CRySTAL FIELD THEORY

FeCRa0J 3+lan)+sorlo)elsenDCt ,0)5 a ) tHa0

2

Kte Ax10*feKCM) K
y fcu CNtBu"=
1la
0a
LR13)(scH3 a s3 e more

ons oit rucomirg ligands

Bondin g
Pawourable
o met
m oul
eta u
wate
eveM taoun
nan bondang wi wadte
dondung
Paasent in excos.

CRYSTL FIELD THEORY eate nelachon

a nelecm
elechron
elechun
to Cuecte
to

model Unes lig and

Elecostatie

a x o n a fMe metal cen eovakaunt sukorachou

coraaut
Sutorathou
Ld mo owet o
met al- iig ad
g ard
Hwne
tv CFT, and Hee
and He
ACeordanq
ACcording
OUy a ngasive paun
a mgatie paunk chag
i eatad
eadh igaud
buhween
mutal
on H Mndu. ad

atr a dhgn
s elserostatic beheeen lenmm d07bitals
here
Jg aunPoiut tharg.
meal ism
alus eriph'm elachroiC on
n
appaoximat
PAovidas Ou spehra
and Uv spe
for
jib CooTdih
pontible

Compound
 hu en
0a) sphenical,
(eus to di ad
he
raised deutabitisI) by
5d-orbitals wen

anue amountt.

ocakadral :
splitina d-6rloitak
mctazonau Haad
n on
A dd- rbitals a
elno
ectae dral fed igand elucmom paivs auy
in mase ebitals axe epotled by #he fisdd,
The do 2y and da2 orbit als have E Ca ymmay

g and4 ad ane he
ad i t e i h d at uwusundng
dza oreitaly tave t29
oerey. e dy dyz and and ar
a u diuctuol bohua te iqaunds
mm ey Pny

Resulb ng enery diffenunee d o

Bce2
8da-
3d- orbitals a s
er
b r b l

3Aya d
sPut 'wdo a levela.

Degenerote d h ehe elecrostaht 3ny euchostatic jala

aunie oxbitos
i d d u u t d o y Hae occaed by poink e
Pount chaged gands easges is ockauedsal,Kue
sphesi cal, engs nay elechma
3d oroitalk ana 3-d o bi tal a ha Pav
oannesdw or cirec- at lg amds s
TOused ott goberical e l e
d-or bHals day and da ae direcked taitaorbit
ener t I eetechrs
chns

lsna orbitds o
abe oecte holween pain
Me Hham 6Rner d-orloital Re ando
Acuoeed w epharicA

baxyeanhe O.64
A

OvAo
Spuriea bchahedral d
ue iom

orbitas au O-4 A balad and e

22 eg orbi haly o e 06 Ao
abore ms enrq eRee 2g ortals naue to tal
orbitals

NO PUST
 e o6Ao
o2 +2 Ao
C o g a h ' 'ons
ou
co9urah
p a e

ic
ie
e lcmm
behween Kae el cm

C FS E : Enovg dounca
an
ockaht dras and fied
duue do
G) the d-0routau p e enu puevcal
heltnaf
o
(9 derbiteu eope n u
o u l d
erease tue rgi wwfoly.orbi la Ceuels o
behueen

etanedral Cowmpoumd

Fares ectunq Ao: i pwn

m dan

mera tomi L Aame chag dm

ha

NahD d i hn ghel
uld cpttting enugy
Cstal Aan
metal cahon, dechrons tlower
whene no0 o d-ombital
Covmptex fTOtsreineo

to prusena
ERhT and Te t3
duue hern
auls z*

uu e to
to ughe
ug
u poo tnI+5 pusheS inside cts
Shoildug eck and gand
elecirm
and
b Rh and
Lacted
o o l t als au RolLooed
highest.or I
4Hence, ngy p Men C o t

Aoct

RhUD IrCmy
Co L eni ng.
UnueaseA:
wuh 1Mr
Aoc eleekpu
eleekep
meal ion
2 Chaa
om
densty u
danstyu
n , Hence
ighu,Hence ,

aas
Oci dan on
gtat. migheaL.
o Aocr ond
e ood
unteacion
e T ) and
e ( ) for given ig a

E-Compluxes e oniclation
8Baty.
&tae
ncHLasing
houau ou
pecoChumital sriu:
Nasweinands
3)
Ac inceae a we go
ild igand
lOeak and shong
to utd igonds.
arong
weak aoms:O<N<C)

srory donoT
weak
Weak

NCS N Ha<en bey phan Co

HO
 Aoct Caltutaion ani 0nign

calaulaud uom lLcnonic abioph om spechroscopc

Vaus a
fo coui Ch me
Aoto Eg: d' complex [Tt (t,0)6
oud kak epAeuudtud
e - t8
uaulh a
uwgy
.Absorphon o on
elachronic
conkiqunaki
Caange i
a measu AoC
doce
meaSLUN

Amax quve!
measue
Tue
diiuor Syskems hunig
mud
easnwnen oAoct
d- ela c o n .
mere han i
Spoun Conylra
Conyloret
Ënergy: koo and azh on
Stabiusalton
stau dheld
Cystal
Cny
contqurah'on iu t
exanmpte cor d swtm, t e a
Ps an

stabulisahon euvg%= 0:4 4

babycenre,
CFSE ) -0 4 ) + tea)(o64.)
Simidony, Ror dssem
(2) -o4 A.) + o(o.bAo)
CFSE
-0 8Ao.
12A.
cfs 30-4 4 ) -
d systt,
for
for
d sen

4t 4-4
dew spn
Fhglh S p n
C SE -4ova)+
cFSe 3-o4d)+ oia) - 1' 6A+
- 6 A
 chns tu
ele
plaLe 2
nert
rnuived t c u to
duu
weak
w eak band au
band
orloitad CFSE ic cmau
sa an
pain tnergy s karar
tisand
lisand 3h
sin " paime a l n

d5-rms
T[Fe (en.P*
[fe(nao)1

-
4 4 + 4 4 4+4q 444+
.
weak bondimq ugand Srona bondung gand
i g h spin Compde Souo gun camplex

CFSE 3(-0 44.)+2{0-6Ao) CFSE- 5-0A.) +2P

-2 A.t 2P
o P Ao 7P

ond ond too spin eonplexes o i

Mn 33 4s1 My'2 3d5

Jow sin

eA

-4-4444Ai *
Moa20,J*
AockP
CFSE 304 a.)+ 2l06A) CF SE = 5(-0 4 A.) 2
- Ag 29.
weak ligand
Shog and
 dcusms Co ct ah edsas feld).

P-E -
H B - 4 4 4 t

Ht4+44 44 t
Hhigh qin Complex Jow spin compex.

t CPse = 4(-0:4.H 2/ota.) CF SE 6-0:4 Ao) +2

-0:4 2 4 Ao+2P

pauirg u ty orbtal Pai orborbi tal in

due to ue intenal d to int ernal eongu ahon
H H mtal eu.
COnkguyauon u a l un.
Jt NOT be Cause2 Ha he 2exa pag dmt
and and ue poainng
lug
nun net ünctuded. lig cunedand s nce 2P
conoi olis ed o kpart+ eFSE,

STRONfIELD La LPIN
AicG AND ComPLEx >
larung ket f a
dahu ouupords al
duigu or lod epin
Dhauy an orbital Lpuitting
diougram fov eauk
eauu o Ouakadnl
e Outahadnl
ebmpluxe
Fe(Ca0)&8 e (¢NDC|. lndit nuar
unpaind elschon
Kpu m
dub 4 w im aan ow m
hk
cal culat CCe.
Fe LA
fet2
 e C a ] 9+

PE

A4
444 KK- 4 44K
4-1-4 t
So ea eld igand Sreraield 9igor
ow epun mplux
1igh epn comple

3 (-0 4 A) +2(0 b4. cese 6(-o 4 4)+2P

erSE =

- 24 A.+ 2P

hu 22P tt u m
m
anigurakovn
fse fpr d
2 Explain w veb. tal aulas
f SE for
and Pespt e
d d maye 2
eaen tor
each Ca
are
pomible
arvargemen
pesetH
wo

Ca) d BysHm

tig
ACD o
Low spunn

E 4
4 4 +K 44 L 4+
CFSE 3(-0)+2(044
2P
sE 5-044)+
2A.+2
ouy
talue pla
Exa pai 2P
erbitalu and honca
w tuo

involved
 bd6Lystem
dow spun
C Hin

a
H4-44K 4-4 4 4 K
44+*
CFSE 4--4A)+20-6A.) CFSE 6(-0u d»)P
0-4 2-4 do+2P
JExa paising ocey uly ch
ofH tog orbitals.
So4L
teurn '2r uclu ded. TuL
uiut pay du to Hue
Unt unal LOnkiur ation g Metd u "

hah epn douo

A4 A+t-+1
esSE5(-04A)+2(ot A) CFSE =
e-0va)+ 1(o-6A)+?
24+ l2 Ao
-1'8A t ?
-0 84o
Exra auung acRwu oaulu m
eTbital rom taa.
tuA AD
evbita a aliadu
dul o painud
uhrna igurah0n
u ion.
Q. Letsitia COy
Ockaudnal wuNa kuve
6bavd) quti eally favauable