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Nece MR 0175 2001
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STD-NACE MROL7S-ENGL 2003 MM L4S2981 003304 760 mm 'MROT75-2000 was an American National ‘Standard. ANSI Approval ofthe 2001, ‘dition of M0175 is expected by August 2001.STD-NACE MROL7S~ENGL 2001 MM L4YS2981 0503102 624 mm ANACE ern Item No. 21304 TO THE CORROSION SOCIETY Standard Material Requirements Sulfide Stress Cracking Resistant Metallic Materials for Oilfield Equipment ‘This NACE Intemational standard represents a consensus of those individual members who have reviewod this document, its scopa, and provisions. Its acceptance does not in any respect preclude anyone, whethor he has adopted the standard or not, from manufacturing, marketing, purchasing, oF using products, processse, or procedures not in conformanco with this standard, Nothing contained inthis NACE Intemations standard is to bo construed as granting any righ, by Implication or otherwise, to manufacture, sell, or use in connection with any mothod, apparatus, or product covered by Letters Patent, of as indemniying of protecting anyone against llbiity for Infringement of Letters Patent. This standard represerts minimum requirements and should in no Way Be interpreted as a restriction on the use of botter procedures or materials. Neither is this ‘standard intended to apply In al cases relating tothe subject. Unpredictable circumstances may ‘negate tho usefulness of this standard in specific instances. NACE Intemational assumes no responsibilty for tho Interpretation or use of this standard by other partios and accepts responsibilty for only those official NACE International Interpretations. Issued by NACE Intemational in accordance with lis governing procedures and polices which preclude the issuance of interpretations by individual voluntoars. Users ofthis NACE Intemational standard are responsi for reviewing appropriate health, safety, ‘environmental, and regulatory documents and for detormining thelr applcabilty in relation to th ‘standard prior to is use. This NACE Intemational standard may not nooossarly adarese al potential health and safety problems or environmental hazards associated with tho use of ‘materials, equipment, and/or operations detailed or referred to within this standard. Users of this NAGE Intemational standard are also responsible for establishing appropriate ho ‘environmental protection practices, in consultation wih appropriate rogulalory authorities if ecessary, to achieve compliance with any exiting applicable regulatory requlroments prior to the Use of this standard. CAUTIONARY NOTICE: NACE Intemational standards are subject to periodic review, and may be revised or withdrawn at any time without prior notice. NACE Intemational requis that action be taken fo reaffirm, revise, or withdraw this standard no later than five years from the date of iit publication. The user Is cautioned to obtain the latest adiion. Purchasore of NACE International ‘standards may receive current Information on all standards and other NACE International publications by contacting the NACE Intemational Membership Services Department, 1440 South ‘Greek Dr., Houston, Texas 77084-4906 (telephone +1 [281]228.6200). eevised 2001-03-09 ‘Approved March 1975, NACE Intomational +1440 South Crook Dr. Houston, Texas 77084-4908-8340 +1 (281)226-6200 ISBN 1-57500-021-1 (©2001, NACE InternationalSTD-NACE MROL75-ENGL 2001 Mm L4S298) OSO320S &T? MR0175-2001 Foreword ‘This NACE standard materials requirement is one step In a sories of committee studios, reports, ‘symposia, and standards that have been sponsored by former Group Committee T-1 (Corrosion ‘Control in Petroleum Production) relating tothe general problem of sulde stress cracking (SSC) of metals. ‘Much of this work has boon directed toward the oll- and gas-production industry. This ‘standard is a matorals requiromont for motals usod in oll and ga service exposed to sour gas, to bo used by oll and gas companies, manufacturers, engineors. and purchasing tho guidelines and specific requirements in this standard are based on fold materials listed, as used in speciic components, and may be appicable to other components and ‘equipmont in the ol-preduction industry oto other Industilos, as determined by the user. Users of ‘this standard must be cautious in extrapolating tho contont of this standard for use beyond its “Tho materials, heat treatments, and moist property requremonts givon In. this. standard roprosont tho bost judgment of Task Group 081 {fomerly T-1F-1) and ks edministrate Spectic ‘Technology Group (ST) 22 on Ol and Gas Production—Motalurgy (formerly Unk Commitee T- 1 on Metallurgy of Oilfield Equipment). ‘This NACE standard updates and suporsodes all previous editions of MRO17S. The orignal 1978 edition of the standard superseded NACE Publeation 1165 (1973 Revision) ted “Sule CCracking-Resistant Metalic Matorals for Valves for Production and Pipeline Service,” and NACE Publication 1816S tiled “Recommendation of Materials for Sour Sorce” (which included Tentative ‘Speafestions 150 on vals, 81 on sovero Weight logs, 60 on tubular goods, and 60 on rominal woight loss). "This standard wil Bo rovsad as necessary to reflect changos in technology. (See Paragraph 18) ‘Whonaver persia, the rocommended materials are defined by reference to.gccorigd gonaig ‘descriptors (ouch a8 UNS” numbers) andor accepted standards, such as AIS\ APL.® ASTM or DIN stonderds. In NACE standards, the terms shal, must, should, and may are used In accordance with {tho defintions of thase terms In the NACE Pubfoations Style Manual, 4th ed., Paragraph 7.4.1. Shall and must are used to stato mandatory requirements. Should is ised to stale ‘Something considered good and is rocommondad but la not mandatory. May le used lo ‘late something considored optional. { Motals and Atoys in he Une’ Nurboing Sytem (ast role) a ont publaton of he Amorcan Soualy for Testing and Matt (ASTM) and he Socaly et Automotve. Enghesre Ine. (SAE), 400 {Germano De, Warrendale PA 15068 {Sorcan ton and Sto! tite AID, 1133 Yh St NW, Washington,DC 200062701 American Perot insti (APD, £229 | St NW, Wasringion, DG 20005. {@hanercan Socket fr Testng an Matals(ASTH), 100 ar Harbor De, West Conshohocken, PA 10428 968, Deutsches instut tor Nomung (IN), Pesach 1107, 0-1000 Bun 9, Federal Repub of Gonnary. ‘Arrows in the margins Indicate technical or major editorial revisions that were approved by NACE International STG 32 and Incorporated Into the 2001 edition of MRO175. Revisions are not indicated In the ‘tables or index. NACE International .STD-NACE HROL75-ENGL 2001 MM b452981 OS0310b 533 mm MRO175-2001 NACE International Standard Material Requirements. Sulfide Stress Cracking Resistant Metallic Materials for Oilfield Equipment i 122 Applcabiity.. 1.3 MROT75 Application 1.4 Control of Sulfide Stross Cracking (SSC)... 155 Acceptable Materials 1.8 Procedures for the Addition of New Materais or Processes. 1.7 Hardness Requirement 1.8 Materials Handling eee 1.9 Procurement. 1.10 Material Replacement 2. Dofinitions.. 3. Ferrous Metals 3.1 General 8.2 Carbon and Low-Alloy Stoets 3.3 Froe-Machining Steels. OSLOENNN+455 3.4 Cast Iron 9 3.5 Austenitic Stainless Stools 9 6 Ferttic Stainless Steels. 2 3.7 Martensitic Stainless Si 2 3.8 Precipitation-Hardening Stainless Stools .. 4.4 General 4.2 Other Alioys. 5. Fabrication, 5.1 General 5.2 Overlays 53 Welding 54 Identification Stamping 5.5 Throading 58 Cold-Deformation Processes 6.2 Exposed Batting 8.3 Nonexposed Baking 7, Flatngs and Coatings. 7.1 General NACE InternationalSTD-NACE MROL?S-ENGL 2002 MM 452963 OSO307 477 a 7.2 Nitriding . & Special Components... 8.1 General 82 Bearings 19 8.3 Springs .. — 19 8.4 Instrumentation and Control Devices 19 85 Seal Rings. i. : 20 86 Snap Rings ..... 8.7 Bearing Pins . 88 Duplex Stainless Stee! for Wellhead Components 8.9 Spocial Process Woar-Resistant Parts.. 9. Valves and Chokes 913 Internal Valve and Pressure Regu mponent 10. Wells, Flow Lines, Gathering Lines, Facilities, and Fiold Processing Plants Subsuriace Equipment 104 — Wolheads.. 105 Flow Lines and Gathering Lines. 10.8 Production Facies. 10.7 Com, Control of Briling and Weil Servicing Environments. 113. Diling Equipment 114 Blowout Preventer (BOP) 115 Choke Manifolds and Choke and Kil Lines. 118 Dri Stom Testing 147 Formation-Testing toois 14.8 Floating Drilling Operation 11.9 Wall-Servicing Equipment. Roforences. Tables 41. Description of Test Levels. 2. Test Data, ‘3. Stainless Stools Acceptabie for Direct Exposure to Sour Environments 4. Nonferrous Materials Accoptable for Direct Exposure to Sour Environmenis, 8. Accoptable AP! and ASTM Specifications for Tubular Goods 6. Acceptable Materials for Subsurtace Equipment for Direct Exposure to Sour Environment ‘ther Sources of Mater Figures Figure 1: Sour Gas Systems... Figure 2: Sour Multiphase Systems Index History of the Addtion of Materials to MRO175.. NACE InternationalSTD-NACE MROL7S-ENGL 2001 MM LYS2941 0503104 306 mm (MRO175-2001, Section 1: General 1.1. Seope: 1.4.1 This standard presents metalic material roqulromenis for resistance to sulfide strees cracking (SSC) for petroleum production, driling, gathering and flowing equipment, and fild proosssing feces to be used In hydrogen sulfide (HS)-bearing_hydrocafion sorce. This standard ts applicable to the materials ‘andlor equipment speciiod by the materials standards Inattutions listed in Table 7 (or by equivalont standards ‘or specications of other agencies). This standard does ‘not include and is not intended to include dasign ‘Other forms. of corrosion and other ‘odes of failure, although outside the scope of this ‘standard, should also be considered in design and ‘operation of equipment. Severely corrosive conditions: ‘may lead to failures by mechanisms othor than SSC and ‘should be mitigated by corrosion inhibition or materials. selection, which are outside the scope of this standard. For example, somo lowerstrongh stools used for pipelines and vessels may be subjected to fallure by Bist cracking or hydrogen induced (stopwise) cracking ‘a a result of hydrogen damage associa with goneral Corrosion in the presence of HeS."* Also, austenitic slainless stools and evon more highly alloyed matoials ‘may fall by a type of chloride stress corrosion cracking ‘thal I promoted by elevated tomporature, aggravated In ‘some cases by the presence of HES. 1.1.2. Many of the materials intially inctuded in MROI7S ‘wore included basod on fold uso under vatiod ‘conditions and the toms for inclusion did not record the ‘environments on which acceptance of those alloys into MMROI7S was based. MROI75 has spectiod ‘endronmental limits for alloys included more recently. ‘Tho stated environmental limits represent conditions under which the alloys successfuly passed laboratory ‘tests. Because SSC fs dependent on the environment, Including stress, HS partial pressure, tho presence of ‘elemental sur, salinity, pH, and metaurgicalcondtion ofthe alloys, the actual environmental Limits may not hhave been defined for any alloys in MAOI75. is the ‘users responsibilty to determine both (1) the degree of accuracy to which laboralory tost data, and (2) the ‘degree of applicability of qualifying fold experience, simulates the criical variablos of tho intended _agoliction. NACE International 1.2 Aeplicabiity 1.2.1 This standard applies to all components of equipment exposed to sour environments, wher felluro by SSC would (1) provent the equipment from being restored to an operating condition wiilo continuing 19 Contain pressure, (2) compromise the integrty of the prossure-containment system, and/or (8) prevent the basic function of the equipment from occuring. ‘Materials selection for items such as almosphoric and lowpressure systems, walor-handing facies, sucker ‘ods, and subsurface pumps are covered in’ greator detail in othor NACE Intemational and API documents and are outside the scope of this standard. 1.3 MROI75 Application Sulfide strose cracking (SSC) is affected by factors Including the folowing: (1) _motal chomical composition, strongth, heat treatment, ‘and microstructure; (2) hydrogen fon concentration (pH) ofthe environmant; (8) eS concentration and total pressure; (4) ‘otal tonsio stress (appliod plus residual); (©) temperature; and © time. ‘Tho usor shall determine whether or not the environmental conditions are auch that MROI7S apples. 1.3.1 MROI7S. shall apply 10 conditions containing Wator as a liquid and HeS excoeding the limits detined In Paragraph 1.3.1.1. t should bo noted that highly Susceptible matoriis may fall in less sovero ‘environments.STD-NACE MROL7S-ENGL 2003 MM L4S2982 0503205 242 mm MRO175-2001 1.3.1.1 All gas.® gas condensate,” and sour crude o™ (except as noted) ‘When the partial pressure of HS in a wot (water as 4 liquid) gas phaso of a gas, gas condensata, of ‘crude ol system is equal to or excoeds 0.0008 MPa. ‘abs (0.05 psia). 1.32 MRO175 need not apply (the usor shall
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