Sri Chaitanya IIT Academy., India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
JEE-ADVANCE-2023-P2-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 4) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 5 – 7) +4 -2 3 12
with partial mark
Questions with non-negative
Sec – III(Q.N : 8 – 13) +4 0 6 24
integer Answer Type
Sec – IV(Q.N : 14 – 17) Paragraph Numerical Value 3 0 4 12
Total 17 60
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 18 – 21) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 22 – 24) +4 -2 3 12
with partial mark
Questions with non-negative
Sec – III(Q.N : 25 – 30) +4 0 6 24
integer Answer Type
Sec – IV(Q.N : 31 – 34) Paragraph Numerical Value 3 0 4 12
Total 17 60
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 35 – 37) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 38 – 41) +4 -2 3 12
with partial mark
Questions with non-negative
Sec – III(Q.N : 42 – 47) +4 0 6 24
integer Answer Type
Sec – IV(Q.N : 48 – 51) Paragraph Numerical Value 3 0 4 12
Total 17 60
 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
MATHEMATICS Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: −1 In all other cases
1
1. Let f : 1,    R be a differentiable function such that f 1  and
3
x
x3
3 f  t  dt  xf  x   , x  1,   . Let e denotes the base of the natural logarithm. Then
3
1
the value of f  e  is
e2  4 loge 4  e 4e2 e2  4
A) B) C) D)
3 3 3 3
Key: C
Sol: 3f  x   f  x   xf '  x   x 2
dy 1 1
x  2y  x 2 , y.   ln x
dx x2 x
1 1
y 1  , c
3 3
2 x2
y  x ln x 
3
e2 4e2
y  R   e2  
3 3
2. Consider an experiment of tossing a coin repeatedly until the outcomes of two
1
consecutive tosses are same. If the probability of a random toss resulting in head is ,
3
then the probability that the experiment stops with head is
1 5 4 2
A) B) C) D)
3 21 21 7
Key: B

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
HH  HTHH  HTHTH  .....
Sol:
THH  THTHH  .......
 
  p 1  p   p   p 1  p  p
r r 2
r 1 r 1
 2   2 
 1   1  1
   9    9  
 3  1  2  9  1  2  9
 9  9
 1  2  1  2  1 2 5
       1   
 3  7  9  7  7 21 21
  
3. For any y  R,let cot 1  y    0,   and tan 1  y     , . then the sum of all the
 2 2
 6y   2
solutions of the equation tan 1  1 9  y 2
, for 0  y  3, is equal to
  cot   
 9  y2   6y  3
   
A) 2 3  3 B) 3  2 3 C) 4 3  6 D) 6  4 3
Key: C
Sol: O y  3
 1  2x
tan 1 a  cot 1   
x 8
x
tan 1 x   x  3
2
y2  2 3y  4  0
y 3
2y  3 3
2x
tan 1 x  tan 1 x 
3
 1
tan 1 x  x
6 3

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
6y 1
  6 3y  y 2  9  0
9  y2 3
y 2  6 3y  9  0
4 36
 
4. Let the position vectors of the points P,Q,R and S be a  ˆi  2ˆj  5k,b
ˆ  3iˆ  6ˆj  3k,
ˆ
 17 16 
c  ˆi  ˆj  7kˆ And d  2iˆ  ˆj  k,ˆ respectively, Then which of the following
5 5
statements is true
A) The points P, Q, R and S are NOT coplanar
 
b  2d
B) is the position vector of a point which divides PR internally in the ratio 5:4
3
 
b  2d
C) is the position vector of a point which divides PR externally in the ratio 5:4
3
 
D) The square of the magnitude of the vectors b  d is95
Key: B

Sol: P  1,2, 5 a

Q  3,6,3 b
17 11 
R , ,7 c
6 5

S  2,1,1 d
1 2 4
  
 PQ PR PS   2 1 10
 
1 1 0
1 6  10   2 12  10   4  2  1

 16  4  12  0
 
b  2d 7 8 5
 , ,
2 3 3 3

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 ONLY if (all) the correct option(s) is (are) chosen;
Partial Marks: +3 if all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 if three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 if two or more options are correct but ONLY two options are chosen, and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –2 in all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
Choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

5.  
Let M  a ij ,i, j  1,2,3 , be the 3  3 matrix such that a ij  1 if j  1 is divisible by i,

otherwise a ij  0 .Then which of the following statements is(are) true ?

A) M is invertible
 a1   a1   a1 
B) There exists a nonzero column matrix  a 2  such that M  a 2    a 2 
a   a   a 
 3  3  3

0
 
3

C) The set X  R : MX  0  0 , where 0   0 
0

 
D) The matrix (M-2I) is invertible , where I is 3  3 identify matrix
Key: BC
Sol: a11  a12  a13  1
a 21  1 a 22  0 a 23  1
a 31  0 a 33  0 a 32  1
1 1 1 
M  1 0 1  M  0
 
 0 1 0 
B) a1  a 2  a 3  a1

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
a1  a 3  a 2
a 2  a 3
a 2  a 3 0 and a1  0
C) MX=0
a1  a 2  a 3  0
a1  a 3  0 always true
a2  0
SO set will have other solution then o
D) M  2I  0,BCD
2
 1  1
6. Let f :  0,1  R be the function defined as f  x    4x   x    x   , where  x 
 4  2
denotes the greatest integer less than or equal to x. Then which of the statements is (are)
true?
A) The function f is discontinuous exactly at one point in (0, 1)
B) There is exactly one point in (0, 1) at which of the function f is continuous but NOT
differentiable
C) The function f is NOT differentiable at more than three points in (0, 1)
1
D) The minimum value of the function f is 
512
Key: AB

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
 1
 0 0x
4

 2
1  1 1 1
 X   X   x
 4  2 4 2
f x   2
Sol:
2  X  1   X  1  1
x
3
   
4  2

2 4

  2
1  1 3
3  X    X    x 1
  4  2 4

1 1
Continuoual at x  ,
4 2
3
diss at x 
4
1
not diffat x 
2
1 5
min of f  x   at x 
432 12

d 2f
7. let S be the set of all twice differentiable function f from R to R such that x  0
dx 2
for all x   1,1 .For f  S,let X f be the number of points x   1,1 for which

f  x   x. Then which of the following statements is(are) true ?

A)There exists a function f  S such that X f  0
B)For every function f  S , we have X f  2
C)There exista a function f  S such that X f  2
D)There does NOT exista any function f in S such that X f  1
Key: ABC
Sol: Basic conceptual

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
A) Any concave upward graph above y=x
B) Any graph through (0, 0) and (1,0) etc
C) Concave upward and line max intersections can be 2 only
D) byent with y=x curve can exist

SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
Designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks: 0 in all other cases.

  
8. For x  R , let tan 1  x     , . Then the minimum value of the function
 2 2
x tan 1 x
e
t cos t 
f : R  R defined by f  x    dt is
0 1  t 2023
Key: 0
x tan 1 x
e t cos t
Sol: f x   dt
0 1  t 2023

e

x tan 1 x cos x tan 1 x 
f ' x  
2023

1  x tan 1 x 
Always non zero
x
f ' x   0  tan 1 x  0
2
1 x

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

- +
o
At x=0 local min (Or)
For x  0 (or) x  0 f  x  is +ve min happened at x=0 only logically
f 0  0
9. For x  R , let y  x  be a solution of the differential equation
dy 2
 x2  5
dx
  
 2xy  2x x 2  5 such that y  2   7 .Then the maximum value of the

function y  x  is
Key: 16
dy 2

x2  5
dx
 
 2xy  2x x 2  5 
y  2  7
 y 
 2   2x
 x 5
y
 x2  c
2
x 5
7
 4  C  C  7  4
45
C  3  Y  15  2X 2  X 4
2
16   X 2  1
 
Sol: y max  16

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
10. Let X be the set of all five digit numbers formed using 1,2,2,2,4,4,0.For example,22240
is in X while 02244 and 44422 are not in X. Suppose that each element of X has an
equal chance of being chosen. Let p be the conditional probability that an element chosen
at random is a multiple of 20 given that it is a multiple of 5. Then the value of 38p is
equal to
Key: 31
Sol: 1,2,2,2,4,4,0
N (multiple of 20) =38
0
1,2,2,2  4
46
1,2,2,4  12
26
46
2,2,4,4 6
2626
2,2,2,4  4
=38
In Multiple of 20 which are divisible by 4  last 2 digits divided by 4
    10
2,2,1  1
2,2,4  3
2,4,4  3 =7
31
38-7=31  ans  p  38p=31
38

11. let A1,A 2 ,A 3,..........A be the vertices of a regular octagon that lie on a circle of radius 2.
8

Let P be a point on the circle and let PAi , denotes the distance between the points P and
Ai for i  1,2,.........8. If P varies over the circle, then the maximum value of the product
PA1.PA 2 ......PA8, is

Key: 512

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

Sol:   
z8  28   z  2  z  2d  z  22 .... z  27 
z  2 z  2d .......... z  2d7  z8  28

8
 z  28

 28 (2)

 29

Loids at are (z8 )  z

 a 3 b  
 
12. Let R   c 2 d  : a,b,c,d  0,3,5,7,11,13,17,19 . Then the number of invertible
 0 5 0  
  
matrices in R is
Key: 3780

Sol: Total = 84  4096

M  ad  bc
ad  bc
1
41  41  7  7
2 7  2  41
3 1
24  7 4  6  84
Total =316
Ans: 4096-316=3780

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
13. Let C1 be the circle of radius 1 with center at the origin.Let C2 be the circle of radius r

with center at the point A   4,1 ,where 1  r  3. Two distinct commom tangents PQ and
ST of C1 and C2 are drown.The tangent PQ touches C1 at P and C2 at Q.The tangent
ST touches C1 at S and C2 at T.Mid points of the line segments PQ and ST are joined to

form a line which meets the x-axis at a point B. If AB  5 ,then the value of r 2 is
Key: 2
Q
P

 0,0  B A 4,1

r 1 S T  x  y 2   y  12  r.2
x  y2  1
2
Sol:
Line. x 2  y 2  8 x  2 y  17  r 2  0
8s  2 y  18  r 2
18  r 2
y0 x
8
2
 18  r 2 
 AB   5   4   1  5

 8 
2
 32  18  r 2 
  4
 8 
 
14  r 2
2 or -2
8
r 2  16  4 =2 r2  2

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases
PARAGRAPH-I
Consider an obtuse angled triangle ABC in which the difference between the largest and

the smallest angle is and whose sides are in arithmetic progression. Suppose that the
2
vertices of this triangle lie on a circle of radius 1.
(There are two questions based on PARAGRAPH “I” ,the question given below is
one of them)
2
14. Let a be the area of the triangle ABC. Then the value of  64a  is
Key: 1008
Sol: a,b,c abc

2b  a  c C A 
2
x
C  CA
2
x
B   2A
2
2cos 2a  sin A  coaA
2  cos A  A   1
x  x 
  2R 2SA L   2A  L   A 
2  2 
3 7

4 4
ANS-16  9  7  1008

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
15. Then the inradius of the triangle ABC is
Key: 0.25

r
s
3 7 1
Sol:   2
16 3b
3 7 1 1
 2  
16 3  2  cos 2A 4

PARAGRAPH-II
Consider the 6  6 square in the figure .Let A1, A 2 .....A 49 be the points of intersection(
dots in the picture) in some order. We say that A i and A j are friends if they are adjacent
along a row or along a column. Assume that each point Ai has an equal chance of being
chosen.

(there are two questions based on PARAGRAPH “II” ,the question given below is
one of then)
16. Let pi be the probability that a randomly chosen point has i many friends ,
i=0,1,2,3,4.Let X be a random variable such that for i=0,1,2,3,4,,the probability
P  X  i   pi . Then the value of 7E  X  is
Key: 24

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
xi 0 1 2 3 4
Sol: 4 20 25
p(x i ) 0 0
49 49 49
8  60  100 168 24
2  4 3  20 4  25   
E X     49 49 7
49 49 49
7  E  X   24
17. Two distinct points are chosen randomly out of the points A1, A 2 ,.....A 49 . Let p be the
probability that they are friends. Then the value of 7p is
Key: 0.5
_____________ 4 
______________12 

_______________13 

______________14   511  711
_______________15 

_______________16 
_______________17 

Sol: 
 35  7   2
49C2
776 4 1
7P  
49  48 2

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
PHYSICS Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
18. An electric dipole is formed by two charges +q and q located in xy-plane at (0,2) mm
and (0,2) mm, respectively as shown in the figure. The electric potential at point p
(100,100)mm due to the dipole is v 0 . The charges +q and q are then moved to the
points (-1, 2) mm and (1, -2) mm, respectively. What is the value of electric potential at P
due to the new dipole?

A) V0/4 B) V 0/2 C) V 0/ 2 D) 3V0/4

Key: B
Kp cos   1  KP
Sol:  V0  cos     2V0
r2  2  r2

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
p
Now new dipole momentum P'   5
A2

KP ' cos  45    KP 5
Hence V '    cos 45.cos   sin 45.sin  
2 2
r 2r
5 1 2 1 1  V 2 1 V
 2V0  .  .  2 0  0
2  2 5 2 5 2 2 2
19. Young’s modulus of elasticity Y is expressed in terms of three derived quantities, namely

the gravitational constant G, planck’s constant h and the speed of light c, as Y  C hG 
which of the following is the correct option?
A)   7,   1,   2 B)   7,   1,   2
C)   7,   1,   2 D)   7,   1,   2
Key: A

Sol: Y has dimension of strong i.e ML-1T -2

  
ML-1T-2  C  hG   LT 1   ML2T 1  ML3T 2 
ML-1T-2  M  L 23T  2 
    1,   2  3  1 and      2  2
Solving the above we will set α=7,β=-1,and  =-2
20. A particle of mass m is moving in the xy-plane such that its velocity at a point (x,y) is
 
given as v    yxˆ  2xyˆ  , where a is a non-zero constant. What is the force F acting on
the particle?
 
A) F  2m 2  xxˆ  yyˆ  B) F  m 2  y xˆ  2x yˆ 
 
C) F  2m 2  y xˆ  x yˆ  D) F  m 2  xxˆ  2y yˆ 

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
Key: A

dv 1
Sol: V   yx  2 x y
  a   Vyx  2Vx y
 
dt

  2xx  2y y
   22 xx  22 y y Hence F 1  2m 2 xx  y y
 
21. An ideal gas is in thermodynamic equilibrium. The number of degrees of freedom of a
molecule of the gas is n. the internal energy of one mole of the gas is U n and the speed
of sound in the gas is v n . At a fixed temperature and pressure, which of the following is
the correct option?
A) v3  v 6 and U 3  U 6 B) v5  v3 and U 3  U 5
C) v5  v 7 and U 5  U 7 D) v 6  v7 and U 6  U 7

Key: C
p rRT
Sol: Speed of sound = =
p M

Cp  n / 3  1 R 2
r  1
Cv nR n
n
And U=  n 0 RT 
2

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.
22. A monochromatic light wave is incident normally on a glass slab of thickness d, as shown
in the figure. The refractive index of the slab increases linearly from n1 to n 2 over the
height h, which of the following statement(s) is (are) true about the light wave emerging
out of the slab?

 2 2 
 n  n d 
2 1 
A) It will deflect up by an angle tan 1   .
 2h 
 
 
  n  n 1 d 
B) It will deflect up by an angle tan 1  2 .
 h 
C) It will not deflect
D) The deflection angle depends only on  n 2  n1  and not on the individual values of n1
and n 2

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
Key: BD/Bonus
Sol: The wave front entering will have different velocities at different after entering the slag
dn
Time taken to cross slab at B= 2
C
dn
Time taken to cross the slab at A= 1
C
Hence extra distance travelled.
 dn dn 
Beyond emergence at A=  2  1  c  d  n2  n1 
 c c 
d  n2  n1 
Hence tan  
n
Deflection angle depends on  n2  n1 
23. An annular disk of mass M, inner radius a and outer radius b is placed on a horizontal
surface with coefficient of friction  as shown in the figure. At some time, an impulse
J0 xˆ is applied at a height h above the center of the disk. If h  h m then the disk rolls
without slipping along the x-axis which of the following statement(s) is (are) correct?

A) For   0and a  0, h m  b / 2
B) For   0and a  b, h m  b
C) For h  h m, the initial angular velocity does not depend on the inner radius a

D) For   0and h  0, the wheel always slides without rolling.

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
Key: ABCD
j h
Sol: J 0 h=Icm ω ω= 0
Icm
Linear impulse= p
j
j0  P V= 0
M
j
Hence = 0
Mb
When a  b
j h
i= Mb 2 ω= 0 hb
Mb 2
24. The electric field associated with an electromagnetic wave propagating in a dielectric

   107  
medium is given by E  30(2 xˆ  y)sin
ˆ 14
 2  5  10 t  z   v m 1. Which of the
  3  

following option(s) is (are) correct?

[given: the speed of light in vacuum, c  3  108 ms 1 ]

7
  107  
A) Bx  2  10 14
sin  2  5  10 t   z  Wb m 2
   3  


7
  107  
B) By  2  10 14
sin  2  5  10 t  z   Wb m2 .
  3  


C) The wave is polarized in the xy-plane with polarization angle 30 with respect to the
x-axis
D) The refractive index of the medium is 2.
Key: AD

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
   107 
Sol: E  30 2 x  y sin  2  5  1014 t 
  z 
  3 

107 w 5  1014  3

w  2  5  10 14
 k  2 
3
v 
k 107
 3  107  5

c 3  108 10
Hence     2
v 3  107  5 5
E E 30 5  2
 v, Hence B  
B V 3  108
Taking B is perpendicular to V and considering E 1  B 1 is along propagation
So is along -ve x-axis and thing along the y-axis
30 5  2 1
Bn    2  107
8 5
3  10
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases..
25. A thin circular coin of mass 5 gm and radius 4/3 cm is initially in a horizontal
xy-plane. The coin is tossed vertically up (+z direction ) by applying an impulse of

102 N-s at a distance 2/3 cm from its center. The coin spins about its diameter and
2
moves along the + z direction. By the time the coin reaches back to its initial position, it
competes n rotations. The value of n is––––––.
[given: The acceleration due to gravity g=10 ms2 ]

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
Key: 30

mR 2
Sol: J.r  .w and J  mVcm
4

2Vcm 2  J
time t  
g mg
n.2  t
t  2  J 4Jr  2  J
n  
2 m  g  2 mR 2  mg  2

8J 2r 2r

2 2
mR  mg  2 mR  mg
2
2   102
 3
16
25  106   104  10
9
 30
26. A rectangular conduction loop of length 4 cm and width 2 cm is in the xy-plane, as
shown on the figure. It is being moved away from a thin and conducting wire along the
3 1
direction xˆ  yˆ with a constant speed v. the wire is carrying a steady current I  10 A
2 2
in the positive x-direction . A current of 10 A Flows through the loop when it is at a
distance d=4 cm from the wire. If the resistance of the loop is 0.1  then the value of v is

––––– ms1

[Given: The permeability of free space 0  4107 NA2 ]

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

Key: 4
Sol: Induced emf depends on velocity along y axis
Total induced emf is V y B1l  V y B2 .l  

 V yl  B1  B2   

 V .sin   B1  B2  l  

v
  B1  B2  l  
2
v  i  i  voil  1 1 
  0  0 l      
2  2 d1 2 d 2  4  d1 d 2 
Now i  E / R , Putting thevalues we get v=4

27. A string of length 1m and mass 2  105 kg is under tension T. when the string vibrates,
twoSuccessive harmonics are found to occur at frequencies 750 Hz and 1000 Hz. The
value of tension T is––––Newton.
Key: 5
Sol: Ans-5

Successive reasonane f1 
nv
and f 2 
 r  1 v
2l 2l

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
v
Hence f 2  f1 
2l
T
 1 T
 250  
2l 2 ml

T  25  104  2  105  1
 5N
28. An incompressible liquid is kept in a container having a weightless piston with a hole. A
capillary tube of inner radius 0.1 mm is dipped vertically into the liquid through the
airtight piston hole, as shown in the figure. The air in the container is isothermally
100
compressed from its original volume V0 to V0 with the movable piston, Considering
101
air as an ideal gas, height(h) of the liquid column in the capillary above the liquid level in
cm is ––––.

[Given : surface tension of the liquid is 0.075N m 1 , atmospheric pressure is 105 N m2

acceleration due to gravity (g) is 10m s2 , density of the liquid is 103 kg m 3 and
contact angle of capillary surface with the liquid is zero]

Key: 25

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
Sol: ANS(25)
2T p
h 
 g  g
p
2  0.75 101
 
3 3 3
1  10  10  10 10  10

15 105
 
1 101  104
10
 .15   .25m  25cm
100
dN
29. In a radioactive decay process, the activity is defined as A   , where N(t) is the
dt
number of radioactive nuclei at time t. two radioactive sources, S1 andS2 have same

activity at time t=0. At a later time, the activities of S1 and S2 are A1 and A 2 , respectively.

When S1 and S2 have just completed their 3rd and 7rd half-lives, respectively, the ration
A1 / A 2 is––––––.
Key: 16
Sol: ans(16)
A0
 x1t
A1 A0e
  2n
A2 A0e x2t A0
2n
A0
 8  27  24  16
A0 23
7
2

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
30. One mole of an ideal gas undergoes two different cyclic processes I and II, as shown in
the P-V diagrams below, In cycle, I, processes a,b,c and d are isobaric, isothermal,
isobaric and isochoric, respectively. In cycle II, processes a', b',c' and d' are isothermal,
isochoric, isobaric and isochoric, respectively. The total work done during cycle I is W1
and that during cycle II is WII . The ratio W1 / WII is –––

Key: 2
Sol: ANS(2)
SOL- W1  4 P0V0  8 P0V0 ln 2  2 P0 3V0
W2   P0V0  4 P0V0 ln 2
W1 8ln 2  2
 2
W2 4ln 2  1

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases
PARAGRAPH-I
S1 and S2 are two identical sound sources of frequency 656 Hz. The source S1 is located

O and S2 moves anti-clockwise with a uniform speed 4 2ms1 on a circular path around
O, as shown in the figure. There are three points P,Q and R on this path such that P and R
are diametrically opposite while Q is equidistant from them, A sound detector is placed
at point P. The source S1 can move along direction OP.

[Given: The speed of sound in air is 324 ms1 ]

31. When only S2 is emitting sound and it is at Q, the frequency of sound measured by the
detector in Hz is–––––.
Key: 648
Sol: When only S 2 is emitter

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

v0
450

v  656 324 324

f '    656  648Hz
vs cos 450 324  4 2 
1 328
2
32. Consider both sources emitting sound. When S2 is at R and S1 approaches the detector
with a speed 4 m s-1, the beat frequency measured by the detector is ______ Hz.
Key: 8.2
Sol: Frequency detected from S 2 = 656Hz
324
Frequency detected from S1 = 656  =664.2
324  4
Hence beat frequency=(664.2-6.56)Hz =8.2Hz
PARAGRAPH-II
A cylindrical furnace has height (H) and diameter (D) both 1 m. It is maintained at
temperature 360 K. The air gets heated inside the furnace at constant pressure Pa and its
temperature becomes T=360 K. The hot air with density  rises up a vertical chimney of
diameter d=0.1 m and height h=9 m above the furnace and exits the chimney (see the

figure). As a result, atmospheric air of density ρa =1.2kg m-3 ,pressure Pa and temperature
Ta=300 K enters the furnace. Assume air as an ideal gas, neglect the variations in  and T
inside the chimney and the furnace. Also ignore the viscous effects.
[Given: The acceleration due to gravity g=10 m s-2 and π=3.14 ]

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

33. Considering the air flow to be streamline, the steady mass flow rate of air exiting the
chimney is _______ gm s-1
Key: 60.80
v
P
C
B

A0 v0
0T0 Pw

Sol:

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
Ans-60.80
0T0  T
Sol-  1.2  300  p  360  p  1
Between A & B
1 1
P0  v02  P  v2  gh ________(1)
2 2
D2 d 2
v0  v _____(2) between B & C
4 4
1 1
P  v2  P0  0g  H  h   v 2 ___(3)
2 2
From (1) and (2)
2
1  d2  1 1  d4 
P0    v   P  v 2  gh  0g  H  h   v 2 1    gh
2  D2  2 2  D 4

20
 v2  g  H  h   2gh  2  1.2  10  10  2  10  9

 240  180  60
 v  60m / s
d 2 
Qm    1  102  60  60.80
4 4
34. When the chimney is closed using a cap at the top, a pressure difference P develops
between the top and the bottom surfaces of the cap. If the changes in the temperature and
density of the hot air, due to the stoppage of air flow, are negligible then the value of P
is _____N m-2
Key: 20
Sol: Ans: 20
RT
P 4T4  T    1kg / m3 P1  P0 4 g  10

P2  P0 g  10 P   P4    g  10  0.2  10  10  20

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
CHEMISTRY Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
35. The correct molecular orbital diagram for F2 molecule in the ground state is

A) B)

C) D)
Key: C
   
Sol:  2  * 2  2  * 2     2   2    * 2  * 2 
1s 1s 2s 2s 2 p z2 2 p 2 p
 2 px 2 py   x y 

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
36. Consider the following statements related to colloids.
I) Lyophobic colloids are not formed by simple mixing of dispersed phase and dispersion
medium.
II)For emulsions, both the dispersed phase and the dispersion medium are liquid.
III) Micelles are produced by dissolving a surfactant in any solvent at any temperature.
IV) Tyndall effect can be observed from a colloidal solution with dispersed phase having
the same refractive index as that of the dispersion medium
The option with the correct set of statements is
A) I and II B) II and III C) III and IV D) II and IV
Key: A
Sol: I. Lyphobic colloids are not formed by simple mixing of DP and D.M
because there is no interaction between D.P and D.M
II. Emulsion is a colloidal solution in which both D.P and D.M are liquid
37. In the following reaction, P,Q,R, and S are the major products.

 i Mg,dry ether

 P
Cl  ii H2O

 i Mg,dry ether
 ii CO2 .dry ether
 Q
 iii  H3O+
Cl
 iv  NaOH

 i Mg,dry ether
 ii CH3CHO,then H 2O  R

Cl  iii CrO3

 i  ethanolic NaCN
 ii H2 /Ni
  S
 iii CHCl3 /KOH,Δ
Cl  iv LiAlH4 , then H2O

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
The correct statement about P, Q, R, and S is
A) P is a primary alcohol with four carbons.
B) Q undergoes Kolbe’s electrolysis to give an eight-carbon product.
C) R has six carbons and it undergoes Cannizzaro reaction.
D) S is primary amine with six carbons
Key:B
Sol:

Mg,dry ether


Cl MgCl

H 2O

+Mg  OH  Cl
P

Mg,dry ether


Cl MgCl

CO 2

C  OH
O
NaOH

C-ONa
O
Q

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Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

Mg,dry ether


Cl MgCl

CH3 -C-H
O
CH 3

CrO3 CH 3 CH3
O
R OH

NaCN


Cl CN

H 2 /Ni

CH 2  NH 2

CHCl3 /KOH

NH-CH3 LiAlH 4 NC
S

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
38. A disaccharide X cannot be oxidized by bromine water. The acid hydrolysis of X leads to
a laevorotatory solution. The disaccharide X is
CH 2OH CH 2OH
O O
H H H
H
OH H H OH
OH
O CH 2OH
H OH OH H
A)
CH2OH
CH2OH
H O
H O
H
H
OH H
HOH2C O OH H OH

H OH H OH
B)
CH2OH
CH2OH
O H
OH O OH
H
O H
OH H OH H
H
H H
H OH H OH
C)

CH 2OH CH 2OH
O H H O H
H
H H
OH H H OH
OH O OH
H OH OH H
D)
Key: A
Sol: Sucrose

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

39. The complex (es), which can exhibit the type of isomerism shown by  Pt  NH3 2 Br2  ,is

(are)  en=H 2 NCH 2CH 2 NH 2 

A)  Pt  en  SCN 2  B)  Zn  NH3 2 Cl 2 

+
C)  Pt  NH3 2 Cl4  D)  Cr  en  2  H 2O  SO 4  

Key: CD
Sol: *

 Pt  NH 3  Br2  Square Planar

 2 
Geometricalisomerism

 Zn  NH 3  Cl2   tetrahedralcomplex
 2 
-does not exhibit G.I

 M  aa  b 2   Sq planar
doesnot exhibit G.I

+
* Cr  en 2  H 2O  SO4  :  M  aa 2 bc   Octahedral  exhibit G.I 

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
40. Atoms of metals x, y and z form face – centred cubic (fcc) unit cell of edge length L x ,
body – centred cubic (bcc) unit cell of edge length L y , and simple cubic unit cell of edge

length L z , respectively.

3 8 3
If rz  ry ; ry  rx ; M z  M y and M z  3M x , then the correct statement(s)
2 3 2
is(are):
(Given: M x ,M y and M z are molar masses of metals x, y and z respectively; rx,ry and

rz are atomic radii of metals x, y and z, respectively.)

A) Packing efficiency of unit cell of x > Packing efficiency of unit cell of y > Packing
efficiency of unit cell of z
B) L y  L z

C) L x  L y

D) Density of x > Density of y

Key: ABD
Sol: Let MX  K rx  b L X  2 2b
8b  32b 
M Y  2K ry  LY  
3  3 
M X  3K rz  4b L Z  8b 
A. Packing efficiency of X  F .c.c  >Packing efficiency of Y[b.c.c]>Packing efficiency of Z[Simple
Cubic]
32b
B. Ly  Lz  8b Here L y  Lz
3
D. for unit cell X
4M X 4M Y
Density= For unit cell Y Density=
N A.L3X N A.L3Y

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
3
Density of X  2 M X   LY  Density of X
   1
Density of Y  M Y   LX  Density of Y
Densityof X  Density of Y
41. In the following reaction P, Q, R and S are the major products.

4 i KMnO ,KOH,Δ
 P
H 3CH 2C 
 ii H3O
MeOOC COCl

 i  NaOH,H
2
  Q
O

 ii H3O

COOMe

 i  H O , 
3
 R
 ii H 2CrO4

CN

The correct statement(s) about P, Q, R and S is (are)

A) P and Q are monomers of polymers dacron and glyptal, respectively.

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
B) P, Q and R are dicarboxylic acids.
C) Compounds Q and R are the same.
D) R does not undergo aldol condensation and S does not undergo Cannizzaro reaction.
Key: CD

p=

Sol: COOH

Q and R= Iso pthalicacid

S= terephalicacid
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
42. H 2S  5 moles  reacts completely with acidified aq potassium permanganate solution. In
this reaction, the number of moles of water produced is X, and the number of moles of
electrons involved is Y. The value of  X  Y  is:
Key: 18
Sol: 2MnO-4 +5H 2S+6H + 
 2Mn 2+ +5S+8H 2O
 4 2
43. Among  I3  ,SiO4  ,SO2Cl2 ,XeF2 ,SF4 ,ClF3 , Ni  CO 4 ,XeO2F2 ,  PtCl4  ,XeF4 and

SOCl2 , the total number of species having sp3 hybridized central atom is:
Key: 5
Sol: I3+ ,SiO4-
4 ,SO 2Cl 2 ,Ni  CO 4 ,SOCl 2  SP
3

XeF2 ,SF4 ,ClF3 ,XeO2F2  SP3d

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

XeF4  SP3d 2
PtCl2- 2
4 :dsp :squareplanar

44. Consider the following molecules: Br3O8 , F2O, H 2S4O6 , H 2S5O6 and C3O 2
Count the number of atoms existing in their zero oxidation state in each molecule. Their
sum is _____.
Key: 6
Sol: H 2S4O 6 : Two sulphurs with zero oxidation state
H 2S5O 6 : Three sulphurs with zero oxidation state
C3O 2 : One carbon with zero oxidation state

45. For He , a transition takes place from the orbit of radium 105.8 pm to the orbit of radius
26.45 pm. The wavelength (in nm) of the emitted photon during the transition is____
(Use:
Bohr radius, a = 52.9 pm

Rydberg constant, R H = 2.2  1018 J

Planck’s constant, h = 6.6  1034 J s

Speed of light, c = 3  108 m s1 )

Key: 30

n2
Sol: rn  52.9
Z

n2
105.8  52.9
2
On solving

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
Ans  =30nm

46. 50mL of 0.2 molar urea solution (density = 1.012 g mL1 at 300K) is mixed with 250mL
of a solution containing 0.06g of urea. Both the solutions were prepared in the same
solvent. The osmotic pressure (in Torr) of the resulting solution at 300K is_____

(Use: Molar mass of urea = 60 g mol1 ; gas constant, R = 62 L Torr K 1 mol1 ;

Assume,  mix H = 0,  mix V = 0)
Key: 682
Sol: solution-I 50ml, 0.2 molal urea solution with density 1.012 g/L of solution wt of solution
=50.6 gram Let urea = x gram
Solvent = (50-x) gram
x  1000
Molality =
60  (50.6  x)
1000x
0.2 
60   50.6  x 
X=0.6gram
Solution II- 0.06 gram urea in 250ml. solution
Total wt of urea =0.6+0.06
= 0.66gram
Total volume =50+250 =300ml
 0.66 100 
 =C. R T=   62  300 =682 torr
 60  300 

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
47. The reaction of 4 – methyloct – 1 –ene (P, 2.52g) with HBr in the presence of
 C6H5CO 2 O2 gives two isomeric bromides in a 9 : 1 ratio, with a combined yield of
50% . Of these, the entire amount of the primary alkyl bromide was reacted with an
appropriate amount of diehtylamine followed by treatment with aq K 2CO3 to give a non
– ionic product S in 100% yield.
The mass ( in mg) of S obtained is ______
(Use molar mass in g mol1 : H = 1; C =12; N = 14; Br = 80)
Key: 1791
Sol:

SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases

PARAGRAPH-I
The entropy versus temperature plot for phases  and  at 1 bar pressure is given. ST
and So are entropies of the phases at temperature T and 0 K , respectively:

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

6


5

ST -S0 J mol K -1 -1

Temperature  K  600

The transition temperature for  to  phase change is 600 K and

C p,  C p, = 1 J mol1 K 1 . Assume Cp,  Cp, is independent of temperature in the
 
range of 200 to 700 K. C p, and Cp, are heat capacities of  and  phases,
respectively.
48. 
The value of entropy change, S  S in J mol 1K 1 , at 300 K is: 
(use: ln 2 = 0.69, Given: S  S = 0 at 0 K)
Key: 0.31

600 C p dT
Sol: S600  S300  
300 T
600
 C p ln [for  -phase]
300
 C p ln 2
Similarly:-
600
S600  S300  C p ln [ For  -phase]
300
 C p ln 2

 S600,  S600,    S300,  S300,   C p  C p  ln 2

      

1   S300,  S300,   1 0.69  S600,  S600,  6  5

 
1  0.69   S300,  S300, 

0.31   S300,  S300, 

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s

49.  
The value of enthalpy change, H  H  in J mol 1 , at 300 K is________.

Key: 300

Sol: H 600  H 300  C p . 600  300  C p  1 j / mole K 

 
 1 300
H 600  H 300  300..........1
At 600K H  T S
Given S at 600K is 1J/mole K
H 600 K  600  1  600J
From eq(1) 600  H 300  300
H 300  600  300 H 300  300 J

PARAGRAPH-II
A trinitro compound 1, 3, 5 – tris – (4 – nitrophenyl) benzene, on complete reaction with
an excess of Sn/HCl gives a major product, which on treatment with an excess of

NaNO 2 / HCl at 00 C provides P as the product. P, upon treatment with excess of H 2O

at room temperature, gives the product Q. Bromination of Q in aq medium furnishes the
product R. The compound P upon treatment with an excess of phenol under basic
conditions gives the product S.

The molar mass difference between compounds Q and R is 474 g mol1 and between

compounds P and S is 172.5 g mol1 .

50. The number of hetero atoms present in one molecule of R is_______.

(Use molar mass (in g mol1 ): H = 1; C = 12, N = 14, O = 16, Br = 80, Cl = 35.5
Atoms other than C and H are considered as hetero atoms
Key: 9

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 Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
51. The total number of carbon atoms and hetero atoms present in one molecule of S is:

[Use molar mass in g mol1 : H = 1; C = 12, N = 14, O = 16, Br = 80, Cl = 35.5

Atoms other than C and H are considered as hetero atoms]
Key: 51
Sol: 50 & 51
N 2Cl

P=

N 2Cl N 2Cl

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Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P2-QP & Sol’s
OH

Q=

OH OH

OH

Br Br

R=

Br Br

OH OH

Br Br

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