Education -: KwaZulu-Natal Department of Education * REPUBLIC OF SOUTH AFRICA This question paper consists of 16 pages including 4 data sheets and 1 answer sheet.Physical Sciences P2 2 Preparatory Examinations - September 2017 Nsc INSTRUCTIONS AND INFORMATION 1 Yiite your centre number and examination number in the appropriate spaces on the ANSWER BOOK. 2. _ This question paper consists of TEN questions. Answer ALL the questions in the ANSWER BOOK. 3. Start EACH question on a NEW page in the ANSWER BOOK. 4. Number the answers correctly according to the numbering system used inthis question paper. 5. Leave ONE line between two ‘sub questions, for example between QUESTION 2.1 and QUESTION 2.2. 6 You may use a non-programmable calculator. 7. You may use appropriate mathematical instruments. 8. You are advised to use the attached DATA SHEETS. 9. Show ALL formulae and ‘substitutions in ALL calculations, 10. Round off your final numerical answers to a minimum of TWO decimal places, 11. Give brief motivations, discussions et cetera where required, 12. Write neatly and legibly, sopyright reserved Please tum nuarPhysical Sciences P2 Preparatory Examinations - September 2017 3a NSC QUESTION 4: MULTIPLE CHOICE Four options are provided as possible answers to the following questions. Each question has only ONE correct answer. Write only the letter (A - D) next to the question number (1.1 — 1.10) in the ANSWER BOOK, for example 1.1 D. 4.1. Which one of the following organic compounds contains a carbonyl group? A Haloalkanes B Alkanes ¢ Alcohols D Aldehydes (2) 4.2 Which one of the following reaction types represents the conversion of ETHENE to CHLOROETHANE? ‘A Substitution B _Hydrohalagenation © Dehydrogenation D Elimination @) 4.3. Inwhich one of the following reaction types is methyl methanoate formed? A Esterification B Hydrolysis © Dehydration D hydration (2) 4.4 50cm? of a0,1 mol.dm® solution of hydrochloric acid is poured on to 5 g of magnesium powder inside a ‘small test tube at room temperature. ‘Which one of the following factors will increase the rate of this reaction? A Using 100 om? of a 0,1 mol.dm* solution of hydrochloric acid at room temperature. B Using 5g of magnesium ribbon. © _ Decreasing the temperature of the acid solution to 10 °C D Increasing the temperature of the acid solution to 80 °C (2) Copyright reserved Please tum overPhysical Sciences P2 15 ‘opyright reserved Please turn aver 4 Preparatory Examinations - September 2017 NSC Graph B below represents the Maxwell-Boltzmann energy distribution curve for @ reaction mixture at a temperature of 300°C. Area X represents the number of molecules in the mixture that have enough kinetic energy for the Teaction to take place. ‘Numbst of miei ¥ The temperature of the mixture is now increased o 500 °C. Which ONE of graphs A to D represents the distribution curve ofthe mitre at this higher temperature? AA BB coc D D 2) A mixture of $0, gas and O, gas was placed into a closed container at 300°C with a small amount of V5, 280,(9) + O49) = 280;(9) At certain times, various changes in the physical conditions applicable to the reaction or to the chemicals themselves, were made. The graph below represents the rate of reaction against time. 8 : 5 ae ee Which one of the changes below explains the change in the graph at 20 s? A Decrease in pressure. B Increase in pressure. © Decrease in temperature, D Addition of a catalyst. @Physical Sciences P2 5 Preparatory Examinations - September 2017 NSC 1.7 Consider the ionisation reaction below: H,SOs(ag) + H20() = HSO, (aq) + H,0° (24) ‘A conjugate acid-base pair is: A H,SO, ; HSO; B H,80, ; H,0° c H,SO, ; H,0 D -HSO; ; HO" @ 4.8 During the electrolysis of a concentrated sodium chloride solution, water is reduced and not sodium ions because... A Na’ is a stronger reducing agent than H,0. B Na’is a stronger oxidising agent than H,0. c H,0 is a stronger reducing agent than Na’. D H,0 is a stronger oxidising agent than Na’, (2) 4.9 Asolution of copper (I) chloride (CuCl,) must be stored in a metal container. ‘Which one of the following metals should“ be used? Ag Zn Mg Fe (2) vomD 4.10 Which one of the following fertilizers provides the least nitrogen per mole of fertilizer? A Ammonium phosphate B Ammonium nitrate C Potassium nitrate D Calcium nitrate @) [20] Copyright reserved Please tum overPhysical Sciences P2 6 NSC QUESTION 2 (Start on a new Page.) The letters A to F in the table below represent eight organic compounds. CH;COCH,CH,CH, but-2-ene c o CHCCH,CH, ES chloro-3-ethylheptane FE CH,COOH 2.1 Write down the IUPAC name of compound A. 2.2 Write down the general formula of the homologous series to which compound C belongs. 2.3 Write down the structural formula for compound E. 24 Write down the name of the functional group to which compound D belongs. 25 Draw the structural isomer for compound F 26 Write down the name of the homologous series to which compound B belongs. QUESTION 3 (Start on a new page.) Leamers investigate the evaporation of ethanol, ethanal and etharioic acid, They place 2 ml of each ofthe liquids in a watch glass. They then obsewe the change in the volume of the liquids. ETHANOL ETHANAL ETHANOIC ACID 3.1 Which one of the above liquids would have the largest volume after 10 mins? 3.2 Give an explanation for the answer to QUESTION 3.1, 3.3 Which one of the liquids will have the highest vapour Pressure after 10 mins.? 34 Give an explanation for the answer to QUESTION 3.3, Preparatory Examinations - September 2017 2) (a) (3) a) (2) (1) [0] (1) (3) (a) (3) [8] ‘opyright reserved Please turn overPhysical Sciences P2 7 Preparatory Examinations - September 2017 NSC QUESTION 4 (Start on a new page.) The flow diagram below represents various organic reactions. Study the reactions and answer the questions that follow. PROPANE In a ‘HCl x i HH c H 4.1. State thé reaction condition required for reaction I 4.2. Write down the formula of the catalyst used in reaction II. 43. Propane reacts with excess oxygen. Write down a balanced equation for this reaction using molecular formulae. 4.4 Use structural formulae a write a balanced equation for reaction III. A structural isomer of the product of reaction Tis reacted with butanoic acid, to form an ester. 4.5 Write down the name of the catalyst used in this reaction 4.8 Write down the structural formula of the ester that is formed. 4.7 Name the ester that is formed Question 4.6 QUESTION 5 (Start on a new page.) Ethene is used as a monomer in the preparation of a macromolecule, polyethene. 5.1 Define a macromolecule. 5.2 Name the process by which polyethene is manufactured. 53 Write down the structural formula for the monomer used to prepare polyethene. (1) (1) (3) @) (4) (2) @) 113] (2) a (2) Copyright reserved Please lurn overPhysical Sciences P2 8 Preparatory Examinations - September 2017 NSC QUESTION 6 (Start on a new page.) In investigating the factors that affect the rate of reaction, some leamers react calcium carbonate with excess dilute hydrochloric acid, in a conical flask. The apparatus is setup as shown below. The change in mass of the conical flask and its contents are recorded every minute. ‘The results for this investigation are shown in the table below. [Time (s) o;1}2{/3{/4{[5)6]7), 8] 9 Mass of flask and its contents (g)] 178 176.2174, 11172,7[172,9172,2172,41172,1172,172,4] 6.1 Write down an investigative question for this investigation. @ 6.2 State the independent variable for this investigation. (a) The above table is re-drawn in the special answer sheet provided. 6.3 Complete the table by filling in the values for the mass of CO, produced. 2) 6.4 Plot a graph of mass of CO, produced vs time elapsed. 6) 6.5 Give a reason why the mass of the flask and its contents remains constant after 6 s. 0) 6.6 Calculate the total volume of CO, (g) produced at room temperature (25°C). Assume the molar gas volume of CO, (g) at this temperature is 24,46 dm°. ~ 3) The experiment is now repeated at a higher temperature. The volume and concentration of the HCI and the mass of CaCO, used are the same as in the original investigation. 6.7 On the same system of axes used to draw the graph in QUESTION 6.4, draw a sketch graph of mass of CO, produced vs time elapsed, at the higher temperature. Label this graph as N. (2) 6.8 Use the collision theory to explain the difference between the two graphs obtained. fl (3) [9] | Copyright reserved Please turn overPhysical Sciences P2 9 Preparatory Exeminations - September 2017 NSC QUESTION 7 (Start on a new page.) Ten (10) grams of hydrogen gas and 355 g of chlorine gas are heated together in a sealed 500 cm® container. Equilibrium is reached at 450 °C. He (g)+Ck(g) = 2HCI(g) ; AH <0 The equilibrium constant for this reaction at 450 °C is 60. 7.4 Calculate the mass of chlorine gas present at equilibrium. The temperature is now increased to §50 °C while the volume is kept constant. The system reaches a NEW equilibrium. 7.2 State Le Chatelier's principle. 7.3 ~ Howwill the following be affected in this new equilibrium? Write down only INCREASE, DECREASE or REMAINS THE SAME. 7.3.1 The equilibrium constant. 7.3.2 The volume of He present. 74 Use Le Chatelier’s principle to explain the answer to. QUESTION 7.3.2. QUESTION 8 (Start on a new page.) 8.1 Concentrated hydrochloric acid with a concentration of 10 motdm’ is diluted to form 500 cm’ of a 0,25 moldm™ solution. 8.1.4 Is the diluted hydrochloric acid a strong acid or a weak acid? 8.1.2 Calculate the volume, in cm’, of the concentrated hydrochloric acid that must be used. 8.1.3 Calculate the pH of the 0,25 motdm’ solution of HCI. 82 Calcium carbonate forms a large percentage of sea shells. In order to determine percentage purity of the calcium carbonate in sea’ shells, learners react 5 g of powered sea shells with the 500 cm’ of the diluted hydrochloric acid prepared in QUESTION 8.1. The reaction that takes place is tepresented by the following balanced equation. CaCO; (s) + 2HCI (aq) —— CaCl, (aa) + 1,0) + CO2(9) “The excess HCI is then titrated with 140 cm? of a 0,2 molxim™ solution of sodium hydroxide. 8.2.1 Calculate the mass of CaCO, present in the sample of sea shells. 8.2.2 Calculate the percentage purity of the calcium carbonate in the in the sea shells, (10) @) a) (1) (2) {16] (a) (6) @) @) @) [20] Copyright reserved Please tum overPhysical Sciences P2 10. Preparatory Examinations - September 2017 Nsc QUESTION 9 (Start on a now page.) 91 9.2 »pytight reserved ‘An 800 m athlete, was recently placed first in an intemational event after the original winner was disqualified. This athlete was required to return the silver medal and receive a new gold medal, ‘When the silver medal was returned it had scratch marks, The following apparatus was setup to coat the medal with a thin layer of silver. Electrode P liver Medal ‘AQNO3 solution 8.1.1 Will the medal be the anode or the cathode? 8.12 State the direction in which the current must flow in the extemal Circuit. (State from silver medal to P or P to silver medal) 8.1.3 The concentration ofthe electrolyte solution (AgNO) remains constant during the process. Briefly explain why this happens, 914 Give the symbol for the metal that must be used as electrode An electrochemical cell is setup under standard conditions as shown below, Copper (Cu) is used as the cathode and an unknown metal Y as the anode of the cell. The voltmet connected across the two electrodes shows an initial reading of 2,70 V. ‘Salt Bridge CuCl, 9.2.1 State the standard conditions that are applicable to this cell, 9.2.2 State the energy conversion that takes Place in this cell. 9.2.3 State two functions of the salt bridge. 9.2.4 Use the information given to identify the metal Y. Show all calculations. 9.2.5 Write down the oxidation half reaction, 9.2.6 Write down the cell notation (symbolic Notation) of this cell, Please ten avsor (ty a) 2) (a) (2) (1) (2) 6) @)Physical Sciences P2 4 Preparatory Examinations - September 2017 NSC ‘Some silver nitrate (AgNO,(aq)) is added to the Cu half-cell. 9.2.7 How will the reading on the voltmeter be affected? Write down INCREASE, DECREASE OR REMAIN THE SAME. (a) 9.2.8 Give an explanation for your answer in QUESTION 9.2.7. (3) [24] QUESTION 10 (Start on a new page.) 40.1 The flow diagram below shows two industrial processes that result in the production of a fertilizer, X. Process A Process B N, H, |: NH, step 1] 0, NO step 2] 0, No, sepaf | j— HNO, x 10.1.1. Write down the name of Process A. (4) 10.1.2 Name the method used to obtain the N, (g) used in Process A. (1) 10.1.3 Write down the name of Process B. () 10.1.4 Name the catalyst used in Step 1 of Process B. (1) 10.1.5 Write down the formula of the othier reactant in Step 3 of Process B. (1) 40.1.6. State two reasons why it is necessary to manufacture fertilizers on an industrial scale. (2) 10.1.7. Give the name of fertilizer X that is produced. (1) 40.2. The following information is found on a 50 kg bag of a fertilizer that you purchase for your lawn. 22:10 : 18 (22) 40.2.1 What information can you obtain from these numbers? @ 10.2.2 Calculate the percentage composition of the nutrients in the bag. @) 10.2.3 The number 18 in the ratio above represents a particular element. Briefly discuss the role this element plays in the development and growth of plants. @) [15] TOTAL : 150Physical Sciences P2 12 Preparatory Exeminations - September 2017 NSC DATA FOR PHYSICAL SCIENCES GRADE 12 PAPER 2 (CHEMISTRY} GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12 VRAESTEL 2 (CHEMIE) TABLE 1: PHYSICAL CONSTANTSITABEL 1: FISIESE KONSTANTES: NAMEINAAM SYMBOLISIMBOOL | VALUE/WAARDE ‘Standard pressure < Standaarddruk P 1.018 108 Pa Molar gas volume at STP vo DA anno Molére gesvolume by STD Standard temperature Standaardtemperatuur ft — Taras op Seaer e 16x 10% C ‘Avogadio’ conetant Na 6,02 x 10” mort TABLE 2: FORMULAEITABEL 2: FORMULES PH = 4og(H30°) Kw = [HsO"]]OH] = 1 x 10 atiby 298 K Ey = Eoice ~ Ean (ES Ely Ee orlof : Blat = Enact ~ Eis Ey = Entase — Eons” Copyright reserved Please turn overPreparatory Examinations - September 2017 13 NSC Physical Sciences P2 Bez zee. a7 | on | pW} wa | Sa] 4O | Na | WO | wy | Rd dN | on | ed | UL cor | zor | vor | oor | 6s | ge | ze | 96 | 96 | +6 | 6 | 26 | b6 | 06 ext | ezr | 69+ | er | Sor | e9t | Gab | zab | Zar | osb veh | teh | oFb ny] aA | wi] 4a | OW | Ad | aL | PD | na | ws | Wd PN | 4d | 8D we w | oz | 69 | o9 | zo | 99 | oo | vo | 9 | zo | 9 | 09 | oo | o8 oy jeu gl44 og | ge | 28 Soe |e eee Oe er SaY [eet ORT [eee [ver [rer Tez, [eck |zer | eh ua [a glod glia didd dial si6H [nv jjd | 41 jsO jou | M el |sHalet |ea S| 89 S| os oe lea [ea [ze [is (os _|ez_|ez |se loz |oe | oe jee |zz jus joe | $8 ier fier jezy jeer j6tr [arr |zbr aor [oor |eor | tor 96 |z6 | 16 | 68 | se | 98 ax | 1 Ser saseiuss| ui s/pos elpd gua sina g)oL SiON e|GN | 4Z 3) a4s 2] qa S| *o_ [es [zo [us oo ler ler |e lor ise |o le |e |w lov joe jee |i vite SL PSE EL] Ok | 8 eo pes jes pes [es [es jis [ey | ay) om | oe my ag gles si sv 8]29 2)/e9 a) Uz 2)/N9 g| IN =/09 sed Sua) 49 a) pos ajeo spy xe _[oe [ve [ee | ze | ve [oe joc [ee |sz [oz lex |v [ee 12% lie oz__| 6b oy |sse [ec [ve [ee |i esseuuooje emoneyes epsepeueg ye | & wy j2og)s tid Ris cava sseu 9]WOye BAREio4 eyeUupKosddy BW 3) eN er_ {ar {sv |gp |r | eb 1 ze__| tb oz [er jer |v [a ju s'eo 6 Z wn | 4a z/OS) NE OR Gs pooquis_| he | zeummebeuonyers eg as oF 6 8 L 9 s joquixs 2 eh AyngeBeucnse73 ¥ £ v + 2H HS z leyeBurooyy TALNFTSIAZA L Joquinu sWoTy a” a WwW WwW www w w piaseeciyWeateat-{Getece' eeteet 1 attest 7 'steset 1 atssed | Sescim’ | esate eitesse. letasei’ ttessh, Cestsee. eesseee.autesssa.d z + NAWITA NVA T3EVL ayFIGOMAd FIG: TSVL ‘SLNSNA1S JO A TAVL Ddonwad SL ‘¢ 318V1 Please turn overPhysical Sciences P2 14 Preparatory Examinations - September 2017 NSC TABLE 4A: STANDARD REDUCTION POTENTIALS. TABEL 44: STANDAARD-REDUKSIEPOTENSIALE Half-reactions/Halfreaksies F- cot HeQ2+ 2H #2e- 2 -2H0 MnO; +8Ht+5e a Mn +aieo | +161 Cug +26 = 2c +138 CHOF + 14H +6e = 26+ THO | +433 Ong) + 4H*+4e- 4. 2H20 44,23 MnO2+4H*+2e- Mn? + 2H20- +123 ‘ Pe +2 Lt +120 Br() +20 28 +107 NO, +4H*+3e = NOG@)+2H20 | +096 ey Hg? +20 2 Hg +025 & ‘@ Agtte ow Ag +080 g z NO3 +2H*+e" 2 NOx9)+H20 | +0,80 g g Fev+e 2 Foe +077 & g 02{g) +2H"+ 26” HeO2 +068 § 5 ht2e = a +054 g § cute 2 cu +052 3 3 SO2+4H+4e° = S+2H0 +045 2 g 2He0+02+ 4a 40H +040 3 ° C420 = +0334 s g SOF 44H 426 = Souq) + 24:0] +017 5 g Cute cut +0.16 3 2 sat t2e LS +018 e 3 S+2H" +267» HS(@) $0.14 2 &§ 2H +20 Hela) 0,00 2 Fetrde a Fe 0,06 = 3 Po +20 Pb 0.13 2 > Sni*+2e" Sn -0.14 3 & NP 20 Ni -027 3 s crete To» fa g x Co +26 Cd 0.49 2 = Cmte 4 cr -0.44 3 ie Fe*+2e = Fe -0,44 2 3 or +36 2 cr -0,74 z 8 2426 4 Zn -0,76 z 2100+ 20" = Hg) +20H- | —0.83 Cr +2e- Cr 0,91 7 Mn 426° Mn =1,18 AON 36 a AL = 1,66 Mg" +20 = Mg ~2,38 Notte a Na -271 CaP +20 a Ca -287 SH420 2 SF ~ 269 Batts 2e = Ba Cree = cs Kee 2 Kk =u Uitte L—__ibse = | 3.05 | Copyright reserved Please turn overPhysical Sciences P2 15 Preparatory Examinations - September 2017 Nsc TABLE 4B: STANDARD REDUCTION POTENTIALS TABEL 4B: STANDAARD-REDUKSIEPOTENSIALE Half-reactions/Halfreaksies wee = Kite = K cette = Cs Bat +2e Ba Sr+2e = St Cat #20 Ca Netter = Na Mg? +2e = Ma Att +36 AL Mit +20 = Ma Or +20 = Cr 2HLO +22 = Halg) + 20H" Zi +20 = Zn cpt +3e" Cr Fet+2e w Fe Cte wm Cr Ce +260 = Cd Co 420° = CO NE 207 oN Snt+2e = Sm Pb +2e = Pb Feite3e = Fe 2H +20 = Haig) S+2Ht+2e = H:Si0) Sntt+2e = Sni cutee = Cut 44H +26 = SOxg) +2420 | +017 Gu +26 = Cu +034 2HO+0r+4e = 40H +040 S02+4H*tde" = S+ 24:0 +046 Cute = Cu +052 let2e me 2h +084 nig) + 2H" +26" Hae +068 Fette = Fem +077 NOS #2Ht+e = NOX) +H:O | +080 Agtite = Ag +080 Hg +e = Hal +085 NOZ +4H' +36 2 NOG) +2H20 | +0,98 Brat) +20 = 28 +107 Perde = Pt +120 MnO2+ 4H +2e- = Mn#*#2H0 | +1,23 Ox(g) + 4H" +4e7 = 2H: +123, cno® + tat ree = 2cet+ THO | 41,99 Chig)+2e" = 26t $4.36 MnO] + 8H +50" = Mn+ AHO | 44.54 Hao + 2H e = 240 +7 Cotte wm CoM +481 Fog) +20 a OF +287 Please turn overPhysival Sciences P2 Preparatory Examinations - September 2017 NSC Copyright reserved Please turn overPhysical Sciences P2 Preparatory Examinations - September 2017 Nsc Name: Answer sheet Q6.4 and Q6.7 [rime (s) ofi1[2]3[4l[sl[e|7|sle [Mass of flask and its contents (g)| 178 |176,21174, 1172, 7/172, 3172.2) (72,1172, 11172, 1172, 1] jass of CO, (g) produced (9) |