Classifi & Nome Exercise Module-3-2
Classifi & Nome Exercise Module-3-2
Level # 1 .................................................................................... 85
Level # 2 ........................................ ......................................... 60
Level # 3 ........................................ ......................................... 30
Level # 4 ........................................ ......................................... 11
CH3 CH3
Homologous series
Q.24 CH3–CH–C–O–C–CH3
Q.19 In homologous series : CH3
O
(A) Molecular formula is same
(B) Structural formula is same
(C) Physical properties are same The common name of given ester is -
(D) General formula is same
(A) neo butyl iso butyrate
Q.20 Which of the following is the first member of
ester homologous series ? (B) t-butyl n- butyrate
(A) Ethyl ethanoate (B) Methyl ethanoate
(C) Methyl methanoate (D) Ethyl methanoate (C) t- butyl iso butyrate
(D) iso butyl iso butyrate
Q.21 W hich of the following is the triad of a
homologous series -
(A) CH3NH2, (CH3)2NH, (CH3)3 N Q.25 The structure of allyl vinyl thioether is -
(B) C2H5OH, (CH3)2CHOH, (CH3)3COH
(A) CH2 = CH – CH2 – S – CH2 – CH = CH2
(C) Both the above
(D) CH2 = CH2, CH3 – CH = CH2, (B) CH2 = CH – S – CH2 – CH = CH2
C2H5 – CH = CH2 (C) CH2 = CH – S – CH = CH2
(D) None
Q.26 Ethyl methyl vinyl amine has the structure - Q.30 Which of the following is crotonic acid :
(A) CH2 = CH-COOH
(A) CH3 CH2 N CH2 CH CH2
| (B) C6H5-CH=CH-COOH
CH3 (C) CH3-CH=CH-COOH
CH COOH
(B) CH3 CH2 N CH CH2 (D) ||
| CH COOH
CH3
Nomenclature based on derived
(C) CH2 CH N CH CH2
| system
CH3
(D) CH N CH CH Q.31 The derived name of (CH3)4C is –
3 2
| (A) Tetramethylmethane
CH3 (B) 2,2-Dimethylpropane
(C) Neopentane
Q.27 Which of the following are correctly matched– (D) None of these
(a) Trimethyl amine (CH3)3 CNH2
(b) Isobutyronitrile (CH3)2 CHCH2CN Q.32 The structural formula of isopropyl carbinol
is–
(c) Secondary butyl alcohol C 2H5 CHOH
(A) (CH3)2 CHOH
|
CH3 (B) CH3–CHOH–CH2–CH3
(C) (CH3)2 CH.CH2OH
(d) Acetoisonitrile CH3 N C (D) (CH3)3COH
(A) a and b (B) b and c
(C) c and d (D) a and d Q.33 The derived name of butenyne is –
(A) Vinylacetylene (B) Ethenylacetylene
(C) Ethenyl ethyne (D) Ethynyl ethene
Q.28 The structure of –butylene bromide is
(A) CH3–CH(Br) CH(Br)CH3 Q.34 The derived name of iso-valeric acid is.
(B) CH2(Br)CH(Br)CH2CH3 (A) Ethyl methyl acetic acid
(C) (CH3)2C(Br)CH2Br (B) iso-propyl acetic acid
(D) None (C) trimethyl acetic acid
(D) all are
Q.29 The structure of Isobutyro-isonitrile is : – Q.35 Derived name of CH2=CH–CH2CO–CH3 is –
(A) 1-Pentene-1-one
(A) CH3 CH CH3 CN
| (B) Allyl methyl ketone
CH3 (C) 4-Pentene-2-one
(D) Vinyl acetone
(B) CH3 CH CH2 C N
|
CH3
Nomenclature of IUPAC system
(C) CH3 CH CN (Using only preffix)
|
CH3
(D) CH3 CH N C Q.36 I.U.P.A.C. name of (CH3)2CH–CH2–CH2Br is
|
CH3 (A) 1-bromo pentane
(B) 2-methyl-4-bromo pentane
(C) 1-bromo-3-methyl butane
(D) 2-methyl-3-bromo propane
Q.37 Which one of the following I.U.P.A.C. name is
correct ?
Q.42 The IUPAC name of is -
(A) 2-Methyl-3-ethyl pentane
(B) 2-Ethyl-3-methyl pentane
(A) 2-bromo-4-isopropylpentane
(C) 3-Ethyl-2-methyl pentane
(B) 2, 3-dimethyl-5-bromohexane
(D) 3-Methyl-2-ethyl pentane
(C) 2-bromo-4, 5-dimethylhexane
F Cl (D) 5-bromo-2, 3-dimethylhexane
| |
CH3 C CH2 C CH3
Q.38 Q.43 Give the IUPAC name of
| |
CH2CH3 CH2CH3
CH3
The IUPAC name of this compound is : |
(A) 2-fluoro-4-chloro-2,4-diethyl pentane H3 C C CH3
(B) 3-fluoro-5-chloro-3-methyl-5-ethyl hexane |
CH3 CH2 CH2 CH CH CH2 CH2 CH3
(C) 3-chloro-5-fluoro-3,5-dimethyl heptane
|
(D) 3,5-dimethyl-5-fluoro-3-chloro heptane H3 C CH
|
Q.39 The IUPAC name of the compound CH3
(A) 4-isopropyl-5-ter. butyl octane
CH3 CHCH2CH3 is:
| (B) 4-ter. butyl-5-isopropyl octane
C6H5 (C) 2-methyl-3-propyl-4-ter. butyl heptane
(A) 2-cyclohexyl butane (D) 2, 2-dimethyl-3-propyl-4-isopropyl heptane
(B) 2-phenyl butane
(C) 3-cyclohexyl butane Q.44 The IUPAC name of the compound Br (Cl)
(D) 3-phenyl butane CH.CF3 is :
(A) haloethane
Q.40 What is the correct IUPAC name for the
(B) 1, 1, 1- trifluoro-2-bromo-2- chloroethane
following compound ?
(C) 2-bromo-2-chloro-1, 1, 1- trifluoroethane
CH3 (D) 1-bromo-1-chloro-2, 2, 2- trifloro ethane
|
CH3 (CH2 )4 CH C CH2 CH2 CH3
| | Q.45 The IUPAC name of is -
CH3 CH2 CH3
(A) 4-ethyl -3- methyl hexane
(B) 3-ethyl -4- methyl hexane
(A) 3,4 - Dimethyl -3-n - propyl nonane (C) 3-methyl -4- ethyl hexane
(B) 6, 7 - Dimethyl -2- n- propyl nonane
(D) None of these
(C) 6,7- Dimethyl -7- ethyl decane
(D) 4- Ethyl- 4, 5 - dimethyl decane
Nomenclature of IUPAC system
Q.41 The IUPAC name of C 6H5 CH CH2 CCl3 (Using functional group)
|
C 6H5
is ; Q.46 The I.U.P.A.C. name of (C2H5)2 CH.CH2 OH is
(A) 1,1,1-trichloro-3,3-diphenyl propane (A) 2-ethyl butanol-1
(B) 1,1-diphenyl-3,3,3-trichloro propane (B) 2-methyl pentanol-1
(C) both (A) and (B)
(C) 2-ethyl pentanol-1
(D) none of these
(D) 3-ethyl butanol-1
Q.47 I.U.P.A.C. name of compound is Q.51 The correct name of 3,3-dimethyl propanamide is
(A) 2-methyl butanamide
CH3 CH CH2 CHOH CH3 (B) 3-methyl butanamide
|
CH2 CH3 (C) iso-propyl ethanamide
(D) iso propyl acetamide
(A) 4-methyl-3-hexanol
(B) heptanol
(C) 4-methyl-2-hexanol
Q.52 IUPAC name of is :
(D) none of these
(A) But-2-ene-2,3-diol
Q.48 The correct IUPAC name of (B) Pent-2-ene-2,3-diol
(C) 2-methylbut-2-ene-2,3-diol
CH3 CH2 C COOH is : (D) Pent-3-ene-3,4-diol
||
CH2
Q.53 The IUPAC name of
(A) 2-methyl butanoic acid BrCH2 CH CO CH2 CH2 CH3 is :
(B) 2-ethyl- 2-propenoic acid |
CONH2
(C) 2- carboxy-1- butene
(D) None of the above (A) 2-bromo methyl-3-oxo hexanamide
(B) 1-bromo-2-amido-3-oxo hexane
(C) 1-bromo-2-amido-n-propyl ketone
Q.49 The correct IUPAC name of :
(D) 3-bromo-2-proponyl propanamide
CH3 CH2 CH CH2COCl
| Q.54 The IUPAC name of
CH3
CH3 CH2 CH COOC2H5 is
(A) 3-methyl pentanoyl chloride |
(B) 3-methyl butanoyl chloride CH3
(C) 1-chloro-3-ethyl butanone (A) 2-ethyl-ethyl acetate
(D) 1-chloro-3-methyl pentanone (B) ethyl 3-methyl butanoate
(C) ethyl 2-methyl butanoate
Q.50 IUPAC name of the following compound is – (D) 2-methyl butanoic acid ethylester
CHO
|
Q.56 CH 3 CH 2 CH CH CH 3
(A)1-Brom o-3, 5-epox y-4, 4-di methyl -2- |
hexanone CH 3
(B) 1-Bromo-3,3-dimethyl-2-oxo-2-hexanone
The IUPAC name of this compound is
(C) 1-Bromo-3,3-dimethyl acetone (A) 2-isopropyl butanal
(D) 1-Bromo-4,4-dimethyl-5-oxo-hexanone (B) 2-ethyl-3-methyl butanal
(C) 3-ethyl-2-methyl butanal
(D) 2-methyl pentane-3-aldehyde
Q.57 The IUPAC name of Q.62 The IUPAC name of CH2 = CH – CCH is –
CH2 CHO (A) 1–Butenyne–3 (B) 1–Butynene–3
|
OHC CH2 CH2 CH CH2 CHO is : (C) Vinyl acetylene (D) all of them
(A) 4, 4-di(formylmethyl) butanal
(B) 2-(formylmethyl) butane-1, 4-dicarbaldehyde
(C) hexane-3-acetal-1, 6-dial Q.63 I.U.P.A.C. name of, is
(D) 3-(formylmethyl) hexane-1, 6-dial
(A) 4, 5-dimethyl oct-4-ene
Q.58 The suffix of the principal group, the prefixes (B) 3, 4-dimethyl oct-5-ene
for the other groups and the name of the parent
in the structure (C) 4, 5-dimethyl oct-5-ene
(D) None
HO CH2 CH CH C CH2 C C OH
| | || ||
CH3 Cl O O
Q.64 The correct IUPAC name of 2-ethyl-3-pentyne
are given by the set : is :
(A) -oic acid, chloro, hydroxy, oxo, methyl,
4-heptene (A) 3-methyl hexyne-4
(B) -oic acid, chloro, hydroxy, methyl, oxo, (B) 4-ethyl pentyne-2
4-heptene (C) 4-methyl hexyne-2
(C) -one, carboxy, chloro, methyl, hydroxy,
(D) None of these
4-heptene
(D) -one, carboxy, chloro, methyl, hydroxy,
4-heptene Q.65 The I.U.P.A.C. name of following structure
Q.59 The IUPAC name of compound (CH3) C.C.C. (CH3) CH (CH3) is -
COOH CH COOH (A) 3-methyl-4-hexynene-2
| (B) 3-methyl-2-hexenyne-4
COOH
(C) 4-methyl-4-hexenyne-4
(A) Tricarboxy methane (D) all are correct
(B) Propane trioic acid
(C) Tributanoic acid
(D) 2- carboxy propanedioic acid Q.66 The IUPAC name of is -
(A) 2-ethyl-3-methyl-1-penten-4-yne
Q.60 The IUPAC name of is - (B) 2-ethyl-3-methyl-4-pentyn-1-ene
(A) 4-oxo-2-pentanol (C) 4-ethyl-3-methyl-1-pentyn-4-ene
(B) 4-hydroxy-2-pentanone
(D) 4-ethyl-3-ethyl-4-penten-1-yne
(C) pentane-4-ol-2-one
(D) pentane-2-one-4-ol
Q.61 The I.U.P.A.C name of the compound having Q.67 The IUPAC name of the given compound is :
(A) Octylcyclopentane
(A) 1-amino-2-carboxybenzene
(B) 3-cyclopentyloctane
(B) 2-amino-1-carboxybenzene
(C) cyclopentaneoctane
(C) 1-amino-2-benzenecaroxylic acid
(D) 6-cyclopentyloctane
(D) 2-aminobenzenecarboxylic acid
Q.83 The IUPAC name of camphor is -
Q.78 The systematic name for
is :
(A) ortho hydroxy methyl phenol
(B) 2-hydroxy benzyl alcohol
(C) salicyl alcohol
(D) 2-hydroxy methyl phenol (A) 6-oxo-1,2,2- trimethyl bicyclo [2,2,1] heptane
(B) 1,7,7-trimethyl bicyclo [2,2,1] heptan-2-one
Q.79 The IUPAC name of (C) 1,5,5-trimethyl bicyclo [2,1,1] hexan-2-one
(D) 1,7,7-trimethyl bicyclo [2,1,2] heptan-2-one
is -
Q.84 The IUPAC name of compound is -
(A) 1-phenyl-1-acetyloxyethane
(B) 1-acetoxyethylbenzene
(C) 1-phenylethyl ethanoate
(D) 1-methylbenzyl acetate
Naming of Spiro/Bicyclo
compounds
(A) Bicyclo [2.2.1] hept-2-ene
(B) Bicyclo [2.2.1] hept-5-ene
(C) Bicyclo [2.1.2] hept-2-ene
Q.80 The name of the compound is - (D) Bicyclo [1.2.2] hept-2-ene
Q.81 Which of the following structures represents (A) Spiro [5.3] nonane
bicyclo [3.2.0] heptane -
(B) Spiro [3.5] nonane
(C) Spiro [5.4] nonane
(A) (B)
(D) Spiro [4.5] nonane
(C) (D)
Q.3 The general molecular formula of nitroalkanes (1) 2-Octanone (A) CH3(CH2)5COCH3
is : (2) Trimethyl amine (B) (CH3)3C–NH2
(A) CnH2nNO2 (3) Acrolein (C) CH2 = CH – CN
(B) Cn + 1 H2n + 3 NO2
(4) Vinyl acetylene (D) CH2 = CH – C CH
(C) Cn + 1 H2n NO2
(D) Cn + 1 H2n + 2 NO2 Code is :
(A) 1 and 4 (B) 2 and 3
Q.4 Write the correct IUPAC name of the following (C) 2 and 4 (D) 1 and 3
bond line formula :
Q.10 Number of heteroatoms present in the following
N heterocyclic compound :
(A) 3-cyclopropyl-3-ethyl-2-propene
(A) 2- (N-methyl amino) -4-methyl pentane (B) 1-cyclopropyl-1-ethylpropene
(B) N, 4-dimethyl pentan-2-amine (C) 3-cyclopropyl-2-pentene
(C) 2-(N-methyl amino)-3-isopropyl propane (D) (1-ethyl-1-propenyl) cyclopropane
(D) 2-(N-methyl amino)-1, 4, 4-trimethyl butane
(A) 3-(1-butynyl)-3-vinyl-2-pentadienal
(B) 5-ethynyl-3-vinyl-2-pentenal Q.41 The IUPAC name of is -
(C) 3-vinyl-2-heptene-6-ynal (A) 3-cyclobutylcyclopropane
(D) 5-acetylenyl-3-ethenyl-2-pentenal (B) 1-cyclopropyl-3-methylcyclobutane
(C) 1, 3-cyclopropylmethylcyclobutane
Q.36 The IUPAC name of (D) 2-methylbicyclo [4.3.0] heptane
is -
(A) 1, 1-dimethyl-1, 3-butanediol (A)(2-chloro-1-methyl)ethyl-2-methylpropanoate
(B) 4-methyl-2, 4-pentanediol (B) 2-chloropropyl 2-methylpropanoate
(C) 1, 3, 3-trimethyl-1, 3-propanediol (C) chloroisopropyl isobutyrate
(D) 2-methyl-2, 4-pentanediol (D) 1, 2-dimethyl-2-chloroethylpropanoate
Q.43 The IUPAC name of Q.49 The IUPAC name of is -
is - (A) 2-acetyl-2-buten-1-ol
(A) benzyl benzoate (B) 3-hydroxymethyl-3-penten-2-one
(B) 2-phenylethyl phenylacetate (C) 3-ethylidene-4-hydroxy-2-butanone
(C) 2, 2-diphenyl ethylethanoate (D) 3-acetyl-2-buten-4-ol
(D) 2-phenylethyl phenylethanoate
Q.50 The IUPAC name of the given structure is -
Q.55
is -
The IUPAC name of the above structure is :
(A) 2, 4, 5 - Triethyl-3-nonene (A) 2-Bromo-4-carbamoyl-5-chloroformyl-3-
(B) 5, 6 - Diethyl -3- methyl -4-decene formylhexanoic acid
(C) 2, 4, 5 - Triethyl -3- octene (B) 5-Bromo-3-carbamoyl-2-chloroformyl-4-
formylhexanoic acid
(D) 3 - Heptyl - 5- methyl-3- heptene
(C) 4-Formyl-2-chloroformyl-5-carbamoyl-5-
bromohexanoic acid
Q.56 x-Ethyl-y, z- dimethyl-p-heptanol is the IUPAC (D) 2-Chloroformyl-3-carbamoyl-4-formyl-5-
name of the compound - bromohexanoic acid
x, y, z, p are -
(A) 4, 5, 5, 3 (B) 1,2, 2, 4 (A) 6-Chloro-4-ethyl-5-methyl-5-hepten-1-yne
(B) 5-methyl-4-ethyl-6-chloro-5-hepten-1-yne
(C) 4, 3, 3, 5 (D) None
(C) 6-Chloro-4-ethyl-5-methyl-1-hepten-5-yne
(D) 2-Chloro-4-ethyl-methyl-6-hepten-2-ene]
Q.57 The IUPAC name of following polyfunctional
compound is -
is -
Cl
(A) 3-chloro-2-(1-propenyl)-2,4-hexa-di-enoic
Q.5 The IUPAC name of is - acid
(B) 4-chloro-5-(1-propenyl) 2,4- hexa-di-enoic
(A) 2-carboxyethylcyclohexanone
(B) 3-(2-oxocyclohexyl) propanoic acid acid
(C) cyclohexanone-2-propanoic acid (C) 3-chloro 2,3-di(1-propenyl) propanoic acid
(D) 2-propanoic cyclohexanone (D) 4-carboxy 5-chloro octa-2, 4,6-tri-ene
group/s ..............
(A) 7,7-Dimethyl bicyclo [3.1.1] hept-3-ene-2-
one
(B) 6,6-Di-methyl bicyclo [3.1.1] hept-3-ene-2- Q.17 The name of substituent present in the compound
one
(C) 2,2-Dimethyl bicyclo [3.1.1] hept-5-ene-4- CH3
one
(D) 5,5-Dimethyl bicyclo [3.1.1] hept-2-ene-1- CH–CH2COOH
one
is ...........
Cl
Q.13 Write the correct IUPAC name of the following
spiro compound :
Q.18 The correct structural formula of 3-hexenyne-1
......
O
Q.21 Propanal, CH3CH2–C is an unsaturated
H
Br compound.
(A) Ethyl-1-bromo 4-benzoate
O O
(B) Ethyl-4-bromobenzoate
(C) Bromo benzoate
(D) Bromo benzene ester Q.22 The IUPAC name of CH 3–C–C–Cl is 1-chloro-
1, 2-propadione.
Q.15 Give IUPAC name of the following :
CH2CHO O
Br
Q.23 Esters are the compound having a –C– and
H
Q.27 Statement I : is called
CN
cyclohexancarbonitrile.
Statement II : It is an aromatic compound.
Q.3 The IUPAC name of the compound Q.1 The correct IUPAC name of the compound is-
[
CH3
|
is - CH3 CH2C CH CHCH2 CH3
|
(A) 3,3 -dimethyl-1-hydroxy cyclohexane CH3CH2 CH CH2CH2CH2CH3
(B) 1, 1 – dimethyl–3– hydroxy cyclohexane (A) 5,6-diethyl-8-methyl dec-6-ene
(C) 3,3-dimethyl-1-cyclohexanol (B) 5,6-diethyl -3-methyl dec -4-ene
(C) 6-butyl-5-ethyl-3-methyl-oct-4-ene
(D) 1,1 - dimethyl - 3- cyclohexanol (D) 2,4,5-triethyl-3-ene
Q.2 IUPAC name of the compound is Q.4 Choose the correct IUPAC name for
CH3 CH CHO
|
CH3 CH2 CH3 is-
CH3 N C CH2CH3
CH3 CH2CH3 (A) Butan-2-aldehyde
(B) 2-Methylbutanal
(A) 3-dimethyl amino-3-methyl pentane (C) 3-Methylisobutyraldehyde
(B) 3(N,N-trimethyl) 3 - amino pentane (D) 2-Ethylpropanal
(C) 3, N, N -trimethyl pentane
(D) 3, N, N-(dimethyl amino)-3-methyl pentane
O
||
Q.3 The IUPAC name of Q.5 IUPAC name of C 6H5 C Cl
OHCCH = CH–CH–CH =CH2 is
| (A) Benzoylchloride
CH2CH2CH2CH3 (B) Benzenecarbonylchloride
(C ) Chlorophenyl ketone
(D) phenylchloroketone
(A) 5-Vinyloct-3-en-1- al
(B) 4-Butylhexa-2, 5-dien-1-al
(C) 5-Vinyloct-5-en-8-al
(D) 3-Butylhexa-1, 4-dien-8-al.
ANSWER KEY
LEVEL # 1
Qus. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Ans. D C C D C A B D B D C B B A C C C D D C D B B C B
Qus. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
Ans. B C A D C A C A B D C C C B D A B B C B A C B A A
Qus. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. B B A C B B D B D B B A A C B A C D B C C B B A A
Qus. 76 77 78 79 80 81 82 83 84 85
Ans. C D B C D C D B A B
LEVEL # 2
Qus. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Ans. D C B B A B A A A C A B A B C A A A C C D D C C A
Qus. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
Ans. D C A B C C C B B C D A C C C B A B C C A C C B A
Qus. 51 52 53 54 55 56 57 58 59 60
Ans. A B B A B A C C B A
LEVEL # 3
LEVEL # 4
SECTION -A
Qus. 1 2 3 4 5 6
Ans. C B C B D D
SECTION -B
Qus. 1 2 3 4 5
Ans. B D B B B