SULIT 4541/1 (PP) 4541/1 (PP) Kimia Kertas 1 Peraturan Pemarkahan Oktober 2022 MAKTAB RENDAH SAINS MARA. PEPERIKSAAN AKHIR SIJIL PENDIDIKAN MRSM 2022 KIML Kertas 1 Peraturan Pemarkahan —_———————————— Untuk kegunaan pemeriksa sahaja Peraturan pemarkahan ini mengandungi 3 halaman bercetak [Lihat halaman sebelah, 4541/1(PP) © Hk cipta Bohagian Pendidikan Menengah MARA SULITSULIT 2 4541/1 (PP) Table of Specification SPMRSM 2022 No. Construct Topic ‘Type Of Item Key i Remembering F4LA2__[M.Choice A 2 ‘Remembering F4LA3__|M. Choice B 3 Remembering F4La4 M. Choice A 4 Remembering F4LA6 | M. Choice A 5 ‘Remembering F4LA5__|M. Choice A 6 Remembering F4LA7 __|M, Choice B 7 Remembering F4LA8 M. Choice c 8 ‘Remembering FSLA9 | M. Choice D | 9 Remembering FSLAI0 | M. Choice A 10 Remembering F5LA9__|M. Choice B 1 Remembering FS5LA10 a 12 Remembering FSLAI D B Remembering FSLAI2_|M.Choice Cc 14 Remembering FS5LAI3__| M. Completion A 18 Understanding F4LA2 | M. Choice B 16 Understanding: F4LA2 | M. Choice c 7 Understanding, F4LA3 M, Choice D 18 Understanding F4LA4 M. Choice £ 9 Understanding: F4LA4 | M. Choice Cc | 20 Understanding F4LAS M. Choice B 21 ‘Understanding F4LA6 _| M. Choice B 22 Understanding F4LA7 M. Choice D B Understanding F4LA7__|M. Choice A 4 Understanding, FS5LAI4 | M. Choice D 5 Understanding F5LA9 | M. Choice B % Understanding FSLAI0 | M. Choice D 27 Understanding FSLA11__|M. Completion c 28 ‘Understanding FSLAI2 M. Completion D 29 Understanding FSLAI4_|M. Choice D 30 Applying F4LA3__|M. Choice D 31 Applying F4LAs M. Choice c 32 Applying F4LA6 | M. Choice D 3 Applying F4LAT _|M. Choice B 34 ‘Applying FSLA9 | M. Choice D 3 Applying F5LA9__|M. Choice D 36 Applying FSLAIL M. Choice A 37 Applying | FS5LA10 | M. Completion B 38 Applying F4LA6 _|M. Choice B 39 Analyzing FSLA9__ | M. Choice A 40, ‘Analyzing, F5LA9_ |M.Choice D 4541/1(PP) © Hak cipta Buhagian Pendidikan Menengah MARA. SULITSULIT 3 4541/1(PP) Key No. A 9 B 10 G 8 D 13 ‘Total 40 _ Blement _ Code Remembering PKOL Understanding KKOI Applying KKO2 Analyzing KKO3 Bvaluatin KK04 Creatins KKOS END OF MARK SCHEME 4541/1(PP) © Hak cipta Babagian Pendidikan Menengsh MARA SULITSULIT 4541/2(PP) 4541/2 (PP) Kimia Kertas 2 November 2022 MAKTAB RENDAH SAINS MARA. PEPERIKSAAN AKHIR SIJIL PENDIDIKAN MRSM 2022 KIMIA, Kerias 2 Peraturan Pemarkahan Untuk Kegunaan Pemeriksa Sahaja Peraturan Pemarkahan ini mengandungi 19 halaman bereetak [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULITSULIT. 2 4541/2(PP) MARKING GUIDELINES PAPER 2 Symbol Meaning Wt - replace the whole sentence / - replace the previous word (] - can be summarized from explanation __orbold - key word adp - avoid double penalty wer - wrong cancel right a = accept r - reject ecf = error carry forward 4841/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULITSULIT 3 SECTION A 4541(PP) No. Mark Scheme Sub | Total | Mark | Mark [Able to state the physical state of fats at room temperature correctly] Answer: Solid (b) [Able to name the reaction for the conversion of saturated fats into unsaturated fats correctly] Answer: Hydrogenation // Addition of hydrogen © | [Able to state the type of food additives and funetion of citric acid in the cake correctly} PI. Type of food additives P2, Function of citric acid Answer: PL. Antioxidants 2, Slow down the oxidation of fats in food // Prevent oily or greasy food from becoming rancid. (d) [Able to state one other example of food additives in the cake correctly] Sample answer: Preservatives / flavourings / stabilisers // emulsifiers// dyes Total 5 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Batagian Pendidikan Menengah MARA SULITSULIT 4 4541/2(PP) | Sub] Total ae - Mark Seliems Mark | Mark 2 | @ | @ | [Able to state the meaning of molecular formula correctly] Answer: (Chemical formula that shows the actual number of ator of each element in a molecule/compound 1 1 Gi) | [Able to write the molecular formula of aspirin correctly] Answer: CollsOs ry (ii) | [Able to state the type of particle of aspirin correctly] | Answer: Molecule 1 1 (b) [Able to give two information that can be interpreted from the chemical equation correctly] P1. Identify reactants and product 1 P2, Mole ratio//quantity ratio of reactant and product 1 2 Sample answer: 4 mol of aluminium reacts with 3 mol of oxygen to produce 2 mol of aluminium oxide // 4 aluminium atoms react with 3 oxygen molecules to produce 2 units of aluminium oxide _ Total | 5 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengeh MARA SULITSULIT 5 4541(PP) Soh ‘Sub | Total No. Mark Scheme Mark | Mark 3 [@ [Able to state the meaning of isotopes correctly] ‘Sample answer: Atoms of the same element with the same proton number but different nucleon number // Atoms of the same element with the same number of 1 1 protons but different number of neutrons (b) [Able to draw the atomic structure of Si-28 correctly] PI. Nucleus is shown and correct number of shell 1 P2. Correct number of electron and label proton and I 2 neutron in the nucleus Sample answer: | | () [Able to calculate the relative atomic mass of Si correctly] PL. Calculation 1 P2, Correct answer 1 2 Sample answer: RaMorsi = 228281 +15x291413%30) 100 @ [Able to state one example of isotopes used in medicine field correctly} Sample answer: Cobalt-60 // lodine-131 i " “Accept any suitable isotopes Total | 6 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipts Bahagisn Pendidikan Menengah MARA, SULITSULIT 4541/2(PP) Mark Scheme [Able to write the electron arrangement of ion T correctly] Answer: 2.8.8 Sub | Total Mark | Mark () [Able to state the position of element S in the Periodic Table of Elements correctly] Answer: Period 2, Group 16 () [Able to arrange the atomic size of the elements in descending order correctly] Answer : Q,T,U,P,R,S @ [Able to state the element that exists as monoatomic gas correctly] Answer: U @ [Able to explain answer in d(@) correctly] Sample answer: ‘Atom has achieved stable octet electron arrangement [Able to explain the difference in reactivity between the two elements correctly] Sample answer PL, Size of Q atom is bigger than P atom/ [Atomic size] P2, Attraction forces between nucleus and the valence electron in Q atom is weaker than P atom // Q atom is easier to lose electron than P atom, Total | 7 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULITSULIT No. Mark Scheme 4541(PP) Sub | Total Mark | Mark [Able (o state the meaning of the polymer correctly] Answer: A Jong chain molecule that is made from a combination ‘of many repeating basic units/monomers. &) | @ [Able to draw the structural formula of the monomer correctly] anme YA nswer: ‘o: q / H — CHs (ii) [Able to state the type of polymerisation reaction in the production of the polymer correctly] Answer : Addition polymerisation (iii) [Able to state one of the uses of the polymer correctly] Sample answer: Food container // Plastic bottles // Ropes // Twine * Accept any suitable answer ©} a [Able to choose and justify the use of natural rubber or synthetic rubber in the making of this sport shoe sole correctly] PL. Choose the type of rubber P2 & P3. Justification Sample answer: PI. Natural rubber 2, Soft (which makes foot is more comfortable) 3, Low heat resistance (This will make the sole become sticky and less slippery. This makes the sole can grip the flooring better.) oR PI. Synthetic rubber P2. More elastic. (It ean retain its shape longer. The shoe can be wear longer) P3. More/High heat resistant.(The shoe sole is not easily worn) a1 | 3 @ [Able to suggest one way to overcome the issue correctly] Sample answer: Recycle // Reuse // Reduce Total | 8 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bobagian Pendidikan Menengah MARA. SULITSULIT 4541/2(PP) No. Mark Scheme ‘Sub | Total | Mark | Mark 6 | @) a Gi) [Able to write the electron arrangement of atom X correctly] Answer: 2.8.2 [Able to state the type of forces of attraction correctly] Answer: Electrostatic attraction forces // Electrostatic forces of attraction (i) [Able to write the chemical equation for the formation of the compound correctly] PL. Correct formula of reactant and product P2, Balanced chemical equation Answer: 2X + Y2 + 2XY // 2Mg + O: > 2MgO yy [Able to calculate the mass of XY produced when 0.1 | mol of X react with Y in excess correctly] PI. Mole ratio P2. Mass of XY with correct unit Sample answer: PL. 2 mol X produce 2 mol XY // 0.1 mol X produce 0.1 mol XY P2. Mass of XY = 0.1 x (24+16)=4 ¢ Note: Apply ecf PI fiom 6(a)(iii) (b) [Abie to identify the type of compound and explain the two properties of white solid correctly] PI. Covalent compound// Covalent covalent bond P2, Consists of neutral molecule /! no fice moving ion present P3. Weak attraction forces between molecules// ‘Weak intermolecular forces of attraction// Weak Van der Waals force between molecules Total | 9 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULITSULIT 9 4541(PP) Sub Total No. Mark Scheme ature (NOE 7 | (a) | (@ | [Able to state the meaning of heat of precipitation | correctly] Answer: Heat change when 1 mole of precipitate is formed from | 1 1 their ions in aqueous solutions. a: specific definition (ii) | [Able to state one information that can be obtained from the energy level diagram correctly] Sample answer Precipitation of barium sulphate is an exothermic reaction // 1 I 1473.2 kJ heat is released when | mol of barium sulphate is formed // Total energy content of reactants is higher than total energy content of products Gil) | [Able to name solution X correctly] Answer: | Barium chloride // Barium nitrate 2 1 1: Formula (iv) | [Able to write ionic equation correctly] Answer: Ba®* + SO > BaSOy L |i (b) | (i) | [Able to calculate the increase in temperature with | unit correctly) PI. Number of mole of Po(NOs)2/NaSOy P2, Heat released, Q 1 P3. Temperature change, 0 with unit 1 Answer: hy}? P1. Number of mole of Pb(NOs)2 = MV /1000 =1x25/1000 = 0.025 mol Number of mole of Na:SO; = 1 x 25/1000 = 0.025 mol P2. 1 mol of PSO, released 50.4 kI 0.025 mol of PbSOs released 1.26 kJ // Q= AH (n) = 50400 (0.025) = 1260 J 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Meneagah MARA [Lihat halaman sebelah SULITSULIT 10 4541/2(PP) Mark Scheme Sub | Total Mark | Mark P3. 0=Q/me— 1260 (25425) (4.2) =6°C Gi) [Able to suggest how to obtain the result correctly] ‘Answer: Use 0.5 mol dnv* lead( I) nitrate solution and 0.5 mol dny® sodium sulphate solution (©) [Able to choose the best fuel for cooking and justify your choice correctly] P1. Fuel chosen P2. Justification 1 2 Sample answer: PL. Methane P2. Cheaper OR PL. Octane P2. The fuel value is higher // Easier to handle // Safer __ Total | 10 SULIT 4541/2 (PP) © Hok Cipta Bahagian Pendidikan Menengah MARA,SULIT uw 4541(PP) No. Mark Scheme Sub | Total Mark Mark [Able to state all anions present in NaCl solution correctly] Sample answer: Chloride and hydroxide ions // Cl’ & OH ® [Able to name the product formed at electrode P correctly] Answer: Chlorine : formula Gi) [Able to explain the selection of ions to be discharged at electrode P correctly] Answer: Concentration of chloride ions/Cr is higher than hydroxide ions/O1 | 5) [Able to describe a chemical test to verify the product formed at electrode P] PL, Method and reagent P2, Observation Sample answer: PI. Place a damp blue Litmus paper into a test tube containing the product formed P2, Blue litmus paper turns to red and then bleached (b) [Able to write the half equation correctly] Answer: 40H > 02 +2H,0 + 4c" ©) @ [Able to compare and explain the difference in the observations correctly] Sample answer: PI. Inference based on observation in Test tube I and I P2. Reason for observation in Test tube I 3, Reason for observation in Test tube I] PI. Test tube I: Lead metal formed Test tube I: No reaction occurs P2, Test tube I: Lead{ Il) ion receives/gains electron to form lead atom // Lead is displaced from lead(Il) nitrate solution by iron // [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Meneagah MARA SULITSULIT 12 4541/2(PP) No. Mark Scheme Sub | Total Mark | Mark Tron is more electropositive than lead /7 E® value of iron is more negative than E® value of lead 3. Test tube II : Copper cannot displace lead from lead(M1) nitrate solution// Copper less eleciropositive than lead // E? value of copper is more positive than E? value of lead (ii) [Able to suggest an action to be taken to ensure reaction occurs in test tube II correctly] | Sample answer: Change copper wire with a more electropositive metal // Change copper wire with a metal with more negative E° value, ff Change lead(II) nitrate solution with silver nitrate solution 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA, Total | 10 SULITSULIT 13 SECTION B 541(PP) No. Mark Scheme Sub Mark Total Mark @ [Able to choose and explain the method to relieve the stomach pain faster] PL. Method 2, & P3. Explanation Sample answer: PI. Chew the antacid tablet P2. Chewing will break the tablet into smaller size P3, Larger total surface area of tablet exposed / react, with acid 141 Gi) [Able to calculate the average rate of reaction for | Set I and Set II with unit correctly] Answer PA. Set I : 48.00/2 = 24 cm* mint | P2, Set II: 72.00/4 = 18 em? min” Gi) [Able to write a balanced chemical equation and calculate the mass of calcium carbonate correctly] P1. Correct formulae of reactants and products 2, Balanced equation P3, Number of mole of CO P4. Mole ratio 5, Mass calcium carbonate with correct unit Answer! P1&P2, 2HCL+ CaCO; ——CaCh + CO: + HO. Sample answer: P3. Number of mole carbon dioxide; ‘olume /molar volume 2 /24000 = 0.003 mol P4, 1 mol of COs produced by 1 mol of CaCOs 0.003 mol of CO) produced by 0.003 mol CaCOs Note: Apply ecf P4 from P1 & P2 PS. Mass of CaCO: = 0.003 x molar mass = 0,003 x 80 =0.24g [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULITSULIT 4 4541/2(PP) Sub Total No. __ Mark Scheme Seri (wate |b) [Able to suggest the change that can be done to Set I and explain the changes based on collision theory correctly] | PL. Changes to obtzin Set II P2-P5. Explanation using collision theory P6, Changes to obtain Set IIT P7-P10. Explanation using collision theory Sample answer: To obtain Set PI. Use zine granules // Use bigger size of zinc if Explanation: P2, Zinc granules have smaller total surface area 1 exposed to collision P3, Frequency of collision between H* ions and Zn atoms is lower 1 | P4. Frequency of effective collision between H” ions and Zn atoms is lower 1 PS, Rate of reaction will be lower 1 Toobtain Set IT 6. Add copper(I) sulphate (solution) ot Explanation: P7. The presence of copper(II) sulphate as catalyst provide alternative pathway with lower activation 1 cnergy P8, More colliding particles able to achieve the lower activation energy 1 P9, Frequency of effective collision between H* ions and Zn atoms is higher 1 P10. Rate of reaction will be higher 1 | wo *Note: -reject decreases far P3, Pd and PS -reject increases for P9 and P10 | Total | 20 4541/2 (PP) © Hak Cipta Bahagian Pendidilan Menengah MARA SULITSULIT 15 4541(PP) Mark Scheme ‘Sub | Total Mark | Mark Dn] @ [Abie to state the method and physical properties involved in the separation process of crude oil correctly] Answer PI. Fractional distillation P2. Boiling point @ [Able to draw the structural formulae for both distillates correctly] PI. Structural formula of 2,2,4-trimethylpentane P2, Structural formula of butane Answer (b) [Able to write the chemical equation for the combustion of hexane and calculate volume of carbon, dioxide gas correctly] PI. Correct formulae of reactants and products P2, Balanced equation P3. No. of mole of hexane P4. Mole ratio PS.Volume of carbon dioxide gas with comect unit Sample answer: PI&P2. CoH + 19/202 + 6CO2+ 7H:0 P3. No of mole CoHis= 258 / (12(6)+14(1)) = 3 mol P4. | mol CoHisproduce 6 mol COz 3 mol CoHisproduce 18 mol CO2 Note: Apply ecf P4 from P1 & P2 PS, Volume of CO» gas = 18 x 24= 432 dm’ 141 1 5 [Lihat halaman sebelah 4541/2 (PP) © Hak Cipta Bahaginn Pendidikan Menengah MARA, SULITSULIT 16 4541/2(PP) No. ‘Mark Scheme “Sub | Total Mark | Mark ©) | @ [Able to suggest the name of alcohol P, write the molecular formula of compound Q, state the homologous series of compound R and name of Reaction III correctly] Answer: PI. Ethanol // propanol P2. CoHs // CsHs P3, Alkane P4. Oxidation (i [Able to compare the sootiness of the flame correctly] PI. Calculate % of C by mass in compound Q P2, Calculate % of C by mass in compound R P3, Compare the % of C by mass between both compounds P4, Compare the sootiness of the flame Sample answer: P1.% of C by mass in compound Q / C2H = _(12x2)__ x 100 = 85.71% (202) + 4(1) P2. % of C by mass in compound R / CHs = _U12x2)__ x 100 = 80% (2(12) + 6(1) P3.% of C by mass in compound Q / C2E is higher than compound R/ CoH P4, compound Q / CzELs produces more soot / higher sootiness than compound R / C:H OR PI. % of C by mass in compound Q / CsEIs = _(12x3)__ x 100 = 85.71% (3(12) + 6(1) P2. % of C by mass in compound R / = __(12x3 x 100 = 81.81% (312) + 80) P3. % of C by mass in compound Q / CsHs is higher than compound R / C:Hs P4, compound Q / CsHs produces more soot / higher sootiness than compound R / CaF 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULITSULIT 7 4541(PP) Sub Total No. Mark Scheme Mark | Mark @ [Able to justify the use of artificial ethene for fruit ripening process correctly] PI. Agree/Disagree P2&P3. Justification i rH | 3 Sample answer: PL. Yes //itean be used. 2. It induces fruit ripening. P3. The ripening process of the fruits becomes faster / takes shorter time. OR PI. No // it shouldn't be used. P2. It decrease the fruit shelf-life//Fruit easily become over-ripe, 3. Cause vomiting / diarthoea / sore throat / shortness | of breath “Note: accept any suitable answers Total | 20 [Likat halaman sebelah 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA, SULITSULIT 18 4541/2(PP) SECTION C ‘Sub | Total No. Mark Scheme Mart: | Mark 11 ] @) | @ | [Able to state the basicity of ethanoic acid and explain correctly] Sample answer: PL. Monoprotic 1 P2.1 mol of ethanoie acid ionise in water to produce 1 2 1 mol of H ion. // 1 molecule of ethanoie acid ionise in water to produce I H* ion, (ii) | [Able to state and explain the differences in the observation between experiment I and II correctly] P1. Observation of experiment I and IT 1 2. Inference of experiment I and IT 1 P3. Explanation of experiment I and IL 1 3 Sample answer: Experiment T Experiment IT PI. Balloon does not inflate// No change _| P2- Balloon inflate 1 P2. No carbon dio: 2, Carbon dioxide gas | | gas telease//No released//Reaction | | 1 reaction occur occurs P3. Exist as molecule // P3, Presence of H* 1 no H’ present (5) | (i) | [Able to identify solid salt X, black solid Y, brown gas Z and name substance P correctly] Answer: PL. Salt X: Copper(Il) nitrate P2. Solid Y: Copper(Il) oxide P3, Gas Z: Nitrogen dioxide PA, Substance P: Nitric acid a: formula for PI, P2 & P3 r: formula for Pa | 4541/2 (PP) © Hak Cipta Bahagion Pendidikan Menengah MARA, SULITSULIT 19 4541(PP) No. Mark Scheme Sub | Total Mark | Mark P2. Balanced chemical equation P3. No. of mole of salt X P4, Mole ratio PS.Volume of gas Z with correct unit Answer: P3. No. of mole of X P4. 2 mol Cu(NOs)2 produce 4 mol NO» Note: Apply ecf P4 from P1 & P2 PS. Volume of gas Z (i) | [Able to write a balanced chemical equation and calculate the volume of gas Z correctly] PL. Correct formula of reactant and products PL&P2, 2Cu(NOs)2 + 2Cud + 4NO: + 0: AV(64+2(14}+6(16)) = 0.05 mol 0.05 mol Cu(NOs}s produce 0.1 mol NOz Lx 24 =2.4 dm? test correctly] PI. Suggested chemical substance P2, Name of reaction P3. Ionic equation P4,P5&P6. Confirmatory test Sample answer: carbonate a: formula P2. Neutralisation P3. H+ OH + ILO test tube, © [Able to suggest chemical substance used to treat the waste, name the reaction and describe confirmatory | PI. Calcium oxide // caleium hydroxide // caleium P4. Pour 2 cm of the waste water into a test tube. PS. Add (a named metal carbonate / metal) into the P6. No effervescence occur // No gas bubbles ‘Total 20 PERATURAN PEMARKAHAN TAMAT 4841/2 (PP) © Hak Cipta Buhagian Pendidikan Meneogah MARA SULIT