—_ ee r UES NEM ean oul: CLASSIFICATION OF SOLIDS IL 2 as 4 5 * (@) hydrogen bonds Which of the following properties does not define 4 crystalline solid? (a) When cut into picces, have irregular surface (b) Isotropic in nature (©) Anisotropic in nature (A) Both (a) and (by Solid CO, is an example of (a) covalent solid (©) molecular solid (b) metallic solid (d) ionic solid. Which of the follow ag statements is trac? (a) Molecular erystals are very hard and incompressible. (b) “Ionic crystals have very low volatil (©) Metallic bond is directional and rigi (@) Boron nitride has an ionic erystal structure. Wax is an example of (a) ionic crystal (c) molecular crystal (b) covalent exystal (@)_ metallic crystal. Graphite is a soft solid lubricant, extremely difficult 10 | melt. The reason for this anomalous behaviour is that graphite (a) is a non-crystalline substance (b) is an allotropic form of diamond (©) has molecules of variable molecular masses like polymers (@) has carbon atoms arranged in large plates of rings of strong bound cerbon atoms with weak interplate bonds. Which one has the highest melting point? (a) Tonic crystal (b) Molecular crystal (©) Covalent crystal (d)_- Metallic erystal Which of the following is a pseudo solid? (a) CaF; (b) Glass () NaCl (d)_ All of these Which solid will have weakest intermolecular forces? (a) Ice (b) Phosphorus (c) Naphthalene (d) Sodium fuoride Which of the following pairs is not isomorphous? (a) BaSQ,,KMnO, —_()_KCIO,, KBF, (c) FeSO,-7H,0, MgSO,-7H,0 (d) NaCiO3, NaNOy ‘The interparticle forces in solid hydrogen are (b) covalent bonds (c) coordinate. bonds (d) van der Waals forces. 11. Which among the followin 14, | 18, . | 20. Will show ani (b) Harium chig He (a) Glass : (HM) Poper ie (o) Wood ne of the following forms & molec, wh solidified? (a) Silicon carbide (ce) Rock salt “The pure erystalline substance en hested grag forms a vuabid liquid at constant temperate gag higher temperature, turbidity Completely disp, Ichaviour is a characteristic OF substance fo () liquid ery @) isomorphous sa (0) Calcium ys, (a) Meth (a) allotropie crystals (6) isomeric erystals The major binding force in diamond, silicon aq is (a) electrostatic force (6) covalent bond force (b) clectrical ataction (a) van der Waals The hardest substance among the follo (a) Bec ) grap (©) titanium @) sic ‘The material used in the solar cells contains (a) C (b) Si (S$ «) Ti For two ionic solids CaQ and Kl, identify the wg statement among the following. (a) CaO has high melting point (b) Lattice energy of CaO is much larger than tn KL (6) Klis soluble in benzene (@) None of these, Which of the following statements about amorph solids is incorrect? (a) They melt over a range of tempers (b) They are anisotropic. (e) There is no orderly arran; (a) They are rigid and incompressible. ent of particles Which of the following is not correct for ion (a) They possess high melting point. (b) They all are electrolyte. (c) They exhibit the property of isomosphis™™ (d) They exhibit directional propertics of the bon alline variety of (b) sodium sificate (d) silicon Quartz is a (a) silicon carbide Ae) silica Scanned with CamScannersolid State cRYSTAL LATTICE, UNIT CELL AND CLOSED pACKED STRUCTURES 3}, The number of unit cells in 88.5 @) 6x10" () 15 = 10" of NaCl is nearly (b) 3s 102 (a) OS «10 22, Srusture ofa mina oxie is eubie close-packed (cep), The cabs nicl oma oxide amps ne One fouath ofthe tetrahedral vos ane accupie by divalent metal and the octaheural vis are occupied by a monovalent metal , The formula ofthe oxide is () 4:80 (b) ABO, (0) AND, (8) A,Og 23, Total volume of atoms present in a face-centred cubie wit cell of « metal is (ris atomic radius) os aw Boo 2 1 a) Pre ob) Sw (ey Pap © 5 & Se Be wy 24 In fee lattice of NaCl structure, if the diameter of Na* is x, and the radius of C1” is y, then the edge length of [NaCl in the crystal is (a) 22 (b) rey (xt 2y (@) none of these, 28 The second order Bragy diffraction of X-rays with = 1.00 A from a set of parallel planes in a metal occurs a an angle of 60". The distance between the scattering planes in the erystal is (2) OS75A (b) LODA (©) 200A) 145A 26, In spinel structure, O? ions are cubic closed packed, In corundum, oxide ions have h 9 A hinary solid (AS) has a zine blende structure with 4 ions constituting the lattice and A” ions oceupying 25% tetrahedral holes, The formula ofthe solid is () AB, (b) AB 0) Ay (d) AB mngement, What Percentage of actaedal voi are occupied by AI? (a) 33% — (by 50% (0) 66% (d) 78 Cl erystallises in the same type of itice as NaCI does TE tal ye 807 thon the rato ofthe sides of unit cell for KCI to that for NaCl is (a) La (b) 0.8 (c) 04 (4) 17 Atoms of element 1 form Ap Intice and those of the element 4 occupy 2/3" of tetrahedral voids. The ratio of number of atoms of 4 and B in the compound is @) 2:3) 4:3] 3:4 (43:2 Which of the following arrangements correctly represents hexagonal and cubic close packed structure respectively? (8) ABCABC 4 and ABAD (D) ABAB soo and ACBACB (©) Both have ABA@...... arrangement. (d) Boh have ABCABC ..... arrangement. Ratio ofthe total volume of bce to simple eubie structure is (9) 33:8) 8:3v3 (© AEs @) 1:25 The ionic radii of Rb“ and I> are 1.46 and 2.16 A shoes VA ofthese keaneoecmpetby 4 | Sey. hemos yuslenpct sme xin) cations and 1/2 of the octahedral holes are occupied by is cations 8°". The general formula of this compound is (2) CsCl ype @) NaCl ype (3) AsB0, (y' 48,0, (6) Z08 wpe (@) Cay ype (©) ABO @) 42,0 38. The crystal system of a compound with unit cel! 21. MW rsir. ties between 0.414 to 0.732, the cation will dimensions a ~ 0.387, 4 ~ 0.387, anc = 0.504 nm and Gee Hy sexagnt (a) cubic hexagonal vt 1 void : ihctacs Gea citeaesca (6) orthorhombic (@) thombshede 28 In a nonmal spine type structure the oxide ions are 3% Petentage of fee space in cuie close packed Sorte etwas a tee 1 Soke a ocepiad and in body centred packed structure are respectively by Zn‘* jons and 50% of octahedral holes are occupied. 7 qa ai on a a ee by Fe” ions, The formula of the compound is 20% * Loc () Zn3Fe204 () ZnFe,0, 40. TiO, isa well known example of (e¥ ZnFe,0, (8) ZaFe;02 () triclinic system (b)_ tetragonal system moclinic m (d) none of these. 29. tmacompound, atoms of element ¥ form cep tatce and | (©) monoclinic system (d)_none of these. ‘those of clement occupy 2/3 of tetrahedral voids. The | 41. Which one of the following is correct about ferrit formula of the compound will be (2) These possess formula 48,0, (where is divalent ON © UH OG KY and B is trivalent cation). 30, Ina face centred cubic arrangement of A and 8 atoms, 0 Nad pee wine structure, atoms are at the comers of the unit cell and atoms 0 MEA, Feit at the face centres. One of the 4 ators is missing from (2) All of the al ne corner in the unit cell. The simplest formula of the 42, compound is (0) 48 CsBr has ace structure with edge length 4.3 A, The shortest inter-ionic distance in between Cs” and Bris (a) 3.72 (b) 1.86 fe) 744) AS (b) ABy (©) AB (A) AnsBs ee Scanned with CamScanner10 43, Which of the following compounds have an antifluorite structure? | (@) KO tb) BaF, (@) CuBr) Til 44, Ina solid AB having the NaCI structure, 4 atoms occupy the comers of the cubie unit eel. Iall the face centred atoms along one of the axes are removed, then the resultant stoichiometry of the solid is (a) AB; (b) AB (6) Ay) AB 45, The total number of atoms required to form a ust eel of bec lattice will be () 6 8 oo wr 46. The unit cell with the siructure given below represents rystal system. soe fo (a) cubic (b) onthorhombie (6) tetragonal (8) trigonal 47, Acompound formed by elements 4 and B erystallises in cubic structure in which 4 atoms are atthe comers ofthe ‘cube while B atoms are atthe centre of cube. Formula of the compound is (0) 4B, (b) AB, (@) AB, (ABD 48, Number of unit cells in 4g of X (atomic mass = 40) which cexystallises in be pattem is (Ny = Avogadro number) (a) O.1Nq (b) 2*0.1.N LNs > as () 2* Ng 49, Which is not the correct statement for jonie solids in which positive and negative ions ate held by strong electrostatic attractive forces? (8) The radius ratio r./r_ increases as coordination ‘number increases. (b) Asthe difference in size of ons increases, coordination ‘number increases. (©) When coordination number is eight, rr rato lies \ between 0.225 to 0.414. (@ In ionie solid of the type AX (ZnS, Wurzite), the coordination number of Zn’” and S*- respectively are 4 and 4. In hexagonal close packing of spheres in three dimensions (a) In one unit cell there are 12 octahedral voids and all are completely inside the unit cell (b)"In one unit cell there are six octshedral voids and all, are completely inside the unit cell (€) In one unit cel there are six octahedral voids out of | which three are completely inside the uit ell nd ‘other three are from contributions of octabedral voids which are partially inside the unit cell si. 2, Wie none unit cell there are 12tetrahoy, completely inside the unit cll, @ Wa “a, | ‘The arrangement of the fst 180 layer, op, dither, in cp aed CCP AETOMBETENS jy tly same in both cases {by pany same and partly diferent {c) ferent from each other (a) nothing definite {a) exac ‘Antifuorite structure is derived from Mr by trey (a) heating fuorite crystal lattice {by subjecting Muorite SCI 0 igh prey {6} interchanging the postions of posite ag jons inthe lattice (4) one of these. ep ‘The arrangement ABC ABC * (a) octahedral close packing (b) hexagonal close pa (6) tetrahedral close packing | (4) cubic close packing In hep arrangement, the coordination number ©8 (6 (oy 12 10 Foran octahedral arrangement the lowest radius ri, (a) 0.155 (b) 0.732 (©) OAM (4) oxy “The radius ofthe Na" is 95 pn and that of Cl pm, Predict the coordination number of N @ 4 (6) 6 os (a). Unpredictable Analloy of copper, silver and gold is found to hive consituting the cep Inte, silver atoms occupy centres and gold atom is present at body cent, ay has a formula (a) CuAg:Au (o) CuAgyAu (b) CupAgaAu (d) CuAgau At the limiting value of radius ratio r, 5 (2) forces of attraction are larger than the fos repulsi (©) forces of atraction are smaller than the fe? repulsion (6) forces of attraction and repulsion are just 0 (@) none of these. ‘A binary solid (4°B°) has a rock salt structure #62 length is $00 pm and radius of cation is 75 pm, radius of anion is (@)_ 100 pm (b) 125 pm (©) 250 pm (@) 325 pm A solid bas a bec structure. If the distance of 8 approach between the two atoms is 1.73 A. The tse of the cell is (3) 200 pm (©) 1822 pm 0) V5 /V2pm @ Scanned with CamScanner