MATRIX SCIENCE ACADEMY

Chemistry MHT CET L1 2022-23

Time : 60 Min Chem : Groupwise Paper Marks : 50
Hints and Solutions

01) Ans: D) NH2 2

Sol: Fe  H2O6  complex ion has six H2O
Sol: NH2  
ligands which are weak-ffield ligands. The
oxidation state of Fe is +2.
02) Ans: A) sodium acetate.
Fe26  4s2 3d6  Fe2  3d6.
Sol: Here, CH3COONa CH3COO  Na 
The crystal field d-orbital energy diagram for
H2O H  OH CH3COOH  NaOH 2
Fe  H2O  will be as follows.
 6
03) Ans: B) ionization isomers.
Sol: Both contain same composition but give
different ions in the solution, hence ionization
isomerism.
There are four unpaired electrons and the complex
ion is paramagnetic in nature.
04) Ans: B) 13
1014 16) Ans: B) inversion.
Sol: Here, [H ]   1013 mol / litre ,
101
Hence, pH  13 . 17) Ans: B) D-(+)-glyceraldehyde

05) Ans: D) anionic,homoleptic 18) Ans: B) on increasing dilution.

Sol: In weak electrolyte the degree of dissociation is
06) Ans: A) aldoes very small. Therefore it increases with increasing
dilution.
07) Ans: B) 107 M
19) Ans: A) 100%
Sol: Ksp of BaSO4  1.5  109 , Ba   0.01 M Sol: By the Ostwald's dilution law, because degree
of ionization is directly proportional to the dilution.
1.5  109
 SO4    1.5  107
0.01 20) Ans: A) glucopyranose

08) Ans: D) 4 21) Ans: B) Lactose

Sol: The co-ordination number = Number of ligands
attached. 22) Ans: C) bring down the specific heat of water.
Sol: Ethylene glycol is added for lowering down the
09) Ans: A) casein freezing point of water in order that it does not
freeze.
10) Ans: D) reducing sugar
Sol: The hemiacetal group at C-1 of the second ring 23) Ans: C) Benzene-1, 2, 3-triol
is not involved in glycosidic linkage. Hence,
Maltose is a reducing sugar which gives positive
Tollen's test and positive Fehling test.

11) Ans: B) pyridinium chlorochromate

Sol:
12) Ans: A) 3-Methylphenol
24) Ans: A) hydroxy toluenes.
13) Ans: A) Titanium
Sol: Ziegler-Natta catalyst is (CH3CH2 )3 Al  TiCl4 .

14) Ans: B) ionization.

Sol: Polar solvent facilitate ionization of strong Sol:
electrolytes because of dipole-ion attraction.
25) Ans: B) (i) o-and p-bromophenol and
15) Ans: D) 4, paramagnetic (ii) 2, 4, 6-tribromophenol
Sol:

JEE-MAIN, MHT-CET, NEET/AIPMT, MHT-CET-XI - New Syllabus (MH)

 MATRIX SCIENCE ACADEMY

38) Ans: B) CH3  CH2  CH2  CH2  CH2  OH

Ni
Sol: CH3  CH  CH  CH2  CHO  H2 

CH3  CH2  CH2  CH2  CH2  OH
H2 and Ni reduces
| |
 C H  C H  to  CH2  and  CHOto  CH2  OH

39) Ans: A) Dry ether

Sol: Dry ether is used as catalyst as
Dry ether
Mg  CH3I   CH3MgI

40) Ans: D) CH3CH2CH2  O  CH2CH2CH3

In aq. solution, phenol ionizes to give phenoxide in
Conc.H SO
which highly activates benzene ring and give Sol: CH3  CH2  CH2  OH 
2
413K
4

trisubstituted product while in presence of CS 2 an CH3CH2CH2  O  CH2CH2CH3
inert solvent phenol is unable to ionize due to
which benzene ring is slightly activated. Hence,
monosubstituted product is obtained. 41) Ans: C) tetraammine copper (II) nitrate

26) Ans: C) Polymer of nucleotides 42) Ans: C) cis [PtCl2 (NH3 )2 ]

Sol: Nucleic acids are polymer of nucleotides. Sol: cis [PtCl2 (NH3 )2 ]

27) Ans: B) potassium trioxalatoaluminate (III) 43) Ans: A) Glycine

Sol: The simplest   amino acid is glycine.
28) Ans: B) NH4OH  NH4Cl
Sol: Here, NH4OH NH4  OH 44) Ans: B) acetone.
[O]
NH4Cl NH4  Cl Sol: CH3  C H CH3   CH3  C CH3
| ||
OH O
29) Ans: B) C6H5CH2OH
45) Ans: B) S  Ksp
Sol: For a binary electrolyte,
Ksp  S  S  S2 i.e. S  Ksp
Sol:

30) Ans: B) number of possible ligands around 46) Ans: C) Ethoxyethane

metal ion in a complex
47) Ans: D) Potassium trioxalatoferrate (III)
31) Ans: A) +1
48) Ans: B) acid B.
33) Ans: D) possess chirality Sol: As acid having higher pK a value are weak
acid.
34) Ans: C) nature of solute molecules.
Sol: The degree of ionization of a solute depends 49) Ans: D) CH3CH2CH2MgI
upon its nature, concentration as well as
temperature.
Sol:
35) Ans: D)  7
Sol: Since the solution is acidic, pH < 7. This is
because [H ] from H2O [107 ] cannot be
neglected in comparison to 1012 M.

36) Ans: D) an aldehydic group.

Sol: Glucose + Tollen's reagent  Gluconic acid + 50) Ans: B) Co  en3 Cl3 
Silver mirror
Sol: Co  en3 Cl3 
37) Ans: D) zero.
Sol: Because of presence of strong ligand, all the
e  get paired. Thus, number of unpaired electrons
are 0.

JEE-MAIN, MHT-CET, NEET/AIPMT, MHT-CET-XI - New Syllabus (MH)