Determination of Radon and Thoron Activity in The Soil by Using Solid Statenuclear Track Detectors Ssntds Passive Technique
Determination of Radon and Thoron Activity in The Soil by Using Solid Statenuclear Track Detectors Ssntds Passive Technique
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ISSN: 0976-8610
CODEN (USA): AASRFC
Determination of Radon and Thoron Activity in the Soil By using Solid State
Nuclear Track Detectors (SSNTDs), Passive Technique
Huda R. Algaim1, Rifat M. Dakhil2 and Isa J. Al-Khalifa3
1
Environment and Pollution Department, Basrah Technical College, Foundation of Technical
Education, Basrah, Iraq
2
Petrochemical Engineering Department, Basrah Technical College, Foundation of Technical
Education, Basrah, Iraq
3
Physics Department, College of Education, Basrah University, Basrah, Iraq
______________________________________________________________________________
ABSTRACT
Radon and thoron activity concentration levels have been determined in the soil of Basra Governorate, Iraq. The
area of the study included three districts, they are Hayy-Alabas, Hayy-Aljameeat and Almuaficia.. In this
investigation CR-39 and LR-115 type2 solid state nuclear track detectors and a cylindrical plastic container
technique are used. The samples are taken from the surface and the depth 1m for each location. Maximum activity of
radon levels observed is (16200 Bq.m-3) in Hayy-Alabas station number 10 for soil from the surface and minimum
levels is (1560 Bq.m-3) were observed in Almuaficia station number 54 for soil from the surface. The activity of
radon were measured in Hayy-Aljameeat and Almuaficia which are with in normal limits according to
International Commission on Radiological Protection (ICRP). The high values of radon activity are measured in
many locations in Hayy-Alabas and Hayy-Aljameeat. There are many anomalous values of radon activity in the
soil in some stations of Hayy-Alabas has been observed in this study. The reasons of this anomalous has been
220
discussed. The activity concentration of thoron is smaller than the activity concentration for radon (( Ac / Ac222 )
<1) over all study area. The reason of this result has been discussed. The average value of the activity of thoron
concentration Ac220 in the soil samples from the surface equal 2073.33 Bq.m-3, 1893.75 Bq.m-3 and 1822.22 Bq.m-3
for Hayy-Alabas, Hayy-Aljameeat and Almuaficia respectively and the average value for the soil samples from the
depth 1m equal 1666.66 Bq.m-3 , 906.25 Bq.m-3 and 1103.333 Bq.m-3 for Hayy-Alabas, Hayy-Aljameeat and
Almuaficia respectively.
Keywords: Radon, Thoron, CR-39, LR-115 type 2, soil , Activity (Bq m-3).
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INTRODUCTION
Radon is a fascinating type of element in which it is only massive inert gas found every where in different
proportions. This special property of radon make it to unique and have characteristics which are unusual in their
combination [1]. Radon, thoron and their decay products are alpha-, beta- and gamma-emitting nuclei. Inhalation of
these radionuclides represents the main source of exposure to ionizing radiation for population in most countries [2-
5].
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Huda R. Algaim et al Adv. Appl. Sci. Res., 2012, 3(2):950-961
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BASRAH-IRAQ
Figure(1): Basrah Governorate, numbering in station number (s), represent the places where samples taken
from, (the two maps are from Google Earth)
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Measurements of radon are importance because the radiation dose to human population due to inhalation of radon
and its daughters contributes more than 50% of the total dose from natural sources [6]. The dose which deriving
from the presence in the air of 222Rn is linked to the inhalation of its short–lived daughters, which are deposited in
the respiratory organs, if deeply inhaled, emit alpha-particles in direct contact with the bronchial and pulmonary
epithelium. For these reasons, the dose deriving from the exposure to 222Rn in closed spaces has been placed in
direct relation to the risk of lung cancer [7]. It seems that radon accepted the idea and implementation of
globalization of the world by making available itself everywhere. Its existences is strongly tied with the presence of
other elements. Outside air typically contains very low levels of radon, however, it may build up to higher
concentrations indoors when it is unable to disperse [8].
The main source of indoor radon is the soil, the activity concentration of radon coming from the soil can reach
higher and higher values due to the better and better insulation techniques of dwellings. The epidemiological
researches show the relative risk of lung cancer is 1.33 above 200 Bq m-3 [9] and the relative risk increases by 0.15-
0.2 per 100 Bq m-3 [10]. Solid state nuclear track detectors (SSNTD) have been extensively used in this regard and
almost all branches of science and technology [11-14].
In this study, we use a SSNTD technique based on determining detection efficiencies of the CR-39 and LR-115 type
II solid state nuclear track detectors for measuring α - particles due to the radon and thoron series. The relevant
ranges of the emitted α -particles in air and SSNTD utilized, were calculated by means of a TRIM program [15]. In
this work we used (SSNTDs) to evaluate radon and thoron concentrations in various soil samples are brought from
different places from Hayy-alabaas district and the area around it in Basra governorate, In order to set a baseline
data for these areas which would be of great help for radiological database of Iraq.
METHOD OF STUDY
The soil samples were collected from 55 locations in Basrah city during October 2011. The area of study included
three districts Hayy-Alabas, Hayy-Aljameeat and Almuaficia as shown in figure(1). The soil samples where taken
from the surface and depth 1m from each location. The number of soil samples is 110. Each one of these soil
samples is dried in the oven at 120 oC and milled in the grinder. Finally, all samples are sieved (riddled) in sieve
with 300 µ m pores. Each sample of soil of 1cm height is placed in the bottom of the closed cylindrical plastic
container as shown in the Fig.(2) [16].
Soil Sample
Figure(2):Arrangement of the solid state nuclear track detector films placed at a distance of 9 cm above a soil
sample in a cylindrical plastic container
of 2 cm radius.
Identical disks of radius 2 cm of CR-39 and LR-115 type II SSNTDs have been separately placed at a distance of 9
cm above the sample for one month. Two identical films of CR-39 and the same from LR-115 type II are used for
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Huda R. Algaim et al Adv. Appl. Sci. Res., 2012, 3(2):950-961
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each sample to achieve a high accuracy. This long time of irradiation is necessary for secular equilibrium and to
accumulate considerable number of tracks of α -particles that emitted from radon, thoron and their progenies.
After the irradiation, the exposed films were developed in an NaOH solution with chemical etching conditions 2.5
N at 60 oC for 120 minutes for LR-115 type II films and 6.25 N at 70 oC for 7 hours for CR-39 films [17]. After the
chemical treatment of the CR-39 and LR-115 type II detectors the visual counting of alpha particles tracks (i.e. N GCR ,
N GLR ) are carried out by means of an optical microscope.
The global alpha particle track densities that registered on CR-39 and LR-115 detectors (i.e. ρ GCR and ρ GLR ) are
calculated according to the following equations
N GCR
ρ CR
= -------------------------------- ( 1)
AG × t G
G
And
N GLR
ρ
----------------------------- ( 2)
LR
=
AG × t G
G
Where AG is the global area of view and tG is the global time of irradiation, N GCR and N GLR are the average values
of the number of tracks registered on the CR-39 and LR-115 detectors respectively .
Hence, the global density of tracks due to the α -particles emitted by radon, thoron and their daughters, registered
on the CR-39 SSNTD is then
ρ GCR = Ac222 (Bq. cm −3 ) ∑ k i Pi CR Ri +
3
Ac220 4
Ac222
∑ k i Pi
CR
Ri ……………….. (3)
i =1 i =1
The global density of tracks per unit time (tracks.cm-2.s-1) due to the α -particles of the radon and thoron groups
registered on the LR-115 type II SSNTD is then equal to:
Combining eqs.(3) and (4), the following relationship between track densities and thoron to radon ratio is [17]:
3
Ac220 4
ρ CR ∑ ki Pi
i =1
CR
Ri + 222
Ac
∑k i =1
i Pi CR Ri
G
= ………… (5)
ρ LR
Ac220
G
3 P LR
∆R + 4 P LR
∆R 222
Ac
CR
Where, Pi represents the probability for an alpha-particle of energy Eαi and index i emitted at a distance x
from the detector to reach and be registered on the CR-39 SSNTD [17].
LR
The values of Pi CR for each index i are shown in Table (1) and the values of P for each residual thickness are
shown in Table (2).
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Huda R. Algaim et al Adv. Appl. Sci. Res., 2012, 3(2):950-961
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Knowing ρ GCR , ρ GLR , Pi CR and P LR one can determine the Ac220 / Ac222 ratio and consequently the Ac220 and
Ac222 activities of the studied soil samples have been evaluated.
E α i, MeV
Nuclide Ri , cm
Pi CR × 10 −3
Radon group α -particles
222
Rn 5.49 3.90 2.871
218
Po 6.00 4.65 3.383
214
Po 7.68 6.65 4.440
Thoron group α -particles
220
Rn 6.28 4.80 3.391
216
Po 6.78 5.45 3.433
212
Bi 6.08 4.75 3.527
212
Po 8.78 8.36 5.711
Table (2): Values of the probability ( P ) for the α -particles of the radon and thoron groups to be
LR
registered on the LR-115 SSNTD for different residual thickness for (LR-115 films) for the gas volume of the
water samples. Rmin and Rmax are the α -particles ranges in the gas volume which correspond to the lower
and upper ends of the energy window [17].
µm
P LR × 10 −3
Residual thickness, Rmax , cm
Rmin , cm
3 0.46 3.83 203.299
4 0.61 3.52 11.302
5 0.80 3.44 4.329
6 0.98 2.71 1.536
7 1.07 2.66 1.405
8 1.29 2.53 1.336
9 1.42 2.31 0.267
10 1.60 2.02 0.191
220 222
The Ac / Ac ratios and the radon and thoron activity per unit volume for the samples studied have been
determined by using Equations (5) and (4) respectively . The error on track density counting is smaller than 7% for
samples studied. The area of study included Hayy-Alabas, Hayy-Aljameeat and Almuaficia districts in Basrah
Governorate, each location of the study called station. From table(3) to table(8) shows the number of station, the
global track density of LR-115 type II ( ρ G ), the global track density of CR-39 ( ρ G ), the ratio of
LR CR
Ac220 / Ac222 ,
222 220
the activity of 222Rn ( Ac ) and the activity of 220Rn( Ac ) for the soil samples. Table(3), table(5) and table(7) are
concerned with the soil samples from the surface. Table(4), table(6) and table(8) are concerned with the soil samples
from the depth 1m .
From Table(3) and table (4) it is clear that the observed radon concentrations for the soil from the surface and depth
1m in allot of stations in Hayy Alabas district are high than the natural limits [7].
The high levels of radon concentrations in the soil means clearly there are high uranium and radium concentrations
in this soil [18], therefore, the high levels of radon concentrations in many stations in Hayy-Alabas district may be
refer to high concentration of uranium and radium, which need more investigation.
When we lock carefully to the data in table(3) and table(4) we notice the radon concentrations for the soil which got
from the surface of almost stations of study is greater than for soil which got from the depth 1m, this mean there are
external pollution of uranium in the soil of this stations because of in natural case the concentration of uranium is
increase with increasing in depth [19]. The data in table(3) and table(4) is shown in figure(3) and figure(4).
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Table (3): The radon and thoron concentration in the soil samples from the surface in Hayy-Alabas in Basrah
governorate
1.6E+04
1.4E+04
1.2E+04
1.0E+04
8.0E+03
6.0E+03
4.0E+03
2.0E+03
0.0E+00
S1 S2 S3 S4 S5 S6 S7 S8 S9 S10 S11 S12 S13 S14 S15 S16 S17 S18 S19 S20 S21 S22 S23 S24 S25 S26 S27 S28 S29 S30
Station Number
Figure(3): The Radon concentration of the soil samples from the surface and depth 1m in Hayy-Alabas in
Basrah governorate.
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Table (4): The radon and thoron concentration in the soil samples from the depth 1m in Hayy-Alabas in
Basrah governorate.
5000
4000
3000
2000
1000
0
S1 S2 S3 S4 S5 S6 S7 S8 S9 S10 S11 S12 S13 S14 S15 S16 S17 S18 S19 S20 S21 S22 S23 S24 S25 S26 S27 S28 S29 S30
Station Number
Figure(4): The Thoron concentration of the soil samples from the surface and depth 1m in Hayy-Alabas in
Basrah governorate.
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Table (5): The radon and thoron concentration in the soil samples from the surface in Hayy-Aljameeat in
Basrah governorate
Table (6): The radon and thoron concentration in the soil samples from the depth 1m in Hayy- Aljameeat in
Basrah governorate.
From table(5) and table(6) we noted the levels of radon concentrations for hayy-Aljameet stations are in the natural
limits, but the soil from the depth 1m for stations number 32,33,34 and 35 have a high levels in compare with
another stations. The data in table(5) and table(6) is shown in figure(5) and figure(6).
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1.E+04
1.E+04
1.E+04
8.E+03
6.E+03
4.E+03
2.E+03
0.E+00
S31 S32 S33 S34 S35 S36 S37 S38 S39 S40 S41 S42 S43 S44 S45 S46
Station Number
Figure(5): The Radon concentration of the soil samples from the surface and depth 1m in Hayy-Aljameeat in
Basra governorate.
6.E+03
5.E+03
4.E+03
3.E+03
2.E+03
1.E+03
0.E+00
S31 S32 S33 S34 S35 S36 S37 S38 S39 S40 S41 S42 S43 S44 S45 S46
Station Number
Figure(6): The thoron concentration of the soil samples from the surface and depth 1m in Hayy-Aljameeat in
Basrah governorate.
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Table (7): The radon and thoron concentration in the soil samples from the surface in Al Muaficia in Basrah
governorate .
Table (8): The radon and thoron concentration in the soil samples from the depth 1m in Al Muaficia in
Basrah governorate .
From table(7) and table(8) we noticed the levels of radon concentrations for all stations of Almwaficia are in the
natural limits. The data in table(7) and table(8) is shown in figure(7) and figure(8).
1.0E+04
8.0E+03
6.0E+03
4.0E+03
2.0E+03
0.0E+00
S47 S48 S49 S50 S51 S52 S53 S54 S55
Station Number
Figure(7): The Radon concentration of the soil samples from the surface and depth 1m in Almuaficia in
Basrah governorate.
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4.0E+03
3
3.5E+03
3.0E+03
2.5E+03
2.0E+03
1.5E+03
1.0E+03
5.0E+02
0.0E+00
S47 S48 S49 S50 S51 S52 S53 S54 S55
Station Number
Figure(8): The thoron concentration of the soil samples from the surface and depth 1m in Almuaficia in
Basrah governorate
220 222
From all above tables we noticed the ratio ( Ac / Ac ) <1 , this mean thoron concentration is smaller than radon
concentration over all study area may be because of the short half life for thoron in comparison with radon and the
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long irradiation time(one month)[20]. The average value of the activity of thoron concentration Ac in the soil
samples from the surface equal 2073.33 Bq.m-3, 1893.75 Bq.m-3 and 1822.22 Bq.m-3 for Hayy-Alabas, Hayy-
Aljameeat and Almuaficia respectively and the average value for the soil samples from the depth 1m equal 1666.66
Bq.m-3 , 906.25 Bq.m-3 and 1103.333 Bq.m-3 for Hayy-Alabas, Hayy-Aljameeat and Almuaficia respectively.
CONCLUSION
In this investigation, the activity of radon and thoron levels have been measured in the soil of the three districts in
Basra governorate. In this study the maximum radon activity (16200 Bq.m-3 )have been observed in Hayy-Alabas
district, station number 10 for soil from the surface, while the minimum radon activity (1560 Bq.m-3) has been
observed in Almuaficia district, station number 54 for soil from the surface. The average value of the activity of
thoron concentration Ac220 in the soil samples from the surface equal 2073.33 Bq.m-3, 1893.75 Bq.m-3 and 1822.22
Bq.m-3 for Hayy-Alabas, Hayy-Aljameeat and Almuaficia respectively and the average value for the soil samples
from the depth 1m equal 1666.66 Bq.m-3 , 906.25 Bq.m-3 and 1103.333 Bq.m-3 for Hayy-Alabas, Hayy-Aljameeat
and Almuaficia respectively.
The high levels of radon concentrations which observed in the soil samples for any stations in this study are came
may be from the high concentrations of uranium and thorium in this soil, the study of uranium concentrations of
these soils are in progress. The high concentration of uranium and radium in the stations in Hayy-Alabas district are
came from external pollutions because of the radon concentrations for the soil which got from the surface of almost
stations of study is greater than for soil which got from the depth 1m.
220 222
The ratio ( Ac / Ac ) <1 , this mean thoron concentration is smaller than radon concentration over all study area
may be because of the short half life for thoron in comparison with radon and the long irradiation time.
The data in this study is the first investigation and this study provided a basis for the radiation pollution and radon
map in Iraq.
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