SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH)

 

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Sanosil S003
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1. Product identifier
Trade name/designation:
Sanosil S003
1.2. Relevant identified uses of the substance or mixture and uses advised
against
Use of the substance/mixture:
Disinfectant
1.3. Details of the supplier of the safety data sheet
Supplier (manufacturer/importer/only representative/downstream user/distributor):
Sanosil
Eichtalstrasse 49
8634 Hombrechtikon
Switzerland
Telephone: +41 55 254 00 54
Telefax: +41 55 254 00 59
E-mail: [email protected]
Website: www.sanosil.ch
1.4. Emergency telephone number
United States of America: Poison control center - national hotline number 1-800-222-1222 Great
Britain: National phone number 111 Republic of Ireland: National phone number 01 809 2166 Czech
Republic: Toxikologické informační středisko +420 224 919 293, +420 224 915 402 Denmark: Giftlinjen
+45 82 12 12 12 France: numéro ORFILA (INRS) : +33 (0)1 45 42 59 59 Italy: 06-3054343 (24h/24h),
Centro antiveleni Policlinico Umberto I, Roma Spain: National Emergency Telephone Number: +34 91
562 04 20. The information will be provided in Spanish (24h/365 days). Sweden: +46 112 in case of
emergency poisoning and ask for Poison Information both day and night. +46 08-331231 if you have
other questions concerning acute poisonings mon-fri 9.00-17.00.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP]:
Hazard classes and hazard Hazard statements Classification pro
categories cedure
Hazardous to the aquatic environment H412: Harmful to aquatic life with long lasting Calculation method.
(Aquatic Chronic 3) effects.

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard statements for environmental hazards
H412 Harmful to aquatic life with long lasting effects.

Supplemental hazard information: -

Precautionary statements Prevention
P273 Avoid release to the environment.

Precautionary statements Disposal

P501 Dispose of contents/container to an installation for the treatment of hazardous waste.

2.3. Other hazards

No data available

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according to Regulation (EC) No. 1907/2006 (REACH)
 

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Sanosil S003
SECTION 3: Composition / information on ingredients
3.2. Mixtures
Hazardous ingredients / Hazardous impurities / Stabilisers:
product identifiers Substance name Concen-
Classification according to Regulation (EC) No 1272/2008 tration
[CLP]
CAS No.: 7722-84-1 hydrogen peroxide 0 – ≤ 1.5
EC No.: 231-765-0 Acute Tox. 4, Ox. Liq. 1, Skin Corr. 1A weight-%
REACH No.: Danger H271-H302-H314-H332
01-2119485845-22-XXXX
CAS No.: 7664-38-2 orthophosphoric acid 0 – ≤ 0.1
EC No.: 231-633-2 Skin Corr. 1B weight-%
REACH No.: Danger H314
01-2119485924-24-0001
CAS No.: 7440-22-4 silver 0 – ≤ 0.03
EC No.: 231-131-3 Aquatic Acute 1, Aquatic Chronic 1 weight-%
REACH No.: Warning H400-H410 M-factor (acute): 1000 M-factor (chronic):
01-2119555669-21-0036 100
Full text of H- and EUH-phrases: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures
General information:
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety
data sheet if possible). Remove victim out of the danger area. Remove contaminated, saturated
clothing. If unconscious but breathing normally, place in recovery position and seek medical advice. Do
not leave affected person unattended.
Following inhalation:
Provide fresh air.
In case of skin contact:
After contact with skin, wash immediately with plenty of water and soap. Take off immediately all
contaminated clothing.
After eye contact:
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding
eyelids apart and consult an ophthalmologist. Remove contact lenses, if present and easy to do.
Continue rinsing.
Following ingestion:
Rinse mouth. Let water be drunken in little sips (dilution effect). Do NOT induce vomiting. Never give
anything by mouth to an unconscious person or a person with cramps. Get medical advice/attention if
you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media:
The product itself does not burn. Water, Dry extinguishing powder, Carbon dioxide, alcohol resistant
foam.
Unsuitable extinguishing media:
Full water jet

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according to Regulation (EC) No. 1907/2006 (REACH)
 

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Sanosil S003
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products:
In case of fire: Carbon monoxide. Carbon dioxide (CO2).
5.3. Advice for firefighters
Special protective equipment for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
5.4. Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Keep closed containers cool by spraying water.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Personal precautions:
Avoid contact with skin, eyes and clothes.
Provide adequate ventilation.
Remove persons to safety.
Use personal protection equipment.
Protective equipment:
Wear protective gloves/protective clothing/eye protection/face protection. See section 8.
6.1.2. For emergency responders
Personal protection equipment:
Personal protection equipment: see section 8
6.2. Environmental precautions
Do not allow to enter into surface water or drains. Prevent spread over a wide area (e.g. by containment
or oil barriers).
* 6.3. Methods and material for containment and cleaning up
For containment:
Provide for retaining containers, e.g. floor pan without outflow. Absorb with liquid-binding material
(sand, diatomaceous earth, acid- or universal binding agents). Dispose of the residus of the product as
hazardous waste (see section 13).
6.4. Reference to other sections
Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13
6.5. Additional information
Losses during use of the product must be collected and disposed of in special containers as special
waste.

SECTION 7: Handling and storage

* 7.1. Precautions for safe handling
Protective measures
Advices on safe handling:
The simultaneous handling of incompatible substances and mixtures must be prevented. Wear personal
protection equipment (refer to section 8).
Use: Surface desinfection with wipes.
Do not use for injecting or spraying.
Advices on general occupational hygiene
When using do not eat, drink or smoke. Avoid contact with eyes and skin.
* 7.2. Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions:
Keep container tightly closed in a cool, well-ventilated place. Keep/Store only in original container.

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Sanosil S003
Requirements for storage rooms and vessels:
Make sure spills can be contained, e.g. in sump pallets or kerbed areas.
Hints on storage assembly:
Do not store together with strong acids.
Storage class: 12 – non-combustible liquids that cannot be assigned to any of the above storage classes
7.3. Specific end use(s)
Recommendation:
The product must whether be sprayed nor misted for disinfection.
Food must not be brought into direct contact with disinfectants or their application solutions. Residues
on treated work surfaces, equipment and apparatus should be kept as low as possible by rinsing with
drinking water.
The use of chemical disinfectants on surfaces and equipment as well as in vessels must be restricted to
non-absorbent materials (metals, glass, ceramics, possibly to non-softened plastics).
After the prescribed exposure time, the disinfected surfaces and equipment as well as the vessels must
be rinsed several times with fresh water of drinking water quality.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
8.1.1. Occupational exposure limit values
Limit value Substance name ① Long-term occupational exposure limit value
type (country
of origin)
② short-term occupational exposure limit value
③ Instantaneous value
④ Monitoring and observation processes
⑤ Remark
ES hydrogen peroxide ① 1 ppm (1.4 mg/m³)
CAS No.: 7722-84-1
EC No.: 231-765-0
VLA (FR) hydrogen peroxide ① 1 ppm (1.5 mg/m³)
CAS No.: 7722-84-1
EC No.: 231-765-0
WEL (GB) hydrogen peroxide ① 1 ppm (1.4 mg/m³)
CAS No.: 7722-84-1
EC No.: 231-765-0
② 2 ppm (2.8 mg/m³)
OSHA (US) hydrogen peroxide ① 1 ppm (1.4 mg/m³)
CAS No.: 7722-84-1
EC No.: 231-765-0
NIOSH (US) hydrogen peroxide ① 1 ppm (1.4 mg/m³)
CAS No.: 7722-84-1
EC No.: 231-765-0
ACGIH (US) hydrogen peroxide ① 1 ppm (1.4 mg/m³)
CAS No.: 7722-84-1
EC No.: 231-765-0
ES orthophosphoric acid ① 1 mg/m³
CAS No.: 7664-38-2
EC No.: 231-633-2
② 2 mg/m³
⑤ VLI, s
IOELV (EU) orthophosphoric acid ① 1 mg/m³
CAS No.: 7664-38-2
EC No.: 231-633-2
② 2 mg/m³
VRI (FR) orthophosphoric acid ① 0.2 ppm (1 mg/m³)
CAS No.: 7664-38-2
EC No.: 231-633-2
② 0.5 ppm (2 mg/m³)
⑤ réglementaire indicative
WEL (GB) orthophosphoric acid ① 1 mg/m³
CAS No.: 7664-38-2
EC No.: 231-633-2
② 2 mg/m³

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according to Regulation (EC) No. 1907/2006 (REACH)
 

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Sanosil S003
Limit value Substance name ① Long-term occupational exposure limit value
type (country
of origin)
② short-term occupational exposure limit value
③ Instantaneous value
④ Monitoring and observation processes
⑤ Remark
OSHA (US) orthophosphoric acid ① 1 mg/m³
CAS No.: 7664-38-2
EC No.: 231-633-2
NIOSH (US) orthophosphoric acid ① 1 mg/m³
CAS No.: 7664-38-2
EC No.: 231-633-2
② 3 mg/m³
ACGIH (US) orthophosphoric acid ① 1 mg/m³
CAS No.: 7664-38-2
EC No.: 231-633-2
② 3 mg/m³
IOELV (EU) silver ① 0.01 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ (silver compounds, soluble, calculated as Ag )
VRI (FR) silver ① 0.01 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ (réglementaire indicative) Argent composés, soluble, calcu
lé comme Ag
WEL (GB) silver ① 0.01 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ (compounds, soluble; calculated as Ag)
NIOSH (US) silver ① 0.01 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ compounds, soluble; calculated as Ag
IOELV (EU) silver ① 0.1 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ (metal)
WEL (GB) silver ① 0.1 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ (metal)
VRI (FR) silver ① 0.1 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ (réglementaire indicative; métal)
ACGIH (US) silver ① 0.01 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ compounds, soluble
OSHA (US) silver ① 0.01 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
ES silver ① 0.1 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
ES silver ① 0.1 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
⑤ (metal, fracción inhalable)
NIOSH (US) silver ① 0.01 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3
ACGIH (US) silver ① 0.1 mg/m³
CAS No.: 7440-22-4
EC No.: 231-131-3

8.1.2. Biological limit values

No data available
8.1.3. DNEL-/PNEC-values
No data available

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Sanosil S003
* 8.2. Exposure controls
8.2.1. Appropriate engineering controls
Provide adequate ventilation as well as local exhaustion at critical locations.
8.2.2. Personal protection equipment

Eye/face protection:
Eye glasses with side protection DIN EN 166
Skin protection:
Use protective gloves in accordance to EN 374. The following material is suitable: NBR Tested protective
gloves must be worn EN ISO 374
Respiratory protection:
In case of inadequate ventilation wear respiratory protection.
In case of an application by wiping >30 min, a respirator with gas filter (against CAS 7722-84-1) must be
used. Filter type: ABEK-P3
8.2.3. Environmental exposure controls
No data available

SECTION 9: Physical and chemical properties

* 9.1. Information on basic physical and chemical properties
Appearance
Physical state: Liquid Colour: colourless
Odour: odourless
Safety relevant basis data
parameter at °C Method Remark
pH 2–3 20 °C
Melting point -1 °C
Freezing point not determined
Initial boiling point and boiling 100 °C
range
Decomposition temperature not determined
Flash point not applicable
Evaporation rate not determined
Auto-ignition temperature not applicable
Upper/lower flammability or not applicable
explosive limits
Vapour pressure 1.9 hPa 20 °C Hydrogen peroxide
Vapour density not determined
Density 1 g/cm³ 20 °C
Bulk density not applicable
Water solubility completely 20 °C
miscible
Partition coefficient: n-octanol/ not determined
water
Dynamic viscosity not determined
Kinematic viscosity not determined

9.2. Other information

No data available

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SECTION 10: Stability and reactivity
10.1. Reactivity
No data available
10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardous reactions
No hazardous reaction when handled and stored according to provisions.
10.4. Conditions to avoid
Strong acid, Strong alkali, Oxidizing agent
10.5. Incompatible materials
No data available
10.6. Hazardous decomposition products
No known hazardous decomposition products.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Substance name Toxicological information
hydrogen peroxide LD50 oral:
CAS No.: 7722-84-1 376 mg/kg (Rat)
EC No.: 231-765-0
LD50 dermal:
3,000 mg/kg (Rat)
LC50 Acute inhalation toxicity (vapour):
2 mg/l 4 h (Rat)
orthophosphoric acid LD50 oral:
CAS No.: 7664-38-2 1,530 mg/kg (Rat)
EC No.: 231-633-2
LD50 dermal:
2,740 mg/kg (Rabbit)

Acute oral toxicity:

Based on available data, the classification criteria are not met.
Acute dermal toxicity:
Based on available data, the classification criteria are not met.
Acute inhalation toxicity:
Based on available data, the classification criteria are not met.
Skin corrosion/irritation:
Based on available data, the classification criteria are not met.
Serious eye damage/irritation:
Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation:
Based on available data, the classification criteria are not met.
Germ cell mutagenicity:
Based on available data, the classification criteria are not met.
Carcinogenicity:
Based on available data, the classification criteria are not met.
Reproductive toxicity:
Based on available data, the classification criteria are not met.
STOT-single exposure:
Based on available data, the classification criteria are not met.
STOT-repeated exposure:
Based on available data, the classification criteria are not met.
Aspiration hazard:
Based on available data, the classification criteria are not met.
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Sanosil S003
Additional information:
No data available

SECTION 12: Ecological information

12.1. Toxicity
Substance name Toxicological information
hydrogen peroxide LC50: 16.4 mg/l (Fish)
CAS No.: 7722-84-1
LC50: 2 mg/l (Daphnia pulex)
EC No.: 231-765-0
EC50: 1.38 mg/l (Alga)
silver LC50: 0.015 mg/l 2 d (shellfish)
CAS No.: 7440-22-4
LC50: 0.00807 mg/l 4 d (fish)
EC No.: 231-131-3
EC50: 0.0092 mg/l 2 d (shellfish)
EC50: 0.00198 mg/l 3 d (Alga)

Aquatic toxicity:
Harmful to aquatic life with long lasting effects.
12.2. Persistence and degradability
Substance name Biodegradation Remark
hydrogen peroxide Yes, rapidly
CAS No.: 7722-84-1
EC No.: 231-765-0
silver Yes, slowly
CAS No.: 7440-22-4
EC No.: 231-131-3

12.3. Bioaccumulative potential

No data available
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
Substance name Results of PBT and vPvB assessment
hydrogen peroxide The substance in the mixture does not meet the PBT/
CAS No.: 7722-84-1 vPvB criteria according to REACH, annex XIII.
EC No.: 231-765-0
orthophosphoric acid The substance in the mixture does not meet the PBT/
CAS No.: 7664-38-2 vPvB criteria according to REACH, annex XIII.
EC No.: 231-633-2
silver The substance in the mixture does not meet the PBT/
CAS No.: 7440-22-4 vPvB criteria according to REACH, annex XIII.
EC No.: 231-131-3

12.6. Other adverse effects

No data available

SECTION 13: Disposal considerations

* 13.1. Waste treatment methods
The product may not be eliminated as municipal solid waste nor allowed to end up in the drainage
system. These packs can be delivered packaging-specific to the existing collection points for hazardous
waste.
13.1.1. Product/Packaging disposal
Waste codes/waste designations according to EWC/AVV
Waste code product:
16 05 07 * discarded inorganic chemicals consisting of or containing hazardous substances
*: Evidence for disposal must be provided.

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Sanosil S003
Remark:
Wastecode according to regulation EU 2014/955
Waste code packaging:
15 01 02 Plastic packaging

Waste treatment options

Appropriate disposal / Product:
Residues of the product have to be collected as hazardous waste.
Appropriate disposal / Package:
Empty packaging can be recycled or eliminated as municipal solid waste.

SECTION 14: Transport information

No dangerous good in sense of these transport regulations.
Land transport (ADR/ Inland waterway Sea transport (IMDG) Air transport (ICAO-
RID) craft (ADN) TI / IATA-DGR)

14.1. UN-No.
No dangerous good No dangerous good No dangerous good No dangerous good
in sense of these in sense of these in sense of these in sense of these
transport regulations. transport regulations. transport regulations. transport regulations.

14.2. UN proper shipping name

No dangerous good in sense of No dangerous good in sense of No dangerous good in sense of No dangerous good in sense of
these transport regulations. these transport regulations. these transport regulations. these transport regulations.

14.3. Transport hazard class(es)

not relevant

14.4. Packing group

not relevant

14.5. Environmental hazards

not relevant

14.6. Special precautions for user

not relevant

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not relevant

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU legislation
Authorisations:
Regulation (EU) No. 528/2012 on biocides
15.1.2. National regulations
No data available
15.2. Chemical Safety Assessment
No data available

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SECTION 16: Other information
16.1. Indication of changes
6.3. Methods and material for containment and cleaning up
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
8.2. Exposure controls
9.1. Information on basic physical and chemical properties
13.1. Waste treatment methods

16.2. Abbreviations and acronyms

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways
ADR European agreement concerning the international carriage of dangerous goods by road
CAS Chemical Abstract Service
CLP Classification, labelling and Packaging
EC50 Effective Concentration 50%
EN European norm
IATA International Air Transport Association
IMDG-Code International Maritime Dangerous Goods Code
LC50 Lethal Concentration 50%
LD50 Lethal Dose 50%
OECD Organization for Economic Cooperation and Development
PBT persistent, bioaccumulative, toxic
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation and Authorization of Chemicals
RID Regulations concerning the international carriage of dangerous goods by rail
SVHC Substance of Very High Concern
UN United Nations
VOC Volatile organic compounds
vPvB very persistent, very bioaccumulative
16.3. Key literature references and sources for data
Security safety data sheet of the ingredients. Inventory of substances of the European Chemical Agency
(ECHA). GESTIS database
16.4. Classification for mixtures and used evaluation method according to
regulation (EC) No 1272/2008 [CLP]
Classification according to Regulation (EC) No 1272/2008 [CLP]:
Hazard classes and hazard Hazard statements Classification pro
categories cedure
Hazardous to the aquatic environment H412: Harmful to aquatic life with long lasting Calculation method.
(Aquatic Chronic 3) effects.

16.5. Relevant R-, H- and EUH-phrases (Number and full text)

Hazard statements
H271 May cause fire or explosion; strong oxidiser.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

16.6. Training advice

Persons charged with the handling and cleaning of the product must be trained prior to start their work
and in regular intervals. They must be informed about the risks using the product and the mesures
to take for efficient prevention. This concerns particularly working security, first aid, health and
environment protection.

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16.7. Additional information
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the
product named in this safety data sheet, for storage, processing, transport and disposal. The information
cannot be transferred to other products. In the case of mixing the product with other products or in the
case of processing, the information on this safety data sheet is not necessarily valid for the new madeup
material.

* Data changed compared with the previous version

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