ATOMIC STRUCTURE

Total No.of questions in Atomic Structure are -

Level # 1 .................................................................................... 67
Level # 2 ........................................ ......................................... 91
Level # 3 ........................................ ......................................... 26
Level # 4 ........................................ ......................................... 38

Total No. of questions ............................................................ 222

 LEVEL # 1
Q.8 The frequency of line spectrum of sodium
is 5.09 x 10 14 sec –1 . Its wave length (in
nm) will be - [c = 3 × 108 m/sec]-
Q.1 The study of cathode rays (i.e. electronic (A) 510 nm (B) 420 nm
discharge through gases) shows that - (C) 589 nm (D) 622 nm
(A) Alpha particles are heavier than protons
(B) All forms of matter contain electrons Q.9 The spectrum of He-atom may be considered
(C) All nuclei contain protons similar to the spectrum of -
(D) e/m is constant (A) H (B) Li +
(C) Na (D) He+
Q.2 Proton is -
(A) Nucleus of deuterium
(B) Ionised hydrogen molecule Q.10 Supposing the energy of fourth shell for
hydrogen atom is - 50 a.u. (arbitrary unit). What
(C) Ionised hydrogen atom
would be its ionization potential -
(D) An -particle
(A) 50 (B) 800
(C) 15.4 (D) 20.8
Q.3 Which is not deflected by magnetic field -
(A) Neutron (B) Positron
Q.11 Supposing the ionization energy of hydrogen
(C) Proton (D) Electron
atom is 640 eV. Point out the main shell having
energy equal to – 40 eV -
Q.4 According to Dalton’s atomic theory, an atom (A) n = 2 (B) n = 3
can –
(C) n = 4 (D) n = 5
(A) Be created (B) Be destroyed
(C) Neither be created nor destroyed
Q.12 A 1-kW radio transmitter operates at a frequency
(D) None
of 880 Hz. How many photons per second does
it emit -
Q.5 Rutherford’s experiment on scattering of alpha (A) 1.71 x 1021 (B) 1.71 x 1033
particles showed for the first time that atom (C) 6.02 x 1023
(D) 2.85 x 1026
has -
(A) Electrons (B) Protons Q.13 On Bohr’s stationary orbits -
(C) Nucleus (D) Neutrons (A) Electrons do not move
(B) Electrons move emitting radiations
Q.6  - particles are represented by – (C) Energy of the electron remains constant
(A) Lithium atoms (B) Helium nuclei (D) Angular momentum of the electron is h/2
(C) Hydrogen nucleus (D) None of these
Q.14 The value of Bohr radius of hydrogen atom is -
(A) 0.529x 10–7cm (B) 0.529x 10-8cm
Bohr’s Atomic Model -9
(C) 0.529x 10 cm (D) 0.529x 10–10 cm

Q.7 The energy of electron in first Bohr’s orbit of Q.15 On the basis of Bohr’s model, the radius of the
H-atom is –13.6 eV. W hat will be its 3rd orbit is -
potential energy in n = 4th orbit - (A) Equal to the radius of first orbit
(A) – 13.6 eV (B) –3.4 eV (B)Three times the radius of first orbit
(C) Five times the radius of first orbit
(C) –0.85 eV (D) –1.70 eV
(D) Nine time the radius of first orbit
Q.16 The correct expression derived for the energy of Q.23 The specific charge of a proton is 9.6 x 107C
an electron in the nth energy level is - kg–1, then for an -particles it will be -
(A) 2.4 x 107C kg–1 (B) 4.8 x 107C kg–1
22me4 2 2me4 7
(C) 19.2 x 10 C kg –1
(D) 38.4 x 107C kg–1
(A) En = (B) En = –
n2h2 nh2

Q.24 For H– atom, the energy required for the removal

2  2me2 2 2me4
(C) En = – (D) En= – of electron from various sub-shells is given as
n2h2 n2h2
under–

Q.17 Ionization energy for hydrogen atom in ergs,

Joules and eV respectively is -
(A) 21.8 x 10–12 , 218 x 10–20 , 13.6
The order of the energies would be –
(B) 13.6 x 218 x 10–20, 21.8 x 10–13
(A) E1 > E2 > E3 (B) E3 > E2 > E1
(C) 21.8 x 10–20, 13.6 , 21.8 x 10–13 (C) E1 = E2 = E3 (D) None of these
(D) 21.8 x 10–13, 13.6, 21.8 x 10–20

Hydrogen Spectrum
Q.18 The velocity of an electron in the third orbit of
hydrogen atom -
(A) 7.28 x107 cm sec–1 Q.25 The wave number of the first line of Balmer
(B) 7.08 x 107 cm sec –1 series of hydrogen is 15200 cm–1. The wave
(C) 7.38 x 107cm sec–1 number of the first Balmer line of Li2+ ion is-
(D) 7.48 x107cm sec–1 (A) 15200cm–1 (B) 60800 cm –1
(C) 76000 cm –1 (D) 136800 cm –1
Q.19 The ionization energy of a hydrogen atom is
13.6eV. The energy of the third-lowest electronic
level in doubly ionized lithium (Z = 3) is - Q.26 The wavelength of the third line of the Balmer
series for a hydrogen atom is -
(A) –28.7 eV (B) –54.4 eV
(C) –122.4 eV (D) –13.6 eV 21 100
(A) 100R (B) 21 R
H H
Q.20 The momentum of a photon with energy 20 eV
is - 21R H 100R H
(C) (D)
(A) 10.66 x 10–27 Kg m sec–1 100 21
(B) 10.55 x 10–27 Kg m sec–1
(C) 10.60 x 10–27 Kg m sec–1 Q.27 Wave number of a spectral line for a given
(D) 10.80 x 10–27 Kg m sec–1 transition is x cm–1 for He+ , then its value for
Be3+ for the same transition is -
(A) 4x cm–1 (B) x cm –1
Q.21 For ionising an excited hydrogen atom, the
energy required in eV will be - (C) x/4 cm–1 (D) 2x cm–1
(A) 3.4 or less (B) More than 13.6
(C) Little less than 13.6 (D) 13.6 Q.28 A photon was absorbed by a hydrogen atom in
its ground state and the electron was promoted
Q.22 A gas absorbs a photon of 300 nm and then re- to the fifth orbit. When the excited atom returned
emitts two photons. One photon has a to its ground state, visible and other quanta were
wavelength 600 nm. The wavelength of second emitted. Other quanta are -
photon is - (A) 2  1 (B) 5  2
(A) 300 nm (B) 400 nm (C) 3  1 (D) 4  1
(C) 500 nm (D) 600 nm
Q.29 Wave-length of the first line of Paschen Series Q.35 How many electrons can fit into the orbitals
hydrogen spectrum is - (R = 109700 cm–1) - that comprise the 3rd quantum shell n = 3 -
(A) 18750 (Å) (B) 2854 (Å) (A) 2 (B) 8
(C) 3452 (Å) (D) 6243 (Å) (C) 18 (D) 32

Q.30 What is the change in the orbit radius when the Q.36 The shape of the orbital is given by -
electron in the hydrogen atom (Bohr model) (A) Spin quantum number
undergoes the first Paschen transition - (B) Magnetic quantum number
(A) 4.23 x 10–10 m (B) 0.35 x 10–10 m (C) Azimuthal quantum number
–10
(C) 3.7 x 10 m (D) 1.587 x 10–10 m (D) Principal quantum number

Q.31 If the shortest wavelength of H atom in Lyman Q.37 The set of quantum numbers not applicable for
series is x, then longest wavelength in Balmer an electron in an atom is –
series of He+ is - (A) n = 1, l = 1, m = 1, s = + 1/2
9x 36x (B) n = 1, l = 0, m = 0, s = + 1/2
(A) (B) (C) n = 1, l = 0, m = 0, s = – 1/2
5 5
(D) n = 2, l = 0, m = 0, s = + 1/2
x 5x
(C) (D) Q.38 Maximum numbers of electrons in a subshell is
4 9
given by -
(A) (2l + 1) (B) 2(2l+1)
Q.32 Which of the following expressions represents (C) (2l+1) 2
(D) 2(2l + 1)2
the spectrum of Balmer series(If n is the
principal quantum number of higher energy level) Q.39 The magnetic quantum number for valency
- electron of sodium atom is -
R(n  1)(n  1) (A) 3 (B) 2
(A) v  cm 1
n2 (C) 1 (D) Zero
R(n  2)(n  2)
(B) v  cm 1 Q.40 Which one of the following represents an
4n 2 impossible arrangement –
R(n  2)(n  2) n  m s
(C) v  cm 1
n2 (A) 3 2 –2 1/2
(B) 4 0 0 1/2
R(n  1)(n  1)
(D) v  cm 1 (C) 3 2 –3 1/2
4n 2 (D) 5 3 0 1/2

Q.41 The set of quantum number for the 19th electrons

Quantum Numbers
in chromium is -
(A) n=4, l=0,m=0, s =+1/2 or -1/2
Q.33 The maximum number of electron in a (B) n=3, l=2,m=1,s=+1/2 or -1/2
principal shell is - (C) n=3, l=2 m= -1,s=+1/2 or -1/2
(A) 2n (B) 2n2 (D) n=4, l=1,m=0,s=+1/2 or -1/2
(C) 2 (D) 2n
Q.42 The electronic configuration together with the
quantum number of last electron for lithium is -
Q.34 Which of the following statements concerning 1
the four quantum numbers is false - (A) 1s22s1 2, 0, 0 +
2
(A) n gives idea of the size of an orbital
1 1
(B)  gives the shape of an orbital (B) 1s22s1 2, 0, 0 + or –
2 2
(C) m gives the energy of the electron in the
1
orbital (C) 1s22s02p1 2, 1, 0 ±
2
(D) s gives the direction of spin of the 1
2 1
electron in an orbital (D) 2s 2s 2,1, 0 ±
2
Q.43 The electronic configuration together with the
Electronic Configuration
quantum number of last electron for lithium is -
1 Q.49 An electron has a spin quantum number
(A) 1s2 2s1 2, 0, 0, +
2 + 1/2 and a magnetic quantum number –1. It
cannot be present in -
1 1
(B) 1s2 2s1 2, 0, 0, + or – (A) d-Orbital (B) f-Orbital
2 2
(C) s-Orbital (D) p-Orbital
1
(C) 1s2 2s0 2p1 2, 1, 0, ±
2
Q.50 If the electronic structure of oxygen atom is
1
(D) 2s2 2s1 2, 1, 0, ±
2
written as 1s2, 2s2 it would

Q.44 Four sets of values of quantum numbers (n, l, violate -

m and s) are given below. Which set does not (A) Hund’s rule
provide a permissible solution of the wave (B) Paulis exclusion principle
equation - (C) Both Hund’s and Pauli’s principles
1 1 (D) None of these
(A) 3, 2, –2, (B) 3, 3, 1, –
2 2
1 1 Q.51 The energy of an electron of 2py orbital is -
(C) 3, 2, 1, (D) 3, 1, 1,
2 2 (A) Greater than 2px orbital
(B) Less than 2pz orbital
Shapes of orbitals, Nodal Plane & Surface (C) Equal to 2s orbital
(D) Same as that of 2px and 2pz orbitals
Q.45 In presence of magnetic field d-sub orbit is -
(A) 5 - Fold degenate
(B) 3-Fold degenerate Q.52 The number of unpaired electrons in carbon
(C) 7-Fold degenerate atom is -
(D) Non- degenerate (A) 2 (B) 4 (C) 1 (D) 3

Q.46 In which of the following pairs is the probability Q.53 When 4 d orbital is complete, the newly entering
of finding the electron in xy-plane zero for both
electrons goes in to -
orbitals ?
(A) 5f (B) 5s
(A) 3d yz , 4d x 2 – y 2 (B) 2p z , dz 2 (C) 5p (D) 6d Orbital

(C) 4dzx, 3pz (D) All of these

Q.47 For 4py orbital : There are -

nodal plane = ........ and azimuthal quantum
number  =
(A) 1, 0 (B) 0, 1 Q.54
(C) 1, 1 (D) 2, 1
Q.48 The maximum probability of finding electron in The above configuration is not correct as it
the dxy orbital is - violates -
(A) Along the x axis
(A) Only Hund’s rule
(B) Along the y axis
(B) Only Pauli’s exclusion principle
(C) At an angle of 45º from the x and y axis
(D) At an angle of 90º from the x and y axis (C) (n + l) rule
(D) (Hund + Pauli) rule
Q.55 Which of the following elements is represented Q.60 A 200g cricket ball is thrown with a speed of
by the electronic configuration - 3.0 x 103 cm sec–1. What will be its de Broglie’s
wavelength - [h = 6.6 x 10–27g cm2 sec–1]
(A) 1.1 x 10–32 cm (B) 2.2 x 10–32 cm
(C) 0.55 x 10–32 cm (D) 11.0 x 10–32 cm

Q.61 Which is the de-Broglie equation -

(A) Nitrogen (B) Fluorine
(A) h = p (B) h = p–1
(C) Oxygen (D) Neon
(C) h = p–1 (D) h = p + 

Q.62 Which of the following has the largest de Broglie

Q.56 The electronic configurations of Cr24 and Cu 29
wavelength given that all have equal velocity -
are abnormal -
(A) CO2 molecule (B) NH3 molecule
(A) Due to extra stability of exactly half filled
(C) Electron (D) Proton
and exactly fully filled sub shells
(B) Because they belong to d-block Q.63 A ball has a mass of 0.1 kg its velocity is
(C) Both the above 40 m/s, find out de Broglie wave length -
(D) None of the above (A) 1.66 x 10–34m (B) 2 x 10–34 m
(C) 3 x 10–34 m (D) 4 × 10–34 m
Q.57 The electronic configuration of chromium (Z =
Q.64 If the uncertainty of position for an electron is
24) is -
zero, what is the uncertainty of the momentum-
(A) [Ne]3s23p63d44s2 (B) [Ne] 3s23p63d54s1
(A) Zero (B) 
(C) [Ne]3s23p63d14s2 (D) [Ne] 3s23p64s24p4
(C) h (D) Infinite

Q.58 The number of d-electrons in Fe2+ (At. no. 26) is Q.65 Which of the following is the most correct
not equal to that of the –- expression for Heisenberg's uncertainty principle
(A) p-Electrons in Ne (At. No. 10)
h h
(B) s-Electrons in Mg (At No. 12) (A) x. p  (B) x. p 
4 4
(C) d-Electrons in Fe atom
(D) p-Electrons in Cl¯ ion (At. No. 17) h h
(C) x. p  (D) x . v =
4 4

De-Broglie, Heisen berg’s Concept

Q.66 The Heisenberg uncertainty principle can be
Q.59 In an electron microscope, electron are applied to -
accelerated to great velocities. Calculate the (A) A cricket ball (B) A foot ball
wavelength of an electron travelling with a (C) A jet aeroplane (D) An electron
velocity of 7.0 megameters per second . The
Q.67 Velocity of helium atom at 300 K is 2.40 x 102
mass of an electron is 9.1×10-28 g -
meter per sec. What is its wave length -
(A) 1.0 × 10–13m (B) 1.0 × 10–7m
(mass number of helium is 4)
(C) 1.0 m (D) 1.0 × 10–10m
(A) 0.416 nm (B) 0.83 nm
(C) 803 Å (D) 8000Å
 LEVEL # 2
Q.1 The wav e character of electron was Q.8 It is known that atoms contain protons, neutrons
experimentally verified by - and electrons. If the mass of neutron is assumed
(A) de - Broglie (B) A. Einstein to be half of its original value whereas that of
(C) Germer (D) Schrodinger electron is assumed to be twice of this original
value. The atomic mass of 6C12 will be -
Q.2 Cathode rays are - (A) Twice (B) 75% less
(A) Electromagnetic waves (C) 25% less
(B) Radiations (D) One-half of its original value
(C) Stream of -particles
(D) Stream of electrons
Q.9 The energy difference between two electronic
states is 46 .12 kcal /mole. What will be the
Q.3 The e/m ratio for cathode rays -
frequency of the light emitted when an electron
(A) Is constant
drops from the higher to the lower energy state
(B) Varies as the atomic number of the element
(Planck' constant = 9.52 x 10-14 kcal sec mole -1)
forming cathode in the discharge tube
(A) 4.84 x 10 15 cycles sec -1
changes
(C) Varies as atomic number of the gas in the (B) 4.84 x 10 -5 cycles sec-1
discharge tube varies (C) 4.84x 10-12 cycles sec-1
(D) Has the smallest value when the discharge (D) 4.84 x 10 14 cycles sec-1
tube is filled with hydrogen
Q.10 Electromagnetic radiation with maximum wave
Q.4 Arrange the orbitals of H-atom in the increasing length is -
order of their energy - (A) Ultraviolet (B) Radio wave
3px, 2s, 4dxy , 3s, 4pz , 3py , 4s (C) X - rays (D) Infrared
(A) 2s < 3s = 3px = 3py < 4s = 4pz = 4dxy
(B) 2s < 3s < 3px = 3py < 4s = 4pz = 4dxy
Q.11 Multiple of fine structure of spectral lines is
(C) 2s < 3s < 3px = 3py < 4s = 4pz = 4dxy due to -
(D) 2s < 3s < 3px = 3py < 4s < 4pz < 4dxy
(A) Presence of main energy levels
(B) Presence of sub- levels
Q.5 Electron, Proton and Neutron were respectively
(C) Presence of electronic configuration
discovered by -
(D) Is not a characteristics of the atom.
(A) James Chadwick, John Dalton, J.J. Thomson
(B) J.J. Thomson, Goldsteine, John Dalton
(C) J.J. Thomson, William Crookes, Goldsteine Q.12 The quantum number not obtained from the
(D) J.J. thomson, Goldstein , James Chadwick Schrodinger’s wave equation is -
(A) n (B) l
Q.6 If the I.P. of Li+2 is 122.4 eV. Find out 6th I.P. of (C) m (D) s
carbon -
(A) 122.4 × 4eV (B) 122.4 × 2eV
Q.13 Wave mechanical model of the atom depends
(C) 122.4 × 3eV (D) 122.4 × 5eV upon -
(A) de-Broglie concept of dual nature of electron
Q.7 If W is the atomic mass and N is the atomic
(B) Heisenberg uncertainty principle
number of an element, the number of -
(A) Electrons = W – N (B) Neutrons = W – N (C) Schrodinger uncertainty principle
(C) Protons = W – N (D) Electrons = W (D) All
Q.14 The correct Schrodinger's wave equation for an Q.21 I.P. of hydrogen atom is equal to 13.6 eV. What
electron with total energy E and potential energy is the energy required for the process :
V is given by - He+ + energy — He+2 + e–
2   2   2  82 (A) 2 × 13.6 eV (B) 1 × 13.6 eV
(A)    (E  V )  0
 2 dy 2 z2 mh2 (C) 4 × 13.6 eV (D) None of these

 2   2   2  8 m
(B)    2 (E  V )  0 Q.22 If elements with principal quantum number
x2 dy 2 dz2 h
n > 4 is not allowed in nature, the number of
possible elements would be -
2 2 2 8  2m (A) 60 (B) 32
(C) + + + (E - V)  =0
x 2 y 2 z 2 h2 (C) 64 (D) 50
(D) None of the above.
Q.23 If the values of (n +  ) is not > 3, then the
maximum number of electron in all the orbital
Q.15 W hich one of the statement of quantum
would be -
numbers is false -
(A) 12 (B) 10
(A) Quantum number were proposed out of
necessity in Bohr model of the atom. (C) 2 (D) 6
(B) Knowing n and l it possible to designated
a subshell .
Q.24 It is not possible to explain the pauli's exclusion
(C) The principal quantum number alone can
principle with the help of this atom -
give the complete energy of an electron in
any atom. (A) B (B) Be
(D) Azimuthal quantum number refers to the (C) C (D) H
subshell to which an electron belongs and
describes the motion of the electron.
Q.25 Uncertainty in position and momentum are
equal. Uncertainty in velocity is -
Q.16 Which orbital is dumb-bell shaped -
(A) s-Orbital (B) p-Orbital h h
(A) (B)
(C) d-Orbital (D) f-Orbital  2
1 h
(C) Both (D)
Q.17 W hich of the f ollowing subshell can 2m 
accommodate as many as 10 electrons -
(A) 2d (B) 3d Q.26 The nucleus of an atom is located at x = y = z = 0.
(C) 3dxy (D) 3dz2 If the probability of finding an s-orbital electron
in a tiny volume around x = a, y = z = 0 is 1 x
Q.18 "No two electrons in an atom can have the same 10–5 , what is the probability of finding the
set of four quantum numbers. "This principle was electron in the same sized volume around
enunciated by - x = z = 0, y = a -
(A) Heisenberg (B) Pauli (A) 1 x 10–5 (B) 1 x 10–5 x a
(C) Maxwell (D) de Broglie. –5
(C) 1 x 10 x a 2
(D) 1 x 10–5 x a–1

Q.19 How many spherical nodes are present in a 4s

orbital in hydrogen atom - Q.27 How fast is an electron moving if it has a
(A) 0 (B) 1 wavelength equal to the distance it travels in
(C) 2 (D) 3 one second -
h m
Q.20 Minimum core charge is shown by the atom - (A) (B)
m h
(A) O (B) Na
(C) N (D) Mg h h
(C) (D)
p 2( KE)
Q.28 Electron corpuscular nature is not connected Q.34 One energy difference between the states n = 2
with - and n = 3 is E eV, in hydrogen atom. The
(A) Diffraction phenomenon ionisation potential of H atom is -
(B) Photo electric effect
(A) 3.2 E (B) 5. 6E
(C) Compton effect
(C) 7.2 E (D) 13.2 E
(D) Mechanical effect by cathode rays
Q.35 Magnetic moments of V(Z = 23), Cr(Z = 24),
Q.29 The correct statement(s) about Bohr’s orbits of Mn(Z = 25) are x, y, z. Hence -
hydrogen atom is/are - (A) x = y = z (B) x < y < z
 n 2h 2  (C) x < z < y (D) z < y < x
(A) r =  2 2 
 4 me  Q.36 The speed of a proton is one hundredth of the
(B) K.E. of the electron = –1/2 (P. E. of the speed of light in vacuum. What is its de-Broglie
electron) wavelength? Assume that one mole of protons
 h  has a mass equal to one gram
(C) Angular momentum (L) = n  
2 [h = 6.626 x 10–27 erg sec] -
(D) All the above (A) 13.31 x 10–3 Å (B) 1.33 x 10–3 Å
–2
(C) 13.13 x 10 Å (D) 1.31 x 10–2 Å
Q.30 In centre-symmetrical system, the orbital
angular momentum, a measure of the Q.37 The ratio of E2 – E1 to E4 – E3 for the hydrogen
momentum of a particle travelling around the atom is approximately equal to -
nucleus, is quantised. Its magnitude is - (A) 10 (B) 15
h h (C) 17 (D) 12
(A) ( 1) (B) ( 1)
2 2
h h Q.38 Consider the following ions -
(C) s(s  1) (D) s(s 1) (1) Ni2+ (2) Co2+ (3) Cr2+ (4) Fe3+
2 2
(Atomic numbers : Cr = 24, Fe = 26, Co = 27,
Ni = 28)
Q.31 Each orbital has a nodal plane. Which of the The correct sequence of the increasing order of
following statements about nodal planes are not
the number of unpaired electrons in these ions
true -
is -
(A) A plane on which there is zero probability
that the electron will be found (A) 1, 2, 3, 4 (B) 4, 2, 3, 1
(B) A plane on which there is maximum (C) 1, 3, 2, 4 (D) 3, 4, 2, 1
probability that the electron will be found
(C) Both Q.39 What are the values of the orbital angular
(D) None momentum of an electron in the orbitals 1s, 3s,
3d and 2p-
Q.32 An electron, a proton and an alpha particle have
kinetic energies of 16E, 4E and E respectively. (A) 0, 0, 6 , 2 (B) 1, 1, 4 , 2
What is the qualitative order of their de Broglie (C) 0, 1, 6 , 3 (D) 0, 0, 20 , 6
wavelengths -
(A) e > p =  (B) p = a > e
Q.40 In an atom two electron move around the nucleus
(C) p < e > a (D) a < e » p
in circular orbits of radii R and 4R. The ratio of
the time taken by them to complete one
Q.33 If Hund’s rule is followed, magnetic moment of revolution -
Fe2+, Mn+ and Cr all having 24 electrons will be (A) 1 : 4 (B) 4 : 1
in order -
(C) 1 : 8 (D) 8 : 7
(A) Fe2+ < Mn+ < Cr (B) Fe2+ < Cr = Mn+
2+ +
(C) Fe = Mn < Cr (D) Mn2+ = Cr < Fe2+
Q.41 A beam of electrons is accelerated by a potential Q.49 The following graph between 2 probability
difference of 10000 volts. The wavelength of the density and distance f rom the nucleus
wave associated with it will be - represents -
(A) 0.0123 Å (B) 1.23 Å
(C) 0.123 Å (D) None of these

Q.42 If the number of electrons in p-orbital are two, 2

then which one of the following is in accordance
with Hund’s rule -
r
(A) p 2x p 0y p 0z (B) p 0x p y2 p 0z
(A) 2s (B) 3s
(C) p 0x p 0y p 2z (D) p x1 p y1 p 0z
(C) 1s (D) 2p

Q.43 If there are six energy levels in H–atom then the

number of lines its emission spectrum in ultra Q.50 The wave length of the last line of Paschen series
voilet region will be - would be -
(A) 6 (B) 5 (A) 9540 Å (B) 8204 Å
(C) 4 (D) 3 (C) 3650 Å (D) 912 Å

Q.44 Magnetic moment of X3+ ion of 3d series is

Q.51 The wavelength of X-ray is 10-6 cm. Its frequency
35 BM. What is atomic number of X3+ ? in Giga Hertz (GHz) will be (Hint : 1 Giga = 109)
(A) 25 (B) 26 (A) 3 × 107 (B) 3 × 109
10
(C) 27 (D) 28 (C) 3 × 10 (D) 3 × 108

Q.45 An electron is moving with the velocity equal to Q.52 Which electronic level would allow the hydrogen
10% of the velocity of light. Its de-Broglie wave atom to absorb a photon but not to emit a photon
length will be - (A) 3s (B) 2p
(A) 2.4 × 10-12cm (B) 2.4 × 10-18cm (C) 2s (D) 1s
–9
(C) 2.4 × 10 Cm (D) None of these
Q.53 Pauli’s exclusion principle states that -
Q.46 Correct set of four quantum numbers for the (A) Nucleus of an atom contains no nagative
valence (outer most) electron of rubidium charge
(B) Electrons move in circular orbits around the
(Z = 37) is -
nucleus
1 1 (C) Electrons occupy orbitals of lowest energy
(A) 5,0,0, + (B) 5,1,0, + (D) All the four quantum numbers of two
2 2
electrons in an atom cannot be equal.
1 3
(C) 5,1,1, + (D) 5,0,0, –
2 2 Q.54 Which element is represented by the following
Q.47 Ratio of time period of electron in first and second electronic configuration -
orbit of H-atom would be -
(A) 1 : 18 (B) 1 : 8
(C) 1 : 2 (D) 2 : 1

Q.48 If x is the velocity of an electron in first Bohr’s

orbit. What would be the velocity of the electron
in third Bhor’s orbit - (A) Nitrogen (B) Oxygen
x x
(C) Fluorine (D) Neon
(A) (B)
9 3
(C) 3x (D) 9 x
Q.55 When an electron jumps from L to K shell - Q.61 When beryllium is bombarded with alpha
(A) Energy is absorbed particles (Chadwick’s experiment) extremely
(B) Energy is released penetrating radiations which can not be
deflected by electrical or magnetic field are given
(C) Energy is neither absorbed nor released out. These are -
(D) Energy is sometimes absorbed and some (A) A beam of protons
times released (B) Alpha rays
(C) A beam of neutrons
(D) A beam of neutrons and protons
Q.56 The orbital diagram in which ‘Aufbau principle’
is violated is - Q.62 The potential energies of first, second and third
Bohr’s orbits of He + cation are E1, E2 and E3.
2s 2p
The correct sequence of these energies is -
(A) (A) E1 > E2 > E3 (B) E1 = E2 > E3
(C) E1 = E2 = E3 (D) E3 > E2 > E1
(B)
Q.63 Which of the following is correct radial probabil-
ity distribution curve for various orbitals ?
(C)

(D) 3s

24r2
(A)
Q.57 d6 configuration will result in total spin of -
(A) 3/2 (B) 1/2
(C) 2 (D) 1 r

Q.58 Bohr’s model can explain - 4p

(A) The spectrum of only hydrogen atom
(B) The spectrum of the atoms of all the
elements 24r2
(B)
(C) The spectrum of only sodium atom
(D) The spectrum of atomic or ionic species
having one electron. r

Q.59 The mass number of dispositive Zn ion is 70.

The total number of neutrons is - 1s
(A) 34 (B) 40
(C) 36 (D) 38 24r2
(C)

Q.60 The energy required to separate an electron from

the level n = 3 of an atom is 9.69 × 10-19 Joules. r
What will be its energy in first excited state -
(A) – 9 × 9.69 × 10–19 J
3p
9  9.69  10 19
(B) – J
4
4 24r2
(C) × 9.69 × 10–19 J (D)
9
(D) None of these
r
Q.64 In which of the following orbital diagrams are Q.69 How many lines in the spectrum will be observed
both Pauli's exclusion principle and Hund's rule when electrons return from 7th shell to 2nd shell ?
violated ? (A) 13 (B) 14
(A) (C) 15 (D) 16

(B) Q.70 In Ca atom how many e– contains m = 0

(A) 12 (B) 8
(C)
(C) 10 (D) 18

(D)
Q.71 In Ne how many e– contains m = –1
(A) 4 (B) 2
Q.65 What are the values of the orbital angular
(C) 0 (D) 1
momentum of an electron in the orbitals 1s, 3s,
3d, and 2p ?
Q.72 When the wavelength of incident light on
(A) 0, 0, 6, 2 (B) 1, 1, 4, 2 metallic plate is halved, the K.E. of emitted
photoelectron will be -
(C) 0, 1 6, 3 (D) 0, 0, 20  , 6 
(A) halved
(B) doubled
Q.66 Which of the following graphs correspond to one (C) unchanged
node ? (D) increased more than double

Q.73 The number of electrons in Na, having n+ = 3

(A) 4 (B) 6
 
(C) 7 (D) 8
(A) (B)

Q.74 Which orbital has 1 nodal plane -

a0 (A) s (B) p
a0
(C) d (D) f

Q.75 How many s electron are there in Cu+ -

(A) 2 (B) 4
  (C) 6 (D) 10
(C) (D)
Q.76 If the total energy of an electron in a hydrogen
a0 atom in excited state is –3.4 eV, then the de
a0 Broglie wavelength of the electron is -
Q.67 The number of elliptical orbits excluding (A) 3.3 × 10–10 cm (B) 6.6 × 10–10 cm
circular orbits in the N-shell of an atom is - (C) 3.3 × 1010 cm (D) 9.3 × 10–12 cm
(A) 3 (B) 4
(C) 2 (D) 1 Q.77 The correct set of quantum numbers to the
unpaired electron of fluorine atom -
Q.68 A compound of vanadium has a magnetic (A) n = 3,  = 0, m = 0
moment 1.73 B. M. The electronic configuration (B) n = 3,  = 1, m = 1
of vanadium ion in the compound is - (C) n = 2,  = 0, m = 0
(A) [Ar] 3d2 (B) [Ar] 3d1 (D) n = 2,  = 1, m = 1
(C) [Ar] 3d3 (D) [Ar] 3d04s1
Q.78 Which of the following statement is correct - Q.87 If ionisation energy of hydrogen atom is 13.6 eV.
(A) Number of angular nodes = n – – 1 I.E. of Li+2 will be -
(B) Number of radial nodes =  (A) 13.6 eV (B) 10.4 eV
(C) Total number of nodes = n – 1 (C) 40.8 eV (D) 122.4 eV
(D) All
Q.88 The wavelength of third lyman series of
hydrogen atom is approximately -
Q.79 The total energy associated per quanta with
(A) 1 × 10–7 m (B) 1 × 10–8 m
light of wavelength 600 nm -
–6
(C) 1 × 10 m (D) 1 × 10–5 m
(A) 3.3 × 10–12 erg (B) 3.3 × 10–6 erg
(C) 6.6 × 10–12 erg (D) 6.6 × 10–6 erg
Q.89 The number of waves made by a Bohr electron
in one complete revolution in its 3rd orbit -
Q.80 Iodine molecule dissociates into atom after (A) 1 (B) 2
absorbing light of 4500 Å. The K.E. of iodine (C) 3 (D) 4
atoms if B.E. of I2 is 240 kJ mol–1 -
(A) 0.43 × 10–19 J (B) 0.216 × 10–19 J
Q.90 If potential energy of an electron in hydrogen
(C) 4.3 × 10–16 J (D) 2.16 × 10–16 J atom is –x eV, then its kinetic energy will be -
(A) x eV (B) –x eV
Q.81 The number of revolution/sec. made by (C) 2x eV (D) x/2 eV
electron in 3rd orbit of hydrogen atom -
(A) 4.88 × 1014 (B) 2.44 × 1014 Q.91 The number of orbitals in n = 3 are -
(C) 9.9 × 1014 (D) 2.44 × 1012 (A) 1 (B) 3
(C) 5 (D) 9
Q.82 Angular and spherical nodes in 3s -
(A) 1, 1 (B) 1, 0
(C) 2, 0 (D) 0, 2

Q.83 The magnetic moment of V4+ ion -

(A) 1.73 (B) 1.41
(C) 3.46 (D) 2

Q.84 Which orbital represents the following set of

quantum numbers n = 3,  = 0, m = 0, s = +1/2 -
(A) 3p (B) 2s
(C) 3s (D) 2p

Q.85 The number of unpaired electrons in Zn+2 -

(A) 0 (B) 1
(C) 2 (D) 3

Q.86 The uncertainly in velocity of electron having

uncertainty in its position of 1Å -
(A) 5.8 × 105 m/s (B) 5.8 × 106 m/s
(C) 5.8 × 107 m/s (D) 5.8 × 108 m/s
 LEVEL # 3
Passage : True or False:
Orbital is the region in an atom where the
probability of finding the electron is maximum. Q.5 The species Na+, Mg2+, Al3+, O2– and F– are
It represents three-dimensonal motion of an iso-electronic.
electron around the nucleus. Orbitals do not
specify a definite path according to the Q.6 The nuclear reaction 94 Be  42 He126 C  01n was
uncertainty principle. An orbital is described with
the help of wave function  . Whenever an used by curie to discover neutron.
electron is described by a wave function, we Q.7 Lyman series of hydrogen spectrum lies in the
say that an electron occupies that orbital. Since visible region.
many wave functions are possible for an
Q.8 All the four quantum number have been derived
electron, there are many atomic orbitals in an
from Schrodinger wave equation.
atom. Orbitals have different shapes; except
s-orbitals, all other orbitals have directional Q.9 The outer electronic configuration of chromium
character. Number of spherical nodes in an atom is 3d44s2.
orbital is equal to (n––1). Orbital angular Q.10 The electron density in xy plane of
momentum of an electron is (  1)  . 3d x 2 – y 2 orbital is zero.

Q.1 The nodes present in 5p orbital are - Q.11 All the atomic orbitals are directional in nature.
(A) one planar, five spherical Q.12 The designation of an orbital, n = 4 and  = 0 is
(B) one planar, four spherical 4s.
(C) one planar, three spherical
Q.13 Chromium atom has six unpaired electrons.
(D) four spherical
Q.14 The energies of various subshells in the same
Q.2 When an atom is placed in a magnetic field, shell are in the order of s > p > d > f.
the possible number of orientations for an orbital
Each of the questions given below consist
of azimuthal quantum number 3 is -
of Statement – I and Statement – II. Use the
(A) three (B) one
following Key to choose the appropriate
(C) five (D) seven
answer.
(A) If both Statement- I and Statement- II are
Q.3 Orbital angular momentum of f-electrons is-
true, and Statement - II is the correct
(A) 2 (B) 3 explanation of Statement– I.
(B) If both Statement - I and Statement - II
(C) 12  (D) 2 are true but Statement - II is not the
correct explanation of Statement – I.
(C) If Statement - I is true but Statement - II
Q.4 Which of the following orbitals has/have two is false.
nodal planes ? (D) If Statement - I is false but Statement - II
(A) dxy (B) dyz is true.
(C) dxz (D) All of these
Q.15 Statement I : 2p orbitals do not have any
spherical node.
Statement II : The number of nodes in p-orbitals
is given by (n – 2) where n is the principal
quantum number.
Q.16 Statement I : All p-orbitals have only one planar Column Matching:
node.
Q.25 Column-I Column-II
Statement II : The number of radial nodes
(A) 2s (P) Angular node = 1
depends on the principal quantum number only.
(B) 1s (Q) Radial node = 0
Q.17 Statement I : A spectral line will be seen for a (C) 2p (R) Radial node = 1
2px – 2py transition. (D) 3p (S) Angular node = 0
Statement II : Energy is released in the form
Q.26 Column-I Column-II
of waves of light when the electron drops from
(A) n = 6  n = 3 (P) 10 lines in the spectrum
2px to 2py orbital.
(B) n = 7  n = 3 (Q) Spectral lines in visible
Q.18 Statement I : Hydrogen has one electron in its region
orbit but it produces several spectral lines. (C) n = 5  n = 2 (R) 6 lines in the spectrum
Statement II : There are many excited energy (D)n = 6  n = 2 (S) Spectral lines in infrared
levels available. region
Q.19 Statement I : The 19th electron in potassium
atom enters into 4 s-orbital and not the
3d-orbital.
Statement II : (n + ) rule is followed for
determining the orbital of the lowest energy
state.
Q.20 Statement I : The free gaseous Cr atom has
six unpaired electrons.
Statement II : Half-filled s-orbital has greater
stability.
Q.21 Statement I : The electronic configuration of
the nitrogen atom is represented as

Statement II : The electronic configuration of

the ground state of an atom is the one which
has the greatest multiplicity.
Q.22 Statement I : For n = 3,  = 0, 1 and 2 and m
may be 0; 0, ± 1 and 0, ± 1 and ± 2.
Statement II : For each value of n, there are 0
to (n – 1) possible values of  and for each value
of , there are 0 to ±  values of m.
Q.23 Statement I : The radial probability distribution
curves of 2s, 3p, 4d and 5f orbitals are identical
in shape.
Statement II : The number of planar nodes
present in these orbitals is different.
Q.24 Statement I : 2px, 2py and 2pz each have one
nodal plane.
Statement II : These orbital are degenrate
orbitals.
 LEVEL # 4
(Question asked in previous AIEEE & IIT JEE)

SECTION : A Q.7 Which of the following sets of quantum numbers

Q.1 An atom has a mass of 0.02 kg & uncertainity is correct for an electron in 4f orbital ?
in its velocity is 9.218 × 10 –6 m/s then
uncertainity in position is 1
(A) n = 4, l = 3 , m = + 4, s = +
(h = 6.626 × 10–34 J - s) 2
(A) 2.86 × 10–28 m (B) 2.86 × 10–32 cm 1
(B) n = 4, l = 4 , m = – 4, s = –
–27
(C) 1.5 × 10 m (D) 3.9 ×10–10 m 2
1
Q.2 Energy of H–atom in the ground state is (C) n = 4, l = 3 , m = + 1, s = +
2
–13.6 eV , Hence energy in the second excited 1
(D) n = 4, l = 3 , m = – 2, s = +
state is – 2
(A) –6.8 eV (B) –3.4 eV Q.8 Consider the ground state of Cr atom (Z = 24).
(C) –1.51 eV (D) –4.3 eV The numbers of electrons with the azimuthal
quantum numbers, l =1 and 2 are, respectively
Q.3 Unertainty in position of a particle of 25 g in
space is 10–5 m. Hence uncertainty in velocity (A) 12 and 4 (B) 12 and 5
(ms–1) is (Planck’s constant h = 6.6 × 10–34 Js)
(C) 16 and 4 (D) 16 and 5

(A) 2.1 × 10–28 (B) 2.1 × 10–34 Q.9 The wavelength of the radiation emitted, when
(C) 0.5 × 10–34 (D) 5.0 × 20–24 in a hydrogen atom electron falls from infinity to
stationary state 1, would be
Q.4 The orbital angular momentum for an electron (Rydberg constant = 1.097×107 m–1)

h
revolving in an orbit is given by l l  1. . This (A) 91 nm (B) 192 nm
2 (C) 406 nm (D) 9.1×10–8 nm
momentus for an s-electron will be given by -
Q.10 Which one of the following sets of ions
represents the collection of isoelectronic
h h species ?
(A) (B) 2.
2 2 (A) K+, Ca2+, Sc3+, Cl–
(B) Na+, Ca2+, Sc3+, F–
1 h (C) K+, Cl–, Mg2+, Sc3+
(C) + . (D) zero
2 2 (D) Na+, Mg2+, Al3+, Cl–
(Atomic nos.: F = 9, Cl = 17, Na = 11, Mg = 12,
Q.5 In Bohr series of lines of hydrogen spectrum, Al = 13, K = 19, Ca = 20 , Sc = 21)
third line from the red end corresponds to where
one of the following inter-orbit jumps of electron Q.11 In a multi-electron atom, which of the following
for Bohr orbits in an atom of hydrogen. orbitals described by the three quantum
members will have the same energy in the
(A) 4  1 (B) 2  5 absence of magnetic and electric fields ?
(C) 3  2 (D) 5  2
(a) n = 1, l = 0, m = 0 (b) n = 2, l = 0, m = 0
Q.6 The de Broglie wavelength of a tennis ball mass (c) n = 2, l = 1, m = 1 (d) n = 3, l = 2, m = 1
60 g moving with a velocity of 10 mt. per second (e) n = 3, l = 2, m = 0
is approximately - (A) (b) and (c) (B) (a) and (b)
(A) 10–16 metres (B) 10–25 metres (C) (d) and (e) (D) (c) and (d)
–33
(C) 10 metres (D) 10–31metres
Q.12 Of the following sets which one does NOT Q.2 Which of the following is violation of Pauli’s
contain isoelectronic species ?[ exclusion principle ?
(A) CN–, N2, C22–
(A)
(B) PO43–, SO42–, ClO4–
(C) BO33–, CO32–, NO3– (B)
(D) SO32–, CO32–, NO3–
(C)
Q.13 According to Bohr's theory, the angular
momentum of an electron in 5th orbit is - (D)

(A) 1.0 h/ (B) 10 h/

(C) 2.5 h/ (D) 25 h/ Q.3 From the given sets of quantum numbers the
one that is inconsistent with the theory is
Q.14 Uncertainty in the position of an electron
(mass = 9.1 × 10–31 kg) moving with a velocity (A) n = 3 ;  = 2 ; m = –3 ; s = +1/2
300 m/s, accurate upto 0.001 %, will be (B) n = 4 ;  = 3 ; m = 3 ; s = +1/2
(h = 6.63 × 10–34 Js) (C) n = 2 ;  = 1 ; m = 0 ; s = –1/2
(A) 5.76 × 10–2 m (B) 1.92 × 10–2 m (D) n = 4 ;  = 3 ; m = 2 ; s = +1/2
(C) 3.84 × 10–2 m (D) 19.2 × 10–2 m

Q.4 The orbital angular momentum of an electron in

Q.15 Which of the following sets of quantum
2s orbital is
numbers represents the highest energy of
an atom ? (A) n = 3,  = 1 h
(A) + . (B) zero
1, m = 1, s = +½ (B) n = 3,  = 2, m 2 2
= 1, s = +½
h h
(C) n = 4,  = 0, m = 0, s = +½ (C) (D) 2 . 2
2
(D) n = 3,  = 0, m = 0, s = +½

Q.16 The ionization enthalpy of hydrogen atom is Q.5 Which of the following has maximum number
of unpaired electron ?
1.312 × 106 J mol–1. The energy required to
(A) Mg2+ (B) Ti3+
excite the electron in the atom from n = 1 to (C) V3+ (D) Fe2+
n = 2 is
Q.6 The electrons, indentified by quantum number
(A) 6.56 × 105 J mol–1
n and , (i) n = 4,  = 1 (ii) n = 4,  = 0
(B) 7.56 × 105 J mol–1 (iii) n = 3,  = 2 (iv) n = 3,  = 1 can be placed in
(C) 9.84 × 105 J mol–1 order of increasing energy, from the lowest to
(D) 8.51 × 105 J mol–1 highest, as
(A) (iv) < (ii) < (iii) < (i)
(B) (ii) < (iv) < (i) < (iii)
SECTION : B (C) (i) < (iii) < (ii) < (iv)
Q.1 What transition in the hydrogen spectrum would (D) (iii) < (i) < (iv) < (ii)
have the same wavelength as the Balmer tran-
sition n = 4 to n = 2 in the He+ spectrum ? Q.7 The first use of quantum theory to explain the
structure of atom was made by
(A) n= 4 to n = 1 (B) n = 3 to n = 2 (A) Heisenberg (B) Bohr
(C) n = 3 to n = 1 (D) n = 2 to n= 1 (C) Planck (D) Einstein
Q.8 For a d-electron, the orbital angular momentum Q.15 The quantum numbers +1/2 and –1/2 for the
is electron spin represent
(A) rotation of the electron in clockwise and
(A) 6h/2 (B) 2 h/2
anticlockwise direction respectively
(C) h/2 (D) 2h/2 (B) rotation of the electron in anticlockwise and
clockwise direction respectively
Q.9 The energy of an electron in the first Bohr orbit (C) magnetic moment of the electron pointing
of H atom is –13.6 eV. The possible energy up and down respectively
value (s) of the excited state(s) for electrons in (D) two quantum mechanical spin states which
Bohr orbits of hydrogen is (are) have no classical analogue
(A) –3.4 eV (B) –4.2 eV
(C) –6.8 eV (D) +6.8 eV
Q.16 Rutherford’s experiment, which estabilished the
Q.10 The energy of the electron in the first orbit of nuclear model of the atom, used a beam of -
He+ is – 871.6 x 10–20 J. The energy of the
(A) –particles, which impinged on a metal foil
electron in the first orbit of hydrogen would be
and got absorbed
(B) –rays, which impinged on a metal foil and
(A) –871.6 x 10–20 J (B) –435.8 x 10–20 J
ejected electrons
(C) –217.9 x 10–20 J (D) –108.9 x 10–20 J
(C) helium atoms, which impinged on a metal
foil and got scattered
Q.11 Ground state electronic configuration of
(D) helium nuclei, which impinged on a metal
nitrogen atom can be represented by foil and got scattered

(A) Q.17 If the nitrogen atom had electronic

configuration 1s, it would have energy lower than
(B) that of the normal ground state configuration
1s2 2s2 2p3, because the electrons would be
(C) closer to the nucleus. Yet, 1s7 is not observed
because it violates.
(D) (A) Heisenberg uncertainty principle
(B) Hund’s rule
(C) Pauli’s exclusion principle
Q.12 The electronic configuration of an element is (D) Bohr postulates of stationary orbits.
1s2 2s2 2p6 3s2 3p6 3d5 4s1. This represents
its Q.18 Identify the least stable among the following :
(A) excited state (B) ground state
(C) cationic form (D) anionic form (A) Li– (B) Be–
(C) B– (D) C–
Q.13 The number of nodal planes in a px orbital is
Q.19 For which of the following the radius will be same
(A) one (B) two as for hydrogen atom n = 1
(C) three (D) zero (A) He+, n = 2 (B) Li2+, n =2
Q.14 The wavelength associated with a golf ball (C) Be3+, n = 2 (D) Li2+ , n = 3
weighing 200g and moving at a speed of 5 m/h
is of the order Q.20 The number of radial nodal surface in 3s and 2p
(A) 10–10m (B) 10–20m
(C) 10–30 m (D) 10–40m (A) 2, 0 (B) 2, 1
(C) 1 , 0 (D) 0, 2
Q.21 According to Bohr's theory , Q.22 Match the entries in Column-I with the
En = Total energy ; Kn = Kinetic energy correctly related quantum number(s) in
Vn = Potential energyrn = Radius of nth orbit Column-II.
Match the following : Column-I Column-II
Column I Column II (A) Orbital angular momentum (P) Principal quantum
(A) Vn/Kn = ? (P) 0 of the electron in a number
(B) If radius of nth orbital (Q) –1 hydrogen-like atomic orbital (Q) Azimuthal quantum
x
 En , x = ? (B) A hydrogen-like one number
(C) Angular momentum in (R) –2 electron wave function
lowest orbital obeying Pauli principle
(C) Shape, size and (R) Magnetic quantum
1 y
(D)  Z ,y  ? (S) 1 orientation of hydrogen number
rn like atomic orbitals
(D) Probability density of (S) Electron spin
electron of the nucleus quantum number
in hydrogen-like atom
 ANSWER KEY
LEVEL # 1
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. D C A C C B D C B B C B C B D
Q.No. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. D A A D A A D B C D B D A A C
Q.No. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. A B B C C C A B D C A B B B A
Q.No. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. C C C C A D A C D D A B D B A
Q.No. 61 62 63 64 65 66 67
Ans. C B A C D B A

LEVEL # 2
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. C D A A D A B C D B B D D C C
Q.No. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. B B B D B C A A D D A A A D A
Q.No. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. B A B C C B B A A C C D B B C
Q.No. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. A B B A B A D D C B B C D B B
Q.No. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. C D A D A B A B C A C D C B C
Q.No. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. B D C A B B D A C A A D A C D
Q.No. 91
Ans. D

LEVEL # 3
1. C 2. D 3. C 4. D 5. True 6. False 7. False 8. False

9. False 10. False 11. False 12. True 13. True 14. False 15. A 16. C

17. D 18. A 19. A 20. C 21. A 22. A 23. B 24. B

25. A  P,R; B  Q,S; C  Q,P; D  P,R 26. A  R,S; B  P,S; C  R,Q; D  P,Q
 LEVEL # 4
SECTION : A
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. A C A D B C C,D B A A C D C B B
Q.No. 16
Ans. C

SECTION : B
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. D B A B D A B A A C A,D B A C D
Q.No. 16 17 18 19 20
Ans. D C B C A

21. A  R; B  Q; C  P; D  S

22. A  Q; B  P,Q,R,S; C  P,Q,R; D  P,Q