REED OW GE aio ' _ BASIC CONCEPT. % Intensive properties '- Independent of mass | afProp. memains same on its fraction] {xz Temp, press, density. sp. vol", sp heat Lép.cy) Sp. enthalphy + Extensive properties? depends on mass Exe volM, enexgy, heat cap, enthalphy PY= maT (x [Pv= ORT Pabs. 9ress.(ka) n> no.of mole = = NO YoIMat canines) perc we masimass of gases Saree oe Recher gas conch (KiTkg-6) > 8.214 Ks} KmalA T= abs. Temp (k) Re mol ut xR (Press = const 1 Cid vo = contt BV=MRT Y= maT e= Cyr Y=(@gyt ; {ty) ! 4 Mid. of Temp measurement *2-sefesence point system; Wee point [i)stesen poi std en [T=a4bP] b> const Po>thermomels ic prop from eg? ($i) (WIce point: T =e sozatbe -O Xs pte at ice point (id steam point !- T= too > Woo = 4 bR —Uii), Single ref. point systern:- ef Point is the Trigele point of water Tip = WK Gremp. at tripple paint (TeaP pier 5 rere zohip ga BEE , Pkp [ \T = 24316 | Pip Fa steam point: we ane mak we mak frteaig got: | s te times of -tvipple point of Hater. * Anis defined as Boi. (erie 4 hibs phase sule oof phase(s,hig,gas) No of component (af ofan) C22 W Fee Wates/ steam 3 44442 3 =2 Sasa dfah (i tee +Wates 5 24 (id Tee + Hateststeam 3 Fz0 WORK INTERACTION _ Sign _cony.:— WWD by the system > We eat (i) WD on the systems ve + closed ¢ open syctem WD in various process !- frocess closed sist: Gedy open sysb (ue (ews, _cinsed sick: § ‘ remiss y ip a Pit. unde = } the curve: a t era BS eenst vol Wo RenTGE:S) Gieonst press. W = PLV-W) Wee | Gi) > Teme. Neen Coe) Wop = Welosed jf =P Piva maT =meh, GupAdiabatic We Pi -Pava. es oe ae Wop =Wielesed W>Palytropie Wy Woon process, ST=C STI, precess Kan pv =e Poly tropic » kos evccsadicbation 20S v= vol" const, Slope fins oles esnst press > * Giyemstvoims 4P | Slope SAqna=0 tha Gid 50th Palytropic, naiabatic grecess’~ slope $8 uF) + Tsothevmal (= 4) > slope = =P * Polytropic (k=n) 3 slope = neg) + Adiabatic (k=¥d > Slope = w EE)! Scanned with CamScannerHEAT INTRACTION . (g- meat] csp, pace) AT Temp dif. ede heat me->Hert oxpacity( $y % vei of sp.heat :— ky subst st temp acid & HR _ eeett heat & requi. dA By kg, aT= ou Weak aad 3486 » Re 3 Cerey > because Op include = #6 includes only Tat. energy. [ ds =| Prele=co-c] Adis alfa gy 3] index Sensible} Phase game Latent 3 Temp same Hest temp. aie eat — phase ait A LAW OF TD Valid for = closed system, cyclic, BV. fh ivev: process. NoTE:= Heat § Work Transfer is @ path fn inexact differential £ Boundary phenomena SO= dbs Gu h Ea of 18+ law of To for afprocess} E=0 3 for cychi 1c ef dE= d(ke+pesu) : pea yc eo [SG= du + SW [PNAid for > closed sys. process Aswerl as aide gev give. process Neglect Keg pe GG= dU + Pav| > for closed, Rev. process [Enthatphy tay = ut oy e(se-enthalphy(h)= ures] Flow work, j # for ideal gas;- [a cu }3 valid fox AU types of process meat mepdt —4£ Ex of Heat transter for closed system :— (i) const vol™ Process (ji) const: press. §e=d0+6n" so= du+pay §e=d(used f= at= red ofngpocrd (iw) Adiabatic process (uv) palytropic process Pi int. enexgy aswell as e+ ove Serres ag? > ©) (y= we = Se tiultie xi Any DOTA = Ba Sma wt 2c AD aggua os foeogs ca POT OFM eg SW Scots fg ‘Open system mass f energy Balance. i mm = const ae locity GAG = hae a = ‘ Steady flow > Teratet Hie) + Geexilnat ch 5 Bay ie ¥als Shs kils kis SEO divide by mm coe v o| (r+ sk Mr) = brs B+ B32), ey 1080 unit = KS/eg @ Steady flow enesg eqn(on Ist lau of To foropnag| formula orm] 48) Qw=hon Sa Gneggle SS, Cha PECange — GD Treatated ( 2. ORG Gi) Tuveine 2G @: 2 Wi) cysea Gii) compresses >. G) seal) 920 ene 2 WD asa ty ae "| Mg () Theetting. © ceativacae {he hal WW Wev=0, g20. [Esse] (ou= EP Gwe] Scanned with CamScanner2" LAW OF TD concept of COPS done (Tn RAC Gasic concept) 13.2nd 19 of tp #E clausiue Thequatity for a cycle. lausius Thequatity := cl § aa. + § 98 5 5 cmposible device $e Entropy : = Measure. of disordemess(exyrandorness aE Entsopy principle :- BORA. device § 48 comer. device (S)yqi =o 5 Rev. device «Bienes fo" | CSuniro ste, — Lerarge Te) (As)unico Stmpossible » # Entropy change of a system for Secsss tn (=, (When heqt is added +o the system} entropy (s)} f= seh Dithen heat is tes fom the stems sy EE ve sue = const (as= ## Entsopy Change of syst fox Int. process ‘— > [as = (58 ln. [As = (EY, + S300 nota prep its dust (Heat addition 5 st quantity Gi) Heat veq9 3 entropy vill inct, deet (ox) const aoe Soges"® depend on Value of S900, TNwe 48 Ti i Th , 5 [trea = Fras} 5, (eRe) oes uate stig 4coanct a\dles- = 1-25 Tsent. comp 2-3-3 const temp: heat adit J,. 3-4 sen}. exon ’¢ 4A) Tsothermal heat sefn, Ar combine 1S g and Jaus of TDi- Serine HT Band Jaws of TD :~ Sa=dusedv4i) gg =tds Ci) From (i) shi) ores appa fox Be (re proces elt-ds = du-vdPb fox Rev ¢ Drv. intews of enthaiphy HFSlope of Various process on dig Osothrermal process @ Rev. Adiabatic process (Gc) cS — dope =o! pe @ wnst voll process: Ww =O) ® Const press (P=ey Tas =dyt pdy cp.ar eae ley @ Slope of const vain > Slope of const press. Ht Entsopy of Tdeal gas in texms of - OTemp £0 [es cre) net & fesHfaungy sania] Pad © Temp { press:- Bes=coin(y-elo[ dy a © Vols. press: [ese cin &) sean s 7 Ar Erhvopy change of finite 4 cond af phase chan of ieagrent Teak u Acrp.body ( have Yap (TE-Ta) | Bbq = hed glTa-Ta)}OSa= Step), eta hotcedua Ue: 9), PSO¥CQ, In e qin @) > SO-Chhig. An (@) “SUMIT KR” Scanned with CamScanner