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RP9 Electrolysis
Essential Content for Temperature
RP10
the 2022 Higher Trilogy Changes
Science Exam
This booklet is split into 3 parts:
Part 1
The first part is a selection of short response questions and answers that are likely
to come in your Chemistry exams this summer. Spend time learning the answers to
these questions, for example you could produce flash cards. You should self quiz
yourself on these questions regularly!
Part 2
Selection of extended response questions (4 to 6 marks) that are likely to be on
your paper this year, either because they have not been assessed in the last couple
of years, or because they come up most years in exams. Prepare and practice your
responses to these questions.
Part 3
Required practical section. In this section you will find step by step guidance for
each practical. This is followed by a page of short response questions and answers
to learn for each of the practicals. There are also some extended response
questions (4 to 6 marks) that are very likely to be on the exam paper this year.
C3: Structure and Bonding Fold page here
1. What are the three types of chemical bonds? 1. Ionic, covalent and metallic bonds.
2. What is an ionic bond? 2. A bond between a metal and non-metal in which
electrons have been exchanged.
3. What is a covalent bond? 3. A bond between two non-metals in which
electrons are shared.
4. What is a metallic bond? 4. A bond between metal atoms in which electrons
are delocalised.
5. How does an ionic compound form? 5. The metal loses electrons to get a full outer shell
becoming a positively charged ion while the
non-metal gains electrons becoming a
negatively charged ion. The oppositely charged
ions are electrostatically attracted to each other.
6. What is the charge of an ion from group 1? 6. +1
7. What is the charge of an ion from group 2? 7. +2
8. What is the charge of an ion from group 6? 8. -2
9. What is the charge of an ion from group 7? 9. -1
10. What is an ionic compound? 10. A giant structure of ions which are held together
by strong electrostatic forces of attraction
between oppositely charged ions.
11. What are simple molecules? 11. Small molecules such as oxygen and water that
contain atoms joined together by covalent
12. What is the state symbol for a solid? bonds.
13. What is the state symbol for a liquid? 12. (s)
14. What is the state symbol for a gas? 13. (l)
15. What is the state symbol for a solution? 14. (g)
16. What are the properties of ionic compounds? 15. (aq)
16. High melting and boiling point. Don’t conduct
electricity when solid but do when molten or
17. Why do ionic compounds have high melting dissolved.
and boiling points? 17. Strong bonds between molecules which takes
18. Why can’t ionic compounds conduct electricity lots of energy to overcome.
when solid? 18. Ions are unable to move freely.
19. Why can ionic compounds conduct electricity
when molten or dissolved? 19. Ions are free and so are able to move.
20. What are the properties of simple molecules?
21. Why do simple molecules have low melting and 20. Low melting and boiling point. Poor conductors.
boiling points?
C4: Chemical Calculations Fold page here
5. 6.02x10 23
5. What is the value of the Avogadro constant?
6. The masses of reactants and products in grams
6. How can the balancing numbers in a symbol is converted into moles which is then converted
equation be calculated using reacting masses? into a simple whole number ratio.
Read the question carefully. Make sure you have checked how many
significant figures you have been asked to give your answer to! If you
Top Tip
haven’t been given atomic masses remember to use your periodic table.
You could be given a volume of a solution and the mass of a substance that it
contains and be asked to use this to calculate a concentration.
Explain what happens when any acid reacts with any alkali.
Model When an acid and alkali react the H+ ions from the acid react with the alkalis
Answer OH- ions to make water.
Model To determine the pH of a solution you could add universal indicator. You
Answer would observe the colour that the indicator turned and use a chart to
identify the pH. You could alternatively use a pH probe by dipping this into
the solution and recording the value on the digital display.
Identify what forms at the __________ electrode and explain how this
Qu
happens.
You will usually be given a diagram of the electrolysis and the name of the
solution that is undergoing electrolysis. You will then be asked what forms
at one or both electrodes and be asked to explain how this happens.
Anode: At the positive electrode negative ions lose their electrons and are
oxidised. If the solution doesn’t contain halides oxygen is made. This oxygen
then reacts with the carbon in the electrode to make carbon dioxide.
Top Tip Cathode: At the negative electrode positive ions gain electrons and are
reduced. If the metal is more reactive than hydrogen, then hydrogen forms
at the electrode instead.
Explain what forms at the cathode during the electrolysis of copper sulfate.
1. Copper forms at the negative electrode.
2. Copper ions have a positive charge...
3. ...and so are are attracted to the oppositely charged negative electrode.
4. The copper ions gain electrons...
5. ...and are reduced...
6. To form copper
Model Explain what forms at the anode during the electrolysis of copper sulfate.
Answer 1. Oxygen forms at the negative electrode.
2. Oxygen ions have a negative charge...
3. ...and so are are attracted to the oppositely charged positive electrode.
4. The oxygen ions lose electrons...
5. ...and are oxidised...
6. To form oxygen. The oxygen then goes on to react with carbon in the
electrode to make carbon dioxide gas.
1. Explain what forms at the electrodes during electrolysis of iron sulfate
2. Explain what forms at the electrodes during electrolysis of copper
chloride
Practice 3. Explain what forms at the electrodes during electrolysis of sodium
chloride
Topic C6 Electrolysis
During electrolysis the negative oxygen ions will be attracted to the positive
Model
electrode that is made of carbon. The oxygen will then react with the carbon
Answer
electrode forming carbon dioxide due to the high temperatures. This means
that over time the electrode will wear away.
Model During electrolysis water breaks down to form hydrogen H+ ions. If the metal
Answer ions produced during electrolysis are less reactive than hydrogen, then it is
the hydrogen ions that are discharged at the negative electrode. Here they
gain electrons to form hydrogen molecules.
Model Halide ions are negatively charged and so will be attracted to the positive
Answer electrode. Here the halide will lose electrons and form molecules. For
example, chloride ions will form chlorine gas.
When an acid is added to an alkali the energy changes. Explain this change.
Qu Define exothermic reaction.
Define activation energy.
At least one of these questions is likely to come up. The examiner is going to
Info
be looking for a clear answer written in a logical sequence.
Be careful that you use key words/phrases accurately (these are in bold in
Top Tip
your model answers below).
When an acid is added to an alkali the energy changes. Explain this change.
Model
An acid reacting with an alkali is an exothermic reaction. This means that
Answer
heat is released to the environment and so the energy within the products
will be less than the energy in the reactants.
Model The minimum amount of energy that particles must have to react when
Answer the reacting particles collide with each other.
6
Leave the remaining
solution to crystallise
over time.
4
Pour the filtered solution into
an evaporating basin and
evaporate the water using a
5 water bath.
Stop heating when
crystals start to
appear.
Practical Video
RP8: Making Salts Practical Fold page here
5. Why is the insoluble base added in excess? 5. To make sure that all of the acid has reacted and is
neutralised.
6. Why is the insoluble base added to warm acid? 6. To increase the rate or reaction.
8. What type of acid would you need to use if you 8. Sulfuric Acid
wanted to make a sulfate?
9. What type of acid would you need to use if you 9. Hydrochloric Acid
wanted to make a chloride?
10. What type of acid would you need to use if you 10. Nitric Acid
wanted to make a nitrate?
11. How is the remaining insoluble base removed from 11. Filtration
the solution?
13. How is the water removed from the salt solution? 13. Evaporation
14. What substances can react with an acid to make a 14. Metal, metal hydroxide, metal oxide, metal carbonate,
soluble salt? alkali.
15. How can we make sure that all the substances have 15. Warm the solution and stir.
reacted when making salts?
16. What safety precautions should you use when 16. Wear safety goggles.
making salts?
Practical RP8 Making Salts
You could be asked this question for lots of different salts. Some that
have come up in the past include:
• Magnesium Sulfate
• Calcium Chloride
• Potassium Chloride
• Sodium Sulfate
Info
To answer this question you will need to do the following:
1. Identify the base and acid that you would add together.
2. Describe how you would ensure all the base had reacted.
3. Describe how you would remove the unreacted base.
4. Describe how you will make sure all the water is removed from
the salt.
Explain how you could make a pure dry sample of magnesium sulfate.
Practical Video
4. Observe and record what happens at the
electrodes.
RP9: Electrolysis Practical Fold page here
You could be asked this question for some different hypothesis. Some
that have come up in the past include:
• When different salt solutions are electrolysed with inert
electrodes, the product at the negative electrode is always a metal.
• When different salt solutions are electrolysed with inert
electrodes, the product at the negative electrode is always
hydrogen.
Info
To answer this question you will need to do the following:
1. Describe how to set up the equipment (drawing a labelled diagram
is even better)
2. Identify what you will be changing
3. Identify what you will record/measure
4. Identify what you will control
7. Repeat steps 1-6 2 more times to identify outliers and calculate an average.
Thermometer
Lid with
hole in
Polystyrene
Cup
Practical Video
RP10: Temperature Changes
Fold page here
1. If you are investigating the effect of a particular 1. Type of acid, concentration of acid, volume of acid,
factor on the temperature change what are the type of metal, surface area of metal, mass of metal
possible variables, one you could change, and the
others you would need to keep the same?
3. How do you determine temperature change? 3. Measure the start and end temperature. Take the
start temperature away from the end temperature.
4. Why should a polystyrene cup be used when 4. Polystyrene is a good insulator and reduces energy
investigating temperature change? transfers with the surroundings.
5. Why should the polystyrene cup used have a lid? 5. Reduces energy transfers with the surroundings.
6. How can you use temperature change to determine 6. Add the metals to a controlled volume of acid in a
the reactivity of some metals? polystyrene cup and record the temperature change.
The larger the temperature change the more reactive
the metal.
10. How would you know if the reaction was 10. The temperature would decrease.
endothermic?
11. What is an endothermic reaction? 11. A reaction that transfers energy from the
surroundings.
12. What is an exothermic reaction? 12. A reaction that transfers energy to the surroundings.
13. How would you know if the reaction was exothermic? 13. The temperature would increase.
Practical RP10: Temperature Change