Safety Data PTC en v.11.0
Safety Data PTC en v.11.0
PTC
SECTION 1. IDENTIFICATION
SDS-Identcode : 308G
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Skin sensitization : Category 1
Precautionary Statements :
Prevention:
P261 Avoid breathing dust, fume, gas, mist, vapors or spray.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical atten-
tion.
P363 Wash contaminated clothing before reuse.
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Disposal:
P501 Dispose of contents and container to an approved waste
disposal plant.
Other hazards
None known.
General advice : In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
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delayed
Protection of first-aiders : First Aid responders should pay attention to self-protection,
and use the recommended personal protective equipment
when the potential for exposure exists (see section 8).
Notes to physician : Treat symptomatically and supportively.
Specific extinguishing meth- : Use extinguishing measures that are appropriate to local cir-
ods cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.
Methods and materials for : Sweep up or vacuum up spillage and collect in suitable
containment and cleaning up container for disposal.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.
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Color : black
Odor : Petroleum
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flammability limit
Solubility(ies)
Water solubility : negligible
Viscosity
Viscosity, dynamic : No data available
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Components:
Graphite:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
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Dilithium azelate:
Acute oral toxicity : LD50 (Rat): > 300 - 2,000 mg/kg
Method: OECD Test Guideline 420
Remarks: Based on data from similar materials
Tris[bis(2-ethylhexyl)dithiocarbamato-S,S'] antimony:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Remarks: Based on data from similar materials
Talc:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Remarks: Based on data from similar materials
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Method: OECD Test Guideline 401
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Quartz:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation
Not classified based on available information.
Components:
Graphite:
Species : Rabbit
Method : OECD Test Guideline 404
Result : No skin irritation
Dilithium azelate:
Species : reconstructed human epidermis (RhE)
Method : OECD Test Guideline 439
Remarks : Based on data from similar materials
Talc:
Species : Rabbit
Result : No skin irritation
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Species : Rabbit
Method : OECD Test Guideline 404
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Graphite:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405
Dilithium azelate:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405
Talc:
Species : Rabbit
Result : No eye irritation
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405
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Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
Not classified based on available information.
Components:
Graphite:
Test Type : Local lymph node assay (LLNA)
Routes of exposure : Skin contact
Species : Mouse
Result : negative
Dilithium azelate:
Test Type : Local lymph node assay (LLNA)
Routes of exposure : Skin contact
Species : Mouse
Method : OECD Test Guideline 429
Result : negative
Remarks : Based on data from similar materials
Talc:
Routes of exposure : Skin contact
Species : Humans
Result : negative
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Test Type : Buehler Test
Routes of exposure : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : positive
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humans
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: Intraperitoneal injection
Method: OECD Test Guideline 474
Result: negative
Remarks: Based on data from similar materials
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: Intraperitoneal injection
Method: OECD Test Guideline 474
Result: negative
Remarks: Based on data from similar materials
Graphite:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative
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Result: negative
Dilithium azelate:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative
Talc:
Genotoxicity in vitro : Test Type: DNA damage and repair, unscheduled DNA syn-
thesis in mammalian cells (in vitro)
Result: negative
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: Intraperitoneal injection
Method: OECD Test Guideline 474
Result: equivocal
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative
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Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: Ingestion
Method: OECD Test Guideline 474
Result: negative
Remarks: Based on data from similar materials
Carcinogenicity
Not classified based on available information.
Product:
Carcinogenicity - Assess- : Petroleum distillates have been classified as not carcinogenic
ment based on DMSO extract content < 3% (Regulation (EC)
1272/2008, Annex VI, Part 3, Note L).
Components:
Talc:
Species : Mouse
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Quartz:
Species : Humans
Application Route : inhalation (dust/mist/fume)
Result : positive
Remarks : These substance(s) are inextricably bound in the product and
therefore do not contribute to a dust inhalation hazard.
Reproductive toxicity
Not classified based on available information.
Components:
Graphite:
Effects on fertility : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
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Result: negative
Effects on fetal development : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Dilithium azelate:
Effects on fertility : Test Type: Reproduction/Developmental toxicity screening
test
Species: Rat
Application Route: Skin contact
Result: negative
Remarks: Based on data from similar materials
Talc:
Effects on fetal development : Test Type: Embryo-fetal development
Species: Rat
Application Route: Ingestion
Result: negative
Effects on fetal development : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Result: negative
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Effects on fertility : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Effects on fetal development : Test Type: Combined repeated dose toxicity study with the
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STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Components:
Quartz:
Routes of exposure : inhalation (dust/mist/fume)
Target Organs : Lungs
Assessment : Shown to produce significant health effects in animals at con-
centrations of 0.02 mg/l/6h/d or less.
Components:
Species : Rat
NOAEL : > 980 mg/m³
Application Route : inhalation (dust/mist/fume)
Exposure time : 4 Weeks
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Dilithium azelate:
Species : Rat
NOAEL : 1,089.75 mg/kg
Application Route : Skin contact
Exposure time : 28 Days
Remarks : Based on data from similar materials
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Species : Rat
NOAEL : 330 mg/kg
Application Route : Ingestion
Exposure time : 54 Days
Method : OECD Test Guideline 422
Species : Rat
NOAEL : > 600 mg/kg
Application Route : Skin contact
Exposure time : 28 Days
Method : OECD Test Guideline 410
Remarks : Based on data from similar materials
Quartz:
Species : Humans
LOAEL : 0.053 mg/m³
Application Route : inhalation (dust/mist/fume)
Remarks : These substance(s) are inextricably bound in the product and
therefore do not contribute to a dust inhalation hazard.
Aspiration toxicity
Not classified based on available information.
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Ecotoxicity
Components:
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
Remarks: Based on data from similar materials
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 10 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Method: OECD Test Guideline 211
Remarks: Based on data from similar materials
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l
aquatic invertebrates Exposure time: 48 h
Remarks: Based on data from similar materials
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 10 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Remarks: Based on data from similar materials
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Graphite:
Toxicity to fish : LL50 (Danio rerio (zebra fish)): > 100 mg/l
Exposure time: 96 h
Test substance: Water Accommodated Fraction
Method: OECD Test Guideline 203
Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Test substance: Water Accommodated Fraction
Method: OECD Test Guideline 202
Dilithium azelate:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 10 - 100 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10 - 100 mg/l
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
Remarks: Based on data from similar materials
Tris[bis(2-ethylhexyl)dithiocarbamato-S,S'] antimony:
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.02 mg/l
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Ecotoxicology Assessment
Chronic aquatic toxicity : Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Talc:
Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): > 100,000 mg/l
Exposure time: 24 h
Ecotoxicology Assessment
Chronic aquatic toxicity : Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
Exposure time: 96 h
Test substance: Water Accommodated Fraction
Method: OECD Test Guideline 203
Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): 45 mg/l
aquatic invertebrates Exposure time: 48 h
Test substance: Water Accommodated Fraction
Method: OECD Test Guideline 202
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Toxicity to fish : LL50 (Pimephales promelas (fathead minnow)): > 100 mg/l
Exposure time: 96 h
Test substance: Water Accommodated Fraction
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials
Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Test substance: Water Accommodated Fraction
Remarks: Based on data from similar materials
Quartz:
Ecotoxicology Assessment
Acute aquatic toxicity : No toxicity at the limit of solubility.
Components:
Dilithium azelate:
Biodegradability : Result: Readily biodegradable.
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Biodegradation: 83 %
Exposure time: 30 d
Method: OECD Test Guideline 301D
Remarks: Based on data from similar materials
Tris[bis(2-ethylhexyl)dithiocarbamato-S,S'] antimony:
Biodegradability : Result: Not readily biodegradable.
Remarks: Based on data from similar materials
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Biodegradability : Result: Not readily biodegradable.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
Bioaccumulative potential
Components:
Dilithium azelate:
Partition coefficient: n- : log Pow: -3.53
octanol/water
2,5-Bis(octyldithio)-1,3,4-thiadiazole:
Partition coefficient: n- : log Pow: > 6.5
octanol/water Method: OECD Test Guideline 117
Mobility in soil
No data available
Other adverse effects
No data available
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Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Empty containers retain residue and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose such containers to heat, flame, sparks, or other
sources of ignition. They may explode and cause injury and/or
death.
If not otherwise specified: Dispose of as unused product.
International Regulations
UNRTDG
UN number : UN 3077
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(Tris[bis(2-ethylhexyl)dithiocarbamato-S,S'] antimony, Anti-
mony, dialkyl dithiocarbamate)
Class : 9
Packing group : III
Labels : 9
IATA-DGR
UN/ID No. : UN 3077
Proper shipping name : Environmentally hazardous substance, solid, n.o.s.
(Tris[bis(2-ethylhexyl)dithiocarbamato-S,S'] antimony, Anti-
mony, dialkyl dithiocarbamate)
Class : 9
Packing group : III
Labels : Miscellaneous
Packing instruction (cargo : 956
aircraft)
Packing instruction (passen- : 956
ger aircraft)
Environmentally hazardous : yes
IMDG-Code
UN number : UN 3077
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(Tris[bis(2-ethylhexyl)dithiocarbamato-S,S'] antimony, Anti-
mony, dialkyl dithiocarbamate)
Class : 9
Packing group : III
Labels : 9
EmS Code : F-A, S-F
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
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Domestic regulation
49 CFR
UN/ID/NA number : UN 3077
Proper shipping name : Environmentally hazardous substance, solid, n.o.s.
(Tris[bis(2-ethylhexyl)dithiocarbamato-S,S'] antimony, Anti-
mony, dialkyl dithiocarbamate)
Class : 9
Packing group : III
Labels : CLASS 9
ERG Code : 171
Marine pollutant : yes(Tris[bis(2-ethylhexyl)dithiocarbamato-S,S'] antimony,
Antimony, dialkyl dithiocarbamate)
Remarks : Above applies only to containers over 119 gallons or 450
liters., Shipment by ground under DOT is non-regulated;
however it may be shipped per the applicable hazard
classification to facilitate multi-modal transport involving ICAO
(IATA) or IMO.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.
US State Regulations
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TSCA : All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory
exemption.
AICS : All ingredients listed or exempt.
Further information
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Flammability
HEALTH / 2
1 FLAMMABILITY
1
Health Instability
2 0 PHYSICAL HAZARD
0
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to
50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-
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vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-
tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-
ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG -
United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent
and Very Bioaccumulative
Sources of key data used to : Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/
Items where changes have been made to the previous version are highlighted in the body of this
document by two vertical lines.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided
relates only to the specific material identified at the top of this SDS and may not be valid when the
SDS material is used in combination with any other materials or in any process, unless specified
in the text. Material users should review the information and recommendations in the specific
context of their intended manner of handling, use, processing and storage, including an
assessment of the appropriateness of the SDS material in the user’s end product, if applicable.
US / Z8
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