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Matrix Acidizing of Sandstone5

This document discusses matrix acidizing of sandstones to treat well damage from invasion of solids. It provides an example where permeability in the damaged zone of a well is reduced due to increased concentration of clays. Simulations show that injecting the same acid at the same rate results in less penetration due to more acid being used to dissolve damaging materials in the first few inches of the formation. Matrix acidizing requires carefully evaluating the well damage and designing treatments tailored to the specific well situation.

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0% found this document useful (0 votes)
25 views

Matrix Acidizing of Sandstone5

This document discusses matrix acidizing of sandstones to treat well damage from invasion of solids. It provides an example where permeability in the damaged zone of a well is reduced due to increased concentration of clays. Simulations show that injecting the same acid at the same rate results in less penetration due to more acid being used to dissolve damaging materials in the first few inches of the formation. Matrix acidizing requires carefully evaluating the well damage and designing treatments tailored to the specific well situation.

Uploaded by

Helya
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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MATRIX AUDIZING OF SmDSTONES

Using the samereservoir dataasin the previous exam-


ple, assumethat the well has beendamagedby invasion
of solids. A well test gives a skin of +8 for this forma-
tion and a depth of damageequal to 3 in. is assumed.
Therefore, the permeability of the damagedzone is cal-
culatedas 10 md. The dissolutionmodel assumesthat the
decreasein permeability in the damagedzone is due to
an increasein the concentration(invasion) of fast react-
ing species(clays).This resultsin a new, decreasedporosi-
ty of 12%, compared with the original 15%.
Injecting the sameHF acid at the samerate results in
a new HF spending,fast reactingmineral concentration,
and slow reactingmineralprofiles asshownin Figs. 14-11
to 14-13.The penetrationis evenlessthan in the first case
becausemore acid is lost to dissolvethe damagingmateri-
als in the first 3 in. of the formation. Such simulation is
useful to adapt the treatment volumes to the severity of
the problem. The capability of quickly simulating such
Radial Distance (in.) a complex processis extremely valuable in helping field
engineersto designtreatmentstailoredto the well situation.
Diversion is usually necessarywhen more than 5 to 7
ft of formation treated. Diversion designis dealt with ex-
Figure 14-g-concentration profile of fast reacting formation
minerals after HF attack, undamaged case. tensively in Chapter 15.

,E 0.96
gj
zl
E
is 0.92
cu
3
E
5
g 0.88
2
5
‘ci
5
g 0.84
. = ,200gavfl
+=250 gal/II

‘0.804 I
2 4 6 8 IO 12
Radial Distance (in.) Radial Distance (in.)

Figure 14-lo-Concentration profile of slow reacting forma-


tion mineral after HF attack, undamaged case. Figure 14-11-HF acid spending profile in a damaged
sandstone.

14-21
RESERVOIR STIMULATION

14-S CONCLUSIONS
Matrix acidizingof sandstones startswith the carefulevalu-
ation of the well and the accuratedetermination of the
natureandseverityof the problem. Then, a possibletreat-
ment fluid is selected.The first selectioncriterion is the
nature and location of the damage. Then, the potential
compatibility problemsbetweenthe rock mineralsand the
fluid are examined.The composition of the fluid is fur-
ther defined by performing flow tests and checking the
absenceof damaging reactions.
As the standardhydrofluoric acid has somelimitations
in terms of too fast reaction and short penetrationand of
byproductsprecipitation, other acid solutions, still using
50 gavfl HF as the dissolving agent, have beendevisedto allevi-
ate these shortcomings. ,’
Oncethe treating fluids andthe sequenceof fluids have
beendefined,treatingparameters,suchasvolmes , rates,
and pressure,are estimatedor calculatedand simulated.
2 4 6 a 10 If the extensionand severity of the damageare knoyn,
Radial Distance (in.) an economicevaluation (production prediction vs treat-
ment cost)canbe performed andthe treatmentresulhscan
be optimized.
Figure 14-l 2-Concentration profile of fast reacting forma- At this stageit is assumedthat the acid is injectedwhere
tion minerals after HF attack, damaged case. there is damage. Placement and diversion techniques,
which are an integral and mandatorypart of every treat:
merit, are discussedin Chapter 15. Thesetechniquesal-
low injection into eachindividual layer of just the volume
of treatmentfluids necessaryfor a given distribution of
damagein eachlayer. Finally, a comprehensivemonitor-
ing of the job effectivenessand a post-treatmentevalua-
tion are necessaryand are describedin Chapter 16.

REFERENCES
Abrams, A., Scheuerman, R.F., Templeton, C.C., and Richard-
son? E.A.: “Higher-pH Acid Stimulation Systems,” JPT (Dec.
1983) 2175-2184.
Almon, W.R., and Davies, D.K.: “Clay Technology and Well
Stimulation,” Truns., Gulf Coast Association of Geological Soci-
eties (1978) XXVIII, l-6.
Bertaux, J.: “Treatment Fluid Selection for SandstoneAcidizing:
Permeability Impairment in Potassic Mineral Sandstones,” paper
SPE 15884, 1986.
0.64 , Boyer, R.C., and Chia-Hsin, Wu: “The Role of Reservoir Lithol-
2 4 6 a 10 ogy in Design of an Acidization Program: Kuparuk River Forma- -
Radial Distance (in.) tion, North Slope, Alaska,” paper SPE 11722, 1983.
Brannon, D.H., Netters, C.K., and Grimmer, P.J.: “Matrix Acidiz-
ing Design and Quality Control Techniques Prove Successful in
Figure 14-13-Concentration profile of slow reacting forma- Main Pass Area Sandstone,” paper SPE 14827, 1986.
tion mineral after HF attack, damaged case. Crowe, C.W.: “Precipitation of Hydrated Silica from Spent

14-22
MATRIX ACIDIZING OF SWDSTONES

Hydrofluoric Acid-How Much of a Problem Is It?” paper SPE Labrid, J.C.: “Stimulation Chimique: Etude Theorique et Ex-
13083, 1984. perimentale des Equilibres Chimiques Decrivant l’attaque Fluorhyd-
Crowe, C.W.: “Evaluation of Agents for Preventing Precipitation rique d’un gres Argileux, ” Revuede 1‘ZnstitutFrancais du Petrole
of Ferric Hydroxide from Spent Treating Acid,” JPT (April 1985) (Oct. 1971) XXVI, 10, 855-876.
691-695. Labrid, J.C.: “Thermodynamic and Kinetic Aspects of Argillaceous
Davies, D.R., Lievaart, L., and Nitters, G.: “The Effects of Cor- Sandstone Acidizing,” SPEJ (April 1975) 117-128.
rosion Inhibitors and Mutual Solvents on Matrix Acidizing Treat- Lafleur, K.K., and Johnson, A.K.: “Well Stimulation in the North
ments,” paper SPE 17153, 1988. Sea: A Survey,” paper SPE 4315, 1973.
Doerler, N,, and Prouvost, L.P.: “Diverting Agents: Laboratory Lund, K., Fogler, H.S., and McCune, C.C.: “Predicting the Flow
Study and Modeling of Resultant Zone Injectivities,” paper SPE and Reactions of HCl-HF Mixtures in Porous SandstonesCores,”
16250, 1987. SPEJ (Oct. 1976) 248-260.
Fogler, H.S., Lund, K., and McCune, C.C.: “Predicting the Flow Maya, L.: “Fluoroboric Acid and Its Hydroxy Derivatives-
and Reaction of HCl/HF Acid Mixtures in Porous Sandstone Solubility and Spectroscopy,” J. Inorg. Nucl. Chem. (1977) 39,
Cores,“, SPIY (Oct. 1976) 248-260. 225-23 1.
Gabriel,’ G.A., and Erbstoesser, S.R.: “The Design of Buoyant McBride, J.R., Rathbone, M.J., and Thomas, R.L. : “Evaluation
Ball Sealer Treatments,” paper SPE 13085, 1984. of Fluoboric Acid Treatment in the Grand Isle Offshore Area Us-
Gdanski, R.D.: “Ah& Retards HF Acid for More Effective Stimu- ing Multiple Rate Flow Test,” paper SPE 8399, 1979.
lations,” OGJ (Oct. 28, 1985) 111-115. McCune, C.C., Fogler, H.S., and Ault, J.W.: “A New Model of
Gdanski, R.D., and Peavy, M.A.: “Well Return Analysis Causes the Physical and Chemical Changes in SandstoneDuring Acidiz-
Re-Evaluation of HCl Theories,” paper SPE 14825, 1986. ing,” SPEJ (Oct. 1975) 361-370.
Gidleyl’ J.L.: ’ ‘Acidizing SandstoneFormations: A Detailed Ex- McLeod, H.O.: “Matrix Acidizing,” JPT (Dec. 1984) 2055-2069.
amination of Recent Experience,” paper SPE 14164, 1985. Muecke, T.W.: “Formation Fines and Factors Controlling Their
Gidley, J.L.: “Stimulation of SandstoneFormations with the Acid- Movement in Porous Media,” JPT (Feb. 1979) 144-150.
Mutual Solvent Method,” JPT (May 1971) 551-558. Pallat, N., Wilson, J., and McHardy, B.: “The Relationship Be-
Gidley, J.L., Ryan, J.C., and Mayhill, T.D.: “Study of the Field tween Permeability and the Morphology of Diagenetic Illite in
Application of Sandstone Acidizing,” paper SPE 5693, 1976. Reservoir Rocks,” JPT (Dec. 1984) 2225-2227.
Guin, J.A., and Schechter, R.S.: “Matrix Acidization with High- Prouvost, L.P., and Economides, M.J.: “Real-Time Evaluation
ly Reactive Acids,” SPEJ (Dec. 1971) 390-398. of Matrix Acidizing Treatments,” Pet. Sci. and Eng. (Nov. 1987)
Hall, B.E. : “The Effects of Mutual Solventson Adsorption in Sand- 1, 145-154.
stone Acidizing,” JPT (Dec. 1975) 1433-1442. Prouvost, L.P., and Economides,M.J.: “Applications of Real-Time
Hall, B.E., Tinnemeyer, A.C., and Underwood, P.J.: “Stimula- Matrix Acidizing Evaluation Method,” paper SPE 17156, 1988.
tion,of the North Coles Levee Field with a Retarded HF Acid,” Schaible, D.F., Akpan, B., and Ayoub, J. A. : “Identification,
paper SPE 9934, 1981. Evaluation, and Treatment of Formation Damage, Offshore Loui-
Hekim, Y., and Fogler, H.S.: “On the Equilibrium Relationships siana,” paper SPE 14820, 1986.
and Stoichiometry of Reactionsin Mud Acid,” Chemical Engineer- Schechter, R.S., and Gidley, J.L.: “The Change in Pore Size Dis-
iizg Science (1977) 32, l-9. tribution from SurfaceReactionsin PorousMedia, ” AKhE J. (May
Houchin, L.R., and Hudson, L.M.: “The Prediction, Evaluation, 1969) 15> No. 3, 339-350.
and Treatment of Formation Damage Caused by Organic Deposi- Scheuerman, R.F.: “A Buffer-Regulated HF Acid for Sandstone
tion,” paper SPE 14818, 1986. Acidizing to 550’ F,” paper SPE 13563, 1985.
Hekim, Y., Fogler, H.S., and McCune, C.C.: “The Radial Move- Shaughnessy,CM., and Kunze, K.R.: ‘Understanding Sandstone
ment of Permeability Fronts and Multiple ReactionsZonesin Porous Acidizing Leads to Improved Field Practices,” JPT (July 1981)
Media,” SPEJ (Feb. 1982) 99-107, 1196-1202.
Iler, R.K.: The Chemistry of Silica: Solability, Polymerization, Col- Smith, C.F., and Hendrickson, A.R.: “Hydrofluoric Acid Stimu-
loid and Sur$aceProperties, and Biochemistry, J. Wiley and Sons lation of Sandstone Reservoirs,” JPT (Feb. 1965) 215-222.
Inc., New York (1979).
Smith, C.F., Crowe, C.W., and Nolan, T.J. : “Secondary Depo-
Kline, W.E.: “The Catalyzed Dissolution of Silicate Materials by sition of Iron Compounds Following Acidizing Treatments,” JPT
Hydrofluoric Acid,” Ph.D. Thesis (1980), University of Michigan. (Sept. 1969) 1121-1129.
Kline, W.E., and Fogler, H.S. : “Dissolution of Silicate Minerals Smith, C.F., Rose, W.M., and Hendrickson, A.R.: “Hydrofluor-
by Hydrofluoric Acid,” Ind. Eng. Chem. Fundam. (1981) 20, ic Acid Stimulation - Development for Field Application,” paper
155-161. SPE 1284, 1965.
Krueger, R.F.: “An Overview of Formation Damage and Well Taha, R., Hill, A.D., and Sepehrnoori, K.: “Simulation of
Productivity in Oilfield Operations,” JPT (Feb. 1986) 131-152. Sandstone-Matrix Acidizing in Heterogeneous Reservoirs,” JPT
Kunze, K.R., and Shaughnessy,C.M.: ‘ ‘Acidizing SandstoneFor- (July 1986) 753-767.
mations with Fluoboric Acid,” SPEJ (Feb. 1983) 65-72.

14-23
RESERVOIR STIMULATION

Templeton, C.C., Richardson, E.A., Karnes, G.T., and Lybarg-


er, J.H.: “Self-Generating Mud Acid (SGMA),” paper SPE 4777,
1974.
Manuel d’Acid$cation des Reservoirs, Ed. Technip, Paris (1983).
Thomas, R.L.: “Method for Acidiziug a SubterraneanFormation,”
U.S. Patent 4,151,878 (May 1, 1979).
Thomas, R.L.: “Method for Acidiziug a SubterraneanFormation,”
U.S. Patent 4,151,879 (May 1, 1979).
Thomas, R.L., and Crowe, C.W.: “Matrix Treatment Employs
New Acid System for Stimulation and Control of Fines Migration
in Sandstone Formations,” JPT (Aug. 1981) 1491-1500.
Thomas, R.L., and Suhy, F.A.: “Method of Treating a Well Us-
ing Fluoboric Acid to Clean a Propped Fracture,” U.S. Patent
4,160,483 (July 10, 1979).
Tyler, T.N., Metzger, R.R., and Twyford, L.R.: “Analysis and
Treatment of Formation Damage at Prudhoe Bay, Alaska,” JPT
(June 1985) 1010-1018.
Walsh, M.P., Lake, L.W., and Schechter, R.S.: “A Description
of Chemical Precipitation Mechanisms and Their Role in Forma-
tion DamageDuring Stimulation by Hydrofluoric Acid,” JPT (Sept.
1982) 2097-2112.
Walsh, M.P., Bryant, S.L., Schechter, R.S., and Lake, L.W.:
“Precipitation and Dissolution of Solids Attending Flow through
Porous Media,” AZChE J. (March 1984) 30, No. 2, March 1984, ,”
317-328.
Wamser, C.A.: “Hydrolysis of Fluoboric Acid in Aqueous Solu-
tion,” J. Am. Chem. &c. (March 1948) 70, March 1948,
1209-1215.
WeZlAnaZysisManual, Dowel1 Schlumberger, Paris: 1984.
Williams, B.B.: “Hydrofluoric Acid Reaction with SandstoneFor-
mation, ” J. Eng. for Ind. (Feb. 1975) 252-258.
Williams, B.B., Gidley, J.L., and Schechter,R.S.: Acidizing Fun-
damentak, Monograph Series, SPE, Dallas (1979) 6.
Wilson, M.D., and Pittman, E.D.: “Authigenic Clays in Sand-
stones: Recognition and Influence on Reservoir Properties and
Paleoenvironmental Analysis,” J. Sed. Pet. (1977) 47, 3-31.

14-24

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