Paper Set 1

CHEM std 11 ch 4 JEE-NEET

Standard: 11 Subject: Chemistry Date: 01/04/2020
Marks: 400 HIREN SAVANI Time: 02H:00M

 
CHEMISTRY


1. In which of the following compounds does hydrogen bonding occur
(A) SiH4 (B) LiH (C) HI (D) N H3
2. Which of the following has zero dipole moment
(A) CH2 Cl2 (B) CH4 (C) N H3 (D) P H3
3. Which has the highest bond energy
(A) F2 (B) Cl2 (C) Br2 (D) I2
4. The correct order of hybridization of the central atom in the following species N H3 [P tCl4 ]2− , P Cl5 and BCl3 is

I
(A) dsp2 , dsp3 , sp2 and sp3 (B) sp3 , dsp2 , dsp3 , sp2 (C) dsp2 , sp2 , sp3 , dsp3 (D) dsp2 , sp3 , sp2 , dsp3

AN
5. In which of the following combination hybridisation of central atom (∗ ) does not change?
• • •
(A) H2 O + C O2 (B) H3 B O3 + OH − (C) BF3 + N H3 (D) None of these
6. Which of the following compounds have the same no. of lone pairs with their central atom?
(I) XeF5− (II) BrF3 (III) XeF2 (IV ) H3 S + (V ) Triple Methylene
(A) IV and V (B) I and III
V (C) I and II (D) II, IV and V
SA
7. Which of the following is paramagnetic
(A) O2 (B) CN − (C) CO (D) N O+
8. Assertion : Cuprous ion (Cu+ ) has unpaired electrons while cupric ion (Cu++ ) does not.
Reason : Cuprous ion (Cu+ ) is colourless whereas cupric ion (Cu++ ) is blue in the aqueous solution.
(A) If both Assertion and the Assertion. correct explanation of correct.
N

Reason are correct (B) If both Assertion and the Assertion.

and the Reason is a (D) If both the Assertion
correct explanation of Reason are correct (C) If the Assertion is cor- and Reason are incor-
RE

but Reason is not a rect but Reason is in- rect.

9. A molecule XY2 contains two σ, two π-bonds and one lone pair of electron in the valence shell of X. The arrange-
ment of lone pair as bond pair is
(A) square pyramidal (B) linear (C) trigonal planar (D) unpredictable
HI

10. An ionic compound is generally a

(A) Good electrolyte (B) Weak electrolyte (C) Non-electrolyte (D) Neutral
11. Assertion : Lone pair-lone pair repulsive interactions are greater than lone pair-bond pair and bond pair-bond
pair interactions.
Reason : The space occupied by lone pair electrons is more as compared to bond pair electrons.
(A) If both Assertion and the Assertion. correct explanation of correct.
Reason are correct (B) If both Assertion and the Assertion.
and the Reason is a (D) If both the Assertion
correct explanation of Reason are correct (C) If the Assertion is cor- and Reason are incor-
but Reason is not a rect but Reason is in- rect.
12. When two atoms of chlorine combine to form one molecule of chlorine gas, the energy of the molecule
(A) Greater than that of separate atoms (B) Equal to that of separate atoms
(C) Lower than that of separate atoms (D) None of the above statement is correct
13. Point out incorrect statement about resonance
(A) Resonance structures should have equal energy
(B) In resonance structures, the constituent atoms should be in the same position
(C) In resonance structures, there should not be the same number of electron pairs
(D) Resonance structures should differ only in the location of electrons around the constituent atoms
14. Which of the following best describes the diagram of molecular orbital?

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 (A) A bonding π orbital (B) A non - bonding or- (C) An antibonding σ or- (D) An antibonding π or-
bital bital bital
15. Low melting point is expected for a solid
(A) Ionic solid (B) Metallic solid (C) Molecular solid (D) Covalent solid
16. In the compound CH2 = CH − CH2 − CH2 − C ≡ CH, the C2 − C3 bond is of the type
(A) sp − sp2 (B) sp3 − sp3 (C) sp − sp3 (D) sp2 − sp3
17. In which of the following molecule µ ( observed) is found to be greater than µ (theoretical)
(A) CHCl3
(C) (D)
(B)

18. Which one of the following does not have a pyramidal shape?
(A) (CH3 )3 N (B) (SiH3 )3 N (C) P (CH3 )3 (D) P (SiH3 )3
19. How many resonance forms can be written for the nitrate ion, (N O3− ) ?
(A) 1 (B) 2 (C) 3 (D) 4

I
20. The decreasing values of bond angles from N H3 (106 ) to SbH3 (101 ) down group−15 of the periodic table is
o o

AN
due to
(A) decreasing lp − bp repulsion (B) decreasing electronegativity
(C) increasing bp − bp repulsion (D) increasing p−orbital character in sp3
21. The strength of bonds formed by 2s − 2s, 2p − 2p and 2p − 2s overlap has the order
(A) s − s > p − p > p − s (B) s − s > p − s > p − p
V (C) p − p > p − s > s − s (D) p − p > s − s > p − s
SA
22. Dipole moment is shown by
(A) 1, 4−dichlorobenzene (B) cis 1, 2−dichloroethene
(C) trans1, 2−dichloro−2−pentene (D) (b) and (c)
23. Which has the shortest C − C bond length
N

(A) C2 H5 OH (B) C2 H6 (C) C2 H2 (D) C2 H4

24. If HCl molecule is completely polarized, so expected value of dipole moment is 6.12 D (deby), but experimental
RE

value of dipole moment is 1.03 D. Calculate the percentage ionic character

(A) 17 (B) 83 (C) 50 (D) 0
25. Water is liquid due to
HI

(A) Hydrogen bonding (B) Covalent bond (C) Ionic bond (D) Vander Waals forces
26. Which pair of molecules are polar species?
(A) CO2 and H2 O (B) BF3 and P Cl3 (C) SO2 and SCl2 (D) CS2 and SO3
27. The molecule which is pyramid shape is
(A) P Cl3 (B) CO32− (C) SO3 (D) N O3−
28. Which of the following molecules has two sigma (σ) and two pi (π) bonds?
(A) C2 H4 (B) N2 F2 (C) C2 H2 Cl2 (D) HCN
29. What is not true about ice?
(A) It has open cage like structure (B) It has less density than water
(C) Each O atom is surrounded by 4 H atoms (D) Each O atom has four H− bonds around it
30. Which is the correct electron dot structure of N2 O molecule
.. .. .. .. .. ..
(A) : N = N = O (B) : N ≡ N + − O :− (C) N = N = O (D) : N = N = O :
.. .. .. .. ..
31. Which of the following pair of molecules will have permanent dipole moment?
(A) N O2 and CO2 (B) N O2 and O3 (C) SiF4 and CO2 (D) SiF4 and N O2
32. An atom of an element A has three electrons in its outermost shell and that of B has six electrons in the outer-
most shell. The formula of the compound between these two will be
(A) A3 B4 (B) A2 B3 (C) A3 B2 (D) A2 B3
33. The bonds in K4 [F e (CN )6 ] are

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 (A) All ionic (B) All covalent
(C) Ionic and covalent (D) Ionic, covalent and coordinate covalent
34. Out of the following which has smallest bond length
(A) O2 (B) O2+ (C) O2− (D) O22−
35. A lone pair of electrons in an atom implies
(A) A pair of valence electrons not involved in bonding (B) A pair of electrons involved in bonding
(C) A pair of electrons (D) A pair of valence electrons
36. Phosphate of a metal M has the formula M3 (P O4 )2 . The formula for its sulphate would be
(A) M SO4 (B) M (SO4 )2 (C) M2 (SO4 )3 (D) M3 (SO4 )2
37. Resonance is due to
(A) Delocalization of sigma electrons (B) Delocalization of pi electrons
(C) Migration of H atoms (D) Migration of protons
38. Sulphuric acid provides a example of
(A) Covalent and Co-ordinate bonds (B) Non-covalent compound
(C) Covalent bond (D) Non-covalent ion

I
39. Which of the following hybridisation has maximum s−characters

AN
(A) sp3 (B) sp2 (C) sp (D) None of these
+
40. The hybridization of Ag in the linear complex [Ag (N H3 )2 ] is
(A) dsp2 (B) sp (C) sp2 (D) CCl4
41. The bond order is not three for
(A) N2+ (B) O22+
V (C) N2 (D) N O+
SA
42. The enolic form of acetone contains
(A) 9 sigma bonds, 1 pi bond and 2 lone pairs (B) 8 sigma bonds, 2 pi bonds and 2 lone pairs
(C) 10 sigma bonds, 1 pi bond and 1 lone pair (D) 9 sigma bonds, 2pi bonds and 1 lone pair
43. The bond order in O2+ is
N

(A) 2 (B) 2.5 (C) 1.5 (D) 3

RE

44. Which of the following bonds require the largest amount of bond energy to dissociate the atom concerned
(A) H − H bond in H2 (B) C − C bond in CH4
(C) N ≡ N bond in N2 (D) O = O bond in O2
HI

45. Assertion : Water is liquid but H2 S is a gas.

Reason : Oxygen is paramagnetic.

(A) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(B) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(C) If the Assertion is correct but Reason is incorrect.
(D) If both the Assertion and Reason are incorrect.
46. Consider following compounds :
(I) H3 X − N CS (II) H3 Y − N CS (III) (H3 X)2 O (IV ) (H3 Y )2 O
The incorrect statement regarding given compound is

(A) If Y is carbon in compounds (II) and (IV ), then both are bent
(B) If X is silicon in compounds (I) and (lll), then both are linear
(C) If X is carbon and Y is silicon then compound (I) is more basic- than compound (II)
(D) If X is silicon and Y is carbon then X − O − X bond angle compounds (III) is greater than Y − O − Y bond
angle in compounds (IV )
47. Which of the following does not contain any co- ordinate bond?
(A) H3 O+ (B) BF4− (C) HF2− (D) N H4+
48. Species having maximum ′ Cl − O′ bond order is
(A) ClO3− (B) ClO3 (C) ClO2 (D) ClO2−
49. Which one among the following does not have the hydrogen bond

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 (A) Phenol (B) Liquid N H3 (C) Water (D) Liquid HCl
50. The ionic bonds X + Y − are formed when
(I) electron affinity of Y is high (II) ionization energy of X is low
(III) lattice energy of XX is high (IV ) lattice energy of XY is low
Choose the correct code
(A) I and II (B) I and III (C) I, II and III (D) All
51. What is the nature of chemical bonding between Cs and F
(A) Covalent (B) Ionic (C) Coordinate (D) Metallic
52. The number of electrons shared by each outermost shell of N2 is
(A) 2 (B) 3 (C) 4 (D) 5
53. The correct order in which the O − O bond length increases in the following is
(A) H2 O2 < O2 < O3 (B) O2 < H2 O2 < O3 (C) O2 < O3 < H2 O2 (D) O3 < H2 O2 < O2
54. The phosphate of a metal has the formula M HP O4 . The formula of its chloride would be
(A) M Cl (B) M Cl2 (C) M Cl3 (D) M2 Cl3
55. Hybridization is due to the overlapping of

I
(A) Orbitals of different energy levels (B) Orbitals of different energy content

AN
(C) Orbitals of same energy content (D) None of the above
56. The group of molecules having identical shape is
(A) P Cl5 , IF5 , XeO2 F2 (B) BF3 , P Cl3 , XeO3 (C) SF4 , XeF4 , CCl4 (D) ClF3 , XeOF2 , XeF3+
57. In benzene, all the six C − C bonds have the same length because of
V
(A) Tautomerism (B) sp2 hybridisation (C) Isomerism (D) Inductive effect
SA
58. The molecular electronic configuration of H2− ion is
2 2 2 2 1 3
(A) (σ 1s) (B) (σ 1s) (σ x 1s) (C) (σ 1s) (σ x 1s) (D) (σ 1s)
59. A molecule may be represented by three structures having energies E1 , E2 and E3 , respectively. The energies of
these structures follow the order E3 < E2 < E1 , respectively. If the experimental bond energy of the molecule is
N

E0 , the resonance energy is

(A) (E1 + E2 + E3 ) − E0 (B) E0 − E3 (C) E0 − E1 (D) E0 − E2
RE

60. Dipole moment of N F3 is smaller than

(A) N H3 (B) CO2 (C) BF3 (D) CCl4
61. The correct order of bond angles is
HI

(A) N O2− > N O2+ > N O2 (B) N O2+ > N O2− > N O2 (C) N O2 > N O2+ > N O2− (D) N O2+ > N O2 > N O2−
62. The type of molecular forces of attaction present in the following compound is

(A) Intermolecular H− bonding (B) Intramolecular H− bonding

(C) van der Waals' force (D) All of these
63. What bond order does O22− have
(A) 3 (B) 2 (C) 1 (D) 0.5
64. Pick out the molecule which has zero dipole moment
(A) N H3 (B) H2 O (C) BCl3 (D) SO2
65. Select correct statement (s)

(A) Acidic strength of HBr > HCl but reverse is true for their reducing property
(B) Basic strength of P H3 > AsH3 but reverse is true for their bond angle
(C) Dipole moment of CH3 Cl > CH3 F but reverse is true for their H ĈH bond angle
(D) Ka1 of fumaric acid is higher than maleic acid but reverse is true for their Ka2
66. Electrovalent bond formation depends on

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 (A) Ionization energy (B) Electron affinity (C) Lattice energy (D) All the three above
67. The correct order of H − M − H bonds angle is
(A) N H3 < P H3 < SbH3 < BiH3 (B) AsH3 < SbH3 < P H3 < N H3
(C) N H3 < P H3 < BiH3 < SbH3 (D) BiH3 < SbH3 < AsH3 < P H3
68. The energy of a 2p orbital except hydrogen atom is
(A) Less than that of sp2 orbital (B) More than that of 2s orbital
(C) Equal to that of 2s orbital (D) Double that of 2s orbital
69. Assertion : Molecules of larger size have higher polarizability.
Reason : Polarizability is observed only in those molecules which has permanent dipole moment.
(A) If both Assertion and the Assertion. correct explanation of correct.
Reason are correct (B) If both Assertion and the Assertion.
and the Reason is a (D) If both the Assertion
correct explanation of Reason are correct (C) If the Assertion is cor- and Reason are incor-
but Reason is not a rect but Reason is in- rect.
70. Among the following molecules which one have smallest bond angle
(A) N H3 (B) P H3 (C) H2 O (D) H2 Sc
71. Atomic number of an element is 26. The element shows

I
(A) Ferromagnetism (B) Diamagnetism (C) Paramagnetism (D) None of these

AN
72. Which of the following arrangement of molecules is correct on the basis of their dipole moments
(A) BF3 > N F3 > N H3 (B) N F3 > BF3 > N H3 (C) N H3 > BF3 > N F3 (D) N H3 > N F3 > BF3
73. A electrovalent compound is made up of
(A) Electrically charged molecules V (B) Neutral molecules
(C) Neutral atoms (D) Electrically charged atoms or group of atoms
SA
74. Among the following the maximum covalent character is shown by the compound
(A) F eCl2 (B) SnCl2 (C) AlCl3 (D) M gCl2
75. The correct order towards bond angle is
(A) sp < sp2 < sp3 (B) sp2 < sp < sp3
N

(C) sp3 < sp2 < sp (D) Bond angle does not depend on hybridisation
76. In which case the bond length is minimum between carbon and nitrogen
RE

(A) CH3 N H2 (B) C6 H5 CH = N OH (C) CH3 CON H2 (D) CH3 CN

77. Maximum covalent character is associated with the compound
(A) N aI (B) M gI2 (C) AlCl3 (D) AlI3
HI

78. Which of the following bond has the most polar character
(A) C − O (B) C − Br (C) C − S (D) C − F
79. Electricity do not pass through ionic compounds
(A) In solution (B) In solid state (C) In melted state (D) None of these
80. Which of the following statements is true

(A) HF is less polar than HBr

(B) Absolutely pure water does not contain any ions
(C) Chemical bond formation take place when forces of attraction overcome the forces of repulsion
(D) In covalency transference of electron takes place
81. The boiling point of a compound is raised by
(A) Intramolecular hydrogen bonding (B) Intermolecular hydrogen bonding
(C) Covalent bonding (D) Ionic covalent
82. The relatively high boiling point of HF is due to
(A) Hydrogen bonding (B) Covalent bonding
(C) Unshared electron pair on F (D) Being a halogen acid
83. The number of electrons involved in the bond formation of N2 molecule

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 (A) 2 (B) 4 (C) 6 (D) 10
84. 0.01 mole of H3 P Ox is completely neutralised by 0.56 gram of KOH hence
(A) x = 3 and given acid is dibasic (B) x = 2 and given acid is monobasic
(C) x = 3 and given acid is monobasic (D) x = 4 and given acid forms three series of salt
85. In the series ethane, ethylene and acetylene, the C − H bond energy is
(A) The same in all the three compounds (B) Greatest in ethane
(C) Greatest in ethylene (D) Greatest in acetylene
86. Which of the following is an electrovalent linkage
(A) CH4 (B) M gCl2 (C) SiCl4 (D) BF3
87. Among the compounds, BF3 , N Cl3 , H2 S, SF4 and BeCl2 , identify the ones in which the central atom has the same
type of hybridisation
(A) BF3 and N Cl3 (B) H2 S and BeCl2
(C) BF3 , N Cl3 and H2 S (D) N Cl3 and H2 S
88. Which set hydridisation is correct for the following compounds
N O2 , SF4 , P F6−
(A) sp, sp2 , sp3 (B) sp, sp3 d, sp3 d2 (C) sp2 , sp3 , d2 sp3 (D) sp3 , sp3 d2 , sp3 d2

I
89. Glycerol has strong intermolecular bonding therefore it is

AN
(A) Sweet (B) Reactive (C) Explosive (D) Viscous
90. The structure of H2 O2 is
(A) Planar (B) Non-planar (C) Spherical (D) Linear
91. Which of the following compounds is not linear
V
SA
(A) SnCl2 (B) HCl (C) CO2 (D) HgCl2
92. Which type of bond is formed between similar atoms
(A) Ionic (B) Covalent (C) Coordinate (D) Metallic
93. The molecular size of ICl and Br2 is approximately same, but b.p. if ICl is about 40 C higher than that of Br2 . It
o
N

is because
(A) ICl bond is stronger than Br − Br bond (B) IE of iodine < IE of bromine
RE

(C) ICl is polar while Br2 is nonpolar (D) I has larger size than Br
94. The P Cl5 molecule is a result of the hybridisation of
(A) sp2 d2 (B) sp3 d (C) spd3 (D) sp2 d3
HI

95. The number of possible resonance structures for CO32− is

(A) 2 (B) 3 (C) 6 (D) 9
96. Incorrect match is
Electron geometry − Possible molecular shape from respective electron geometry
(A) Tetrahedron − Bent (B) Trigonal bipyramidal − Triangular planar
(C) Octahedron − Square pyramidal (D) Pentagonal bipyramidal − Pentagonal planar
97. XeF2 molecule is
(A) Linear (B) Triangular planar (C) Pyramidal (D) Square planar
98. Which of the following is least ionic
(A) C2 H5 Cl (B) KCl (C) BaCl2 (D) C6 H5 N + H3 Cl−
99. Which of the following overlapping is not present in XeO3 molecule ?
(A) sp3 + px (B) sp3 + py (C) dxy + px (D) sp3 + s
100. According to molecular orbital theory, the paramagnetism of O2 molecule is due to presence of

(A) Unpaired electrons in the bonding σ molecular orbital

(B) Unpaired electrons in the antibonding σ molecular orbital
(C) Unpaired electron in the bonding π molecular orbital
(D) Unpaired electrons in the antibonding π molecular orbital

Page No : 6
 ANSWER KEY
 
CHEMISTRY


1-D 2-B 3-B 4-B 5-C 6-C 7-A 8-D 9-C 10 - A
11 - A 12 - C 13 - C 14 - D 15 - C 16 - D 17 - D 18 - B 19 - C 20 - B
21 - C 22 - D 23 - C 24 - A 25 - A 26 - C 27 - A 28 - D 29 - D 30 - B
31 - B 32 - B 33 - D 34 - B 35 - A 36 - A 37 - B 38 - C 39 - C 40 - B
41 - A 42 - A 43 - B 44 - C 45 - B 46 - B 47 - C 48 - B 49 - D 50 - C
51 - B 52 - B 53 - C 54 - B 55 - C 56 - D 57 - B 58 - C 59 - B 60 - A
61 - D 62 - D 63 - C 64 - C 65 - C 66 - D 67 - D 68 - B 69 - C 70 - D
71 - A 72 - D 73 - D 74 - C 75 - C 76 - D 77 - D 78 - D 79 - B 80 - C
81 - B 82 - A 83 - C 84 - B 85 - D 86 - B 87 - D 88 - B 89 - D 90 - B
91 - A 92 - B 93 - C 94 - B 95 - B 96 - B 97 - A 98 - A 99 - D 100 - D

I
V AN
SA
N
RE
HI

Page No : 7
 SOLUTION
 
CHEMISTRY


1. In which of the following compounds does hydrogen bonding occur
(A) SiH4 (B) LiH (C) HI (D) ✓N H3
Sol : (d) Only N H3 forms H−bonds.
2. Which of the following has zero dipole moment
(A) CH2 Cl2 (B) ✓CH4 (C) N H3 (D) P H3
Sol : (b)CH4 have regular tetrahedron so its dipole moment is zero.
3. Which has the highest bond energy
(A) F2 (B) ✓Cl2 (C) Br2 (D) I2
Sol : (b) Due to greater electron affinity Cl2 has the highest bond energy.
4. The correct order of hybridization of the central atom in the following species N H3 [P tCl4 ]2− , P Cl5 and BCl3 is
(A) dsp2 , dsp3 , sp2 and sp3 (B) ✓sp3 , dsp2 , dsp3 , sp2 (C) dsp2 , sp2 , sp3 , dsp3 (D) dsp2 , sp3 , sp2 , dsp3
Sol : (b) Hybridization of N in N H3 is sp3 that of P t in [P tCl4 ]2− is dsp2 that P in P Cl5 is sp3 d and that of B in
BCl3 is sp2 .
5. In which of the following combination hybridisation of central atom (∗ ) does not change?
• • •
(A) H2 O + C O2 (B) H3 B O3 + OH − (C) ✓BF3 + N H3 (D) None of these
6. Which of the following compounds have the same no. of lone pairs with their central atom?
(I) XeF5− (II) BrF3 (III) XeF2 (IV ) H3 S + (V ) Triple Methylene
(A) IV and V (B) I and III (C) ✓I and II (D) II, IV and V
Sol : (c) XeF5− : 2 lone pairs : pentagonal planar
BrF3 : 2 lone pairs : Bent −T − shape
XeF2 : 3 lone pairs : Linear
H3 S + : 1 lone pairs : Pyramidal
CH2 : 2 unpaired ēs (No lone pair) : Linear
7. Which of the following is paramagnetic
(A) ✓O2 (B) CN − (C) CO (D) N O+
Sol : (a) Electronic configuration of O2 is
O2 = σ(1s)2 σ ∗ (1s)2 σ(2s)2 σ ∗ (2s)2 σ(2px )2 π(2py )2
π(2pz )2 π ∗ (2py )1 π ∗ (2pz )1
The molecule has two unpaired electrons So, it is paramagnetic
8. Assertion : Cuprous ion (Cu+ ) has unpaired electrons while cupric ion (Cu++ ) does not.
Reason : Cuprous ion (Cu+ ) is colourless whereas cupric ion (Cu++ ) is blue in the aqueous solution.
(A) If both Assertion and the Assertion. correct explanation of correct.
Reason are correct (B) If both Assertion and the Assertion.
and the Reason is a (D) ✓If both the Assertion
correct explanation of Reason are correct (C) If the Assertion is cor- and Reason are incor-
but Reason is not a rect but Reason is in- rect.
9. A molecule XY2 contains two σ, two π-bonds and one lone pair of electron in the valence shell of X. The arrange-
ment of lone pair as bond pair is
(A) square pyramidal (B) linear (C) ✓trigonal planar (D) unpredictable
10. An ionic compound is generally a
(A) ✓Good electrolyte (B) Weak electrolyte (C) Non-electrolyte (D) Neutral
Sol : (a) Ionic compounds are good conductors of heat and electricity so they are good electrolyte.
11. Assertion : Lone pair-lone pair repulsive interactions are greater than lone pair-bond pair and bond pair-bond
pair interactions.
Reason : The space occupied by lone pair electrons is more as compared to bond pair electrons.
(A) ✓If both Assertion of the Assertion. correct explanation of correct.
and Reason are cor- (B) If both Assertion and the Assertion. (D) If both the Assertion
rect and the Reason is (C) If the Assertion is cor-
a correct explanation Reason are correct and Reason are incor-
but Reason is not a rect but Reason is in- rect.
Sol : While the lone pairs are localised on the central atom, each bonded pair is shared between two atoms. As
a result, the lone pair electrons in a molecule occupy more space as compared to the bonding pairs of electrons.
This results in greater repulsion between lone pairs of electrons as compared to the lone pair -bond pair and
bond pair - bond pair repulsions. Hence (b) is the correct option.
12. When two atoms of chlorine combine to form one molecule of chlorine gas, the energy of the molecule
Page No : 8
 (A) Greater than that of separate atoms (B) Equal to that of separate atoms
(C) ✓Lower than that of separate atoms (D) None of the above statement is correct
Sol : (c) When bond forms between two atom then their energy get lower than that of separate atoms because
bond formation is an exothermic process.
13. Point out incorrect statement about resonance
(A) Resonance structures should have equal energy
(B) In resonance structures, the constituent atoms should be in the same position
(C) ✓In resonance structures, there should not be the same number of electron pairs
(D) Resonance structures should differ only in the location of electrons around the constituent atoms
Sol : (c) In resonance structure there should be the same number of electron pairs.
14. Which of the following best describes the diagram of molecular orbital?

(A) A bonding π orbital (B) A non - bonding or- (C) An antibonding σ or- (D) ✓An antibonding π
bital bital orbital
Sol : An antibonding π orbital best describes the diagram of a molecular orbital. Two orbitals laterally overlap to
form pi bond. Out of phase combination, of these two p− orbitals, give π ∗ M O.
15. Low melting point is expected for a solid
(A) Ionic solid (B) Metallic solid (C) ✓Molecular solid (D) Covalent solid
Sol : (c) Among given solid, molecular solid is weak, hence, it has low melting point.
16. In the compound CH2 = CH − CH2 − CH2 − C ≡ CH, the C2 − C3 bond is of the type
(A) sp − sp2 (B) sp3 − sp3 (C) sp − sp3 (D) ✓sp2 − sp3
Sol : (d) CH2 = CH − CH2 −CH2 − C ≡ CH
sp2 sp3
hybridised

17. In which of the following molecule µ ( observed) is found to be greater than µ (theoretical)
(A) CHCl3
(C)
(B)

(D) ✓
18. Which one of the following does not have a pyramidal shape?
(A) (CH3 )3 N (B) ✓(SiH3 )3 N (C) P (CH3 )3 (D) P (SiH3 )3
Sol : In case of N (SiH3 )3 N atom is sp hybridised, the lone pair is present in 2p orbital and it is transferred to
2

empty d orbital of Si forming dπ − pπ bond . Hence nitrogen with sp2 hybridization has trigonal planar shape.
19. How many resonance forms can be written for the nitrate ion, (N O3− ) ?
(A) 1 (B) 2 (C) ✓3 (D) 4
Sol : (c) Number of resonating structures = 3

20. The decreasing values of bond angles from N H3 (106o ) to SbH3 (101o ) down group−15 of the periodic table is
due to
(A) decreasing lp − bp repulsion (B) ✓decreasing electronegativity
(C) increasing bp − bp repulsion (D) increasing p−orbital character in sp3
Sol : With the increase in electronegativity, bond pairs move farther and farther away from the central atom. As
a result bp − bp repulsion decreases and the angle decreases accordingl
21. The strength of bonds formed by 2s − 2s, 2p − 2p and 2p − 2s overlap has the order
(A) s − s > p − p > p − s (B) s − s > p − s > p − p (C) ✓p − p > p − s > s − s (D) p − p > s − s > p − s
22. Dipole moment is shown by

Page No : 9
 (A) 1, 4−dichlorobenzene (B) cis 1, 2−dichloroethene
(C) trans1, 2−dichloro−2−pentene (D) ✓(b) and (c)
Sol : (d) cis isomer shows dipole moment while that of trans is zero or very low value. Trans 1, 2 di-chloro−2−pentene
will also show dipole moment due to unsymmetry.
23. Which has the shortest C − C bond length
(A) C2 H5 OH (B) C2 H6 (C) ✓C2 H2 (D) C2 H4
Sol : (c) Because of the triple bond, the carbon-carbon bond distance in ethyne is shortest.
24. If HCl molecule is completely polarized, so expected value of dipole moment is 6.12 D (deby), but experimental
value of dipole moment is 1.03 D. Calculate the percentage ionic character
(A) ✓17 (B) 83 (C) 50 (D) 0
Experimental value of dipole moment
Sol : (a) % of ionic character =
Expected value of dipole moment
1.03
= × 100 = 16.83% ≈ 17%
6.12
25. Water is liquid due to
(A) ✓Hydrogen bonding (B) Covalent bond (C) Ionic bond (D) Vander Waals forces
Sol : (a) Water molecule has hydrogen bonding so molecules get dissociated so it is liquid.
26. Which pair of molecules are polar species?
(A) CO2 and H2 O (B) BF3 and P Cl3 (C) ✓SO2 and SCl2 (D) CS2 and SO3
Sol : (c) The net polarity of angular molecules SO2 and SCl2 is not equal to zero.
27. The molecule which is pyramid shape is
(A) ✓P Cl3 (B) CO32− (C) SO3 (D) N O3−
Sol : (a) Due to sp3 hybridization and presence of lone pair of electron on p atom P Cl3 are of pyramidal shape
like that of N H3 .
28. Which of the following molecules has two sigma (σ) and two pi (π) bonds?
(A) C2 H4 (B) N2 F2 (C) C2 H2 Cl2 (D) ✓HCN
π,σ
Sol : H − C ≡ N
σ π

i.e 2 π and 2 σ bonds

29. What is not true about ice?
(A) It has open cage like structure (B) It has less density than water
(C) Each O atom is surrounded by 4 H atoms (D) ✓Each O atom has four H− bonds around it

Sol :

30. Which is the correct electron dot structure of N2 O molecule

.. .. .. .. .. ..
(A) : N = N = O (B) ✓: N ≡ N + − O :− (C) N = N = O (D) : N = N = O :
.. .. .. .. ..
..
Sol : (b) : N ≡ N + − O :− or N ≡ N → O.
..

31. Which of the following pair of molecules will have permanent dipole moment?
(A) N O2 and CO2 (B) ✓N O2 and O3 (C) SiF4 and CO2 (D) SiF4 and N O2
32. An atom of an element A has three electrons in its outermost shell and that of B has six electrons in the outer-
most shell. The formula of the compound between these two will be
(A) A3 B4 (B) ✓A2 B3 (C) A3 B2 (D) A2 B3
Sol : (b) Valency of A is 3 while that of B is 2
so according to Criss Cross rule the formula of the compound between these two will be A2 B3 .
33. The bonds in K4 [F e (CN )6 ] are

Page No : 10
 (A) All ionic (B) All covalent
(C) Ionic and covalent (D) ✓Ionic, covalent and coordinate covalent
Sol : (d) Structure of K4 [F e(CN )6 ] is

34. Out of the following which has smallest bond length

(A) O2 (B) ✓O2+ (C) O2− (D) O22−
Sol : (b) Bond order of O2+ is highest so its bond length is smallest.
35. A lone pair of electrons in an atom implies
(A) ✓A pair of valence electrons not involved in bond- (B) A pair of electrons involved in bonding
ing
(C) A pair of electrons (D) A pair of valence electrons
Sol : It's Obvious.
36. Phosphate of a metal M has the formula M3 (P O4 )2 . The formula for its sulphate would be
(A) ✓M SO4 (B) M (SO4 )2 (C) M2 (SO4 )3 (D) M3 (SO4 )2
Sol : (a) M3 (P O4 )2 means M is divalent so formula of its sulphate is M SO4 .
37. Resonance is due to
(A) Delocalization of sigma electrons (B) ✓Delocalization of pi electrons
(C) Migration of H atoms (D) Migration of protons
Sol : It's Obvious.
38. Sulphuric acid provides a example of
(A) Covalent and Co-ordinate bonds (B) Non-covalent compound
(C) ✓Covalent bond (D) Non-covalent ion
39. Which of the following hybridisation has maximum s−characters
(A) sp3 (B) sp2 (C) ✓sp (D) None of these
1
Sol : (c) s−character in sp = × 100 = 50%
2
1
s−character in sp2 = × 100 = 33.3%
3
1
s−character in sp3 = × 100 = 25%
4
Hence, maximum s−character is found in sp−hybridisation.
+
40. The hybridization of Ag in the linear complex [Ag (N H3 )2 ] is
(A) dsp2 (B) ✓sp (C) sp2 (D) CCl4
Sol : (b)The hybridisation of Ag in complex [Ag (N H3 )2 ] will be sp because it is a Linear complex.
+

41. The bond order is not three for

(A) ✓N2+ (B) O22+ (C) N2 (D) N O+
1
Sol : (a) B.O. for N2+ = [Nb − Na ]
2
1 5
= [9 − 4] = = 2.5.
2 2
42. The enolic form of acetone contains
(A) ✓9 sigma bonds, 1 pi bond and 2 lone pairs (B) 8 sigma bonds, 2 pi bonds and 2 lone pairs
(C) 10 sigma bonds, 1 pi bond and 1 lone pair (D) 9 sigma bonds, 2pi bonds and 1 lone pair
• •O• −H
•
|
Sol : (a) . CH3 − C = CH2
has 9σ, 1 and 2 lone pairs.
43. The bond order in O2+ is

Page No : 11
 (A) 2 (B) ✓2.5 (C) 1.5 (D) 3
Nb − Na 8−3 5
Sol : (b) B.O. = = = = 2.5.
2 2 2
44. Which of the following bonds require the largest amount of bond energy to dissociate the atom concerned
(A) H − H bond in H2 (B) C − C bond in CH4
(C) ✓N ≡ N bond in N2 (D) O = O bond in O2
Sol : (c)Due to multiple bonding in N2 molecule.
45. Assertion : Water is liquid but H2 S is a gas.
Reason : Oxygen is paramagnetic.

(A) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(B) ✓If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(C) If the Assertion is correct but Reason is incorrect.
(D) If both the Assertion and Reason are incorrect.
Sol : Water is liquid but H2 S is gas due to hydrogen bond in water. Oxygen is paramagnetic.
46. Consider following compounds :
(I) H3 X − N CS (II) H3 Y − N CS (III) (H3 X)2 O (IV ) (H3 Y )2 O
The incorrect statement regarding given compound is

(A) If Y is carbon in compounds (II) and (IV ), then both are bent
(B) ✓If X is silicon in compounds (I) and (lll), then both are linear
(C) If X is carbon and Y is silicon then compound (I) is more basic- than compound (II)
(D) If X is silicon and Y is carbon then X − O − X bond angle compounds (III) is greater than Y − O − Y bond
angle in compounds (IV )

Sol :

47. Which of the following does not contain any co- ordinate bond?
(A) H3 O+ (B) BF4− (C) ✓HF2− (D) N H4+
48. Species having maximum ′ Cl − O′ bond order is
(A) ClO3− (B) ✓ClO3 (C) ClO2 (D) ClO2−
Sol : (b) (a) ClO3− B.O. = 1.66
(b) ClO3 B.O. = 2 (max.)
(c) ClO2 B.O. = 1.75
(d) CIO2− B.O. = 1.5
49. Which one among the following does not have the hydrogen bond
(A) Phenol (B) Liquid N H3 (C) Water (D) ✓Liquid HCl
Sol : It's Obvious.
50. The ionic bonds X + Y − are formed when
(I) electron affinity of Y is high (II) ionization energy of X is low
(III) lattice energy of XX is high (IV ) lattice energy of XY is low
Choose the correct code
(A) I and II (B) I and III (C) ✓I, II and III (D) All
51. What is the nature of chemical bonding between Cs and F
(A) Covalent (B) ✓Ionic (C) Coordinate (D) Metallic
Sol : (b) Cs is highly electropositive while F is highly electronegative so they will form ionic bond.
52. The number of electrons shared by each outermost shell of N2 is
(A) 2 (B) ✓3 (C) 4 (D) 5
Sol : (b) Each nitrogen share 3 electrons to form triple bond.
53. The correct order in which the O − O bond length increases in the following is
(A) H2 O2 < O2 < O3 (B) O2 < H2 O2 < O3 (C) ✓O2 < O3 < H2 O2 (D) O3 < H2 O2 < O2
Sol : (c) Due to resonance in O3 , O − O band length will be in b/w O = O and O − O.

54. The phosphate of a metal has the formula M HP O4 . The formula of its chloride would be
Page No : 12
 (A) M Cl (B) ✓M Cl2 (C) M Cl3 (D) M2 Cl3
Sol : (b)The phosphate of a metal has the formula M HP O4 it means metal is divalent so its chloride would be
M Cl2 .
55. Hybridization is due to the overlapping of
(A) Orbitals of different energy levels (B) Orbitals of different energy content
(C) ✓Orbitals of same energy content (D) None of the above
Sol : (c)Hybridization is due to overlapping of orbitals of same energy content.
56. The group of molecules having identical shape is
(A) P Cl5 , IF5 , XeO2 F2 (B) BF3 , P Cl3 , XeO3 (C) SF4 , XeF4 , CCl4 (D) ✓ClF3 , XeOF2 , XeF3+
1
Sol : ClI3 → Hybridisation = 3 + [7 − 3] = 5 (sp3 d)
2
1
XeOF2 → Hybridisation = 3 + [8 − 4] = 5 (sp3 d)
2
1
XeF3+ → Hybridisation = 3 + [8 − 3 − 1] = 5 (sp3 d)
2
All molecules have sp d hybridization and 2 lone pairs. Hence all have identical ( T − shape).
3

57. In benzene, all the six C − C bonds have the same length because of
(A) Tautomerism (B) ✓sp2 hybridisation (C) Isomerism (D) Inductive effect
Sol : (b)All carbon atoms of benzene consist of alternate single and double bond and show sp2 hybridization.
58. The molecular electronic configuration of H2− ion is
2 2 2 2 1 3
(A) (σ 1s) (B) (σ 1s) (σ x 1s) (C) ✓(σ 1s) (σ x 1s) (D) (σ 1s)
Sol : It's Obvious.
59. A molecule may be represented by three structures having energies E1 , E2 and E3 , respectively. The energies of
these structures follow the order E3 < E2 < E1 , respectively. If the experimental bond energy of the molecule is
E0 , the resonance energy is
(A) (E1 + E2 + E3 ) − E0 (B) ✓E0 − E3 (C) E0 − E1 (D) E0 − E2
60. Dipole moment of N F3 is smaller than
(A) ✓N H3 (B) CO2 (C) BF3 (D) CCl4
61. The correct order of bond angles is
(A) N O2− > N O2+ > N O2 (B) N O2+ > N O2− > N O2 (C) N O2 > N O2+ > N O2− (D) ✓N O2+ > N O2 > N O2−
62. The type of molecular forces of attaction present in the following compound is

(A) Intermolecular H− bonding (B) Intramolecular H− bonding

(C) van der Waals' force (D) ✓All of these

Sol :

63. What bond order does O22− have

(A) 3 (B) 2 (C) ✓1 (D) 0.5
Sol : (c)O22−have bond order one
1 2
B.O. = [10 − 8] = = 1.
2 2
64. Pick out the molecule which has zero dipole moment

Page No : 13
 (A) N H3 (B) H2 O (C) ✓BCl3 (D) SO2
Sol : (c) BCl3 has zero dipole moment because of its trigonal planar geometry.
65. Select correct statement (s)

(A) Acidic strength of HBr > HCl but reverse is true for their reducing property
(B) Basic strength of P H3 > AsH3 but reverse is true for their bond angle
(C) ✓Dipole moment of CH3 Cl > CH3 F but reverse is true for their H ĈH bond angle
(D) Ka1 of fumaric acid is higher than maleic acid but reverse is true for their Ka2

Sol :

66. Electrovalent bond formation depends on

(A) Ionization energy (B) Electron affinity (C) Lattice energy (D) ✓All the three above
Sol : (d) Electrovalent bond formation depends on ionization energy of cation, electron affinity of anion and on
lattice energy.
67. The correct order of H − M − H bonds angle is
(A) N H3 < P H3 < SbH3 < BiH3 (B) AsH3 < SbH3 < P H3 < N H3
(C) N H3 < P H3 < BiH3 < SbH3 (D) ✓BiH3 < SbH3 < AsH3 < P H3
68. The energy of a 2p orbital except hydrogen atom is
(A) Less than that of sp2 orbital (B) ✓More than that of 2s orbital
(C) Equal to that of 2s orbital (D) Double that of 2s orbital
Sol : It's Obvious.
69. Assertion : Molecules of larger size have higher polarizability.
Reason : Polarizability is observed only in those molecules which has permanent dipole moment.
(A) If both Assertion and the Assertion. correct explanation of incorrect.
Reason are correct (B) If both Assertion and the Assertion.
and the Reason is a (D) If both the Assertion
correct explanation of Reason are correct (C) ✓If the Assertion is and Reason are incor-
but Reason is not a correct but Reason is rect.
Sol : Assertion is true but Reason is false. As the size of the atom increases the influence of the electric dipole
also increases.
70. Among the following molecules which one have smallest bond angle
(A) N H3 (B) P H3 (C) H2 O (D) ✓H2 Sc
Sol : (d) N H3 = 107 , P H3 = 93 , H2 O = 104.5
o o o

H2 Se = 91o , H2 S = 92.5o
71. Atomic number of an element is 26. The element shows
(A) ✓Ferromagnetism (B) Diamagnetism (C) Paramagnetism (D) None of these
Sol : (a) Element with atomic number 26 is F e.
It is a ferromagnetic.
72. Which of the following arrangement of molecules is correct on the basis of their dipole moments
(A) BF3 > N F3 > N H3 (B) N F3 > BF3 > N H3 (C) N H3 > BF3 > N F3 (D) ✓N H3 > N F3 > BF3
Sol : (d) Ammonia molecule is more basic than nitrogen trifluoride and Boron trifluoride
because ammonia molecule easily gives lone pair of electron.
73. A electrovalent compound is made up of
(A) Electrically charged molecules (B) Neutral molecules
(C) Neutral atoms (D) ✓Electrically charged atoms or group of atoms
Sol : It's Obvious.
74. Among the following the maximum covalent character is shown by the compound

Page No : 14
 (A) F eCl2 (B) SnCl2 (C) ✓AlCl3 (D) M gCl2
Sol : higher the positive charge higher will be covalent character
75. The correct order towards bond angle is
(A) sp < sp2 < sp3 (B) sp2 < sp < sp3
(C) ✓sp3 < sp2 < sp (D) Bond angle does not depend on hybridisation
Sol : (c)Increasing order of bond angle is sp3 < sp2 < sp .
109o 120o 180o

76. In which case the bond length is minimum between carbon and nitrogen
(A) CH3 N H2 (B) C6 H5 CH = N OH (C) CH3 CON H2 (D) ✓CH3 CN
Sol : (d) In CH3 CN bond order between C and N is 3 so its bond length is minimum.
77. Maximum covalent character is associated with the compound
(A) N aI (B) M gI2 (C) AlCl3 (D) ✓AlI3
Sol : (d) AlI3 Aluminiumtriiodide shows covalent character. According to Fajan's rule.
78. Which of the following bond has the most polar character
(A) C − O (B) C − Br (C) C − S (D) ✓C − F
Sol : (d) C − F bond has the most polar character due to difference of their electronegativity.
79. Electricity do not pass through ionic compounds
(A) In solution (B) ✓In solid state (C) In melted state (D) None of these
Sol : (b) Ionic compounds can't pass electricity in solid state because they don't have mobile ion in solid state.
80. Which of the following statements is true

(A) HF is less polar than HBr

(B) Absolutely pure water does not contain any ions
(C) ✓Chemical bond formation take place when forces of attraction overcome the forces of repulsion
(D) In covalency transference of electron takes place
Sol : It's Obvious.
81. The boiling point of a compound is raised by
(A) Intramolecular hydrogen bonding (B) ✓Intermolecular hydrogen bonding
(C) Covalent bonding (D) Ionic covalent
Sol : (b) Intermolecular hydrogen bonding compound contain more b.p. compare to intramolecular hydrogen
bonding compound.
82. The relatively high boiling point of HF is due to
(A) ✓Hydrogen bonding (B) Covalent bonding
(C) Unshared electron pair on F (D) Being a halogen acid
Sol : It's Obvious.
83. The number of electrons involved in the bond formation of N2 molecule
(A) 2 (B) 4 (C) ✓6 (D) 10
Sol : (c) In N2 molecule each Nitrogen atom contribute 3e− so total no. of electron's are 6.
84. 0.01 mole of H3 P Ox is completely neutralised by 0.56 gram of KOH hence
(A) x = 3 and given acid is dibasic (B) ✓x = 2 and given acid is monobasic
(C) x = 3 and given acid is monobasic (D) x = 4 and given acid forms three series of salt
85. In the series ethane, ethylene and acetylene, the C − H bond energy is
(A) The same in all the three compounds (B) Greatest in ethane
(C) Greatest in ethylene (D) ✓Greatest in acetylene
Sol : (d) As the bond order increases, C − H bond energy also increases so it will be greatest in acetylene be-
cause its B.O. is 3.
86. Which of the following is an electrovalent linkage
(A) CH4 (B) ✓M gCl2 (C) SiCl4 (D) BF3
Sol : (b) M gCl2 has electrovalent linkage because magnesium is electropositive metal while chlorine is electroneg-
ative.
87. Among the compounds, BF3 , N Cl3 , H2 S, SF4 and BeCl2 , identify the ones in which the central atom has the same
type of hybridisation

Page No : 15
 (A) BF3 and N Cl3 (B) H2 S and BeCl2
(C) BF3 , N Cl3 and H2 S (D) ✓N Cl3 and H2 S
Sol : (d) In N Cl3 and H2 S the central atom of both (N and S) are in sp3 hybridization state
while in BF3 and N Cl3 central atoms are in sp2 and sp3 hybridization respectively.
In H2 S and BeCl2 central atom are in sp3 and sp2 hybridization In BF3 , N Cl3 & H2 S central atom are in sp2 , sp3 &
sp3 hybridization and in the central atom are in sp3 and sphybridization.

88. Which set hydridisation is correct for the following compounds

N O2 , SF4 , P F6−
(A) sp, sp2 , sp3 (B) ✓sp, sp3 d, sp3 d2 (C) sp2 , sp3 , d2 sp3 (D) sp3 , sp3 d2 , sp3 d2
Sol : (b)N O2 SF4 P F6−
sp sp3 d sp3 d2

89. Glycerol has strong intermolecular bonding therefore it is

(A) Sweet (B) Reactive (C) Explosive (D) ✓Viscous
Sol : (d) Glycerol has a three OH group hence it is viscous in nature.
90. The structure of H2 O2 is
(A) Planar (B) ✓Non-planar (C) Spherical (D) Linear
Sol : (b) Structure of H2 O2 is non-planar. It has open book structure.
91. Which of the following compounds is not linear
(A) ✓SnCl2 (B) HCl (C) CO2 (D) HgCl2
Sol : (a) SnCl2 is V −shaped.
92. Which type of bond is formed between similar atoms
(A) Ionic (B) ✓Covalent (C) Coordinate (D) Metallic
Sol : (b) Similar atoms form covalent bond.
93. The molecular size of ICl and Br2 is approximately same, but b.p. if ICl is about 40 o C higher than that of Br2 . It
is because
(A) ICl bond is stronger than Br − Br bond (B) IE of iodine < IE of bromine
(C) ✓ICl is polar while Br2 is nonpolar (D) I has larger size than Br
94. The P Cl5 molecule is a result of the hybridisation of
(A) sp2 d2 (B) ✓sp3 d (C) spd3 (D) sp2 d3
Sol : (b)The molecule of P Cl5 has sp3 d hybridisation, structure is trigonal bipyramidal.
95. The number of possible resonance structures for CO32− is
(A) 2 (B) ✓3 (C) 6 (D) 9
2−
Sol : (b)There are three resonance structure of CO3 ion.

96. Incorrect match is

Electron geometry − Possible molecular shape from respective electron geometry
(A) Tetrahedron − Bent (B) ✓Trigonal bipyramidal − Triangular planar
(C) Octahedron − Square pyramidal (D) Pentagonal bipyramidal − Pentagonal planar
Sol : (b) In trigonal bipyramidal geometry Ione pairs (if present ) never placed at axial positions

97. XeF2 molecule is

Page No : 16
 (A) ✓Linear (B) Triangular planar (C) Pyramidal (D) Square planar
Sol : (a) XeF2 molecule is Linear because Xe is sp hybridised.
98. Which of the following is least ionic
(A) ✓C2 H5 Cl (B) KCl (C) BaCl2 (D) C6 H5 N + H3 Cl−
Sol : (a) Ethyl chloride is an organic compound so it will be covalent.
99. Which of the following overlapping is not present in XeO3 molecule ?
(A) sp3 + px (B) sp3 + py (C) dxy + px (D) ✓sp3 + s
100. According to molecular orbital theory, the paramagnetism of O2 molecule is due to presence of

(A) Unpaired electrons in the bonding σ molecular orbital

(B) Unpaired electrons in the antibonding σ molecular orbital
(C) Unpaired electron in the bonding π molecular orbital
(D) ✓Unpaired electrons in the antibonding π molecular orbital
Sol : It's Obvious.

Page No : 17