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Seatwork 2

This document contains 6 analytical chemistry problems involving titration calculations: 1. A urine sample was tested for magnesium and calcium content using EDTA titration. 2. A sample containing bromate and bromide ions was titrated with EDTA to determine the percentage of each species. 3. Calcium content of powdered milk was measured by ashing, titrating with EDTA, and calculating the concentration in parts per million. 4. A KCN sample was titrated with silver nitrate and the percentage purity was calculated using the mole ratio and formula weight. 5. Phosphorus content in a sample was measured by precipitation, filtration, acid treatment, reaction with lead, and

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127 views

Seatwork 2

This document contains 6 analytical chemistry problems involving titration calculations: 1. A urine sample was tested for magnesium and calcium content using EDTA titration. 2. A sample containing bromate and bromide ions was titrated with EDTA to determine the percentage of each species. 3. Calcium content of powdered milk was measured by ashing, titrating with EDTA, and calculating the concentration in parts per million. 4. A KCN sample was titrated with silver nitrate and the percentage purity was calculated using the mole ratio and formula weight. 5. Phosphorus content in a sample was measured by precipitation, filtration, acid treatment, reaction with lead, and

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Gia Janella Semilla
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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SEATWORK 2 MCC 109 Analytical Chemistry Summer 2022-2023

1. A 24-hr urine specimen was diluted to 2.000 L. After the solution was buffered to pH
10, a 10.00-mL aliquot was titrated with 23.57 mL of 0.004590 M EDTA. The calcium
in a second 10.00-mL aliquot was isolated as CaC2O4(s), redissolved in acid, and titrated
with 10.53 mL of the EDTA solution. Assuming that 15 to 300 mg of magnesium and
50 to 400 mg of calcium per day are normal, did this specimen fall within these ranges?
(5 pts)

2. A 3.650-g sample containing bromate and bromide was dissolved in sufficient water to
give 250.0 mL. After acidification, silver nitrate was introduced to a 25.00-mL aliquot to
precipitate AgBr, which was filtered, washed, and then redissolved in an ammoniacal
solution of potassium tetracyanonickelate(II):

Ni(CN)42- + 2 AgBr(s) → 2 Ag(CN)2- + Ni2+ + 2Br-

The liberated nickel ion required 26.73 mL of 0.02089 M EDTA. The bromate in a 10.00-
mL aliquot was reduced to bromide with arsenic(III) prior to the addition of silver nitrate.
The same procedure was followed, and the released nickel ion was titrated with 21.94
mL of the EDTA solution. Calculate the percentages of NaBr and NaBrO3 in the sample.
(6 pts)

3. Calcium (AW = 40.0780) in powdered milk is determined by ashing a 1.50-g sample


and then titrating the calcium with EDTA solution, 12.1 mL being required. The EDTA
was standardized by titrating 10.0 mL of a zinc solution prepared by dissolving 0.632 g
zinc metal in acid and diluting to 1 L (10.8 mL EDTA quired for titration). What is the
concentration of calcium in the powdered milk in parts per million? (6 pts)

4. In the Leibig titration of cyanide ion, a soluble complex is formed; and at the
equivalence point, solid silver cyanide is formed, signaling the end point:
2𝐶𝐶𝑁𝑁 − + 𝐴𝐴𝑔𝑔+ → 𝐴𝐴𝐴𝐴(𝐶𝐶𝐶𝐶)−
2 (titration)
− +
( ) [ ( )
𝐴𝐴𝐴𝐴 𝐶𝐶𝐶𝐶 2 + 𝐴𝐴𝑔𝑔 → 𝐴𝐴𝑔𝑔 𝐴𝐴𝐴𝐴 𝐶𝐶𝐶𝐶 2 ] (end point)

A 0.4723-g sample of KCN was titrated with 0.1025 M AgNO3, requiring 34.95 mL.
What is the percent purity of the KCN? FW of KCN is 65.1157. (6 pts)

5. The phosphorus in a 0.2091-g sample was precipitated as the slightly soluble


(NH4)3PO4.12MoO3. This precipitate was filtered, washed, and then redissolved in acid.
Treatment of the resulting solution with an excess of Pb2+ resulted in the formation of
0.2922 g of PbMoO4. Express the results of this analysis in terms of percent P2O5. (5
pts)

6. A 0.6407-g sample containing chloride and iodide ions gave a silver halide precipitate
weighing 0.4430 g. This precipitate was then strongly heated in a stream of Cl2 gas to
convert the AgI to AgCl; on completion of this treatment, the precipitate weighed 0.3181
g. Calculate the percentage of chloride and iodide in the sample. (6 pts)

*****NOTHING FOLLOWS*****

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