected at the point Q on a screen placed 8 cm away from the
point S. The distance d between P and Q (on the screen) is :
(electron's charge = 1.6 × 10–19 C, mass of electron = 9.1 × 10–31 kg)
13. Two particles are projected from the same point with the same speed u such that they
have the same range R, but different maximum heights, h1 and h2. Which of the following
is correct?
(A) R2 = 4 h1h2 (B) R2 = 2 h1h2
2
(C) R = 16 h1h2 (D) R2 = h1h2
14. A particle is moving with speed v x along positive x-axis. Calculate the speed of the
particle at time t = t(assume that the particle is at origin at t = 0).
b2
(A) b 2 (B)
2
2
b b2
(C) (D)
2 4
15. One kg of water, at 20ºC, is heated in an electric kettle whose heating element has a
mean (temperature averaged) resistance of 20 . The rms voltage in the mains is 200 V.
Ignoring heat loss from the kettle, time taken for water to evaporate fully, is close to :
[Specific heat of water = 4200 J/kg ºC),
Latent heat of water = 2260 kJ/kg]
(A) 3 minutes (B) 10 minutes
(C) 22 minutes (D) 16 minutes
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16. Half lives of two radioactive nuclei A and B are 10 minutes and 20 minutes, respectively.
If, initially a sample has equal number of nuclei, then after 60 minutes, the ratio of
decayed numbers of nuclei A and B will be :
(A) 9 : 8 (B) 1 : 8
(C) 8 : 1 (D) 3 : 8
17. In an amplitude modulator circuit, the carrier wave is given by, C(t) = 4 sin (20000 t)
while modulating signal is given by, m(t) = 2 sin (2000 t). The values of modulation
index and lower side band frequency are:
(A) 0.5 and 9 kHz (B) 0.3 and 9 kHz
(C) 0.5 and 10 kHz (D) 0.4 and 10 kHz
18. A uniform cylindrical rod of length L and radius r, is made from a material whose Young's
modulus of Elasticity equals Y. When this rod is heated by temperature T and
simultaneously subjected to a net longitudinal compressional force F, its length remains
unchanged. The coefficient of volume expansion, of the material of the rod, is (nearly)
equals to :
(A) 9F/( r2YT) (B) F/(3 r2YT)
2
(C) 3F/( r YT) (D) 6F/( r2YT)
19. Consider the LR circuit shown in the figure. If the switch S is closed at t = 0 then the
L
amount of charge that passes through the battery between t = 0 and t is :
R
EL EL
(A) (B)
7.3R2 2.7R 2
7.3 EL 2.7 EL
(C) (D)
R2 R2
20. Two sources of sound S1 and S2 produce sound waves of same frequency 660 Hz. A
listener is moving from source S1 towards S2 with a constant speed u m/s and he hears
10 beats/s. The velocity of sound is 330 m/s. Then, u equals:
(A) 15.0 m/s (B) 10.0 m/s
(C) 5.5 m/s (D) 2.5 m/s
21. A plane electromagnetic wave having a frequency n = 23.9 GHz propagates along the
positive z-direction in free space. The peak value of the electric field is 60 V/m. Which
among the following is the acceptable magnetic field component in the electromagnetic
wave?
(A) B 2 10 7 sin 1.5 102 x 0.5 1011 t ˆj (B) B 60 sin 0.5 103 x 1.5 1011 t kˆ
(C) B 2 10 7 sin 0.5 102 z 1.5 1011 t ˆi (D) B 2 107 sin 0.5 103 z 1.5 1011 t ˆi
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22. Find the magnetic field at point P due to a straight line segment AB of length 6 cm
carrying a current of 5 A. (See figure)
( 0 = 4p × 10–7 N-A–2)
23. The electron in a hydrogen atom first jumps from the third excited state to the second
excited state and subsequently to the first excited state. The ratio of the respective
wavelengths, 1/ 2, of the photons emitted in this process is :
(A) 20/7 (B) 7/5
(C) 9/7 (D) 27/5
24. A smooth wire of length 2 r is bent into a circle and kept in a vertical plane. A bead can
slide smoothly on the wire. When the circle is rotating with angular speed w about the
vertical diameter AB, as shown in figure, the bead is at rest with respect to the circular
ring at position P as shown. Then the value of 2 is equal to:
3g
(A) (B) g 3 / r
2r
(C) 2g / r (D) 2g / r 3
25. A solid sphere, of radius R acquires a terminal velocity 1 when falling (due to gravity)
through a viscous fluid having a coefficient of viscosity . The sphere is broken into
27 identical solid spheres. If each of these spheres acquires a terminal velocity, 2, when
falling through the same fluid, the ratio ( 1/ 2) equals :
(A) 27 (B) 1/27
(C) 9 (D) 1/9
26. The number density of molecules of a gas depends on their distance r from the origin as,
4
n r n0 e r . Then the total number of molecules is proportional to :
3/4
(A) n0 (B) n0 3
1/4 1/ 2
(C) n0 (D) n0
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2
1 1 1
(C) sin (D) sin 2
2
1
2 1
28. A tuning fork of frequency 480 Hz is used in an experiment for measuring speed of
sound ( ) in air by resonance tube method. Resonance is observed to occur at two
successive lengths of the air column, 1 30 cm and 2 70 cm. Then n is equal to :
(A) 332 ms 1 (B) 338 ms 1
(C) 384 ms 1 (D) 379 ms 1
29. A spring whose unstretched length is has a force constant k. The spring is cut into two
pieces of unstretched lengths 1 and 2 where, 1 = n 2 and n is an integer. The ratio
k1/k2 of the corresponding force constants, k1 and k2 will be:
1
(A) n (B) 2
n
2 1
(C) n (D)
n
30. A moving coil galvanometer, having a resistance G, produces full scale deflection when
a current Ig flows through it. This galvanometer can be converted into (i) an ammeter of
range 0 to I0 (I0 > Ig) by connecting a shunt resistance RA to it and (ii) into a voltmeter of
range 0 to V(V = GI0) by connecting a series resistance RV to it. Then,
R Ig
(A) R AR V G2 and A
RV I0 Ig
2
2R Ig
(B) R AR V G and A
RV I0 Ig
2
2
Ig R I0 Ig
(C) R AR V G and A
I0 Ig RV Ig
2
I0 Ig R Ig
(D) R A RV G2 and A
Ig RV I0 Ig
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PART –B (CHEMISTRY)
31. What will be the major product when m-cresol is reacted with propargyl bromide (HC C
– CH2Br) in presence of K2CO3 in acetone
(A) (B)
(C) (D)
32. Which one of the following is likely to give a precipitate with AgNO3 solution?
(A) CH2 = CH – Cl (B) CHCl3
(C) (CH3)3CCl (D) CCl4
34. Benzene diazonium chloride on reaction with aniline in the presence of dilute
hydrochloric acid gives :
(A) (B)
(C) (D)
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‘A’ is:
(A) CH2 = CH2 (B) CH3 – C CH
(C) CH CH (D) CH3 – C C – CH3
42. The ratio of number of atoms present in a simple cubic, body centered cubic and face
centered cubic structure are, respectively :
(A) 1 : 2 : 4 (B) 4 : 2 : 3
(C) 4 : 2 : 1 (D) 8 : 1 : 6
44. An ' Assertion' and a 'Reason' are given below. Choose the correct answer from the
following options.
Assertion (A): Vinyl halides do not undergo nucleophilic substitution easily.
Reason (R): Even though the intermediate carbocation is stabilized by loosely held
p-electrons, the cleavage is difficult because of strong bonding.
(A) Both (A) and (R) are correct statements but (R) is not the correct explanation of (A)
(B) Both (A) and (R) are wrong statements
(C) Both (A) and (R) are correct statements and (R) is the correct explanation of (A)
(D) (A) is a correct statement but (R) is a wrong statement.
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45. The molar solubility of Cd(OH)2 is 1.84 × 10–5 M in water. The expected solubility of
Cd(OH)2 in a buffer solution of pH = 12 is :
(A) 6.23 × 10 11 M (B) 1.84 × 10 9 M
2.49
(C) 10 9 M (D) 2.49 × 10 10 M
1.84
49. The decreasing order of electrical conductivity of the following aqueous solutions is:
0.1 M Formic acid (a)
0.1 M Acetic acid (b)
0.1 M Benzoic acid (c)
(A) a > c > b (B) c > a > b
(C) c > b > a (D) a > b > c
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53. NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as per the
equation
2N2O5 (g) 4NO2 g O2 g
The initial concentration of N2O5 is 3.00 mol L–1 and it is 2.75 mol L–1 after 30 minutes.
The rate of formation of NO2 is :
(A) 1.667 × 10 2 mol L 1 min 1 (B) 4.167 × 10 3 mol L 1 min 1
3 1 1
(C) 8.333 × 10 mol L min (D) 2.083 × 10 3 mol L 1 min 1
(A) (B)
(C) (D)
(A) 3, 5-dimethyl-4-propylhept-1-en-6-yne
(B) 3-methyl-4-(1-methylprop-2-ynyl)-1-heptene
(C) 3-methyl-4-(3-methylprop-1-enyl)-1-heptyne
(D) 3, 5-dimethyl-4-propylhept-6-en-1-yne
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59. A solution is prepared by dissolving 0.6 g of urea (molar mass = 60 g mol–1) and 1.8 g of
glucose (molar mass = 180 g mol–1) in 100 mL of water at 27ºC. The osmotic pressure of
the solution is :
(R = 0.08206 L atm K–1 mol–1)
(A) 8.2 atm (B) 1.64 atm
(C) 4.92 atm (D) 2.46 atm
60. The temporary hardness of a water sample is due to compound X. Boiling this sample
converts X to compound Y. X and Y, respectively, are :
(A) Mg(HCO3)2 and MgCO3 (B) Ca(HCO3)2 and CaO
(C) Mg(HCO3)2 and Mg(OH)2 (D) Ca(HCO3)2 and Ca(OH)2
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PART–C (MATHEMATICS)
61. The general solution of the differential equation (y2 – x3) dx – xydy = 0 (x 0) is :
(where c is a constant of integration)
(A) y2 + 2x3 + cx2 = 0 (B) y2 – 2x3 + cx2 = 0
2 2 3
(C) y + 2x + cx = 0 (D) y2 – 2x2 + cx3 = 0
tan x tan
63. Let (0, /2) be fixed. If the integral dx
tan x tan
A(x) cos2 + B(x) sin2 + C, where C is a constant of integration, then the functions A(x)
and B(x) are respectively:
(A) x and loge sin x (B) x and loge cos x
(C) x and loge sin x (D) x and loge sin x
64. Let S be the set of all R such that the equation, cos2 x + sin x = 2 – 7 has a
solution. Then S is equal to :
(A) [3, 7] (B) R
(C) [2, 6] (D) [1, 4]
65. Let f(x) 5 x 2 and g(x) x 1, x R . If f(x) attains maximum value at and g(x)
2
x 1 x 5x 6
attains minimum value at , then lim 2
is equal to :
x x 6x 8
3 3
(A) (B)
2 2
1 1
(C) (D)
2 2
2z n
66. Let z C with Im(z) = 10 and it satisfies 2i 1 for some natural number n. Then :
2z n
(A) n = 40 and Re(z) = 10 (B) n = 20 and Re(z) = 10
(C) n = 40 and Re(z) = – 10 (D) n = 20 and Re(z) = – 10
6
1 x8 3
67. The term independent of x in the expansion of 2x2 is equal to:
60 81 x2
(A) 36 (B) 36
(C) 108 (D) 72
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1
68. If the area (in sq. units) bounded by the parabola y2 =4 x and the line y = x, > 0, is ,
9
then is equal to :
(A) 48 (B) 4 3
(C) 2 6 (D) 24
69. If [x] denotes the greatest integer x, then the system of linear equations
[sin ] x + [– cos ] y = 0
[cot ] x + y = 0
2 7
(A) have infinitely many solutions if , and has a unique solution if ,
2 3 6
2 7
(B) have infinitely many solutions if , ,
2 3 6
2 7
(C) has a unique solution if , and have infinitely many solutions if ,
2 3 6
2 7
(D) has a unique solution if , ,
2 3 6
70. For an initial screening of an admission test, a candidate is given fifty problems to solve.
4
If the probability that the candidate can solve any problem is , then the probability that
5
he is unable to solve less than two problems is :
48 49
164 1 201 1
(A) (B)
25 5 5 5
49 48
54 4 316 4
(C) (D)
5 5 25 5
71. If a1, a2, a3, ……. are in A.P. such that a1 + a7 + a16 = 40, then the sum of the first 15
terms of this A.P. is:
(A) 200 (B) 280
(C) 150 (D) 120
72. An ellipse, with foci at (0, 2) and (0, –2) and minor axis of length 4, passes through
which of the following points?
(A) 2, 2 (B) 2,2 2
73. The length of the perpendicular drawn from the point (2, 1, 4) to the plane containing the
lines r ˆi ˆj ˆi 2jˆ kˆ and r ˆi ˆj ˆi ˆj 2kˆ is:
1
(A) (B) 3
3
1
(C) (D) 3
3
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74. Let A, B and C be sets such that A B C. Then which of the following statements
is not true?
(A) If (A – C) B, then A B (B) If (A – B) C, then A C
(C) (C A) (C B) = C (D) B C
75. If , and are three consecutive terms of a non-constant G.P. such that the equations
x2 + 2 x + = 0 and x2 + x – 1 = 0 have a common root, then ( + ) is equal to :
(A) (B) 0
(C) (D)
76. The tangents to the curve y = (x – 2)2 –1 at its points of intersection with the line x – y =
3, intersect at the point :
5 5
(A) ,1 (B) , 1
3 2
5 5
(C) ,1 (D) , 1
2 2
77. The angle of elevation of the top of vertical tower standing on a horizontal plane is
observed to be 45° from a point A on the plane. Let B be the point 30 m vertically above
the point A. If the angle of elevation of the top of the tower from B be 30°, then the
distance (in m) of the foot of the tower from the point A is:
(A) 15 1 3 (B) 15 3 3
(C) 15 3 3 (D) 15 5 3
78. A triangle has a vertex at (1, 2) and the mid points of the two sides through it are (–1, 1)
and (2,3). Then the centroid of this triangle is :
7 1
(A) 1, (B) ,1
3 3
1 1 5
(C) ,2 (D) ,
3 3 3
79. A person throws two fair dice. He wins Rs. 15 for throwing a doublet (same numbers on
the two dice), wins Rs.12 when the throw results in the sum of 9, and loses Rs. 6 for any
other outcome on the throw. Then the expected gain/loss (in Rs.) of the person is :
1
(A) loss (B) 2 gain
4
1 1
(C) gain (D) loss
2 2
20
80. If C1 22 20
C3 32 20
C3 22 ....... 202 20
C20 A 2 , then the ordered pair
(A, ) is equal to:
(A) (420, 18) (B) (380, 18)
(C) (420, 19) (D) (380, 19)
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1 sin x cos x x
81. The derivative of tan , with respect to , where x 0, is:
sin x cos x 2 2
1
(A) 2 (B)
2
2
(C) 1 (D)
3
82. A circle touching the x-axis at (3, 0) and making an intercept of length 8 on the y-axis
passes through the point :
(A) (3, 5) (B) (1, 5)
(C) (3, 10) (D) (2, 3)
83. The equation of a common tangent to the curves, y2 = 16x and xy = –4 is :
(A) x – 2y + 16 = 0 (B) 2x – y + 2 = 0
(C) x + y + 4 = 0 (D) x – y + 4 = 0
84. A plane which bisects the angle between the two given planes 2x – y + 2z – 4 = 0 and x
+ 2y + 2z – 2 = 0, passes through the point:
(A) (1, 4, 1) (B) (2, 4, 1)
(C) (2, 4, 1) (D) (1, 4, 1)
1
dx 9
85. A value of such that loge is:
x x 1 8
1
(A) (B) 2
2
1
(C) (D) 2
2
86. A group of students comprises of 5 boys and n girls. If the number of ways, in which a
team of 3 students can randomly be selected from this group such that there is at least
one boy and at least one girl in each team, is 1750, then n is equal to:
(A) 24 (B) 28
(C) 27 (D) 25
(A) (B)
18 9
7 7
(C) (D)
36 24
88. A straight line L at a distance of 4 units from the origin makes positive intercepts on the
coordinate axes and the perpendicular from the origin to this line makes an angle of 60°
with the line x + y = 0. Then an equation of the line L is :
(A) 3 1 x 3 1y 8 2 (B) 3x y 8
(C) x 3y 8 (D) 3 1 x 3 1y 8 2
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x 2 sin x
89. lim is:
2
x 0
x 2 sin x 1 sin2 x x 1
(A) 2 (B) 6
(C) 3 (D) 1
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4.
N1 = 60 N2 = 40
10 3 0.2 60 10 3 0.2 40
a1 a2
5 5
a1 – a2 = 0.8
5.
7
6. For a diatomic gas, Cp = R
2
Since gas undergoes isobaric process
7 7
Q= n R T (nR T) = 35 J
2 2
Tsink
7. Efficiency of Carnot engine = 1
Tsource
Given,
1 Tsink Tsink 5
1 …(i)
6 Tsource Tsource 6
Also,
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2 Tsink 62 62 1
1 …(ii)
6 Tsource Tsource 6
Tsource = 372 K = 99°C
5
Also, Tsink 372 = 310 K = 37°C
6
(Note: Temperature of source is more than temperature of sink)
8. 2 rn = n n
10
2 (4.65 10 )
3
3
3 = 9.7 Å
2
kr 4 r 2 dr
0
11. E4 a
e0
4
k4 a
E
4 4 0
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R
2Q kr 4 r 2 dr
0
2Q
k
R4
1 QQ
QE
4 0 (2a)2
R = a81/4
mv
12. R
qB
2m (K.E.)
=
qB
14. v b x
dv b dx bv
; a
dt 2 x dt 2 x
b b x dv b2 b2
a ; a ; v
2 x dt 2 2
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15. Q=P×t
Q = mc T + mL
V2
P = rms
R
(200)2
4200 × 80 + 2260 × 103 = t
20
t = 1298 sec
t 22 min
t NOA NOA
16. NA NOA e
2t/t1/ 2 26
Number of nuclei decayed
NOA 63NOA
= NOA
26 64
NOB NOB
NB NOBe t
2t/t1/ 2 23
Number of nuclei decayed
NOB 7NOB
= NOB
23 8
Since, NOA = NOB
Ratio of decayed numbers of nuclei
63 NOA 8 9
A&B=
64 7NOB 8
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19. q Idt
L /R Rt
E
q 1 e L
dt
0
R
EL 1 EL
q ; q
R2 e 2.7R2
v u v u
f1 f ; f2 f
v v
f
f2 f1 [v u (v u)]
v
f
10 = f2 – f 1 = [2u]
v
u = 2.5 m/s
I 0
22. B 2 sin
4 d
d = 4 cm
3
sin =
5
1 1 1 1 1 1
23. R ; R
n2f ni2 1 32 42
1 7 1 1 1
R ; R
1 9 16 2 22 32
5
=R
4 9
5
1 36 20
2
7 7
9 16
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r 2
24. N sin =m …(i)
2
N cos = mg …(ii)
r 2
tan
2g
r r 2 2 2g
;
3r 2g 3r
2
2
25. We have
2 r2
VT ( 0 )g
9
VT r2
Since mass of the sphere will be same
4 3 4 3
R 27 r
3 3
R
r
3
v1 R2
9
v2 r2
1
27. sin c =
2
2 1 1
2
2
sin
1
2 2
1 1 2
sin 2
1
For TIR
1 u22
sin 2
1
1
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C
29. k1
1
C
k2
2
k1 C 2 2 1
k2 C
1 n 2 n
30. When galvanometer is used an ammeter shunt is used in parallel with galvanometer.
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PART B – CHEMISTRY
31. O
CH3
Above anion act as nucleophile for SN2 attack on CH C – CH2 – Br and acetone acting
as polar aprotic solvent.
32. (CH3)3CCl will give Cl– and most stable carbocation. Hence (CH3)3CCl likely to give a
precipitate with AgNO3 solution.
34. According to NCERT C – N coupling take place, when diazonium ion is treated with
aniline.
1
35. 2LiNO 3 Li2O 2NO 2 O2
2
36. Since carbon in diamond is sp3 hybridized and its C – C bond order is 1. In graphite and
fullerene there is both C – C and C = C in conjugation, hence there is partial double
bond character between carbon atoms.
37. CH3 C C H Ag2 O
CH3 C C Ag
White PPt.
(A) Hg2+/H+
O
H3C C CH3
(B) NaBH4
OH
ZnCl2
CH3 C CH3 Conc.HCl
Turbidity within 5 minutes
(C)
H
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38. If ng = 0
KP = K C
If ng 0, KP KC
Hence (B) is correct answer.
39. en and C2O24 are a bidentate ligand. So coordination number of [Co(Cl)(en)2]Cl is 5 and
K3[Al(C2O4)3] is 6
43.
44. Due to resonance there is partial double bond character between carbon and chlorine,
hence it do not undergoes nucleophilic substitution reaction.
46. (A) EDTA (ethylene diamine tetra acetate) is used for lead poisoning
(B) Cis platin is used as a anti cancer drug
(C) D-penicillamine is used for copper poisoning
(D) desferrioxime B is used for iron poisoning
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48.
49. Stronger the acidic strength greater will be its electrical conductivity.
Ka value of formic acid > benzoic acid > acetic acid.
50. Greater the nuclear charge, stronger will be the attraction, hence lower will be energy of
2s
51. Dihedral angle is then angle between bond pairs present on adjacent atoms.
52. Since NaOH is a strong base hence it reacts with Al2O3 and SiO2 to form salts.
53.
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55. OH
Ph alc.KOH Hg OAc 2 ,H2O
Ph
Cl X NaBH4 Ph
OMDM follow Markonikovs addition rule.
56. According to IUPAC rules, select the largest chain including functional group, if alkene
and alkyne are present at equivalent position then priority is given to alkene.
57. Definitions and property of colloidal will explain & solve above question..
58. Since boron has higher nuclear charge because it has greater atomic number and lower
1st I.E. then beryllium due to fully filled s-orbital.
6 18
59. CRT .0821 300
60 180
= 0.2 .082 300 = 4.926 atm.
60. Mg HCO3 2
aq Mg OH 2
2CO2
PART C – MATHEMATICS
61. y2 x3 dx xy dy 0 x 0
dy
y2 x3 xy 0
dx
dy
or, xy y2 x3
dx
dy 1 2
y y x 2 ……..(i)
dx x
Let y 2
dy d
2y
dx dx
Putting this value in equation (i)
1d 1
x2
2 dx x
d 2
2x2 (ii)
dx x
2
dx
2 nx 1
I.F. e x
e
x2
Sol. of equation (ii)
1 1
3
2x 2 dx C
x 2
2x C
x2
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y2 2x3 cx 2
y 2 2x 3 cx 2 0
Hence correct answer is option B.
62. a.b.c 0
3 1
2 1 0
2 3
2
3 2 1 6 3 4 0
2 2
3 2
6 12 3 0
2
3 18 0
2
6 0 not possible for real
S is empty set
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65. f x 5 x 2
f x attains maximum value when x 2 0 x 2
g x x 1
g x attains minimum value of x 1
x 1 x2 5x 6
Lim 2
x x 6x 8
x 1 x 2 x 3
Lim
x 2 x 2 x 4
2 1 2 3 1
2 4 2
6
1 x8 3
67. 2x2
60 81 x2
1
Term independent of x will be independent of x in
60
6 6
3 1 3
2x 2 Term of x 8 in 2x 2
x2 8 x3
6 r
3 6 r 3
Tr 1 in 2x 2 will be Tr 1
6
Cr 2x 2
x2 x2
6 r
Cr 26 r 1 3r x12 2r 2r
Case I : For term independent of x, 12 4r 0 r 3
T4 6C3 23 33 6 20 23 33
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6
T6 C5 .21 1 .35 . x 8
1 1
Required Answer 20 23 33 6 2 1 35
60 81
72 36 36
Hence the correct answer is option (B).
68. y2 4 x and y x
2 2
x 4 x
4
x 0 and x y x
y
4/
1
Area 4 x x dx
0 9
4/ 4/
x3/ 2 x2 1
2
3/2 2 9
0 0 x
4 2
3/4 x x 16 1
2 3/2
3 2 9
32 8 1
3 9
8 1
3 9
24
Case II
7 1
When , sin ,0
6 2
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3
cos 1,
2
cot 3,
sin 1, cos 1
cot 1,2,3,......
x y 0
Ix y 0 I 1,2,.....
It will have unique solution in all cases x 0, y 0
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74. For A C, A C
B
But A B
option A is NOT true
Let x Cx C A C B
x C A and x C B
x C or x A and
x C or x B
x C or x A B
x C or x C (as
A B C) A=C B
x C
C A C B C (1)
Now x C x C A and
x C B
x C A C B
C C A C B (2)
from (1) and (2)
C C A C B
option B is true
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Let x A and x B
x A B
x C (as A B C)
Let x A and x B
x A B
x C (as A B C)
Hence x A x C
A C
Option C is true
As C A B
B C A B
As A B
B C
Hence the correct answer is option (A)
2 2
76. x y 3 0 ……..(i)
will be chord of contact of parabola
Let the required point is P x1,y1 chord of contact for point P is
y y1 x x1
xx1 4 3
2 2
y y1 2x1x 4x 4x1 6
As equation (i) and (ii) are same line
2x1 4 1 4x1 y1 6
1 1 3
2x1 4 1 4x1 y1 6 3
5 10 y1 9 0
x1
2
y1 1
5
Hence correct answer is , 1 which is option (D).
2
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77. AB 30m NP
MN
In ANM tan 45o 1
AN
M
MN AN
PM MN 30
AN 30
30o B
P
o PM AN 30
In BPM tan 30
PB AN
1 AN 30
3 AN 45o
N A
AN 3AN 30 3
30 3 30 3 3 1
AN 15 3 3
3 1 2
78.
A (1, 2)
E (–1, 1)
F (2, 3)
2 1 y2 2 x3 1 y3 2
1, 1 2 and 3
2 2 2 2
x2 3, y 2 0 x3 3, y3 4
B 3, 0 C 3, 4
x1 x2 x 3 y1 y2 y3
Centroid ,
3 3
1 3 3 2 D 4 1
, ,2
3 3 3
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79.
Coin +15 +12 –6
Probability 6 4 26
36 36 36
6
Probability of doublet
36
4
Probability of sum of 9
36
26
Other probability
36
6 4 26
Expected gain/loss 15 12 6
36 36 36
90 48 156 1
36 36 36 2
Hence correct answer is option (D).
20 20
80. 1 x C0 20C1 20C2 x 2 ....... 20 C20 x 20 ……….(i)
Differential equation w.r.t. x
19 20
20 1 x C1.1 2. 20C2 x ....... 20 20C20 x19 …………..(ii)
Multiply equation (2) by x
19 20
20x 1 x C1x 2. 20C2 x 2 ...... 20 20C 20 x 20 ……….(iii)
Differential equation 3 w.r.t. x
19 18
20 1 x 19x 1 x 1. 20C1 22 . 20C 2 x ...... 202 20
C 20 x19 …….(iv)
Put x 1 in equation (iv)
20 219 19.218 12 20C1 22 20
C2 ...... 20 2 20
C20
18 18
20 2 2 19 20 21 2
18
420 2
A 420, 18
Hence correct Option is (A).
1 sin x cos x
81. Given, y tan
sin x cos x
1 tan x 1
y tan
tan x 1
1 1 tan x
y tan
1 tan x
1
y tan tan x
4
0 x
2
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x 0
2
x 0
4 4
1
y x tan tan x x x ,
4 2 2
dy 1
y x 2
4 x 1
d
2 2
2 2
82. Equation of required circle will be x 3 y r r2
x2 6x 9 y 2 2r y r 2 r2
x2 y2 6x 2ry 9 0 ………(1)
Length of y intercept 2 f2 c rf
2
8 2 r 9
16 r 2 9
r=5
So equation of required circle will be
x 2 y 2 6x 10y 9 0 two circles
x2 y2 6x 10y 9 0 ………..(2)
2 2
x y 6x 10y 9 0 ………..(3)
Given option (C) i.e. (3, 10) satisfy equation (3).
4
83. y mx ……(i) is always tangent to y 2 16x
m
If it is tangent to the xy 4
4
x mx 4
m
m2 x 2 4x 4m
2 2
m x 4x 4m
m2 x 2 4x 4m 0
for tangent D = 0
16 16m3 0
m 1 put in equation (i)
y x 4
So the correct answer is option (D)
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x 3y 2 0 ………(2)
Case II : take negative sign
2x y 2z 4 x 2y 2z 2
2x y 2z 4 x 2y 2z 2
3x y 4z 6 0 ………(3)
Option (B) satisfy equation (3)
1
dx 9
85. loge
x x 1 8
1
x 1 x 9
dx loge
x x 1 8
1 1
dx dx 9
loge
x x 1 8
1
x 9
loge loge
x 1 8
2 1 2 9
loge log loge
2 2 2 1 8
2 1 2 1 9
log loge
2 2 2 8
2
2 1 9
4 1 8
2 2
8 4 4 1 9 4 4
32 2 32 8 36 2 36
4 2 4 8 0
2
2 0
2 1 0
1, 2
Hence the correct answer is option (B).
86. Given 5 boys and n girls
Total ways of farming team of 3
Members under given condition
5
C1 . nC2 5C2 . nC1
5
C1. nC2 5
C2 . nC1 1750
5n n 1
10n 1750
2
n n 1
2n 350
2
n2 3n 700
n2 3n 700 0
n 25
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87. 0,
3
2
1 cos sin2 4 cos6
cos2 1 sin2 4 cos6 0
cos2 sin2 1 4 cos 6
R2 R2 R1,R3 R3 R1
1 cos2 sin2 4 cos 6
1 1 0 0
1 0 1
C1 C1 C2
2 sin2 4 cos 6
0 1 0 0
1 0 1
expanding along first column
2 1 0 1 4 cos 6 0
2 4 cos 6 0
1
cos 6
2
2
6
3
88. OP = 4
given OP makes 60o with x y 0
Let slope of OP = m
m 1
tan60o
1 m
m 1
3 or 3
m 1
m 1 3m 3 or m 1 3 3m
m 3 1 3 1 or m 1 3 3 1
3 1 3 1
m or m
3 1 3 1
3 1 3 1
tan or tan
3 1 3 1
equation of line x cos y sin P
3 1x 3 1y 8 2 or 3 1x 3 1y 8 2
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x 2 sin x
89. Lim
2
x 0
x 2 sin x 1 sin2 x x 1
x 2 sin x
Lim 2
x2 2 sin x 1 sin2 x x 1
x 0 x 2 sin x 1 sin2 x x 1
x 2 sin x
Lim 2 . 2
x 0 x 2 sin x sin2 x x
Applying L’H Rule
2. 1 2 cos x
Lim
x 0 2x 2 cos x 2 sin x cos x 1
2 3
2
2 1
Hence the correct answer is option (A).
90. ~ p ~q p q
Hence the correct answer is option (C).
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