This document discusses petrochemical feedstock and specialty products. It begins by introducing the petrochemical industry and its importance. It then discusses petrochemical feedstock, noting that natural gas liquids and naphtha created during oil refining are used to manufacture various petrochemicals. Key factors like availability, cost and desired product portfolio govern feedstock choice. The document also discusses specialty products derived from basic petrochemical intermediates and how they are used in various markets and applications.
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Lecture 4
This document discusses petrochemical feedstock and specialty products. It begins by introducing the petrochemical industry and its importance. It then discusses petrochemical feedstock, noting that natural gas liquids and naphtha created during oil refining are used to manufacture various petrochemicals. Key factors like availability, cost and desired product portfolio govern feedstock choice. The document also discusses specialty products derived from basic petrochemical intermediates and how they are used in various markets and applications.
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PETROCHEMICAL FEEDSTOCK
AND SPECIALTY PRODUCTS
Contents Introduction
Petrochemical Feedstock
Specialty Products
Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 2
Introduction Petrochemical Industry Petrochemicals constitute a very important segment of world chemicals market, with a share of nearly 40 per cent.
The industry is important as it has several linkages with
other sectors of an economy.
Petrochemicals have backward linkages with other
industries in petroleum refining, natural gas processing and forward linkages with industries that deal in a variety of downstream products. Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 4 Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 5 Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 6 Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 7 Petrochemical Feedstock A feedstock is a raw material that is used to make a useful product in an industrial process.
Natural gas liquids and naphtha that is created from
crude oil during the refining process are used as feedstock to manufacture a wide variety of petrochemicals.
The industry uses a variety of hydrocarbon feedstock
such as different cuts of naphtha from refinery and natural gas (NGL, ethane, propane, butane, LPG).
Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 13
Choice of Feedstock Four crucial factors govern the choice of feedstock in petrochemical plants: availability, cost, power consumption and the product portfolio to be produced.
With respect to availability, the plant owners
need to be assured of continuous availability of feedstock. Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 14 Power accounts for 10 per cent of the cost involved in the cracking of feedstock. an uninterrupted high quality power is required for the same. Hence, many petrochemical complexes use captive power.
The cost of feedstock is the single largest cost in the production
of petrochemicals. Estimates show that cost of feedstock accounts for 40-60 per cent of total costs.
While availability is not much of an issue for naphtha, demand
for propane and butane is curtailed due to both pricing as well as domestic unavailability. LNG imports are, therefore, an increasingly sought option. Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 15 Per the portfolio of products, naphtha is used when a wide range of co-products (including propylene and butadiene derivatives) is desired while natural gas and NGL are preferred when the ethylene output of a cracker is to be maximized since they yield a higher proportion of ethylene.
Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 16
Since each feedstock has a dissimilar composition of hydrocarbons, the percentages of petrochemical product yields are different, depending on feedstock.
For example, using natural gas to produce
ethylene returns 80% ethylene and 20% other products, whereas using naphtha returns only 30% ethylene and 70% other products.
Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 17
Feedstock by Region Specialty Products Petroleum feedstock, natural gas, and tar represent the main production chain drivers for the petrochemical industry.
From these basic components, many important
petrochemical intermediates are produced including ethylene, propylene, butylenes, butadiene, benzene, toluene, and xylene.
These essential intermediates are in turn converted into
many other intermediates and final petrochemical products constructing a complex petrochemical network. Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 20 Specialty and industrial chemicals such as surfactants, ethoxilates, glycoethers and desemulsionates are used in a wide variety of products that serve numerous markets like crude oil production, water treatment, pharmaceutical, cosmetic, detergents, varnishes, paints and cleaning products. Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 22 Specialty Products Polyethylene glycols Polypropylene glycols Polyalkylene glicols (PAG´s) Non-ionic surfactants Chelating Agents Biocides Waxes Oil Field Chemicals (OFCs) Electroplating Green Products Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 23 Global Specialty Chemicals = $545 billion in 2014
Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 24
Production of Specialty Chemical – Acrylic Ester
Uses: Adhesives, Paints and Coatings
Ing. Prof. Nana Derkyi Oil Ref & PChem Engg 25 Value Addition to Petrochemical Feedstock Ensures the Production of Specialty Products of LOVE.