CH HIVE ISTRY N E PART'MI H FdT

ffiGC$E CHEMISTRY PAPHR 3

REV[$EON-KET'

CHEMISIfiY ItOSDLNG CCLLEGE I pnrer 3 te acrswe

 \
Chromiurn, Cr, is a tiansition rnetal.

It is obtained from its oxide by the reaction shcwn.

Crr0o + 2Al **) AlzOs + ZCr

\
(ai What is the oxidation state oi

(i) chromium in CrrO.,

(ii) aluminium in Al"O.?

{b) State the r:educing agant i,n the reaction.

l1l

ic) Describe a test to confirm that the substance named in (b) is a reducinE aQent.

test..........

lTotai: 5]

The compound borazine was first macie over 90 ycars ago, lt was thought to have the
structure shown beicw.

t"t
I

HNH
v
lll
NN
/S-/\ .H
H.
I

lJ

(a) ti) What is the molecular formula and the empirrcal formula oi bcrazine?

motecular {ormula

empirical formula ........--...,.,., ...-... tzl

tii) lf the structural formuia is correct, what will ba the number of bonding electrons
around one nitrogen atorn in ihe molecuie c,f borazrne?

l1l

CHEMISTRY I\tOEDlNG COLLSCE ] paper3 kelaciswe

 iiii) Liquid borazine reacts wilh water to form a;-nmcnia, hydrogen
and an aqueous
scluiion of boric acid. H,BO..

construct a balansed equation for thls reactior,, including state synrbols.

tt'

I {b} carjron forms meny organic .u*uounou *n rn ,", ,t* ,"r,""" n";";
Exptain why carban is abie to fcrm many organic compouncis.
*";--l

.......f1:l
ic) (i) Draw the structural iormuiae of ethyl ethanoate and butanoic acid
showinc ail the
bonds around all the atoms.

ethylethartoate butanoic acid tJt

t*l
(ii) Explain wiry ethvl etharroaie and buianoic acic are said to ce structuralisomers.

"':"'"""""' .............-.... t21

(iii) Describe a chernlcei tesi to distinguish between ethyi ethanoate
and butanoic acirj.
iacf
.vJa .r!rrrrr.,
..,".-.r.-!.,.;.,.

result witfi ethyl ethanoate

result with butanoic aeid

......----."..... lii
Lsl

[-otal: i51

Cl:N4ISTRY tu4OEDlNG COLLEG: pape,3 keraotswe

 A student is provided with aqueous solutions oi fou:' meia, s;:iirai:s. Eacn nretal rod is
3
dippad in turn into each of the four metai suiphate sciut'tons. I-:= 'ss: IS a:e shown in the
table.

tron magneslum
\
cr:pper(il) copper displaced
c0pper displaced
Eulphate
fllagne$+uffi no reaclion I^^.^-^r;^^
IU lCgUtlVi: ^^ .^^^.;^-
sutph,at8

zinc sulphate n,0 re&ctioil ztnc dispiaced

*ron(lI) sulpha,l* lron disptacoci iro,n dtspiaced

{a} Writa the rfista}s in nrder nf i*creasinE rsacttvity.

least reactive most reactlve

t^1
Ll:

(h) $ugge*t an Bxptailation in iernns of electran loss or gai:n for $)ur ansl#er to (a)"

LL]

{c} Write an ionic equation for the reaction r,ihich talces piace bet'.veen ii"on and coppet{ll)
sulphate.

l1)

(d) When an aluminium rcd is dipped into iron(ll) suiphate solution, no change is seen, yet
aluminium is higher in the aciivilv series than iron. Explain why there is no reaction.
t1l

[Total:71

CHEilIISTRY IIOEDING COlLEGE i Daper3 kelao!s!!e

Study the list oi substancas,

heliurn []ere steel haernatite graphtte

catrci*rn carbonate sulphur dioxide carbon monoxide

Choose from the list a substance thai

(a) ciissoives in water to form an acidic soiution, .....-. l1l

(b) is an allotrope of cadrorl, ......,..,... ...... t1l

(c) is a nobte gas, ..,...-.." ........ i1l

id) is an alloy or ca:'bon. ...""... lf l

lTotal:41

a) Complete the tabie to shcw informaticn aboui iha atoms of nragnesium and chlorine.

number of number oi eiectron

atCIrrl
eiectrons neutrons errarlgernent

ffiagnesrum 2A'

chlor[ne 20
l 11
l.+]

(h) ln v,rhich Pariod oi the Perioiic Table is magnesiurn found?

Explaln y*ur answer r.lctr*g dala fro*r thp table absve.

t/t
L-l

Magnasium reacts with chiorine to form a solid, magnesium chloride.

{ci Draw a dot-and-cross diaEram to slrow the bonciing in magnesium chlcride.

t3l

(d) Chlorine reacts with hycirogen lorming hvdrogen chloride.

(i) Name the type of banding in hydrogen chlorida.

lll

Iru]

CHEIIISTRY MO!DlilG COrLrSg i peper 3 ketaorswe

Study the {iow chart shown and answer the questions thai foitciv. Tn: le:ie i's F - I are not the
chemicai symbols for the substances.

mixture o{
gasF+gasH

acid acidified

(a) (i) What is the name of gas H evoived in lhe reacticn?

.....,.....,[1]

(il) Desc:.ibe the coiour change when a drop of Universal lndicator ls added to a
soluti,on of gas li.
from .....,.." . to ....."..... ...... ill
{b} (.i} Give the name and iormula of the cation present in sait G.

name .......

formula .".,...-.t21

{iii Name the white precipitate l.

ll l
(ilfiI Nama i[-re change which occur$ when sa{t G is haated,

t1l

[Totat:6]

CHEh4ISTRY MCEDll.]G COffee ni paper3 keiEotswe

 ,Asample of water from a limestone area neeCed a large quantity cf soap to form iather.
After heaiing, the same arnount oi ihe sample c{ w'ater foimed lather easiiy with a very srnall
quantity of soap.

(a) Name a compound which caused lhe hardness in the sarnole of wator.

l (b) Expiain why hard vuater does not lather easil',,.

...."..."... l1l

.........,..I1l

ic) Explain why after heating the sampie of lvater, iather was formed vrith a very snlail
quantity of soap, lncluCe an equation in Srour answer.

."---."...... t4r

(di Describe how the cor,rpcunC ivhich causes the hardness qets intu- this water"

fT.f2i.R1

Ci]EMiSTRY N,IoEDING ccLLS6E I !a8..: }iEiaCTSW.

I A. student investigates tl":e reactlorr bstttreen
The hydrochlcric ecid is in sxcess
z:nc anc r,i,:.,liiir-l :aiJ.

The stuceni r-lses ihe anparaius sh*wn in tne rlia.trar:.

hycirnoen
*--
:r" "
,J|:i "-^- .
syrrnge

+- ^r
^ls^ll

tr;be helct by
c ni^^^ ^r

cotton

zrnc pou/et
hydrachlo;'ic acii

{a) \iVhat shouirj the studenr co 1c stari the ;-eaction?

(b) The srucient i'eails the v'aiume oi oas 1n ir-re syriirge

The resuits aiE sirown in the ianiel.
) "'rr svery
''vt / rnrnute.

iinre in minutes
volui"r,e oi gas in cm3

(i) Ff ot the resuits ,rn the gric cn pags 5.

CHEMISfRy MOEDTNG COLr:Cf j paler 3 ke aorswe

I
aa
a
(.}

a
fi
C'

LJ

-
O

iime,/ r,rin

(ii) Drav'r the Dest curr/e tirrcugn tne pciitts.

(iii) Exnlain F,,iiy ths volurn* ,rf gas stavs iiie sai-ne. aiier si:l i:rjnutes.

........^..151

(c) The stuCeni c,oes tne aEarn.

The ';rriy diiiErence is "-x?e*fi+n1
ihai the stu,leni uses y/aj"rn. iatnei inan ccii,
hirorochioric a;lC.
Cn tne qrid. drar,,tl"lE sha:e i; the :rap,r vc;,,\lu,l exle:i;c: r_.e
experirnent vliih ihe iiv,arm hvdrocnl*rrc acj,C.
ral
L4l

cHEMlSiRY MC:DtN6 COLieee j caper3 keleotswe

! The diagram shows part of the periaciic Table.

]l":IC^

C N F

S UI Ar
a. Kr

(a) Answer these questions using oniy the elenrenis shown in the diagram

Write dor,o,,n the symbol foi" an elernent i,,,lhich

(i) has five electrcns in its ourer sheli.

Irl
(ii) has diatomic rnoiecules
t1l
{iii} reacts with sodium io form sociium bromide,
t1l
(iv) is a ncirte gas r11
lrJ
(v) has a giant ccvaient structure,
, rir!{rtrritarrr!irrr!rrrrlltr rrrrrr.r}r!tr rrrt rrlrrrrr i1l
(vi) has a lcr+,er proton numbe r than fiuorrne.
l1l
(vii) is ihe most ai:undant gas rn the alr.
t1l

{b) lt/rite dolvn a use f*r each of the fotiol-,ring erenrenis.

(;) arg0n

L1J

(ii) lreliurn

,,..,,.,,,',,,'...,
rrl
L,j

(iii) oxygen

t1l

aHEl/ISTRY MO:DING COLLEGa i oarer 3 kelaotswe

 Tire struciures cf scme crganic compoLlncs ai'c snoi.,,;r neror,v.

H Hrl HiiilHltl-i
i-i-C*H
I
Llrrritt
H
I lirr
i.JHilHHilHH
u i: i
-\_,
trji v-(_

-H;-.r) I

Illr
ttlt
t"."1

lr. O
Ll ^-A
^ u-v-:, U
llil | '".
Hil I
I
C-H
n

(a) Neme cnnrpr:uni A.

l1l

ibi which two of fhe ccmpcuncis A tc E belong to the same homoiogous

series?

til

(c) (i) lvhich one cf ihe comr:ouncs A to E has the same funciional
sroup as ethanoi?

rr r r M I r!rt +Ii11I r I, L r rIr tI rIrrrr, i !r11I r !ri I r,I.I I I .r,r L },1rr

'{' I r 1L r rr, r Lr rI rr I r L i | ! r rI I I I I * r,.' II I r i I f Ir L I iI i rI L I1l
I I {I r I

{ii) Eraw tlre siructure cf ethanof . sircwing ari atoms and bcnds.

li1
t4l

{!ii) Describe hor.o,, eihanci is niade in rncusiry from ethene.

111
Ll)

Ci'lEI\4lSTRY L4OiDtNG COLTEG! i paper3 ke aotswe

(d) ti) which one of th* conrpoulrcis A to E is an unsaturated hydrocarbon?

!trir!r.rItlrrItr!,rlrtrtlrtrlrlrrixrlrt!tltrrfrrrlr[]]irirrrrrrir*x!r5rr.rrt..t.rrr1.t!**.r.!!r..!rlr*tr..]rtrtt, t1]

{ii} Describe a chemical lest far an unsatilrated hydrocarbon.

toct

resuf t tr'l
41
t-

(e) CornpounC E is acidic.

(i) State the name of compcund [.

r4i
I rj

(ii) Dsscribe a iest to show thar compound E is acidic.

td51

roer rlf
tll

CH:lllSTRY l\,1OEDlNG CO,-f ECE i paper 3 ke sotswe

 chicride is dissolved in waier'
(iii Name ihe sciutrcn iarrnad when hyurcgen

tiii)Hycrogenchloridedoesnotconductelectr.icii,vbutitsso}utioninwaterdoesconduct

Explain wh5r 16iu to'

/ 't

lTctal: t+i

and hYdrogen bY the Haher process as shown

in
1"1 Ammonia is manufactured irom nitrogen
the fiow chart.

ia) How is nitrogen obtained from air?

itc,'n hydrogen
{b) Writa a balanced
chemicai equation fcr the manuiacture oi ammonia
and nilrcgen.

(c) Explain why a catalyst is neecied'

r4l
I r.]

(d) Describe a iesi for anr'msnia gas'

r^ -l

tLl
^. ,lra
re*aulis
--

te) Siate one use ol ammonia in industty'

fTntal'-fi
i I vrer. ' l

COLLEGE oaoer 3 keiaotsvJe

CiiEMISTRY MOEDING
r
72 The poliution of air and water is a global concern.

(a) {i} Name one pottutant each of air and water,

air ............,.,.,...

water .........-......"... r2r

(ii) State a source for the air potlutant in (aXi).

sourcs ..... l1l

{iii} Eescrtb* a chemlcal test f,sr wat€r.

test

resulls
".....t21
(b) Suggest a reason why pollutants are of global conce rn.

..,. .. il j
{cl A sample of hard water is found to contain caicium sulphate.

(i) Narrre this type oi harcjness.

,........... ......., [1]

(ii) Give one method oi removing this type of hardness.

...."--..-. i1l

i.lGIat: bJ

13 Sandstone contains silicon dioxide and calcium carbonate. A studenl adds

10 g of sancistcne
to diiute hydrochloric acid so that the calciunr carbonate and the acid react
as shown.

CaCC, + EHC/ --+ CaCt + HrC + CO,

The diagram shows how the reactjon was carried out.

co,ttcn wool

ditute
sandslone hyCrochloric acid

balance

cl-lENltsjRy MoEDtNG CCt-t5GE I paper 3 ketao:swe

 The speeC of the reaction was loilolecj by measuring
the mass of carbon dioxide lcst. Thre
table shows the results.

time I min 0 4 I i2 lo ev {+ td LID

totel mass las.t /g n o.rB io.so io.se-r o+a 0,48 nq, 0.53
On the grid, plot a graph of the totai mass iost, against
iime.

{b) (i) use your graph to ietermine the maximum mass oi cai-bcn
dlaxicie iost.

(ii) Calcutate ine mass of caicium carbcnare that reacted

10 give this mass of carbcn
dioxide.

i'r'l
!c.l

{iii} Calculate tho percentage by mass of calciurn

carbonate in the originat 'l0g ^{
sandstone.

fnl
tLl

fTotal: Bl

CHEIIISTF,Y l,.1OEDlf'lG CCLtlc: i paper 3 xeiaotsvre

14 The diagranr shows how ethanol was prepared from
viaiei- a,r: suga;sciutron.

sugar,
water and
yeast Universal lndicator

{ai Name the process by which ethanoi is produced f i'om wate:- and sugar solution.

... ..i11
(h) Th* gas proouced is bubbled through water
conraining Universal lndicator,

{i} Name the gas produced.

carbon dioxide
......11 l
(il) whai colour changa is observed as the ges is bubbied through
the universal lndicator
soiution?
green to colourless
....... IC
...".i21
(c) A student suEgested boiling the sugar water
and yeast solution so that the reaction can
be kster'. Explain why the solution ihoutC not be
boiied.
it will denature the enzymes

(d) (i) Describe how the ethanol can be separated from

the mixrure after the reaction is
compiete.

by fractionall distillation
............t] l
{ii} when using the method named in (di{ii, describe how you
would know thet all the
ethanol has been separateC,
its boiling point has passed
..,,...,."..........t11
{e} The ethanol is heated with potassiurn dichrornate(vl)
ro torm an organic compound.

(;) Name the organic compound forrned.

.',.',,.".'''.....-.li ]
(ii) Give the structural formula of the organic compound
namei in {e}iii.

l1l

[Totatr s]

CHEMTSIRY M0EDiNG CCLLECI

1 paper 3 ketaotsw€
 The diagrarn shows a brast furnace rised fo-ihe
e>:ti-aciicn of iron.

!Yast* ore cf iron anC

gases other rav,, materiais

hot air

^t^^
>idu

moiten iron

(a) Nanre twa orher mat€riars added into fhe brast

furnace.

and ......,,... "..,..".....l2j

(b) Describe how siag is form*d in the blast furnace.

tl l
{c} The equari*n shows the reducticn oi ircn(iil)
oxicle by carbon mcnoxrce in the blast
fL{rna*e,

FerO,.."... + 3CD ...... 2Fe ..,... + 3COr.."...

(;) --)
compiete the equation by writina the stai€ symbois
of all the substances. t, I
!-.J
(i i) \{hat ts meant by r*duction?

(iii) Describe two reacticns by urhich carbon monoxide jormed

is in the b{ast furnace.
1...._...,.....

2 """"""" ............,.".".i21

CHCt',1lSTRy I/O!DING CC,.Lf Gi ] pape:: retaotswe

 {c} Eihanot is an alcohol.

(i) Slate the general rnolecular forrnule of alcohois.

CnH2n+1OH
t1l
(i i) Write the ,nam€ and formula of another aicohci.
HEXANOL
fiame lormulaC6H13OH -....-_..."._.
l2l
(iri) which compound has a higher merting point. eihanoi your
or compound in ic){ii}?
HEXANOL

Explain your answer.

it has highest number of carbons
..',.,,i2]
{d} Ethanot reacts with ethanoic acid to form ethyi sthanoate.

(i) Wr*te the chemicaHormula of ethvl ethanoate.

"...... Ir l
(il) Narne the homoiogous series to which ethyr
ethanoate berongs.

t1l
(iii) Giye one property of compounds in the same hornologous serie* as
ethanoate, eihyl

(ei How many moiecuies of propene could be nrade by cracking one rnolecuie
csH14? oi hexane,

""":"""'""
Explain yolrr ansiryer"

lloiai: 17]

CHEi\4iSTRY MOiDING COilSe i : paoer: keleo:swe

7V Soiid X was placed in a beaker
at 20 "C and heateC sreaoiiy. The graph
temperature of X changed. shows how the

100

80
temperature ^^
I"C bU

40

2A

o ru 't5
t5 2A
ZA ZS B0gs
time/minutes

{s} ti} $tate the highest remperature at which x was sti,

a soiid.

I1l
tii) State the boiting point of solid X.

11l
{iiu State whether so{id X is pure or irnpure.

11l
Explain your answer,

cl-.lEMlSTRy MOEDTNG CC[:e r ] lapsr 3 k€taotswe

ib) The diagram shows the arrangement of parlicres of
sorid x at zb "c.

use H're grspfi t's dr*w the arranEer*e.nt of parttcias of

x at 60 oc.

ll

CrlEirlSTRY N4CEDiNG COiLeee I Da.er: rieiaotsile

L8 study the reaction scherne
and a*swer the quastions tnar
fcrc*,.

(a) Ide,niity

{i} metat X,
iron

"....."...........t1 l
tiii sntution y,
sodiu hydroxide
.................. i1 r
(iii) gieen precrpitate p,
iron 2
-'..,............. Ill
(ivl brown solid Z.
copper

(b) type cf raactron which cccurs

*#;tI" between meiat x and aqueous
copper(ti)
displacement

{c}
reddish brown

(ii) *r***u o*o"r*;;;-n-,,,."r*,1 tll

nroro""* . -";,;:.
I oxygen

Cl'lElliSTRY IICEDtNG COLLEGE

] Faper: ks16q15y,,.
(d) Actdified ootassium manganate(Vil), KtvlnOl, !v3s used tc oxidise the green precip$iaie
P to iron(lll) hydroxide.

(!) Siate the coiour change of the potassiumr manganate(Vll).

green to coourless
to...".......... ........,..111

(ii) What hapoens to the oxidation state of ircn during the oxidation?
increase
.........,.t11

ffiotalr 10]

CilEMlSiRY [4OE0ll'JG COiLt-e i j paper i ieraot:vre

 19 {a) choose one substance frorn lhe list that fits the given description. you may use each
substance once, more than once or not at all.

bariurn $$lpflats cGp,per calcium hydr:oxide

carbon dioxidp hydrogen oxygEfl
calctunr oxide am,rnonium chloride diamsnd
([) an acidic oxide ..... CO2
rl'l
I r]
{ii} used to dry ammonia
r-t '1

(iii) barium sulphate

a salt prepared by precipitation .,.......,.... r{I]1
L

(iv) diamond
a macrornolecule .....-..-.
t1l
(b) Which tnro substances irom the list would react to
(i) form ammonia when heated together,
ammonium chloride calcium hydroxide
...,. and 1,1
tat
{iU only form a compoilnd wjih a molar mass of 1B g?
water
....,.. and oxygen rl l
I rj

20 (a) Chlorine exists as a diaiomic mstecule.

ti) V/hat is meant by a ciiatamrc molecr_lie?

two atoms of the same element covalently bonded together

t1l
(ii) To which Period of the periodic Tabre rioes
chrorine beiong?
3

{b} f}Ct anO flCt are two isoropes of chtorine.

Give one similariry and one differ,ence between
the two isotope,s.
same no. of protons
simnl*rity

difference different number of neutrons

cHEMlSTRy MOEDING COrLecr

i pap€i 3 ke 3oiswf
 Chiorine reacts urith socjiurn as shown
by ihe equation.
2Nais) + Ci2ig) -4 2Nact(s)
(i) lvhat iype of bonding is in sodium chr*ide,
Nacr ?
covalent bonding

I The oiagram shours part of the rattice structure

oi so,cium chroriie, Nacr.

\.

i'
I
\\\\
%

\\ \\

key

O sodium ion
\l @ chloride ion
'd
di.
t7-

(ii) compiete the diagram to show the ari-angement

of the particres. izl
iiiii calciui'n oxido, has.the same tyoe of
iattice structure as sodium chiaride.
melting potnt of calciur,r oxide is 2600'c The
and mat oJ so*un: chlcride is g0g .c.
why the r:neiiing point of carcium
oxide is higher rhan rhat of sodium
tr:,ffi

CHEMISTRY I\4CEDtNG COttEGE

i paper 3 reiactswe
tr Tebo reactBd a pieca
of mrn^^^.r.._-
or hyurogen
ffiffi. "#ifffl:ffi#,f, Si:nH:,
ionc acrd and
maasured the yolume

y:yluma of hydroE*n / cnrs

{a} ,Drallr a diagram

of the eppsratus
used du.ing the
experiment.

l3l

cljEMISTRy MOEDTNG
coLLre r j paper.s keteotswe
 on the grid, draw a grapil of the vorume of hydi-ogen prociuced
against time.

(c) Use your gi-aph to find the:

{l} volume of hydragen produceci after 33 seconds.

t 11

{[i] timo taken to collect SS cm3 oi hydrogen,

r{1
L rl
(ifi) time taken for- all the magn*sium to react.

la
! |j
I

CHEIIiSTflY [4CEDttiC COLLEGE

i ,aper! kerao:sw€
 (d) ln the experiment above, Teba ur 0'0359 of rnagnesium' The concentration of
hydrochloric acid was 0..10*o'O*ild
He repeeted the experiment using flio same
amouni of magnesiurn wiih 0.1ornol/dm*
sulphuric acid.

Did the sulphuric acid react faeter than, srower

hydrochloric acid?
than or at the Bame rate

Explain your afisr#sr.

z2 The ciiagram shows the arrangement of electrons

in a molecule of arnmonia.

(a) {l} $lame ths typ* *f b*nd between the nitrogen

*nd the hydrngren amffis.

Ill
il0 of ammcnia, showins the bonds you have named
3riiil*?,il*11t''* in (r)

ill
{iii} Stab +ne pr-oporrry of the,sirbg{anres that are composed, Iike
nnolecules. ammonia, of small

{b} Statq orle ffise o{ ar*monia.

CHEMISiRy t,,lOEDiNG COLLeCf

i paoer 3 ketacrsv,,€
 (d) {ii yrx#ff:x-J;fijlj*n,r:
vvhether tne ro*ard reacrion is endothernric
"",* or

The reaction is
",.,.,.....
because ....

I (ii)
fr::iHlif-tl,:dnt'nuous re'ry]ovaj or amnronia
.".............. il l
irom the equiribrium mixrure

-r
L3 During the proCuction oi traditional
beer, grucose is coilverted
dioxide as shown. to ethanci and carbrn

enzymes
cuH,rou ...__-____> zCzHsOH
+ ZC0,
(a) (U Name this process,
fermentation

{ii} .;;,;;.-,;;;;;;;*.,;;;.;;;; i1l

;;
so tht the enzymes in the glucose do not get denatured
-;;;;;;--;:;

{b) {i) Calcuiate the mass of ethanoJ, CtH.CH,

cuH,rc*. prociuced frorn 9.0 g ol glucose,
mass=

IITBSS
= ..,.....-.......,.,...,. s
{'i) carcuiate the number of ms}ecures
of ethancr produced in (b}{f).
il21
(Avogaciro's number
= o.ci* tliiij' , ,

mole *avogadro constant

nurnber of rnoieculas
= .."......
L!)
(ci Describe the chenricai
test to show thailhe gas prociuce,c is carbon
dioxide.
tes't use lime water

cHEMislRy t\4oEDtNG COLLEGE

I pap.,: kejaotswe
24 Hydrochicric acid was added
from a bu.rette to 20 cm3
containing a few drops
of univorsai tnoi"utor. rnl pr of aqueous potassium hydroxide
while the o, ,n* mixrure *"* ,uu*ured
*u*-n-irg -dilc. rne gr.ao-n-.nJ*.
fifl"?a: at
"io ihe pH durins the addirion
or

pH

vciume of acid added/cm3

(ai (i) lvhat was ths pFl of the potassium

hydroxide at first?

(il) State the cclour of the Universal

f
lt,
< l
lndicator when
10 cm3 of acid had
been added.
30 cm3 of acid had been
added'
(iii] what vorunae of the acid ."................. Izl
was added to neutrarise
20 cm3 0f rhe arkaii?

{iv} comment on the reiative concentrations crns Jt;

of the acid anci arkari.

l'J l
L IJ

CiJEI/4ISTBy MOEDING
COLf e C: j paper 3 k€lzorswe
 (b) A student attempted
to prepare poiassium. chloride
potassium hydroxido_and,i5 crystais frcrn the rnixtr.rre
added to th* rnixture and
c#
r;;J.n,or,. acid. smarl afi?ounts of E$cmg
then ,**oir*O] of charoaat w.*ra
{i} Exptain the purpose of adding
charcoaj.
to remove the colour of the solute

(ii) ....'-...-.., ., tll

How was the charcoal removed?
I filtration

(c) Ihe solution .r/as heated to dryness. I1l

{i) What is the coiaur of the

so{id rvhich remained?

{i;} Were the crystais obtained pure?

Exptain.
ilj

td) Give one appiication ot

acid-bese reactions in ciaiiy
rife.

CHEMISTRy MOEDi[]G
COLLfe , I p.oef 3 i(elaotslve
study tl're flow diagram about experiments that were caniec out on salt F.

add d.ilute

paie green
so{uffon eodiunr hydnixide

expose fit lor a day

&firlrlofli:&

(a) Wriie the narnes of the substances be[ow,

arlt
ssrt l)
I

sotrution R ...-.."..."...

solution S ....-.."...... ...............-.... t3l

irh) Narne the section oi the Periociic Tabie in which the metal containec in p is feund.

-.--........111
(c) Write a chemical equation with sta{e symbols to show the iormation of the green
precipitate S.

....^...."..121

(d) (ii Narne the gas found in air that raacts wiih the pale green solution and turns
it
brown.

-..""..-.--..... t1 l
(ii) The cl'lange from a paie grg6n to a brown involves a change in oxidauon number.
Name this type of reaction.

.- .... ... . ..... . 11 l

{e} Describe a test tc identif.y tite colourlsss gas e,

t rrb t , . . .. _ ,. .. .

result tel
tLi
"".!"""'"....

Cl-1El',4lSTRY MOEDiNG CCLLfOT- I ,aoer3 ke aotswe

 The diagranr shows
the electrolysis of
morten read{Il} bromide
using carbon erectrodss,

carbon eiec,tr.adeo

*tr*-
mnlton leed(Il| bromi#e

,ffi

heat

idlJ if) Lab*l ths eathode on

H-re diagram.
{*i wrlte the formufa of
fws ions preseni ij j
in rnort*n lead(Ir}
bromice.

(lf') wrira equadons '.,..- ar:d

for the ca$rode and ...,. it]
enode rsaction..
equa$on
cethoda

anoda equaiion ..,..,... I1l

{h} Why is it necessary to ....,".... r1l

heat the lead(If brornicje?

CrSM SiP\ MCE.r^,.

.,"-"i,v.: .-ULL.t --.
^t L: Ci3e. : .e rctrryr
 I
I
a

27 Gartic cofltains an organic compound wi[r ttrre siructure shov,,n.

HH t,

tl
,'\-nn
NH
n
II
rl n-A

itt \/-
tJ_ u_L/
irt
rll
H{-{ H H H i-.{

{a} (l} Write the molecular and empirical formula of the compound.

rnoleculer tormula

ernpiricaltorrnuta .... l2l

{it} State the colour changa observsd when the compound is shaken with aqueous
brornine.

from........ to,....,....... .....".. t1l

tiNi) Explaln the observation in {a[ii}.

,.........., l1 l
ib) The compound was conrpletely burnt and the gases produced wers passed through
acidified potassiurn manganate{yll) which turned coiourtess.

{ii suggest the name of the gas which caused the change in cotour.

.....-........". [1]
{ii} ls the gas oxidising or reducing?

lil
(iii) Nanre one other gas produced during the cambustion,

.......-.. tll

CHEMISTRY MOEDING COLLEGE i paper3 ketaorswe

 2g rhe diagrarns represent
the structures of
hryc arotropes
of carbon, x and y.

v
{a} {r} ldeniifo each allotrope.

' """""""
{i}}
,?jl-rJJ:_X."X:1."", of il-re ariotropes and ra
skte rhe physicai pr.openy
upan whicr
ailotrope
is used for ..,...."."..
phyeical property

{bi}

{ii}

Ifl

Ci-lEMlSiRY f,tCEDING COLL:GI

i oaper 3 keiaclswe
e
t

29 #kanes ars ohtaircd hy kaotioila{ di#illatian of cr:Lda ojl, In a different proees*

canied out at
the oll Fl+tlnerg Inng drain sfkqre* ara cenve*ed inb udrsgturstsd
lrydrbcarb*n* uv
"n**irg*
{a} Wrtte the meaning of the underlined words.

alrlcanes

distiilation

u*saturatsd

o'
(b) ;-;;; ;;.";*;" ;.., -::,
"";:"0.,",
.,nl,n_, *, o;,._;;;, *;.
0) write an equation for the comprete combustion of propane.

i'i
,,u *,***;-;;;;;;**0.-,*,;;;;;"*-,",n-*;;;.;;;;.

Exnlain your answer.

..,'.....'...",.,.. {1]
(lli) Name the aikane that has fcur carbon atorns in its molacule.

"..,.. t1l
{c} Alkanes wi!tr undargo su,bstitutian reaciions with chl*rine.
(il Yfq an equat,ion for ffre si,mplest substitution reaction between msthana and
cntonn€.

i,l
{,i} ;;*;,;";;;o.o***;',.;;";;;;;

I1l
(d) Sugar can be nnade irrto bean which containe
effianot.
ff) vVhat is flrc nam& ot thi* pmca*s?

{11
{iii $tate two conditions necessary for the process in (i) above.
..."". and
{21
(iiI) Name an organic product of the oxidation o{ ethanol,

CHEtu{ISIRY I.,4OEDiNG COfff e f i paoer -i ke aciswe

 vehicles in cities iike Gaborone
if?tr,tuhXtiT-;;il?.J'or arjd severar poilutanrs
ro ciear

exhaust

I fumes

(a) {i} Name two pollutants in the exhausts

fias€s cf cars.
aeJ
dl lu """""
,. .'""""""
iii) state one\ adverse
^ J. -
.
e#ect of- one of the por{utants
I2l
named in (a}.
pollutani

effect
-....... t1l
{ill}*htq$tqt lhe arnount of poliutants in the
exhausi gases o{ a car engine
be

.............,..,. I1j
{b} The fiow chart shorr..,s a method cf llc,.reiying air.

pass thruugh potas*ium

hydroxide

pass through anhyrlrous

cajcium chloride

Nam* the substance that is removec

vrhen afr passes through

iii
potassiumhydroxicje

{it} anhydrous caicium chl*i.jde

i2l

Ci-lEl!4lSTRY t\l0EDlNG COLI-EGE I paper 3 relaotswe

{c} to the behaviour of moiecules,
r?ffl:#:reference why compression and cooring
heip

.,....t21
(d) The tabie shows the boiring points
oi some oi the geses in
air.

boiling point/.C

(i) Nan'le lwo substances that wirl remain as gases

when arr is coo{ed to *200.c.

.. and ........ ........."...... i1l

(ii) rnethod bv which the rest
[HL[: of rhe cornpon€n,u o{ iiquid air
wi{r be

CH:MISTRY IIOEDtNG COiLfei j papei3 ,retaotswe

 he simplified diagram shows the
structure of the terylene.

n
YLJ
--J ii
;-rr- ---'--c-m-$_-o--- il"o
_ v _t__=_=r__,j(- Li
--tjj ffjj_ L. _ ii
C =r--_--_= f-f_ C ___
--
I (a) (i; ljai-.:e the type ot linkage in ieryfene"

."....
fii) a natura$ pofymer with the sam€ i1
'ame ,nkage as teryiene.
*;;;;*;-;
ri*t neo ;;;;;;-;;;-; ;.;;;;; *..;;-;"*

'-*ffiffi-
4

{21
(b) Proteins ai.e aiso polyrners.

0) Whai are the products of the

acid hydrctysis of proteins?

...,'.,.....'.'.,. |1]
{!l} the producrs of the ac,id hydrorysis
I-ffirll: or proieins are separared
and

separated
..._." i1 l
icientified
.-.. ij j

CH:l\4lSTRY M0f DlNG COLIEGi Daper 3 keiactsv.,€

32 Ttie diagram shows
the labor.atory prsparation
concentrated hydr.ochronc of chlorrne i;_orn manganese
acid. dicxj:e a::

concentrated
hydrochioi-ic
acid

nilengeness
dioxide chtorine

haai y concenti.aled
sulphuric
acid
(a) Name the liquid y and
shte its functicn.
name

function
...........t2]
properry o{ cniorine
't' :;:fJ:e rhar makes ir possible
ior it io be coliecied
b,v the rnerhcd

(e,} The equailon for l1l

the reaction is shcwn
beiou
l*ne, + ......HCi *) MnCl,
+ ......C12 _ ......H-O
{i) Baiance the e,quailon.
(ll) show how the oxidation llJ
number of rnanganese has
changed cruring this
reaction.

{iii) Explain why this is a

redox reaction. """""""""-. l{ Ii!
L

(d) ;;"*;,.: ,^,..^- ^ '""""". il j

"o;.or tiru piJjurnr#ater' some of the chlorine react. forming chioric(i)
"n one
as
acid, ilcro,
(,) Construct the equatron lor
the rear:tion of chtorine,
Clr, wiih waier.

(ii) state the acrion or chiorine "-"""'""'"'. til

111
on damp ritmus paper.

CHEM STRY MCEDII'lC COLLf G: I paoer 3 keiaclswe