Jee Advanced 4 Paper 2
Jee Advanced 4 Paper 2
1. The question paper consists of 3 Subject (Subject I: Physics, Subject II: Chemistry, Subject III: Mathematics).
Each Part has two sections (Section 1 & Section 2).
Type A contains SIX (06) Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B),(C)
and (D), out of which ONE OR MORE THAN ONE CHOICE is correct.
Type B contains THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions. Each
question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
3. Section 2 contains 6 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical
value, then round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero
in the decimal places. In the OMR, do not bubble the sign for positive values. However, for negative values,
Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
4. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your Test Code,
Roll No. and Group properly in the space given in the ANSWER SHEET.
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MARKING SCHEME
SECTION-1 | Type A
This section contains SIX (06) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is
(are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers,
then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.
SECTION-1 | Type B
This section contains THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme;
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
SECTION - 2
This section contains 6 Integer Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical
value, then round-off the value to TWO decimal places. If the answer is an Integer value, then do not
add zero in the decimal places. In the OMR, do not bubble the sign for positive values. However, for
negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct Integer value is entered. There is NO negative marking.
Zero Marks: 0 In all other cases.
SECTION-1 | Type A
This section consists of 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.
1. A hemispherical wedge of radius R is kept on a rough horizontal floor. A small block of mass m is released
from the highest position and it slides down to the bottom along the curved surface. When radius vector
makes an angle with the verticle, speed of the block, Normal reaction of the wedge on block, friction by
the floor on the wedge, acceleration of block are v, N, f and a respectively. Surface between the block and
wedge is smooth. Choose the correct graph(s) [Assume wedge remains at rest throughout the motion]
(A) (B)
(C) (D)
2. Two flasks in the shape of truncated cone have equal capacity, same base area, but different heights. If both
the flasks are filled with water upto the brim, choose the correct statement(s):
3. A load of 5 kg is to be raised by a rope from rest to rest through a height 30 m in least time. The maximum
tension that rope can bear is 150 N. Choose correct alternative(s) : [Take g 10m / s 2 ]
(A) Time is 3s
(B) Maximum speed of load is 20 m/s
(C) Tension in the rope is zero for 2s
(D) Speed of load increases for 1.5s
4. The ends of a rod of length are maintained at temperature 20 and 0 . The thermal conductivity of the
rod at a point is given by K , where is a positive constant and is temperature at that point. If heat
current along the rod is iH and variation of temperature with x (Distance from hotter end) is ( x) then :
A An(2) 0 x
(A) iH (B) iH (C) ( x) 20 .2 x / (D) ( x) 20
5. Four identical masses with mass m each are connected by light rods of length a each to form a rigid square
structure. This structure is placed on a smooth horizontal surface and made to rotate with constant angular
velocity 0 about a fixed vertical axis passing through one of the masses. Force exerted by structure on the
axis is F0 . When the structure is in position shown another mass m moving with velocity V0 ˆj along the
surface hits the mass B and sticks to it. Choose the correct alternative(s)
(A) F0 2 2m02 a
20
(B) Just after impact angular velocity of the structure is
3
4m02 a
(C) Force exerted by structure on the axis after impact is
3
(D) Impulse on mass m (which hit mass B) during collision is 2 2m0 a / 3
6. A cylindrical piston of length and radius R is made to rotate with constant angular velocity 0 inside a
cylindrical tube filled with oil. The clearance between the piston and tube is h( R), is coefficient of
viscosity of oil. Choose the correct option(s).
R0
(A) Shearing stress on the piston is
h
20R 2
(B) External Torque required to rotate the piston is
h
202R3
(C) Power delivered by external agent in rotating the piston is
h
20 R
(D) Shearing stress on the piston is
h
SECTION-1 | Type B
This section consists of THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions. Each question
has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
u v0 v0 u u
(A) n(2) (B) n(2) (C) n(2) (D) 1 n(5)
v0 u u v0
J0 6N s
0 1m
m 1kg
9. Which of the following quantities remain conserved for the disc subsequently.
(A) Speed (B) Angular speed about O
(C) Angular momentum obout O (D) Linear momentum
10. If maximum elongation in the spring is 20 cm in subsequent motion, spring constant k of the spring is:
N N N N
(A) 225 (B) 275 (C) 175 (D) 250
m m m m
SPACE FOR ROUGH WORK
SECTION-2
This section consists of 6 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value, then round-
off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In the
OMR, do not bubble the sign for positive values. However, for negative values, Θ sign should be bubbled. (Example:
6, 81, 1.50, 3.25, 0.08)
1. A particle of mass ‘m’ having collided with a stationary particle of mass ‘M’ deviated by an angle rad
2
where as the particle of mass ‘M’ recoiled at an angle of 30° to the direction of the initial motion of the
particle ‘m’. If after the collision there is 40% loss in kinetic energy of the two particle system, find M/m.
2. A sphere of mass m falls symmetrically on a set of three hemispheres placed in contact with each other on
m
smooth horizontal ground from a height h. Mass of each hemisphere is and radius of each body is R.
2
Neglect any rebounding of hemisphere. If sphere comes to rest after the simultaneous collision with three
hemispheres then ratio of KE of sphere before collision and KE of any hemisphere after collision is p then
find the value of p.
3. In the figure shown a block B of mass m can slide on a fixed horizontal smooth plane. A solid sphere A of
g
radius of the same mass rolls without sliding on the block B. The angular acceleration of the sphere is ,
r
find the value of .
4. A perfectly elastic ball is thrown from the foot of a smooth plane inclined at an angle 37° to the horizontal. If
after striking the plane at a distance 12m from the point of projection, it rebounds and retraces its former
path, speed of projection (in m/s) is____________.
5. A lift is moving up with a constant retardation of 2m / s 2 . When its upward velocity is 5m/s, a boy in the lift
tosses a coin, imparting it an upward velocity of 3m/s, w.r.t. himself. His fingers at the moment of toss are
midway between floor and ceiling, whose total height is 2m. Displacement of coin when it hits the floor is x
metre (in earth frame). Value of x is ( g 10m / s 2 )
6. Hailstones falling vertically with a speed of 10m / s , hit the wind screen (wind screen makes an angle 30°
with the horizontal) of a moving car and rebound elastically. The velocity of the car, if the driver finds the
hailstones rebound vertically after striking is x m/s find the value of x.
SECTION-1 | Type A
This section consists of 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.
1. Which of following chromium compounds and oxidation state of Cr atom in this compound is/are correct?
(A) CrO5 , +6 state of Cr (B) Cr(O 2 )34 , + 5 state of Cr
(C) CrO34 , + 5 state of Cr (D) [Cr(H 2O)6 ]Cl3 , + 3 state of Cr
2. Which of following compound/s shows back bonding?
Θ
(A) BF4 (B) B2 H 6 (C) C Cl3 (D) BF2 (NH 2 )
3. Select correct order/s of electron affinity (E.A.).
(A) N<P (B) OS (C) F < Cl (D) Li < Be
4. Select the correct pair/s of organic compound and their IUPAC names.
(A) CH C CH CH 2 , But 1 en 3 yne
(B) CH 3 C C CH CH CH 2 CH3 , Hex 4 en 2 yne
(C)
(D)
5. One mole of a gas obeying the equation P(V-b) = RT. Which of the following is true for this gas?
(A) The gas have negligible molar excluded volume
(B) The gas have negligible strength of intermolecular forces
(C) The gas have its compressibility factor Z > 1 for the given pressure (P) and temperature (T)
(D) Compressibility factor (Z) of the gas will vary linearly with pressure (P)
SECTION-1 | Type B
This section consists of THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions. Each question
has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
(A) (B)
(C) (D)
10. Using the given pH curve, identify K a value of the weak acid (HX).
(C) S 0 , S 0 (D) S 0 , S 0 , | S | | S |
sys surr. sys surr. sys surr.
12. Given that in a process H 20 kJ / mole , S 100 J / K mole then value of S at 400K will be:
sys sys univ
SECTION-2
This section consists of 6 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value, then round-
off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In the
OMR, do not bubble the sign for positive values. However, for negative values, Θ sign should be bubbled. (Example:
6, 81, 1.50, 3.25, 0.08)
1. From the following list of species ; total number of species in which central atom is showing hybridization in
certain excited state and not in ground state?
NH3 , CH 4 , PCl5 ,SF6 , XeO3F2 , BF3 , BrF5 , IO56 ,SNF3
2. An energetic photon of wavelength strikes to a hydrogen atom (in its ground state). The collision cause
dislodging of the electron. The free electron moves with kinetic energy equal to 1.4 eV. If energy of an
13.6
electron in a hydrogen atom is given as E n eV / atom (n = principal quantum number of the
n2
shell). Value of in nm is (Round off your answer to nearest integer). Take : Planck’s constant
h 6.67 1034 J sec , speed of light C 3 108 m / sec, 1eV = 1.6 1019 J
3. Mn 2 is oxidised to MnO 4 on treatment with S2O82 . Moles of Mn 2 consumed per mole of S2O82 is:
5. Excess of NH 4HS(s) is placed inside a chamber filled with NH3 (g) at 2 atm. On heating the NH 4HS
starts to decompose by following reaction.
NH3 (g) H 2S(g)
NH 4HS(s)
2
At equilibrium total pressure of the gaseous mixture reaches 5 atm. K p for the reaction (in atm ) is:
6. Sum of number of peroxide bonds in 1 molecule of each of the following species is:
H 2O 2 NO 4 H 2SO5 H 2S2O8 CrO5
SECTION-1 | Type A
This section consists of 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.
1. Two particles start from the point 2 , 1 , one moving 2 units along the line x y 1 and the other 5 units
along the line x 2 y 4 . If the particles move towards increasing y, then their new positions are given by
points L & M . Choose those options which have either of x or y coordinates of any of the points L or M .
(A) 2 2 (B) 2 1 (C) 2 52 (D) 5 1
3. For any sequence of real numbers A a1 , a2 , a3 ,........ , define A to be the sequence
a2 a1 , a3 a2 , a4 a3 ,........
Suppose that all of the terms of the sequence A are 1, and that a19 a92 0.
Then
(A) a1 820 (B) a42 575
(C) S5 3335 (D) Number of divisors of S5 will be 8.
10
x 1 x 1
4. The coefficient of the term independent of x in the expansion of 2 3 is same as:
x x 1 x x1 2
13
10
(A) C3
(B) Number of ways of selecting 3 people out of 10
(C) Number of ways of arranging 3 identical ‘+’ signs and 7 identical ‘–’ signs
10
(D) C4
5. If a1, a2 , a3 ,.....an is sequence of positive number which are in A.P. with common difference d and
a1 a4 a7 .... a16 147. Then:
(A) a1 a6 a11 a16 98 (B) a1 a16 49
16
49
(C) a1 a4 a11 a16 6a1 45 (D) Maximum value of a1 a2 .....a16 is
2
SECTION-1 | Type B
This section consists of THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions. Each question
has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
12. A straight line through P (2, b d 1), is inclined at an angle of 60° anticlockwise with positive y-axis. The
coordinates of one of the points on it at a distance (b + d) units from point P is (b, d obtained from previous
question) :
(A) (2 2 3, 5) (B) (3 2 3, 3) (C) (2 3 2, 4) (D) (2 3 2, 3)
SECTION-2
This section consists of 6 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value, then round-
off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In the
OMR, do not bubble the sign for positive values. However, for negative values, Θ sign should be bubbled. (Example:
6, 81, 1.50, 3.25, 0.08)
3. If cos
3 5
are the roots of the equation 8 x 3 4 x 2 4 x 1 0 ,then the value of
, cos , cos
7 7 7
3 3
2 2r 1 2r 1
tan cot 2
is :
7 r 1 7
r 1
4. Number of permutations of 1, 2, 3, 4, 5, 6, 7, 8, 9 taken all at a time, such that the digit 1 appears somewhere
to the right of 2, 3 appears somewhere to the left of 4 and 5 appears in between (not
necessarily exactly in middle) of 6 & 7 is k (7!) , then k is _______.
n
6.
Let 5 2 6 p f , where n N and p N and 0 < f < 1, then the absolute value of
f 2 f pf p is _____ .