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SOLUTION Numericals

1. The document provides 19 chemistry problems involving calculations related to vapor pressure, freezing point depression, and osmotic pressure using various formulas. 2. The problems involve calculating vapor pressure, relative lowering of vapor pressure, freezing points, amounts of solutes, and osmotic pressures of solutions using given values for pure solvent properties, temperatures, masses of solutes and solvents, and molar masses. 3. Different formulas are provided and used in the problems including formulas relating vapor pressure to solute concentration, freezing point depression to solute concentration, and osmotic pressure to solute concentration and temperature.

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55 views

SOLUTION Numericals

1. The document provides 19 chemistry problems involving calculations related to vapor pressure, freezing point depression, and osmotic pressure using various formulas. 2. The problems involve calculating vapor pressure, relative lowering of vapor pressure, freezing points, amounts of solutes, and osmotic pressures of solutions using given values for pure solvent properties, temperatures, masses of solutes and solvents, and molar masses. 3. Different formulas are provided and used in the problems including formulas relating vapor pressure to solute concentration, freezing point depression to solute concentration, and osmotic pressure to solute concentration and temperature.

Uploaded by

Thor
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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SOLUTION

Use the formula:


𝒑𝟎−𝑷𝒔 𝒑𝟎−𝑷𝒔 𝒏𝟐 𝒑𝟎−𝑷𝒔 𝑾𝒃∗𝑴𝒂
= x2 = =
𝑷𝟎 𝑷𝟎 𝒏𝟏 𝑷𝟎 𝑴𝑩∗𝑾𝒂

1. The vapour pressure of water is 12.3kPa at 300K. Calculate vapour pressure of


1 molal solution of a non-volatile solute in it.
2. Calculate the relative lowering vapour pressure for the below mentioned
solution. Vapour pressure of pure liquid at 25 degrees Celsius in 100 mm hg
and mole fraction of the solvent is 0.8.
3. Calculate the relative lowering of vapour pressure for 0.8 vapour pressure of
water at 293 Kelvin is 17.51 mm Hg and lowering of vapour pressure of sugar
solution is 0.0614 mm of Hg.
4. An aqueous solution of 25% non-volatile solute exerts a pressure of 1.004 bar at
the normal boiling point of the solvent. What is the molar mass of the solute.
5. Calculate the mass of a non-volatile solute(molar mass 40g/mol) which should
be dissolved in 114 g octane to reduce its vapour pressure to 80%.
6. Vapour pressure of pure water at 298K is 23.8 mm Hg. 50g of urea (NH2CONH2)
is dissolved in 850g of water. Calculate the vapour pressure of water for this
solution and its relative lowering of vapour pressure.
7. A solution containing 30 grams of non-volatile solute exactly in 90 grams of
water has a vapour pressure of 2.8 kPa at 298 Kelvin further 18 gram of water
is added to the solution and the new vapour pressure becomes 2.9 kPa at 298
K calculate the molar mass of the solute vapour pressure of water at 298 K.
8. 100 gram of liquid A of molar mass 140 g/mol was dissolved in 1000 grams of
liquid B with molar mass 180 g/mol. the vapour pressure of the pure liquid B
was found to be 500 torr. Calculate the vapour pressure of pure liquid A and its
vapour pressure in the solution if the total vapour pressure of the solution is
475 torr.
Use the formula ∆Tf=Kfm ∆Tf=iKfm
9. What mass of sodium chloride must be dissolved in 65 gram of water to lower
the freezing point of water by 7.500C? the freezing point depression constant
for water is 1.860C/m assume, assume Van’t Hoff factor for sodium chloride is
1.87 given molar mass of sodium chloride is = 58.5 gram.
10. Calculate the freezing point of a solution containing 60g of glucose with molar
mass 100 g/mol in 250 gram. Kf of water = 1.86K kg/mol.
11. Calculate the freezing point of solution when 1.9g of magnesium chloride was
dissolved in 50 gram of water, assuming magnesium chloride undergoes
complete ionization Kf of water = 1.86K kg/mol.
12. At 10% solution by mass of sucrose in water has freezing point of 269.15 K.
calculate the freezing point of 10% glucose in water if freezing point of pure
water is 273.15 Kelvin (molar mass of sucrose = 342 g/mol, molar mass of
glucose = 180 g/mol)
13. 19.5 grams of fluoro acetic acid is dissolved in 500 gram of water the depression
in the freezing point of water absorbed is 10Celsius calculate the Vant Hoff
factor and dissociation constant of fluoro acetic acid Kf of water = 1.86K kg/mol.
14. A 5% solution by mass of cane sugar in water has a freezing point of 271K.
Calculate the freezing point of glucose in water if the freezing point of pure
water is 273.15K
15. When 2.56g of sulphur was dissolved in 100 gram of CS2 to the freezing point
is lowered by 0.383 Kelvin calculate the formula of sulphur. Given Kf for CS2 =
3.83 KKg/mol, atomic mass of S=32g/mol.
16. Calculate the freezing point of an aqueous solution containing 10.50g of MgBr2
in 200g of water.(molar mass of MgBr2 =184 g/mol and Kf of water = 1.86
kg/mol.
17. Calculate the amount of KCl which must be added to 1kg of water so that its
freezing point is depressed by 2K.
Use =iCRT , p = iCRT
18. Determine the amount of calcium chloride dissolve in 2.5 litre of water such
that its osmotic pressure is 0.75 atmosphere at 27 0celsius (i=2.47).
19. Determine the osmotic pressure of a solution prepared by dissolving 25 grams
of potassium sulphate in 2 litre of water at 250c assuming that it is completely
dissociated.

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