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DPP 2 6

1. The document is a chemistry exam with 20 multiple choice questions covering topics on solutions, including solubility, concentration units like molarity and molality, Raoult's law, and electrolyte solutions. 2. Questions cover concepts like the factors that determine solubility, concentration calculations using molarity and molality, vapor pressure lowering according to Raoult's law, and osmotic pressure relationships for electrolyte solutions. 3. The document tests students' understanding of key chemistry concepts and calculations related to solutions and solubility.

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Gnaneshwar
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54 views3 pages

DPP 2 6

1. The document is a chemistry exam with 20 multiple choice questions covering topics on solutions, including solubility, concentration units like molarity and molality, Raoult's law, and electrolyte solutions. 2. Questions cover concepts like the factors that determine solubility, concentration calculations using molarity and molality, vapor pressure lowering according to Raoult's law, and osmotic pressure relationships for electrolyte solutions. 3. The document tests students' understanding of key chemistry concepts and calculations related to solutions and solubility.

Uploaded by

Gnaneshwar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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CLASS : XIth SUBJECT : CHEMISTRY

DATE : DPP No. : 2

Topic :-SOLUTIONS
1. Which is not applicable to distribution law?
a) Parke’s process
b) Solvent extraction
c) Pattinson’s process
d)Partition chromatography

2. Which of the following is the expression of Raoult’s law?


(𝑝 = vapour pressure of pure solvent, 𝑝𝑠 = vapour pressure of the solution)
𝑝 ― 𝑝𝑠 𝑛 𝑝𝑠 ― 𝑝 𝑁 𝑝 ― 𝑝𝑠 𝑁 𝑝𝑠 ― 𝑝 𝑁 ― 𝑛
a) = b) = c) = d) =
𝑝 𝑛+𝑁 𝑝 𝑁+𝑛 𝑝𝑠 𝑁―𝑛 𝑝𝑠 𝑁

3. For determination of molar mass of colloids, polymers and protein, which property is used ?
a) Diffusion pressure b) Atmospheric pressure
c) Osmotic pressure d)Turgor pressure

4. 3.0 molal NaOH solution has a density of 1.110 g/mL. The molarity of the solution is
a) 3.9732 b) 2.9732 c) 1.9732 d)0.9732

5. Sodium sulphate is soluble in water, while barium sulphate is sparingly soluble because :
a) The hydration energy of sodium sulphate is more than its lattice energy
b) The lattice energy of barium sulphate is less than the hydration energy
c) The lattice energy has no role to play in solubility
d)The hydration energy of sodium sulphate is less than its lattice energy

6. Distribution law is applicable when :


a) Temperature remains constant
b) Dilute solutions are employed
c) The two solvents are mutually insoluble
d)All are correct

7. 10 𝑐𝑚3of 0.1 N monobasic acid requires 15 𝑐𝑚3 of sodium hydroxide solution whose normality
is
a) 1.5 N b) 0.15 N c) 0.066 N d)0.66 N
8. Density of a 2.05 M solution of acetic acid in water is 1.02 g/mL. The molality of the solution is
a) 1.14 mol 𝑘𝑔―1 b) 3.28 mol 𝑘𝑔―1 c) 2.28 mol 𝑘𝑔―1 d)0.44 mol 𝑘𝑔―1

9. x gram of water is mixed in 69 g of ethanol. Mole fraction of ethanol in the resultant solution is
0.6. What is the value of x in grams?
a) 54 b) 36 c) 180 d)18

10. Dissolution of a solute is an exothermic process if :


a) Hydration energy > lattice energy
b) Hydration energy < lattice energy
c) Hydration energy = lattice energy
d)None of the above

11. Molarity is expressed as


a) L/mol b) Mol/L c) Mol/1000 g d)g/L

12. The amount of anhydrous Na2CO3 present in 250 mL of 0.25 M solution is


a) 6.0 g b) 6.625 g c) 66.25 g d)6.225 g

13. Which of the following compounds correspond to maximum van’thoff factor for dilute solution?
a) HCl b) MgSO4 c) K2SO4 d) K4Fe(CN)6

14. Solute 𝐴 is a ternary electrolyte and solute 𝐵 is non-electrolyte. If 0.1 𝑀 solution of solute 𝐵
produces an osmotic pressure of 2𝑃, then 0.05 𝑀 solution of 𝐴 at the same temperature will
produce an osmotic pressure equal to :
a) 𝑃 b) 1.5 𝑃 c) 2 𝑃 d)3 𝑃

15. A solution of sucrose (molar mass 342 g mol―1) has been produced by dissolving 68.5 g
sucrose in 1000 g water. The freezing point of the solution obtained will be : (𝐾𝑓 for H2O
= 1.86 Kkg mol―1)
a) ―0.372 C b) ―0.520 C c) + 0.372 C d) ―0.570 C

16. A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 290 mm at 300 K. the
vapour pressure of propyl alcohol is 200 mm. If the mole fraction of ethyl alcohol is 0.6, its
vapour pressure (in mm) at the same temperature will be
a) 350 b) 300 c) 700 d)360

17. How many grams of sulphuric acid is to be dissolved to prepare 200 mL aqueous solution
having concentration of [𝐻3𝑂+] ions 1 M at 25℃ temperature.
[𝐻 = 1, 𝑂 = 16, 𝑆 = 32 𝑔.𝑚𝑜𝑙―1]
a) 4.9g b) 19.6g c) 9.8g d)0.98g
18. What is the molarity of 𝐻2𝑆𝑂4 solution if 25 mL is exactly neutralised with 32.63 mL of 0.164
M NaOH?
a) 0.107 M b) 0.126 M c) 0.214 M d)-0.428 M

19. What is the molality of ethyl alcohol (mol. wt. = 416) in aqueous solution which freezes at
― 10 C?.(𝐾𝑓 for water = 1.86 K molality―1)
a) 3.540 b) 4.567 c) 5.376 d)6.315

20. The solubility order for the following gases is :


a) NH3 > 𝐶O2 > O2 > H2
b) H2 > O2 > 𝑁H3 > 𝐶O2
c) CO2 > 𝑁H3 > O2 > N2
d) O2 > H2 > 𝑁H3 > 𝐶O2

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