SDS Kapci 200230 GB
SDS Kapci 200230 GB
2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
Repr. 2 H361d Suspected of damaging the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the GB CLP regulation.
· Hazard pictograms
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H373 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal if swallowed and enters airways.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see on this label).
P331 Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 108-88-3 toluene 10-25%
EINECS: 203-625-9 Flam. Liq. 2, H225; Repr. 2, H361d; STOT RE 2, H373; Asp.
Reg.nr.: 01-2119471310-51-0036 Tox. 1, H304; Skin Irrit. 2, H315; STOT SE 3, H336
CAS: 123-86-4 N-Butyl acetate 2.5-10%
EINECS: 204-658-1 Flam. Liq. 3, H226; STOT SE 3, H336
Reg.nr.: 01-2119485493-29-0002
CAS: 111-76-2 2-butoxyethanol 2.5-10%
EINECS: 203-905-0 Acute Tox. 3, H311; Acute Tox. 4, H302; Acute Tox. 4, H332;
Skin Irrit. 2, H315; Eye Irrit. 2, H319
CAS: 78-83-1 butanol 2.5%
EINECS: 201-148-0 Flam. Liq. 3, H226; Eye Dam. 1, H318; Skin Irrit. 2, H315;
STOT SE 3, H335-H336
CAS: 78-93-3 butanone 2.5%
EINECS: 201-159-0 Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336
· Additional information: For the wording of the listed hazard phrases refer to section 16.
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· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.
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· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
108-88-3 toluene
WEL Short-term value: 384 mg/m³, 100 ppm
Long-term value: 191 mg/m³, 50 ppm
Sk
123-86-4 N-Butyl acetate
WEL Short-term value: 966 mg/m³, 200 ppm
Long-term value: 724 mg/m³, 150 ppm
111-76-2 2-butoxyethanol
WEL Short-term value: 246 mg/m³, 50 ppm
Long-term value: 123 mg/m³, 25 ppm
Sk, BMGV
78-83-1 butanol
WEL Short-term value: 231 mg/m³, 75 ppm
Long-term value: 154 mg/m³, 50 ppm
78-93-3 butanone
WEL Short-term value: 899 mg/m³, 300 ppm
Long-term value: 600 mg/m³, 200 ppm
Sk, BMGV
· Ingredients with biological limit values:
111-76-2 2-butoxyethanol
BMGV 240 mmol/mol creatinine
Medium: urine
Sampling time: post shift
Parameter: butoxyacetic acid
78-93-3 butanone
BMGV 70 µmol/L
Medium: urine
Sampling time: post shift
Parameter: butan-2-one
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
(Contd. on page 5)
GB
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· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
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11 Toxicological information
· Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
111-76-2 2-butoxyethanol
Oral LD50 1,200 mg/kg (ATE)
1,480 mg/kg (rat)
Dermal LD50 400 mg/kg (rab)
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Additional toxicological information:
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity
Suspected of damaging the unborn child.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure.
· Aspiration hazard
May be fatal if swallowed and enters airways.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
(Contd. on page 7)
GB
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· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1263
· UN proper shipping name
· ADR 1263 PAINT
· IMDG, IATA PAINT
· Transport hazard class(es)
· ADR, IMDG, IATA
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15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 5,000 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 50,000 t
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
· Department issuing SDS: Quality Assurance & Environment Departement
· Contact: Chemist / Mohamed Khalil
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Flam. Liq. 3: Flammable liquids – Category 3
Acute Tox. 4: Acute toxicity – Category 4
Acute Tox. 3: Acute toxicity – Category 3
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Repr. 2: Reproductive toxicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Asp. Tox. 1: Aspiration hazard – Category 1
GB
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