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Halogens

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Anita Giri
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64 views13 pages

Halogens

This is the best documents to teaching the student.

Uploaded by

Anita Giri
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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eval Chaxatteristics Compared on and dedcripbon ro vepulved) i prope Lik water, altel oxidizing cl bleating athon 4 and 7, ae aration ined) thavatteriche! axe very _Gchive non = metal have 7° valence e%¢ jpovaleuty\ 1 and Jabymic woleuile ave poisonous and have purgeat frvitati Hi Mipt ond 8. pt jncveases moving down in on State and colduy * Flouvine 2 gas, pale: yellow és Chlorine: gas, greenish yell hyomine i Liguid, reddish bran todine > sokidy shiwins ey wl Theg are good ontdiciuy apeuts 4. Th thou 4) th +542 )) rentrol metiod of spreparahion’s Fram metal habide Cmetals nla o, blen wutel habde, cond. 4,$0u an onidant ie. Mn0, is heated halo AMX + StySy + MnOg SIMMS tA 2Nacl + shy SO, + Mud, > 2NaliSo, + hy DKByt 3H, 60, HMnd, — 2 kHsoy + MS AKI + SH, $0, # ond, 12 kKHSO + Ayn neh 4 Cla, brxond Lave separated and coller ward displacement Galvin Fas Jarre cing’ water condenser infusring Chambe: sulglinnation respectivele duce bo defy nature of physital fase. it 2. From halogen aud. ores fohen cont. halogen acid if heated wit A hal: ts Gheyated Mabs + 4HX — Au. 20 t Dat se yi dt emical properties §s.o\- s A Action with waters iss us Zn absence of Sunlight halogens ¢Us in water at ordinary feuperatire enlipht Hhaety ntecounpote a 2th, + 2tjo b> y Br, 4 o oa 2 Rea and Iy hat effethvey mild aud np bleach wouter Ct Kyo HY + Hoel Hoce —> Wel + rot Coloured substance + FO} —9 lourlett Site action Chlorine bleothst’ by oxidabion, its bleathiug lovine bie yr ie permoneut because aly preset over le of bleathed matter ‘tontittt only oxidant (Oy) serfowe of bleathe but a «) tn cold aud 0 vedu trout: ite alkali colection halide Pence Zainal fj Matec Fests sade Solin bijarenide fy alot heh i olodout aud, Nacl bine aeoHt F Hpl Noo + Ho oi, + 2 Na0y —) nla tliat Naw Fo Sodium Sonam it veate timitar to Chy. Sut te It veatts fy forta bodiunr ine i unstable and herd 2NaoH + 7, Mr rears Ja+ Nao Na Was hot tad cont. alkane Hatopent rence with hat K yer habde and halate tolt, Lip TE farm sodiwn chloride and io. At Hd + Ho wil +t Noo —> Nau ti od + Noon —> Algae + Us anigocl — anlad + Na Rel, #6NaoW 9 GNOU tla Sodium Cedi seal Br & Syicvea tts \ fini 0) wit doy slaked lime and ti Help each) with dry \Slaked Lime iat Uy) Ferimidieclar ayetodees aig Calor, 9 Ch > Cadcle Lary slated timey 9) Unleaching Radout has “Cla wreath with cold lime water f ealdium chloride and calcium hupoch BLOWS NHS COSCO acy eK WISN ivks tient at eciosiRR ORD +S [_ aero c9 with hot time water tp Cold hlovide and Calico eho BAH CACO pied AOE mee i (Giates sand ANOS chy nibogen. us EMI, #5th ——96 Wy ey, (united) 3 < My + 3c ——> wth, + 5nd excess) 5) wll brow Te formes Aram antes $30, aud oltrogen BAM, + BB 6 Ay Bx Wi, = awit. sodiue Ss Gua OD | te form dark cloiived pieuipitabe of ult _frtiodide on Babblig wit solid lod/ne gargs +318 RAY dz, FY 5. Ox a) wits fervouc tabt In audi wedrui Uedovine ovidizer fervout tatt fr ferric sal ts dn acidic wandbicun Ch + fo ——i2nu + QE eS6, tty Soy 4+ (SF 3 Fey (5%), + 450 LFeSOy + 1,8, tO, > Fez 050,) # 2HeL A Gr, yeas Ginsilerly bub less viporously . Ia ig weak oxidizing agent (better veduuug oped) Hverfove get oxidized to ty 6) ltt. Sedlum fuiasulphase Coypo) &, K Bry onidizes +Hsoputphale to sedi oy ¢ tho —> ahd & Nay Sa0, + [of 9 Naso, +S Ae, Sy 0, + Cy ty 9 # Reachtoy with i dle: dau tla! totes thou ate ote QNa, bao F129 Nay Sy 4 Fodine is declourized by Fodivm + Hayefore uted in todine Hidratdn 1.9 ae 8) Goh 40, In pasour’ slabon 1 ebopens ourctizes $0, jut Lp ha vi and itself reduced fo halide. in fh + Myo Sana + f6y 0, + (ISON Log +t yO Hy 604 d ay + 20,0760, =e . 2a ge 6 of Haloperis: Say Chleiae 2 1F is used sas il = fer bleadbjug wood cotton, fab A 4S sds sinfectaut perutilde’ Poy stevie Arles watery oy ae preperation oisouves facet nauctord pas) “pluosgeuaytedryos toda = tos mansfa tive DDT powder, chlord oekfo ttt Sxih idm oye = 40 dissolve rubber il = in nsetatlurey of gold an 27 Cee A. oslint JAY it suned the as anhicephe (Ta halomol ab twcture to prepare ‘edaform (uted ag aubsep hid) y Zomex led 8 gubiseptre aud analge si), a5 Hebovetory reaptut in volumetic oualyels ee) to male auduine iii 1 Fam hy ere = eats white halides. on abi Ha Cl, Aad a Hy + Bx, = AH By Hath 1 2. Fiom Colkali) meted habide , When Colkatidwetel Chintde ix heated with Cont. tgl0y phydropen chloride , Natl + 4350, —— > naga, font Maly Gus as oniditing apeut Herel He Poy ic wed t pmduce HBr and NaBy + 4% pc, > Nan, Nat t Hzpo, 4 From red Phot plonss , halogen a hed P and halogen (Xs) yeaths hatide CPX, and PX form) with tater tp hid open selphide ga luv dioxide | tion wit ras 4) + displaua wlphides and sal ‘ Seulphites —a2 Na Na, St oHa ras by ct HOI Sep Wes ein Acton with Aundrea Gr pives dente white fas of | halide — Nui Het = NIC Loshife forest) “ammonium doy Seduvag “nature ledudug thr jit hens at - ude (Atnb,), Lead dioni Duper > fe) Action inp ag augorece praicium permanganate (KMndy) yf dichromate C kp Cr, 05 4 Concentrated oud oxidised Slight heating ov wit 0, + HH #9 Mutl, tan —S 5 Phe t Aknnd, + 1H ——> 2kel $2) Leno, ELuKU ——>2ket “Hby and HE ave halogen & Ice Mi 7) = “even_tnaeti nium CPE) BHCL HAM; = av aod HE ts dxidiged Gr, and Dy, by HNO, ond ftelp is reduced to NO DUNO; $ GHB —9 44,0 baN0 #527, cone eas RIG ae nee 2HNOs HbHZ ——> 40 FIND FED, once ) Action with Mind, th pretente 4 cmt. 1,50, halep Uberated thew cont. kalo oud & heated cst tnd, powder and conc -H,60 nd, => Ao + 96) MnO + Hp $0q —> Nnb0y + Ho 2Hel + 4) —> Had tay Mn 0, + HaSo, +t 24 A> Mnso, Hy anal Svea eaier a re a phils e ioe 9 98 2) 4 ton vote No reathion occurs 4) Attion with chlorine water Hat bar no action with el wil HBr, Br, is released whi Colour in CS, layer or oval be in fhavth solution. Ch + 2HBy —9dHd + By, veleated which or dak blue wih HE, 7a is tofour in Cf; layer Starete to lution, ey F2HI > 2nu the # This ven ic taken as eliztnetive decd Hel, HOY and HT )_Photacheuveal oxidation tA aly La presente of tut Hu iis oridized buat HAY and HE art tkte By, aud Ty oim air, Bj HAV tly WE=bUIE ee Snr + 0, 8 anaes & a Acton wit CuSO, cobition Only HE veade wit. tuboy tole ive mous iecide onl zy 2 WibOy 4p — 5 Blas) When nt vane : est Te ig iiah— to, HATS = 6 borat - as reducer a = th madio'ne as sl ie a

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