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Thermodynamics Assignment

This document contains 17 chemistry problems involving calculations of various thermodynamic quantities like internal energy, work, heat, enthalpy, and free energy. The problems cover topics like ideal gases, heat of combustion reactions using bomb calorimetry, phase changes, and standard enthalpy of reaction calculations using standard heats of formation. The goal is to use the provided data and thermodynamic equations to solve for the requested thermodynamic quantities.

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Saransh Kumar
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© © All Rights Reserved
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Download as PDF, TXT or read online on Scribd
33 views

Thermodynamics Assignment

This document contains 17 chemistry problems involving calculations of various thermodynamic quantities like internal energy, work, heat, enthalpy, and free energy. The problems cover topics like ideal gases, heat of combustion reactions using bomb calorimetry, phase changes, and standard enthalpy of reaction calculations using standard heats of formation. The goal is to use the provided data and thermodynamic equations to solve for the requested thermodynamic quantities.

Uploaded by

Saransh Kumar
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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ASTER PUBLIC SCHOOL (GNW)

CLASS- XI, SUBJECT- CHEMISTRY


1. A system absorb 400 J of heat and does work equivalent to 150 J on the surrounding. Calculate the
change in internal energy of the system.
2. A gas expand against a constant pressure of one atm from a volume of 5L to 10L. During the process
system absorb 400 J of heat from the surroundings. Calculate the change in internal energy of the system.
3. If 5.0 L cylinder contained 10 mole of hydrogen gas at 27°C. Due to leakage, entire gas escape into the
atmosphere. The atmospheric pressure is 1 atm. Calculate the work done by the gas assuming hydrogen to
be an ideal gas.
4. The enthalpy change (∆H) for the reaction N2(g) + 3H2(g) →2NH3(g)
Is -92.38 KJ at 298 K. What is ∆U at 298K?
5. Calculate the different between the heat of reaction at constant pressure and volume for the reaction
2C6H6(l) + 15O2(g) →12CO2(g) + 6H2O(l) at 25°C in KJ.
6. The heat of combustion of methane CH4(g) is measured in a bomb calorimeter at 298.2 K and is found
to be -885.50 KJ/mil. Find the value of enthalpy change ∆H.
7. 2 mole of an ideal gas at 2.0 atm and 25° C are compressed isothermally to 1/3 of its volume by an
external pressure of 6 atm. Calculate heat, work done and change in internal energy.
8. A system has internal energy 500 J. If 500 aj of heat is supplied to it and at the same time it does 300 J
of work. Calculate the internal energy of the system in the new state.
9. Heat of combustion of methane at constant volume and 298 K has been found to be 885 Kjmol-¹.
Calculate the enthalpy of combustion under constant pressure. .
10. 0.16 g of methane was subjected to combustion at 27°C in a bomb calorimeter. The temperature of
calorimeter system was found to be raised by 0.5° C. Calculate the heat of combustion of methane at
constant volume and at constant pressure. The thermal capacity of calorimeter system is 17.7 KJ K-¹.
11. Heat of combustion of methane at constant volume and at 298 K has been found to be -885 KJ mol-¹.
Calculate the enthalpy of its combustion under constant pressure condition.
12. When 2 gram of benzene are burnt in a bomb calorimeter, the heat produced is 83.6 Kj at 298 K.
Calculate the enthalpy of combustion of benzene.
13. 400 cm³of a gas are compressed to half of it’s volume by applying a pressure of 0.5 atm. During the
process 6.5 j of heat flows out to the surroundings. Calculate ∆U of the system.
14. Calculate the work done in calories when 5 moled of an ideal gas are compressed isothermally andd
reversibly from a pressure of 1.5 atm to 15 atm at 27°C.
15. 10 moles of a gas are heated at constant volume from 20°C to 30°C. Calculate the change in the
internal energy of the gas. The molar heat capacity of the gas at constant pressure, Cp=6.82 cal K-¹mol-¹
and R= 1.987 calK-¹mol-¹.
16. For the reaction, NH4Cl(s) →NH3(g) + HCl(g) at 25°C, enthalpy change ∆H=+177 KJ/mil and
entropy change ∆S=+285 J/k mol. Calculate the free energy change at 25°C and predict wheather the
reaction is spontaneous or not.
17. Calculate the standard enthalpy change for the reaction: CH4(g) + 2O2(g) →CO2(g) + 2H2O(l) ,
given that the standard heats of formation of CH4(g), CO2(g) and H2O(l) are -74.91 KJ mol-¹, -394.12 KJ
mol-¹ and -286.31 KJ mol-¹ respectively.

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