MBR Operators Workshop Draft Presentations
MBR Operators Workshop Draft Presentations
Basics
TODAY’S AGENDA
• Basics
• Break
• Case Study
• Break
• Case Study
• Quiz
Basics
• Terms, Definitions
• Submerged Membrane Unit Structure and
Function
• System Components
• Managing MBR System Performance
• Biofilm Management
• Controls
• Biological Nutrient Removal
•
Terms and Definitions
The rate of filtration per unit area of membrane material is called flux. Defined here in the U.S. as
gallons per square foot.
• Typical value 12 gfd at 10°C
• 14 at 15°C
• 17 at 20°C
• The pressure difference across a membrane during filtration is called transmembrane pressure
(TMP)
• Typical TMP at design flux rates 0.5‐1.0 psig
• Maximum TMP 3.0 psig
• Air Scour
• Determined by number of membranes and flux rate
• The interdependency between biological process conditions and membrane hydraulic performance
through a biofilm is termed BioHydraulics
Measuring TMP
Pumped
PS System
PG
5
Terms and Definitions
• Production Capacity: The net permeate flow rate over a given period of continuous operation
accounting for CIP procedures and relaxation.
– Average Daily Flow (ADF): The net daily flow requirement generally occurring during dry
weather conditions and lasting nine (9) months.
– Maximum Monthly Flow (MMF): The net daily flow requirement generally occurring
during wet weather conditions and lasting three (3) months.
– Peak Daily Flow (PDF): The net daily flow required during peak daily flow conditions and
lasting 24hr.
– Peak Hourly Flow (PHF): The net peak hourly flow requirement generally occurring
during wet weather flow conditions and lasting 4hr.
Submerged Membrane Unit (SMU)
Structure and Function
Tube
Cartridge Anatomy
‐ABS plate
Type 515
-1.64ft x 4.92ft
‐Chlorinated polyethylene
membrane
-15.61ft2 Area
‐Thermal weld process
Tube ‐Polyester plenum material
‐0.4 m mean pore size
‐<0.2 m effective pore size
Submerged Membrane Unit (SMU)
Structure and Function
Submerged Membrane Unit (SMU)
Structure and Function
Membrane case
Diffuser case
Diffusers
Submerged Membrane Unit (SMU)
Structure and Function
• Flat Plate Geometry
Matters
– Fixed spacing between
cartridges (8 mm)
– Very little for “solids” to
hang up on
– Airlift pump action keeps
sludge moving between
cartridges
Submerged Membrane Unit (SMU)
Structure and Function
• Acts like an airlift pump
– Continuous coarse bubbles at
the bottom
– Fully enclosed
– Air scour in constant contact
with the membranes
– Continuous movement of
mixed liquor keeps tank
contents well mixed and in
suspension
System Components
• Fine Screen
– Achilles heel of all
MBRs
– Ideal to have
duty/standby
– Ensure there is no
bypass
– Outdoor installations
may require heat
tracing
System Components
• Permeate Pumps
– Ideal to have
dedicated pumps for
each MBR basin with
a common standby
– Make sure there
aren’t high points in
the suction piping
that can lead to air
binding
System Components
• Blowers
– MBR tanks and pre‐
air basins should have
separate blowers
(though they can
share a common
standby)
– Make sure you have
spare parts such as
belts or filters on
hand at all times
System Components
• Clean in Place
– Semi‐automatic
– Pumped or Mazzei
injector
– Become familiar with
isolation valves,
especially the vent
valve
Managing MBR System
Performance
Biological Process
Solids Handling
Design
Integration
Pre‐Treatment &
Controls
MBR SYSTEM
Plant Hydraulics Equipment
Selection
Operation
Aeration Systems &
Maintenance
Managing MBR System
Performance
• Think MBR system not membranes
Process Condition Impact on MBR
Air leaks / Air Lock in Permeate Pipe False ‘High’ TMP → Reduced Capacity
DirectlyCan
Biofilm Impacts Hydraulics
Represent 90% of
Total Resistance Across
and Cleaning Membrane
(TMP)
Biofilm Management
• Good
Biofilm Management
• BAD
Biofilm Management
Ideal Non‐Uniform
Thick
Stable
Variable
High TMP
Increased TMP
TMP
TMP
Biofilm Management
Relaxation
Air Scouring
• The rise velocity of bubbles • Permeate
impacts shear force and suspended while
biofilm thickness aeration continues
• Intensity requirement is a • Increases biofilm
function of deposition rate porosity
(flux) and fluid viscosity • Decreases biofilm
• Defined air flow pathways thickness
promote even distribution • Can increase overall
• Turbulent velocity (slug flow) sustainable flux
maximizes effect
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Biofilm Management
Normal Filtration Relax
Biofilm Management
mg/l
MPE50
TM for upsets &
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Biofilm Management
Maintenance Cleaning Recovery Cleaning
• Intended to remove surface • Intended to “dislodge
particles from membrane
(biofilm or cake) fouling.1
microstructure.”1
• Does not involve taking • May take from >4‐24hrs.
tanks out of service for
• Requires that membranes
extended periods of time be soaked in concentrated
(~1‐4hr) chemical solution.
• Routine procedure • Generally a non‐routine
• Can return to MBR filtration procedure for flat plate
mode in ~15 minutes systems
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Biofilm Management
Pressure
Chemical Eductor Flow Meter
Regulator
Stock Chemical
Supply
Control Valve
The Operator’s Toolbox
Biofilm Management
Suspected Recommended Alternate Cleaning Solution Cleaning
Fouling Cleaning Chemical Cleaning Weight Percent Duration
Material Chemical
Aluminum Oxalic Acidc Citric Acid 0.5% to 1.0% 0.5 - 1.0 hrs
Oxidea
Ferric Oxidea Oxalic Acidc Citric Acid 0.5% to 1.0% 0.5 - 1.0 hrs
# Cartridges 1.35gal
VCS # SMU
SMU Cartridge
# of SMUs = 3
# of Cartridges = 200
Biofilm Management
Calculate the approximate concentration of the cleaning solution (CCS) that should
be used at the given MLSS concentration
CCS MLSS 1
3
CCS 15,000mg / l 1 5,000mg / l 0.5%
3
Calculate the dilution factor (fD) given the concentration of the stock chemical and
the cleaning solution weight percent calculated above
wt % StockChemical 12.5%
fD fD 25
wt %CleaningSolution 0.5%
Biofilm Management
Calculate the amount of stock chemical (VSC) required to perform the
Maintenance Cleaning
VCS
800 gal
32 gal
VSC VSC
25
fD
Therefore, only 32 gallons of 12.5% bleach are required to makeup the cleaning solution
Controls
• Control System
Architecture
–PC and PLC networked via
Ethernet
–Remote access gained
through dial‐up modem or
VPN
Controls
• The Plant’s Brain
Controls
• The Brain is Dead
Controls
• Manual Operation (becoming the brain)
• Think logically about how flow comes into the
plant
• Concentrate on the absolute basics
– Screens
– Recycle
– Air scour
– Permeate flow
– Achieve a good balance
Biological Nutrient Removal
• Nitrogen
– Raw Wastewater contains nitrogen in the form of:
1. Organic nitrogen
2. Ammonia‐N (NH3‐N)
3. Nitrite (N02‐N)
4. Nitrate (NO3‐N)
TKN = 1 + 2
TIN = 2 + 3 + 4
TN = 1 + 2 + 3 + 4
Inert nitrogen = 2% of TN
Biological Nutrient Removal
• Autotrophic Bacteria
– Known as Aerobes or Producers
– Use carbon dioxide as their sole source of carbon
– Perform Nitrification
• Nitrosomonas convert ammonia to nitrite
• Nitrobacter convert the nitrite to nitrate
• Together they break down ammonia into nitrates
– Use dissolved oxygen to oxidize ammonia
– Thrive in the aeration basin and can survive in
anoxic
– Very sensitive to pH changes and toxins
Biological Nutrient Removal
• Nitrification
– Presence of oxygen
– Occurs in Pre‐Air and MBR basins
– Autotrophic bacteria are slow growing. Longer SRT
– Nitrification consumes alkalinity @ 7.14 g alkalinity/g NH3‐N
• Nitrification ( NH3 to NO3) 4.57 gO2/gNH3
– Nitrosomonas
• NH3 to NO2 3.43 gO2/gNH3
– Nitrobacter
• NO2 to NO3 1.14 gO2/gNO2
– Electron Acceptor: Oxygen
Biological Nutrient Removal
• Denitrification
– Absence of free oxygen
– Occurs in Anoxic basin
– Heterotrophic bacteria
– Denitrification recovers 50% alkalinity lost in nitrification @ 3.57g
alkalinity/g NO3‐N
• Denitrification ( NO3 to N2 gas)
– Alcaligens, Pseudomonas
• NO3 to N2 2.86 gO2/gNO3
– Oxygen Equivalent of NO3
– Electron Acceptor: Nitrate
– BOD:TN ratio greater than or equal to 4
Biological Nutrient Removal
Heterotrophs also known as Anaerobes or Consumers
• They use BOD as their principle source of carbon
• 80‐90% of the overall population
• In the right environment, they perform Denitrification
• They are facultative
• They can use dissolved oxygen to oxidize BOD
• Or they can use oxygen from Nitrates to oxidize BOD
• Thrive in the aeration basin and thrive in the anoxic basin
• Compared to autotrophs, they are less sensitive to pH
changes and toxins
Biological Nutrient Removal
Characteristics or Traits A H
Perform Nitrification
Perform Denitrification
Require a long SRT
Require a short SRT
More sensitive to pH
Less sensitive to pH
Make up 10‐20% of the MLSS population
Make up 80‐90% of the MLSS population
Thrive in the aeration basin
Thrive in the anoxic basin
Use free oxygen when metabolizing
Use oxygen found in nitrate when
metabolizing
Biological Nutrient Removal
• 100:1
For every 100 Pounds of BOD coming into the plant: a minimum of 1 Pound of
Phosphorous is needed to promote cell growth
• 20:1
For every 20 Pounds of BOD coming into the plant: a minimum of 1 Pound of Nitrogen
is needed to promote cell growth
• 7:1
For Every 1 Pound of Ammonia that is oxidized in the process: 7.14 Pounds of
Alkalinity (as CaCO3) is consumed
• 4.6:1
For every 1 Pound of Ammonia Nitrogen that is oxidized to Nitrate: 4.57 Pounds of
Oxygen is utilized.
• 4:1
For every 1 Pound of Nitrate to be reduced: 4 Pounds of BOD must be available
• 3.5:1
For every 1 Pound of Nitrate that is reduced in the system: 3.57 Pounds of Alkalinity
(as CaCO3) is recovered
Biological Nutrient Removal
• Phosphorus
– Raw wastewater contains phosphorus in the form
of:
1. Orthophosphate
2. Polyphosphate
Biological Nutrient Removal
• Phosphorus Accumulating Organisms (PAOs)
– Store carbon as an energy source in anaerobic
environments
– Burn polyphosphorus during this process and
release orthophosphate
– Convert carbon to energy and uptake phosphorus
in aerobic environments for cell growth, known us
luxury uptake
Conclusions
• Flux is critical to proper operation of your Kubota
membranes
• Kubota SMUs are designed specifically for
wastewater treatment
• MBRs are a system of components including the
membrane
• Biofilm management is key to preventing premature
fouling
• Plants can be operated manually in emergencies
• Autotrophs, heterotrophs and PAOs allow us to
remove nutrients biologically
MBR System Upgrade and Replacement
Brian Codianne
Regional Manager, Kubota MBR Systems
[email protected]
425-898-3888
1
The Focus
Operators
• Sticking with our customers
• Reconnect with those who have slipped away
Process
• Ensuring plants are consistent with current standards
• Improving plants that are below standards
Equipment
• Membrane Units
• Pumps and blowers
• Instrumentation
Controls
• Proactive Tools
2
Operators
Biological Process
Solids Handling
Design
Integration
Pre-Treatment &
Controls
MBR System
Plant Hydraulics Equipment
Selection
Operation
Aeration Systems &
Maintenance
4
4
To Ensure Proper Performance
• TMP / Permeability
• Air scour rate
• Permeate flow rate
• Process aeration requirements
• MLSS
• Filterability
• CSS testing
5
Process
6
Equipment Improvements
Larger Cartridge
Original Cartridge
15.61 Ft2/Cart
8.61 Ft2/Cart ʻLego Blockʼ
Module
108 Ft2/Mo
・Different models are available with various types of Membrane Cartridge and Module.
・ES-EK, with original 510 Membrane Cartridge is the long standing workhorse.
・RM-RW, with larger 515 Membrane Cartridge, same footprint, more capacity.
©2018 Kubota Corporation All Rights Reserved. 10
・SP, with ʻLego Blockʼ Membrane module, more compact, energy efficient, diffuser options.
When to Replace Your Membranes
• Damaged
– Identify root cause
• Age
– Forensic testing can determine strength and flow capacity
• Plant expansion
• Desire more efficient operation
• System turndown
– Handling more flow with fewer membranes leads to energy efficiency
• Other types of membranes not working as advertised
Controls
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13
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Improving the Performance and Increasing the Capacity of
Existing and Older MBR Systems
Small Plant
• 80,000 GPD MBR facility installed in 2011
• History of operational issues (2011 to 2015)
– Failure to meet hydraulic capacity
– Sludging
– Over flow events
– Short circuiting
• All of the above blamed on the membranes
• Owner wanted to fix operational issues and expand to a
capacity of 100,000 GPD
• Engineer wanted to replace with another type of membrane
Issues Form Perceptions
• Inability to meet hydraulic demand
• Sludging
• Over flows
• Short Circuiting
• “It’s the membranes”
Fundamental Issues
• Fine Screening
– Existing 2‐mm bar screen is inadequate
– Replace with a 2‐mm internally‐fed drum
• Hydraulics
– Uneven RAS returns
– Reconfigure the plant
• Permeate Pumps
– Issues with cavitation and air lock
– Replace pumps and reconfigure piping
• Control System
– Existing system uses unsupported, proprietary architecture
– Replace the control system
Construction
• Construction tasks
– Install new equipment including fine screens, permeate
pumps, and SMUs
– Reconfigure the plant hydraulics
– Change the control system
• And do all this while keeping the plant online
Existing Tank Layout
MBR 1 PA 1 PA 2 MBR 2
AX 1 AX 2 AX 3 EQ 1 EQ 2
AX EQ
Retrofit plan Proposed by KMU
• Retrofit ES to RM
• Split the plant MBR 1 PA 1 PA 2 MBR 2
AX1 AX2 EQ
Screen
Medium Sized Plant
• 2 MGD MBR facility installed in 2004
• History of operational issues
– Poor screening
– Sludging
– Frequent foaming events
– Limited instrumentation and control
– Permeate pumps cross connected across two tanks (upper
and lowers on separate pumps)
• Owner wanted to fix operational issues and prepare for future
expansion
SMU Upgrade
New Units
Old Units
SP-600
EK-400
6,459 ft2
3,444 ft2
surface area
surface area
88% more in
same footprint
Construction
• Construction tasks
– Install new fine screens and SMUs
– Reconfigure the plant hydraulics
• Changed permeate piping to one pump aligned to one tank
arrangement. More flexibility
– Change the control system
• Added air scour control and monitoring
• Added ability to rotate membrane basins as needed
• And do all this while keeping the plant online
Replacing Other Membrane Types
• Microfiltration membrane.
• Allows for higher sustained flux and mixed liquor concentrations.
• Virus removal testing has shown Kubota microfiltration membranes can achieve the log
removal rates at ultrafiltration membranes.
• Ease of use. Simple cleaning procedures.
• Weak chemical solutions injected inside the membranes via the permeate piping under
atmospheric pressure, so no pressurized back pulsing is required.
• Membranes and MLSS stay in the tank.
• Kubota membranes are rigid plates with fixed spacing.
• This provides an open flow path between membranes to minimize the accumulation of debris
or mixed liquor.
• Prevents membrane material that is adjacent to each other from sticking together, which is
common with hollow fiber and flexible sheets. The sticking together of membrane material
reduces the available surface area, which in turn reduces hydraulic capacity and requires more
frequent and intensive chemical cleaning procedures.
• Superior strength and durability with the use of chlorinated polyethylene as compared to PVDF.
• Membrane zones can be used as an active part of the biological process, and membrane air scour can
contribute to the process oxygen demand.
• This results in an overall smaller plant footprint and greater process flexibility.
And in Conclusion!
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Thank you
Brian Codianne
Regional Manager, Kubota MBR Systems
[email protected]
425-898-3888