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Hess's Law Problems

1. This document provides 8 chemistry problems involving calculating heats of reaction using Hess's law and given thermochemical equations. 2. The problems ask the student to determine heats of reaction for various reactions by adding the standard enthalpy of formation values of reactants and products. 3. Standard enthalpy of formation values are provided for reference thermochemical equations to use in the calculations.

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62 views3 pages

Hess's Law Problems

1. This document provides 8 chemistry problems involving calculating heats of reaction using Hess's law and given thermochemical equations. 2. The problems ask the student to determine heats of reaction for various reactions by adding the standard enthalpy of formation values of reactants and products. 3. Standard enthalpy of formation values are provided for reference thermochemical equations to use in the calculations.

Uploaded by

Hus Sein
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Name_____________________

Date________________Pd___

Chemistry: Hess’s Law Problems

1. Calculate the value of Ho/kJ for the following reaction using the listed
thermochemical equations:

P4O10(g) + 6 PCl5(g) 10 Cl3PO(g)


1/4 P4(s) + 3/2 Cl2(g) PCl3(g) Ho/kJ = -306.4
P4(s) + 5 O2(g) P4O10(g) Ho/kJ = -2967.3
PCl3(g) + Cl2(g) PCl5(g) Ho/kJ = -84.2
PCl3(g) + 1/2 O2(g) Cl3PO(g) Ho/kJ = -285.7

2. Given the following equations and Ho values, determine the heat of


reaction (kJ) at 298 K for the reaction:

2 SO2(g) + 2 P(s) + 5 Cl2(g) 2 SOCl2(l) + 2 POCl3(l)


SOCl2(l) + H2O(l) SO2(g) + 2 HCl(g) Ho/kJ = +10.3
PCl3(l) + 1/2 O2(g) POCl3(l) Ho/kJ = -325.7
P(s) + 3/2 Cl2(g) PCl3(l) Ho/kJ = -306.7
4 HCl(g) + O2(g) 2 Cl2(g) + 2 H2O(l) Ho/kJ = -202.6

3. Calculate the heat of combustion (kJ) of propane, C3H8 using the listed
standard enthapy of reaction data:

C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(g)

3 C(s) + 4 H2(g) C3H8(g) Ho/kJ = -103.8


C(s) + O2(g) CO2(g) Ho/kJ = -393.5
H2(g) + 1/2 O2(g) H2O(g) Ho/kJ = -241.8

4. Given the following equations and Ho values given below, determine


the heat of reaction at 298 K for the reaction:
2 N2(g) + 5 O2(g) 2 N2O5(g)
2 H2(g) + O2(g) 2 H2O(l) Ho/kJ = -571.6
N2O5(g) + H2O(l) 2 HNO3(l) Ho/kJ = -73.7
N2(g) + 3 O2(g) + H2(g) 2 HNO3(l) Ho/kJ = -348.2

5. Given the following equations and Ho values, determine the heat of


reaction at 298 K for the reaction:

C(s) + 2 H2(g) CH4(g)


C(s) + O2(g) CO2(g) Ho/kJ = -393.5
H2(g) + 1/2 O2(g) H2O(l) Ho/kJ = -285.8
CO2(g) + 2 H2O(l) CH4(g) + 2 O2(g) Ho/kJ = +890.3

6. Given the following equations and Ho values, determine the heat of


reaction (kJ) at 298 K for the reaction:

B2H6(g) + 6 Cl2(g) 2 BCl3(g) + 6 HCl(g)


BCl3(g) + 3 H2O(l) H3BO3(g) + 3 HCl(g) Ho/kJ = -112.5
B2H6(g) + 6 H2O(l) 2 H3BO3(s) + 6 H2(g) Ho/kJ = -493.4
1/2 H2(g) + 1/2 Cl2(g) HCl(g) Ho/kJ = -92.3

7. Given the following equations and Ho values, determine the heat of


reaction (kJ) at 298 K for the reaction:

2 OF2(g) + 2 S(s) SO2(g) + SF4(g)


OF2(g) + H2O(l) O2(g) + 2 HF(g) Ho/kJ = -276.6
SF4(g) + 2 H2O(l) 4 HF(g) + SO2(g) Ho/kJ = -827.5
S(s) + O2(g) SO2(g) Ho/kJ = -296.9

8. Determine Ho/kJ for the following reaction using the listed enthalpies of
reaction:

N2H4(l) + 2 H2O2(g) N2(g) + 4 H2O(l)


N2H4(l) + O2(g) N2(g) + 2 H2O(l) Ho/kJ = -622.3 kJ
H2(g) + 1/2 O2(g) H2O(l) Ho/kJ = -285.8 kJ
H2(g) + O2(g) H2O2(l) Ho/kJ = -187.8 kJ

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