FIITJEE

ALL INDIA TEST SERIES

JEE (Advanced)-2022
CONCEPT RECAPITULATION TEST – II
PAPER –1
TEST DATE: 30-06-2022
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 57 questions.
 Each subject (PCM) has 19 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-B & Section-C.
Section – A (01 – 04, 20 – 23, 39 – 42): This section contains TWELVE (12) questions. Each question has
FOUR options. ONLY ONE of these four options is the correct answer.
Section – A (05 –10, 24 – 29, 43 – 48): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – B (11 – 13, 30 – 32, 49 – 51): This section contains NINE (09) questions. The answer to each
question is a NON-NEGATIVE INTEGER.
Section – C (14 – 19, 33 – 38, 52 – 57): This section contains NINE (09) question stems. There are TWO
(02) questions corresponding to each question stem. The answer to each question is a NUMERICAL
VALUE. If the numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places.

MARKING SCHEME
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
Section – C: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

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AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22 2

Physics PART – I
Section – A (Maximum Marks: 12)
This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.

1. During walking, work done by fraction is:

(A) Positive
(B) Negative
(C) Zero
(D) None of these

2. The time period of small vertical oscillations of pendulum is: (A

pendulum bob is hanging in equilibrium with the help of two identical
elastic wires as shown in the figure.) θ θ
(A) 2 m / YA Y, A,  Y, A, 
(B) 2 m / 2YA
m
(C)  m / YA
(D) None of these

3. The average degree of freedom per molecule of a gas is 6. The gas performs 25J work, while
expanding at constant pressure. The heat absorbed by the gas is:
(A) 75J
(B) 100J
(C) 150J
(D) 125J

4. The radioactive sources A and B have half lives of 2hr and 4hr respectively, initially contain the
same number of radioactive atoms. At the end of 2 hours, their rates of distintegration are in the
ratio:
(A) 4:1
(B) 2:1
(C) 2 :1
(D) 1:1

Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).

5. A student skates up a ramp that makes an angle 30° with the

z R y
horizontal. He/she starts (as shown in the figure) at the 
bottom of the ramp with speed v 0 and wants to turn around x
over a semicircular path xyz of radius R during which he/she
reaches a maximum height h (at point y) from the ground as h
shown in the figure. Assume that the energy loss is negligible
30°
and the force required for this turn at the highest point is
provided by his/her weight only. Then (g is the acceleration
due to gravity)
1
(A) v02  2 gh  gR
2

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 3 AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22

3
(B) v02  2 gh  gR
2
(C) The centripetal force required at points x and z is zero
(D) The centripetal force required is maximum at points x and z

6. A rod of mass m and length L, pivoted at one of its ends, is hanging

vertically. A bullet of the same mass moving at speed v strikes the rod
horizontally at a distance x from its pivoted end and gets embedded in it.
The combined system now rotates with angular speed  about the pivot. x
L
The maximum angular speed ωM is achieved for x=x M . Then:
3vx 

(A) = V
L  3x 2
2

12vx
(B) = 2
L  12 x 2
L
(C) xM =
3
V
(D) M = 3
2L
7. In an X-ray tube, electrons emitted from a filament (cathode) carrying current I hit a target (anode)
at a distance d from the cathode. The target is kept at a potential V higher than the cathode
resulting in emission of continuous and characteristic X-rays. If the filament current I is decreased
to I/2 , the potential difference V is increased to 2V, and the separation distance d is reduced
to d/2 , then:
(A) the cut-off wavelength will reduce to half, and the wavelengths of the characteristic X-
rays will remain the same
(B) the cut-off wavelength as well as the wavelengths of the characteristic X-rays will remain
the same
(C) the cut-off wavelength will reduce to half, and the intensities of all the X-rays will
decrease
(D) the cut-off wavelength will become two times larger, and the intensity of all the X-rays will
decrease

8. Two identical non-conducting solid spheres of same mass and charge are suspended in air from
a common point by two non-conducting, massless strings of same length. At equilibrium, the
angle between the strings is  . The spheres are now immersed in a dielectric liquid of density
-3
800 kg m and dielectric constant 21. If the angle between the strings remains the same after the
immersion, then
(A) electric force between the spheres remains unchanged
(B) electric force between the spheres reduces
(C) mass density of the spheres is 840 kg m -3
(D) the tension in the strings holding the spheres remains unchanged
-1
9. Starting at time t = 0 from the origin with speed 1 ms , a particle follows a two-dimensional
x2
trajectory in the x-y plane so that its coordinates are related by the equation y  . The x and y
2
components of its acceleration are denoted by a x and a y , respectively. Then:

(A) a x  1ms 2 implies that when the particle is at the origin, a y  1ms 2

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AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22 4

(B) a x  0 implies a y  1ms 2 at all times.

(C) at t = 0, the particle’s velocity points in the x-direction
(D) ax = 0 implies that at t = 1s, the angle between the particle’s velocity and the x axis is 45°

330π
10. A source is moving in a circle given by x 2 +y 2 =R 2 with a constant speed m/s in clockwise
6
sense. A detector is at rest at (2R, 0). Find the coordinates of the source at the instant when the
detector records the same frequency as that of the source (speed of sound = 330 m/s):
 3R R 
(A)  ,  
 2 2
 3R R 
(B)  , 
 2 2 
(C)  0, R 
(D)  R, 0 
Section – B (Maximum Marks: 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.

11. Consider one mole of helium gas enclosed in a container at initial pressure P1 and volume V1. It
expands isothermally to volume 4V1. After this, the gas expands adiabatically and its volume
becomes 32V1. The work done by the gas during isothermal and adiabatic expansion processes
Wiso 16
are Wiso and Wadia , respectively. If the ratio  ln2 , then find the value of k ?
Wadia k

12. A stationary tuning fork is in resonance with an air column in a pipe. If the tuning fork is moved
1
with a speed of 2ms in front of the open end of the pipe and parallel to it, the length of the pipe
should be changed for the resonance to occur with the moving tuning fork. If the speed of sound
1
in air is 320 ms , the smallest value of the percentage change required in the length of the pipe
k
is , find the value of k ?
8

 r
13. A circular disc of radius R carries surface charge density   r    0  1   , where  0 is
 R
a constant and r is the distance from the center of the disc. Electric flux through a large spherical
surface that encloses the charged disc completely is 0 . Electric flux through another spherical
0 32
surface of radius R/4 and concentric with the disc is  . If the ratio of is , then find the
 k
value of k?

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 5 AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22

Section – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 14 and 15

Question Stem

The potential difference  V  between the positive and negative terminals V  volt 
2.0
of a cell changes with the current through it as shown in the graph

O 5 iA

14. Find the internal resistance of the cell.  in ohm 

15. Find the emf of the cell  in volts 

Question Stem for Question Nos. 16 and 17

Question Stem

A tank placed on ground has water filled in it, up to a height H. A small hole
is punched in its side wall at a height h from the bottom. Water jet strikes the
ground at a horizontal distance x . H
Hole
(Take H = 2 meter)
h
x

16. For what value  in meter  of h is x maximum?

17. For two value of h, we get same range  X  . If one value of h is H/4 , what is its other value?

 in meter 
Question Stem for Question Nos. 18 and 19
Question Stem

A rod is translating on a V-shaped rail as shown in the figure at an

instant. P

θ=37°
v0 =10 m/s
O θ=37°

18. Find the velocity (in m/s) of point of intersection P.

19. Find the angular velocity of intersection point P with respect to observer O.

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AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22 6

Chemistry PART – II
Section – A (Maximum Marks: 12)
This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.

20. Identify reactions correctly match with their names?

(A) O O O O Perkin
Ph C H
 i  MeCOO  / MeCOOH, Ph CH CH C OH
reaction
O
(ii) H +

(B) O O CH3 Cannizaro

OH  reaction
2 
 CH3

(C) Friedel Crafts

OH OH reaction
+
H
 
O

(D) O Haloform
conc. reaction
2H C H H-COO   CH3 OH
NaOH

For the gas phase reaction N 2  3H 2  2NH3 the equilibrium constant is 10

5
21. atm 2 at 300K.
G for the reaction will be:
(A) 28.72 kJ
(B) 28.72 kJ
(C) 14.3kJ
(D) Zero

22. In salt analysis, cations of group IIIrd can be tested by adding certain reagents. Which is the
correct combination for the above mentioned test?
(A) Bi 3 , NH 4 Cl / NH 4 OH
(B) Fe3 , NH 4 Cl / NH 4OH
(C) Cr 3 , H 2 S / HCl
(D) Al 3 , NH 4 OH / H 2 S


23. In a titration, H 2 O 2 is oxidised to O 2 by MnO4 in acidic medium. If 24 ml H2O2 requires 16ml of

0.1M MnO4 , then the volume strength of H2O2 will be:
(A) 0.167
(B) 1.89
(C) 3.72
(D) 0.93

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 7 AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22

Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).

24. Out of the following, which is not correct match for radial
probability of finding the electron of 2s orbital?
(A) A  H , B  He  , C  Li 2 
(B) A  He , B  H , C  Li 2 
(C) A  Li 2  , B  He  , C  H
(D) A  Li 2 , B  H , C  He 

25. The compound Na 2 IrCl6 reacts with triphenylphosphine in diethylieneglycol in an atmosphere of

CO to give  IrCl  CO  PPh 3 2  , known as ‘Vaska’s compound’.
(Atomic number of Ir = 77)
Which of the following statements is correct?
(A) The IUPAC name of the complex is carbonylchloridebis (triphenylphosphine) iridium(III)
(B) The hybridisation of the metal ion is sp3
(C) The magnetic moment (spin only) of the complex is zero
(D) The complex shows geometrical as well as ionization isomerism

26. Choose the correct statement from the following:

(A) The slag obtained during extraction of iron is heavy and has lower melting point than that
of metal
(B) At temperature below 983 K(approx) CO is chief reducing agent in blast furnance.
(C) In zone refining impurities moves in the direction of heater.
(D) Electrolytic reduction of Al2 O3 is known as Hall-Heroult process.

27. Select the correct statement.

(A) Three moles of phenylhydrazine and one mole of aldose required to produce
phenylosazone.
(B) Glucose form gluconic acid with Br2 /HOH
(C) Glucose form Glucaric acid with HNO3
(D) Lowering in carbon chain can be done by Kiliani Fischer method.

28. Select the CORRECT statement.

(A) At Boyle’s temperature a real gas behaves like an ideal gas irrespective of pressure.
TBoyle 27
(B) 
TCritical 8
(C) On increasing the temperature four times, collision frequency (Z1) becomes double at
constant volume.
(D) At high pressure Van der Waals constant ‘b’ dominates over ‘a’.

1.1eq. of SOCl 2 Br2 Br2

HO 2 C   CH 2 3  CH 2 CO 2 H P1 P2 P3
29. +KOH /red P
2. NH 3 1eq.
 ,intramolecular SN2
  P4
Which are correct?

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AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22 8

(A) P1 is H 2 N  CO  CH 2 3  CH 2CO 2 H

(B) P2 is H 2 N   CH 2 3  CH 2 CO 2 H
(C) P3 is H 2 N   CH 2 3  CH  Br   CO2 H

(D) P4 is
N
+
CO 2
H H

Section – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.

30. Xe react directly with F2 in different condition (by volume mixture) of Xe & F2 at suitable
condition
Example: - Xe + F2   XeF2
(2 : 1)
Ration of Xe and F2 is given to make different Xenon (Fluoride)n products.
XeF2  Xe:F2  x : a  1: 0.5
XeF4  Xe:F2  x : b
XeF6  Xe:F2  x : c
Find the value of a  b  c when x  2

31. Borax and kernite both are consist of Na 2 B4 O 7 xH 2 O . Find sum of H 2 O molecules in formula of
borax & kernite.

32. When 0.2 g of acetic acid is added to 20 g of benzene, its freezing point decreases by 0.8°C.
Find the % dimerisation of acetic acid in benzene, K f (Benzene) =5 K-kg mol .

Section – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 33 and 34

Question Stem

A solid compound ‘G’, of formula C15H15ON, was insoluble in water, dilute HCl, of dilute NaOH. After
prolonged heating of ‘G’ with aqueous NaOH, a liquid, ‘H’, was observed floating on the surface of the
alkaline mixture. ‘H’ did not solidify upon cooling to room temperature; it was steam-distilled and
separated. Acidification of the alkaline mixture with hydrochloric acid caused precipitation of a white
solid, ‘I’. ‘I’ is a paramethyl benzene derivative.
Compound ‘H’ was soluble in dilute HCl, and reacted with benzenesulfonyl chloride and excess KOH to
give a base-insoluble solid, ‘J’.
Compound ‘I ’ , m.p. 180°C, was soluble in aqueous NaHCO3, and contained no nitrogen.
What were compound G, H, I and J?

33. The number of Carbon atoms in ’I ‘ will be

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 9 AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22

Molecular weight of 'H'

34. The will be
53.5

Question Stem for Question Nos. 35 and 36

Question Stem

In coordination chemistry there are a variety of methods applied to find out the structure of complexes.
One method involves treating the complex with known reagents and from the nature of reaction, the
formula of the complex can be predicated. An isomer of the complex Co(en)2(H2O)Cl2Br, on reaction with
concentrated H2SO4 (dehydrating agent) it suffers loss in weight and on reaction with AgNO3 solution it
gives a white precipitate which is soluble in NH3(aq.) [Atomic weight of Co = 59, Br = 80, Cl = 36]

35. Number of geometrical isomers of the formula of the above original complex are (including the
complex)

36. Molecular weight of cation of the above complex.

Question Stem for Question Nos. 37 and 38

Question Stem

Boron compounds are not only used for therapeutic but also for diagnostic applications. A class of
pyrrole-containing boron compounds are used as dyes to stain and image various (transparent)
organelles inside the living cells, which are ordinarily difficult to see. The B  N bonds in these
compounds are very stable even under biochemical condition, and hence the compounds do not interfere
with cellular processes. Two representative examples of such dyes are given below:

N N N N X=F/Cl/Br
B B
X X X X

 P Q

37. What is the oxidation state of boron (B) in compound P?

38. The degree of unsaturation among the dyes (P) and (Q) which will preferentially stain fat tissues

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AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22 10

Mathematics PART – III

Section – A (Maximum Marks: 12)
This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.

39. P is any point, O being the origin. On the circle with OP as diameter the points Q and R are on
the same side of the diameter such that POQ = QOR = , if P, Q and R be complex numbers
z1, z2, z3 respectively such that 2 3z22 =  2  3  z1 z3 then the value  is
(A) 30
(B) 45
(C) 15
(D) 18

2x 2 x
40. For a function f: R  R, such that f  f  = 2f(1) for all x  R and f(0) = 0, then f(x) is
 2   2 
(A) even function
(B) odd function
(C) periodic
(D) none of these

41. If a, ˆ cˆ are unit vectors, then the maximum value of aˆ  bˆ  cˆ 2  bˆ  cˆ  aˆ 2  cˆ  aˆ  bˆ 2 must

ˆ b,
be
(A) 9
(B) 12
(C) 15
(D) none of these

42. Let A(, 0), B(, 0), C(, 0), D(, 0) and ,  are the roots of equation ax 2 + 2hx + b = 0 while , 
are the those of a1x2 + 2h1x + b1 = 0 if C and D divides AB in the ratio  : 1 and  : 1 respectively
also ab1, hh1, a1b are in A.P., then  +  is equal to
(A) 2
(B) 1
(C) 0
(D) none of these

Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).

43. If x1 and x2 are positive numbers between 0 and 1, then which of the following is/are true?
 x  x 2  sin x1  sin x 2
(A) sin  1 
 2  2
 x  x 2  tan x1  tan x 2
(B) tan  1 
 2  2
 x  x 2  log x1  log x 2
(C) log  1 
 2  2
2
 x1  x 2  x12  x 22
(D)   
 2  2

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 11 AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22

44. Let Sn(n  1) be a sequence of sets defined by

S1 = {0}, S2 =  
3 5
, , S3 =
2 2
, ,
3 3 5
8 11 14

S4 = 
15 19 23 27
, ,
4 4 4 4
, 
, … then

439
(A) third element in S20 is
20
431
(B) third element in S20 is
20
(C) sum of elements in S20 is 589
(D) sum of elements in S20 is 609

45. The lines (m  2) x + (2m  5) y = 0, (m  1) x + (m2  7) y  5 = 0 and x + y  1 = 0 are

(A) concurrent for three values of m
(B) concurrent for one values of m
(C) concurrent for no values of m
(D) are parallel for m = 3

x
46. Let the function f: [–1, 1]  R is defined by f(x) =  sin t  cos t dt , then
1
(A) f(x) is one-one function
(B) periodic function
(C) monotonic function
 4 2
(D) f(x)  0, 
  

 a2 
47. Let f(x) = (ln(a2 – 3a – 3)) |sinx| +   cos x  x  R (where [.] denote greatest integer function)
9
be such that f(x + T) = f(x), then
(A) if T  Q, then a  {–1, 4}
(B) if T  Q, then a  (–, –1]  {4}
 3  21 
(C) if T  Q, then a   3, 
 2 
 3  21 
(D) if T  Q, then a   3, 
 2 

a b c d
48. Let a, b, c, d > 0 and if x =    , then for some a, b, c, d, the
abd abc bc d ac d
value of
1
(A) x=
2
5
(B) x=
3
3
(C) x=
2
5
(D) x=
4

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AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22 12

Section – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.
2 3 16 17
49. The polynomial p(x) = 1 – x + x – x + ... + x – x can be written as a polynomial in y where
2  k 
y = x + 1, then let coefficient of y be k then  (where [.] denote greatest integer function)
 400 
is_______

50. Let the area enclosed by the curve |x – 60| + |y| = |x/4| be 4(n!) then the value of n is__________

51. Let f(n) denote the square of the sum of the digits of natural number n, where f 2(n) denote f(f(n)),
3 f 2011  2011  f 2010  2011
f (n) denote f(f(f(n))) and so on. The value of 2013 = ___________
f  2011  f 2012  2011

Section – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 52 and 53

Question Stem

Let f  x   2 x  3 ,1  x  5 and for rest of the values f  x  can be obtained by using the
relation f  5 x    f  x  x  R .

The maximum value of f  x  in 5 ,5  for

4 5
52.   2 is__

53. The value of f  2007  , taking   5 , is___

Question Stem for Question Nos. 54 and 55

Question Stem

Let f  x  be a polynomial of degree 5 with leading coefficient unity, such that

f 1  5, f  2   4, f  3  3, f  4   2 and f  5   1 , then:

54. f  6  is equal to____

55. Sum of the roots of f  x  is equal to____

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 13 AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/22

Question Stem for Question Nos. 56 and 57

Question Stem

Consider a triangle ABC with vertex A  2,  4  . The internal bisectors of the angles B and C are
x  y  2 and x  3 y  6 respectively. Let the two bisectors meet at I .

56. If  a, b  is incentre of the triangle ABC then  a  b  has the value equal to___

57. If  x1 , y1  and  x2 , y2  are the co-ordinates of the point B and C respectively, then the value of

 x1 x2  y1 y2  is equal to____

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