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Poll
CHEMISTRY (C-29)
Syllabus: Solutions

Choose the correct option. (2) Both statement-I and statement-II are true
1. Sum of mole fractions of all the components in a (3) Both statement-I and statement II are false
solution is equal to (4) Statement-I is correct but statement-II is false
(1) 1 (2) ∞
5. Incorrect thermodynamic relation for ideal solution
(3) 0 (4) 10 is
2. The mass of glucose (C6H12O6) required in making (1) Δmix G < 0
2kg of 0.5 molal aqueous solution is
(2) Δmix S < 0
(1) 100 g
(2) 150 g (3) Δmix H = 0

(3) 165 g (4) Δmix V = 0

(4) 200 g 6. Which of the following mixtures shows negative
3. Consider the following statements about Henry's deviation from Raoult's Law?
law (1) CHCl3 + CH3COCH3
(I) The partial pressure of the gas in vapour
(2) C6H6 + C7H8
phase(p) is proportional to the mole fraction of
the gas in the solution (3) C2H5OH + CH3COCH3
(II) For a gas, higher the value of KH at a given (4) C2H5Br + C2H5Cl
pressure, lower will be its solubility in the liquid
7. Incorrect statement about azeotropes is
(III) Aquatic animals are more comfortable in
warm water than in cold water (1) These are binary mixture having same
Correct statement(s) among the following composition in liquid and vapour phase
is/are (2) Boils at a constant temperature
(1) I only (2) I and III only (3) The components of azeotropes can be
(3) I and II only (4) I, II and III separated by fractional distillation
4. Statement I: Dissolution of gas in liquids is an (4) 68% nitric acid and 32% water by mass, form
exothermic process. maximum boiling azeotrope
Statement II: Solubility of gases in liquid 8. Unit of Ebullioscopic constant is
decreases with rise in
temperature. (1) K mol kg–1 (2) K kgmol–1
In the light of the above statements, choose the (3) kg mol–1 (4) kg mol g–1
correct answer from options given below.
9. The value of Cryoscopic constant increases
(1) Statement-I is incorrect but statement-II is true

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Poll-29 Chemistry
(1) On increasing the value of enthalpy of fusion (4) 0.1 M NaCl

(2) On increasing the freezing point of the pure 15. The lowering of vapour pressure for 2 molal
solvent aqueous solution of glucose is (vapour pressure of
water = 760 mm of Hg)
(3) On decreasing the molar mass of the solvent
(1) 26.4 mm of Hg
(4) On increasing the molality of the solution
10. Osmosis involves (2) 34.27 mm of Hg

(1) Flow of solvent from concentrated solution to (3) 18.27 mm of Hg

dilute solution
(4) 760 mm of Hg
(2) Flow of solute from concentrated solution to 16. Mole fraction of a gas in water 0.02 at STP, its
dilute solution Henry's Law constant is
(1) 2 × 102 bar
(3) Flow of solvent from dilute solution to
concentrated solution (2) 0.05 bar
(3) 50 bar
(4) Flow of solute from dilute solution to
(4) 5 × 102 bar
concentrated solution
17. An ideal solution is prepared by mixing two volalite
11. Which of the following colligative property is widely liquids A and B. If the vapour pressure of the
used to determine the molar masses of proteins solution is 180 mm of Hg, then the mole fraction of
and polymers? B in vapour phase is
(1) Relative lowering of vapour pressure (P°
A = 150 mm of Hg and PB° = 200 mm of Hg )
(2) Elevation in boiling point (1) 0.67
(2) 0.34
(3) Depression in freezing point
(3) 0.75
(4) Osmotic pressure (4) 0.50
12. van't Hoff factor of AlCl3 at 0.1 M is 2.8. 18. If 50 mL of 0.01 M Al2(SO4)3 is mixed with 100 ml
Percentage dissociation of AlCl3 is of 0.02 M BaCl2, then the concentration of Cl– ion
in the solution is
(1) 30 (2) 60 (1) 0.016 M (2) 0.026 M
(3) 90 (4) 50 (3) 0.06 M (4) 0.004 M
19. Which of the following properties will have
13. The correct order of freezing point for 10 g
identical values for dilute equimolar solutions of
aqueous solution each of urea, glucose and
different non-electrolytes in the same solvent?
sucrose is
(I) Boiling point
(1) Tf(glucose) > Tf(urea) > Tf(sucrose) (II) Freezing point
(2) Tf(sucrose) > Tf(glucose) > Tf(Urea) (III) Osmotic pressure
(IV) Vapour pressure
(3) Tf(urea) > Tf(glucose) > Tf(sucrose) (1) I only (2) I and II only
(4) Tf(sucrose) > Tf(urea) > Tf(glucose) (3) I, II and III only (4) I, II, III and IV
20. If vapour pressure of water at 293 K is 17.50 mm
14. Which of the following aqueous solution is isotonic of Hg, then the vapour pressure of water when
with 0.1 M aq. K4[Fe(CN)6]? 18g of glucose is dissolved in 450 g of water at
293 K is
(1) 0.05 M glucose
(1) 10.97 mm of Hg (2) 17.43 mm of Hg
(2) 0.2 M MgCl2 (3) 14.24 mm of Hg (4) 31.21 mm of Hg
(3) 0.1 M Al2(SO4)3

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Poll-29 Chemistry

Corporate Office :Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

Poll
CHEMISTRY (C-29)
Answer Key

1. (1) 11. (4)

2. (3) 12. (2)
3. (3) 13. (2)
4. (2) 14. (3)
5. (2) 15. (1)
6. (1) 16. (3)
7. (3) 17. (1)
8. (2) 18. (2)
9. (2) 19. (4)
10. (3) 20. (2)
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Poll-29 Chemistry

Corporate Office :Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

Poll
CHEMISTRY (C-29)
(Solution and Answers Key)

1. Answer (1) 11. Answer (4)

[NCERT-Page 37 ] [NCERT-Page 55]
2. Answer (3) 12. Answer (2)
[NCERT-Page 39 ] [NCERT-Page 58]
3. Answer (3) 13. Answer (2)
[NCERT-Page 42] [NCERT-Page 52]
4. Answer (2) 14. Answer (3)
[NCERT-Page 43 ] [NCERT-Page 56]
5. Answer (2) 15. Answer (1)
[NCERT-Page 47] [NCERT-Page 49]
6. Answer (1) 16. Answer (3)
[NCERT-Page 48] [NCERT-Page 41]
7. Answer (3) 17. Answer (1)
[NCERT-Page 48] [NCERT-Page 44]
8. Answer (2) 18. Answer (2)
[NCERT-Page 51] [NCERT-Page 38]
9. Answer (2) 19. Answer (4)
[NCERT-Page 53] [NCERT-Page 49]
10. Answer (3) 20. Answer (2)
[NCERT-Page 55 ] [NCERT-Page 50]
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