[SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022

M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD

REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS
SECTION – A (Marks 13)
Q.1 Encircle the correct option i.e. A / B / C / D. Each part carries one mark.
Obtained Marks

Total Marks 113=

13
i) Non-typical transition elements are of group;
⒜ Group V-B ⒝ Group VI-B ⒞ Group I-B ⒟ Group II-B
ii) Which of the following specie has a highest paramagnetic behaviour?
⒜ Iron, Fe ⒝ Iron (II) Ion, Fe+2 ⒞ Manganese, Mn ⒟ Chromium, Cr
iii) Which of the following element have half-filled d-orbitals?
⒜ Iron, Fe ⒝ Copper, Cu ⒞ Manganese, Mn ⒟ Nickel, Ni
iv) Bronze is an alloy of;
⒜ Cu 60 – 80 % & Zn 20 – 40 % ⒞ Cu 90 – 95 % & Sn 5 – 10 %
⒝ Ni 60 %, Cr 15 % & Fe 25 % ⒟ C 70 %, Fe 20 % & Cr 10 %
v) The unit of magnetic moment is;
⒜ Tesla, T ⒞ Henry, H
⒝ Bohr Magneton, BM ⒟ Debye, D
vi) Catalyst used in the decomposition of hydrogen peroxide is;
⒜ Vanadium Pentaoxide, V2O5 ⒞ Manganese Dioxide, MnO2
⒝ Iron, Fe ⒟ Zinc Oxide, ZnO & Chromium Oxide, Cr2O3
vii) The transition metal which can show highest oxidation state is;
⒜ Chromium, Cr ⒝ Manganese, Mn ⒞ Iron, Fe ⒟ Copper, Cu
viii) Iron oxide is used as catalyst in the process;
⒜ Contact process ⒝ Ostwald process ⒞ Hydrogenation ⒟ Haber process
ix) The substance which does not contain unpaired electrons are;
⒜ Ferromagnetic ⒝ Paramagnetic ⒞ Diamagnetic ⒟ Electromagnetic
x) Which of the following has highest oxidation state?
⒜ Chromium, Cr ⒝ Manganese, Mn ⒞ Iron, Fe ⒟ Copper, Cu
xi) The magnetic moment of iron is;
⒜ 3.87 BM ⒝ 4.9 BM ⒞ 5.29 BM ⒟ 6.93 BM
xii) The transition elements show variable oxidation state due to the involvement of electrons of;
⒜ ns orbitals and (n-1)p electrons ⒞ np orbitals and (n-1)p electrons
⒝ ns orbitals and (n-1)d electrons ⒟ ns orbitals and nd electrons
xiii) Ammonia acts as ligand as well as base in case of reaction with;
⒜ Chromium, Cr ⒝ Manganese, Mn ⒞ Iron, Fe ⒟ Copper, Cu

Hard Work and Determination is the Key to Success

 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS
SECTION – B (Marks 24)
Q.2 Answer FOLLOWING parts. The answer to each part should not exceed 5 to 7 lines.
(3×8=24)
i) Compare the properties of cuprous and cupric compounds.

Marks Obtained _______________ out of 3

ii) How iron (II) ion catalyzes the reaction between persulphate ions (peroxodisulphate ions),
S2O8–2 and iodide ions, I–?

Marks Obtained _______________ out of 3

Hard Work and Determination is the Key to Success
 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS
iii) How iron (II) salts and iron (III) salts react with the following;
a) Sodium hydroxide b) Carbonate Ion

Marks Obtained _______________ out of 3

iv) In 3d series, Vanadium has 3 unpaired electrons while Chromium has 6 unpaired electrons but
the binding energy of vanadium is higher than chromium. Give reason.

Marks Obtained _______________ out of 3

Hard Work and Determination is the Key to Success
 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS
v) Differentiate between paramagnetic, ferromagnetic and diamagnetic behaviour.

Marks Obtained _______________ out of 3

vi) Why transition element can form substitutional alloys? Give the composition of bronze, brass
and nichrome alloys.

Marks Obtained _______________ out of 3

Hard Work and Determination is the Key to Success
 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS
vii) Give the reactions showing the ligand nature as well as the basic nature of ammonia.

Marks Obtained _______________ out of 3

viii) Define the following terms;
a) Coordination Number b) Coordination Sphere

Marks Obtained _______________ out of 3

Hard Work and Determination is the Key to Success
 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS
SECTION – C (Marks 13)
Attempt FOLLOWING questions in detailed. [13 × 1 = 13]
Q.3 a) What is meant by Ligand? Describe its classification. [5]

Hard Work and Determination is the Key to Success

 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS

Marks Obtained _______________ out of 5

Hard Work and Determination is the Key to Success
 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS
Q.3 b) Explain the catalytic activity of transition elements. Why transition elements can be
used as catalyst. Write the process which catalyzed the following elements (or their
compounds).
i) Titanium ii) Vanadium iii) Zinc [5]

Hard Work and Determination is the Key to Success

 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS

Marks Obtained _______________ out of 5

Hard Work and Determination is the Key to Success
 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS
Q.3 c) Differentiate between FeO and Fe2O3 chemically. [3]

Hard Work and Determination is the Key to Success

 [SUBJECT SPECIALIST (CHEMISTRY)] 0342 55 61 022
M.PHIL. ORGANIC CHEMISTRY, QUAID-E-AZAM UNIVERSITY, ISLAMABAD
REVISION TEST HSSC II – CHEMISTRY
CHAPTER # 14 d- AND f- BLOCK ELEMENTS / TRANSITION ELMENTS

Marks Obtained _______________ out of 3

Hard Work and Determination is the Key to Success