SINGHANIA UNIVERSITY

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B. TECH-
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MATHIVIATICS

UNIT 1
Asymptotes, Curvature, Multiple point and Curve tracing

UNIT 2
Partial differentiation, Maxima and Minima

UNIT 3

Length of plane curve, Volumes and surface of solid of

revolution, Double and Triple integrals, Gamma and Beta
function

Unit 4

Differential equation of first order and first degree, Linear

differential equation with constant coefficients

Unit 5

Linear differential equation of second order

 SINGHANIA UNIVERSITY
diploma -1 sem I
MATHMATICS I
UNIT 1
Asymptotes, Curvature, Multiple point and Curve tracing

UNIT 2
Partial differentiation, Maxima and Minima

UNIT 3

Length of plane curve, Volumes and surface of solid of

revolution , Double and Triple integrals , Gamma and Beta
function

Unit 4

Differential equation of first order and first degree, Linear

differential equation with constant coefficients

Unit 5

Linear differential equation of second order

 (Contents J
Chapters Page No.

UNITS-I

1. Sphere 1.1 - 1.34

2. Cone 2.1 - 2.16

3. Cylinder 3.1 - 3.12

UNITS-II

4. Matrices 4.1 - 4.50

I UNITS-III

5. Vector Func~ions of a Real Variable, their Derivatives

and Scalar and Vector Fields 5.1 - 5.58
6. Integration of Vectors 6.1 - 6.36
7. Integral Theorems 7.1 7.54
UNITS-IV §l
8. Velocity and Acceleration 8.1 - 8.24
9. Rectilinear Motion in a Resisting Medium 9.1 - 9.24 fJ.X1
the
I UNITS-V
I §1.
10. Series Solutions of Second Order Linear
Differential Equations 10.1 - 10.34
11. Partial Differential Equations of First Order 11.1 - 1 J .43
0 Appendix-A AJ - A.06
0 Appendix-B B.l - B.l7
0 Model Question Papers-I, II 1 - 4

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CA31 01 Optimization
Optimization of functi9ns of _qne .and-. merw. variebl!=S with and_ without
constraints: -Kuhn-Tucker condi1:1ons; :gradient methods; /iii ear
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 BCA-103 MATHEMATICS

External Marks: 80
Internal Marks: 20
Time: 3 hours
Note: Examiner v.-111 be required to set NINE questions in all. Question Number 1 will consist of
roral 8 parts (short-answer cype questions) covering the encire syllabus and \\ill carry 16 marks. In
addition ro the compulsory question there will be four units i.e. Unit- I to Unit-IV. E"\am.iner u,'ill ser
two questions from each Unit of the syllabus and each guesrion will carry 16 marks. Smdent will be
required to attempt FIV't questions in all. Question Number 1 will be compulsory. In addition ro
compulsory question, student v..ill have to attempt four more questions selecting one question from
each Unit.
UNIT I
SETS: Sets, Subsets, Equal Sets Universal Sets, Finite and Infinite Sets, Operation on Sets,
Union, Intersection and Complements of Sets, Cartesian Product, Cardinality of Set, Simple
Applications.
DETERMINANTS: Definition, Minors, Cofactors, Properties of Detenninants, Applications
of determinants in finding area of triangle, Solving a system of linear equations.
MATRICES: Definition, Types of Matrices, Addition, Subtraction, Scalar Multiplication
and Multiplication of Matrices, Adjoint, Inverse, solving system of linear equation Cramer's
Rule.
UNIT II
RELATIONS Al'il) FlJNCTIONS: Properties of Relations, Equivalence Relation,
Partial Order Relation Function: Domain and Range, Onto, Into and One to One
Functions, Composite and lnverse Functions. ·
LIMITS & CONTINUITY: Limit at a Point, Properties of Limit, Computation of Limits of
Various Types of Functions, Continuity of a functior, at a Point, Continuity Over an Interval,
Sum, product and quotient of continuous functions, lntennediate Value Theorem. Type of
Discominuities.
UNIT Ill
DIFFERENTIATION: Derivative of a function, Derivatives of Sum, Differences, Product
& Quotient of functions, Derivatives of polynomial, trigonometric, exponential, logarithmic,
inverse trigonometric and implicit functions, Logarithmic Differentiatioh, Chain Rule and
differentiation by substitution.
UNIT IV
INTEGRATION: Indefinite Integrals, Methods of Integration by Substitution, By Parts,
Partial Fractions, Integration of Algebraic and Transcendental Functions, Reduction
Formulae for simple and Trigonometric FLmctions, Definite Integral as Limit of Sum,
Fundamental Theorem of Integral Calculus, Evaluation of definite integrals by substitution,
using properties of definite integral,

SUGGESTED READINGS
I. C.L.Liu: Elements of Discrete Mathematics, McGraw Hill.
2. Lipschutz, Seymour: Discrete Mathematics, Schaum's Series
3. Babu Ram: Discrete Mathematics, Vinayek Publishers, New Delhi.
4. Trembley, J.P & R. Manohar: Discrete Mathematical Structure with Application
to Computer Science, TMH.
S. Kenneth H. Rosen: Discrete Mathematics and its applications, TMH.
6. Doerr Alan & Levasseur Kenneth: Applied Discrete Structures for Computer
Science, Galgotia Pub. Pvt. Ltd.
7. Gersting: Mathematical Structure for Computer Science, WH Freeman &
Macmillan.
8. Hopcroft J.E, Ullman J.D.: Introduction to Automata theory, Languages and
Computation, Narosa Publishing House, New Delhi.
 "1,··-
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t~'· B.A./B.Sc. I -PAPER I

t...... .'.LGEBRA & TRIGONOMETRY

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b,·; ALGEBRA
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~ Section ~ I (3 Questions)
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~~~ Syrn.m.etric, Skew-symmetrices, Hermitian and Skew-Hermitian matrices. Elementary oper:.:r:ions O!:l

•ns on i9, :::ar.rices. Inverse of a matri-..:::. Linear independence of row and column matrices. Row rank, colunm rank
..,..,d r:mk of a matr.!x. Equivalence of colmnn and row ~-1J..!r.s. Eigenvalues. e.igen vectors and the characteristic

e· c
fi? equarion of a maL.--i.--..:::. Cayley Harni..iron theore....-n and its use .in finding inverse of a mat:ri.'r. Applications of
~-.~. =:2.-tticcs m a sys~e:-::l of li..'"le:t:: (bot..l::. homogene':)US and non-ho::nogene:::ms) egu.r~ti.cr::s. Theorems on ccr::.sis:ez.c;;-
Sg:· - - lin .
~ ::-~ a system ot ear equations.

It:. Section • II (2 Questions)

~ "Rdarior:s b~t'w·ecn the roots ~r::C cocffic.i.cnts of general polynomial equation m one: -;--az.i.ablc:.

iable.
~ .. ~-:1sformation of equations. Descarte's rule of signs. Solution of cubic equations (Ca:rdan method) and
~ -· 3-:quddiatic equation.; (Des carte's an.d Ferari ~,feillods).
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Section · III (3 Questions)
-&,: ~.1app.ings. Equivalence relations and partitions. Congruence moduio n.
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~ydic ii~-- Definition of a group with ex<Unples and simple properties. Subgroups. Generation of groups. Cyclic
;r::•.J.ps. Coset dccompo.sition. Lagrange's theorem and its consequences. Fermars and Euler's theorem.
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,rem.
o: of H-o.r:aomorplN.sm and Isomorphism. :Normal subgroups. Quotient groups. The fundamental theorem of
.:::Cr:::wmorphism. Permutation groups. Even and odd permutations. The alternating groups A 11• Cayley's
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~_:.. G:e:::rem. Introciucnon ro rings, Subrings, integral do:mains and fields. Characteristic of a ring.
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TRIGONOMETRY

~ Section - IV (2 Questions)
t- Del'vioivre's theorem and its applications. Direct and inverse circular and hyperbolic function-s .
.:..ogarithm of a complex quantity. Expansion of trigonometrica1 functions. Gregory's Series. SurnmzciD.u oi
~ene~.

Note: The examiner is requested to set ten questions in all selecting guesrions section wise as indicate;:! in. th-e.
JC
syll;.bus. The ca..-:;didate 1s ::<eqcired to .;::ttempr E>-;ce questions selecting atkast: one question from e.;t6
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section.
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I & I.
B.A.IRSc. I (Paper II)
CALCULUS AND ORDINARY DIFFERENTIAL EQUATIONS

Section I (2 Questions)
Successive differentiation. Leibnitz theorem. Maclaurin and Taylor series expansions.
Asymptotes. Curvature. Tests for concavity and convexity. Points of inflexion. Multiple points,
Tracing of curves in Cartesian and polar coordinates.
Section II (3 Questions)
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~. Reduction formulae. Quadrature. Rectification. Volumes and surfaces of solids of
revolution.--· -

Section III (3 Questions)

~ Exact ctifr€rential equations. First orde;·-hlgher degree equations solvable for x, y, p.
Clairaut's form and singular solutions. Geometrical meaning of a differential equation.
Orthogonal trajectories. Linear differenti5'r~quations with constant coefficients ....Homcgeneou$
linear ordiJ:¥~rY differential equations, Total differential equations. · ·
''· . -:·-
Section IV (2 Questions)
Linear differential equations of second order. Transformation- of the equation by chang-·
ing the ·dependent variable/the independent variable, reduction of order. Method of variation of
parameters and unknown coefficients. Ordinary simultaneous differential equations.
Note. The examiner is requested to set ten questions in all selecting questions sectionwise as
indicated in the syllabus. The candidate is ~equired t-o attempt five questions selecting at least one ques-
tion from each section.
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£ Vector Analysis ~ 'Til

f': S,e~on I ( 2 Questions)
-'!'::or t Scalar and vector product of three vectors. Product of four vectors. Reciprocal vectors. Vector
f~nnanon. Gradient, Divergence and Cud.
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£; -~n. Theorems of Gauss. Green, Stokes and problems based on these ~J
fl• Geometry
~Section Ill ( 3 Questions) · ·.·. ~i
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f; General equation of second degree. Tracing of conics. System of conics. Confocal conics. Polar
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f:;:~tion of a conic.
b· 5ection IV ( 3 Questions) J ··~
f General corucoids. Paraboloids. Plane Sections of Conicotds. Generating lines. Confocal Conicoirls.
t'' lkJoccion of Second Degree Equation. Sphere, Cone, Cylinder '

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in the syllabus. The candidate is required to attempt five questions selecting atleast one question
from each section.
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 B.A./B.Sc. PART II
PAPER I
BM 201A- ADVANCED CALCULUS

. Soction - I (3 Questions)

Definition of a sequence. Theorems on limits of sequences. Bounded and monotonic sequences.

'C"u·Chjr's convergence criterion: Sequential continuity. Properties of continuous functions. Uniform
...:ontinuity. Series of non-negative terms. Comparison tests. Cauchy's integral test Ratio tests. Raabe's,
bgatithmic, de Morgan and Bertrand's tests, Gauss t~st.Alternating series. Leibnitz's theorem...1\.bsolute
· m:i conditional convergence.

Mean:,alue theorems and their geometrical interpretations. Darbou.x's intermediate value theorem
.fur derivatives. Taylor's theorem with various forms of remainders. · -._ •
Limit and continuity of functions of two variables. Partialranfereotiarioo. Change <:>f.~blei,
'C!::cler's theorem on homogeneous fu?ctions. Taylor's theorem for fu;nctions of two v~~~es)~~~~~f.- ~--·
!\fa-, minima and saddle points of functions of two variables. Lagrange's multiplier iriei:&q'f~ ~:':• .
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;c~aitn: - III (2 Questions)

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Envelopes. Evolutes. Indeterminate forms.

- IV (2 Questions)
... ?;,ta and Gamma functions. Double and triple integrals. Dir:ichlets integrals. Change of order of
~~rna on in double integrals.

The e.'";:amine.r is requested to set ten questions in all selecting questions secrionwise as indicated
\ .,, in the syllabus. The candidate is required to attempt five questions selecting 3tleast one question
from each section.
 .B.A./JliS!', PAWL:II
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PAPER II- . -: "'::"i'.; . ''·-

Section- I (2 Questions) · . . . ··-·· . ;. • . .·. ;_ .

.Series solutions of differentiaiequations: Bessel, Legendre £~:!~method, 'f'id·f:i,~ge~tjjc
equat!On& Bessel,. Legendre and Hypergeometnc funcbons and thett properttes - ~onvergence, i:eCUJ'tence
and 'genei.ring:iioi!ariions Ottliogonolity c>f· Bessel functi:ot.J~ -ami L:egcm~:j'io'lj<h<i~ :'n":.::·<f ,;·( ··
-- 7... ~~-~-T·:~:c- -~(r; : --l:_1;:;·::;·_.;.;::; ~;···:_: :.: ·;,~, _~-:r:~i:•i..:~ :'1·.<:-;:a-::-t. -~i{J ·_:.:; ~~=~l:')tf~.:J;:i;.·:r,:~~;i;.:~~(t:" _,-~.:_3-·:u
Section- II.(~-r9:,uestions) _ . r.--·· -~·-;,.·- .,.-· ... ·.: ... :·~t-:·-.,) i·i;t:;.c·,.-J·D·;;: z:orx~JoH .;2-;:i.\ l··-8. ;o
J~~~ce l,';~n~;~.ti~n ,•-Litl~a;ri.IL<if:w~~Pla!'e.:~ansi~~~~~~r;k;!a;e·
cransfoo;ns.-Lap]JI~o:ansro.ms of derhtuiVe.-anafuti:gtijlfl.>S~~ifi6t"4"1!!"~~·- ..
oftramfunns:.•Coa<rolulionim.mem.:Sol1ltllion0lf. ,,._.;..,~·~de~- 7=-'-:' ~-
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of diffete~ti2-l:.equation_s. --+:::::.-~:'::. ,--.,.~;.-:_··;-:-·_;-;·:~ --~ :,,,-;, -.5; ..:Ji::.~/;~ · _,. ;- --'-,;.:.. ~----~~·-· ··....--- ~
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eguacions of secOD>i ordd•4~mnogerle~~§-ftt>ri'~<~Q~~ftg~~5f~~~~~~~tsi' .
J':u:nal dlfferential equanons reducible .•~~l>O<i& wt~.e.qnsrant:~oef§:~.,~;J3 >>'-''··•''". ,.,,.,.,..,,,,,!'''·' _
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Secti<)a,-I,Yr(2~s) .•.. ·•.-

• ··~rial Geometry - C~s with torsio,;; pru;cipal normal, osculating circle; bino$U, Sen:et
- Fre!lei:fu$j,ii!ire, M'&S~f centte.of curvatu.re, sp#ericai·~iifre, surfaces, enV<;lop~ edge of regreS,ion, , · .;
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fonttii/hd,'{Jl''inagnirudes of the first ordeL · "~
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Note: The examiner is requested to set ten questions fu·an-selec~g ciues.tions sect:iomvise--~s ~~~te·d-~irl:tb.e
•I

syllabus. The candidate is required to attempt five quesrioriS selecting atleast·one questiOOftom ~:i<=:b
section.

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ISYLLABUS I ~­
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B:t,
B.A./B.Sc. PART II ,.' .
PAPER III
BM 203A - MECHANICS
1. ,_•'.
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Section- I (3 Questions)
Conditions of equilibrium of Coplanar forces. Virtual work in two-dimensions. Proof of principle
of virtual work and its converse for coplanar forces. Forces which may be omitted in forming the
equation of virtual work.
Section - II (2 Que•tions)
Forces in three dimensions. Stable and unstable equilibrium.

Section - III (3 Questions)

Velocities and accelerations alpog radial_and trans..ve....-se_ directions, and alo?g tangential and normal
_Qirec~~~s.-Sitr>ple1u.r1Jlo11fc motion. Elastic strings. --- . ···
Motion on smooth and rough plane curves. M,Qtipn in_a_resisting medium. Motion of particles of
~~ngmass.

Section - IV (2 Questions)
S:entral Orbits. Kepler's laws of motion.
Motion of a particle in three dimensions. Acceleration in terms of different coordinate system$.

Note: The examiner is requested to set ten qu~stions in all selecting questions sectionv;>ise as indicated in the
syllabus. The candidate is required to attempt five questions selecting adeast one question from each
section.

----
 ... 1:1.sc. Part-Ill, Syllabus B.Sc. Part-Ill, Syllabus 15
(i) One major experiment 15 MarY..s Unit-Ill : Solution of Equations : Bisection, Secant, Regular falsi,· NewlOn's
(ii) 'Hvo minor experiments Method. Roots of Polynomials. Interpolation. Lagranges.and }!C"rmite interpolation,
- 20 Marks
(iii) Record of Practical Work Divider! Differences, Difference Schemes, Interpolation. Formu!ns using Differences.
7 Marl:i
"- (iv)Oralll:st (Viva-Voce) NtJmericnl Differentiation
8 Mart!>
~Paper I: Analysis · Unit-TV : Numerical Quadrature :-NeWton-Cote's Fo;mu/as Gauss Qiladra:urc,
Real-Analysis Formulas. Chebychev's Formulas. Linear equati_ons. Direct. methods of solving systems
~f linear equations (Gauss Elimination, LU decompo~ition, Cholesky Decorriposition)
Unit-1 : Riemann inrcgral, Integrability of cOntinuous and monotonic functions. i interactive Methot:ls (Jacobi, Gat,~ss Seidal, R<.~laXation Methods).
The fundamentcll theorem of int~gral calculus, mean value theoreni.s of integral '
calculus. Improper Integrals and their convergence,· Comparison tests, Abel's an~ Unit-V : Ordinary Differenti<'~l_ Equations. Euler mcthod.f Single-step methods,
Dirichlcr~s tests. FruUani's imegral. Integral as a function of a parameter. Ru"nge-lwtta's m.:!thods. Multi-aep methods, Milne·Simpson" method, MC:thods based
· Unit-11: Continuity, derivability and intergrability o( an integral of a function of a on numerical integration, ·MI.Ihods ~ased on Numerical differentiation, Boundary
parameter. Partial derivation and differentiability of real valued functions of two Value Problems, Eign value }lroblems.
variables. . ~i) Discrete MathematicS
C01nplex Analysis Unlt-1 :Sets and Proposition~-Cardinality, MathematiCal Inductions. Principle ot
Unit-lii : Complex numbers as ordered pairs. Geometric reprcscn~ution of lnclusi6n and excluslion. Computabitity and-... Formal . Languages~Ordercd · .se~s.
complex numbers. Stereographic projection. Cominuity and differentiability of corpplcx Languages. Phrase Structure Grammers. Types of Gr·arnmers and Umguages.
fuhctions. Analytic functions. Cauchy-Ricman equations. H~rmbnic functions. Unit-11 :·Pcrmu_fationS, Combin"arionS and disc;rcte pi-obability.
Metf.iC Spaces · Unit-in: Rel<ltions and f:unetions: Binary-relationst_Equiva\cnce H.e!ntions and
Unit-TV: Definition and example of mctr!c SPf!CCs. Neighbourhoods. Limit point, partitions. Partial order relations and tattices. Chains and AmichJins-Pigcon Hole.
interior points, open and closed set~ Closure and interior, 'Boundary points. Subsp~ce ·_ Principt.e.
of a metric space. Cauchy sequences, completeness. · Unit-IV : Graph and planr.r Graphs-Basic "Ierminology. Mulligraphs. Weighted
Unit-V: Continuous (t,mctions. Uniform conlinuity. Isomerry·and h·omomorphism, Graphs~ Paths and Circuits. Shortest paths. Eulirian Paths and Circuits. 1tavel!ing ·
Eguival~nt matrks. · · _salesmab problem. Planar Graphs.
~Paper H: Abstract Algebra . . U9lt-V : lloo\iean Algeb~as-Latticcs and Algebraic struclrucs. Duality.
Unft-I: Group-Automorphisms, inner automoq~hism, Automorphism groups and Distrit\l.ltive and complemented Lalliccs. Boolean Lauices and Boolean Algebras.
their computations. Conjugacy relations. Norma!iser, Counting Principle and the class · llooleah · Functions. and l?.xpre:Ssions;. Propositional calculus. Design and
equation of finite group. Center for g:oup of prime order. lmplcn_)cntation of Digital Networks-SwitChing Circuits.
Unit-IJ : Normal Subgroups. Quotient groups. The fundamenral ..th.corcm o( .\ (iii) DHTerential Geometry nnd Terisor Caiculus
homomorphism, Permutation groups. Even and odd·permutarions. Cayley's theorem. Unit~~ : Local Theory of Curvcs~Spacc curves. Examples. Planer curves. elices.
Unit-III : Ring theory-Ring homomorph-ism, Ideals arid Quotient-Rings ... Serret-F~~nct apparatUs. Exis_t_ence of space curVes. InVolutes' and evolutCs of curves.
Euclidean rings. Plynomial firigs. Polynomi~ls over' the Rational field, Definition and Local Theory of Surfaces-Pan~metric patches on surface. First Fundamental form and
cxamptes of vector spaces. Subspaces. Sum ~nd direct sum ofsubspaccs. Ljnear. span arc length. Normal Curvature. ·
Linear dependance, [ndependance and their basic prqpcrlies. . U~I~·II: a·eodesic Curvature and Gauss formi.Jta, Shape operator Lp of a surface
at a poi_QL- Vector field along a cuJ_"V~. Second a_nd third fundamentl:ll forms of a surface.
UnH-IV : Basis, finite dimensional vector spaceS: Existence t_heorem for bases.
Invariance of the number of clements of a basis set. Dimension, Existence ·of
t Weierig~rten ~ap. Principal curVatures .0-aUssian· Curv~ture. Mean and normat
complementary_subspace of a subspace of-finite dimc;nsional vector space. J?imension · f curvatures.
of sums of subspaces. Quotient space and its dim~nsion. Linear transformations and Urii~~III: Global the<!lry of surfaces-Geddesic Coordinate pathccs. Gauss-Bonner
their representation as matrices. 'f'!le Algebra of linear t~an.Sformaiions. The rank a
fOrmU:Iae. Euter characteristic of surface:.
nullity theorem. u~·lt~IV : Elements of general Riemannian Geometry-Concepts of manifolds and
Unit-V: Inner product spaces'-Cauchy Schwarz inequality. Orthogqna! vectors, examp!~s. Riemannian metric. "Thnsor fields. Covarient· diffcrentialion Syrilmctry--
OrthogOnal Complements. Orthonormal sets and -bases, Hessel's inequality for P!lite properti~s of curvature tensor. ·
dil'nef!sional spaces. _Gramschmidt orthogonalization process. Unit-V: ('..oncepts of affine connc:.:tion. Christoffel symbols. Curvature and Thrtion
Paper HI: Any one of the folliJwing· papers tensors.': Riemannian metric. and afftine connection Geodesic and norm'a! coordinates,
(i) Programming inC and Numerical Analysis rund,fJm6nt.ai Theorem of Riemannian Geometry.
Unit-1: Programmer's model of a computer. Algorithms. Flow ch3rts. Data" types. i (iv} Probability T.heory and Optitftiz:ition
I
Arithmetic 8nd input/output instructions. Decisions Control structu_rcs. Decision l-.robahility Theory:

I
statements. Logical ami Conditional operators. Loop case control structures. Uuit-1 : Notion of probability : Random experiment,_ ~mpiC space, axiom of
· Unit-II :. Functions. Recursions·, PreprocesorS. Arrays. Puppcting · Ot strings. probability, elementary prQperties of probability, ._e:qually likely outcome proble.ms.
Structures pointers. flie formatting. Handom variable~; : '"Concept, cumulative distribution functiOn, discrcate a.n~
 M.A./.!\l.Sc.(.Pre,·ious) lVf'athcmntics E xa rn inalion

Sthernt~ of E.xamiu:.tr.inn : Annua~ Sthemc~

Note: l)upc1·s I to V tlt'l' t'rlmpul:-;ory·

Pap('t·- .1: /\dvnncc<l Ab-stn)C.t Algchn1

'';"cachi;1g ~ {) HtHU'S p~r \\-1.'.\.'-k

Examination: CfHnmou fm Rt');1lll:~r!i\otH:oUcgi~t1f' C;uuhd:ttt\"

3 Hrs. dur:1tiou

Noit•:

Thi~ r:Jt't'l'
is divided lnw FiVE Unit~. TWO que,<;! ions '1.\"ili h~ SCi from ta-.h Unii.
c~ndiJ.:ncsare required lo anempt FiVE qu{"SfiO!lS in all .laking ONE questinn frcm cad1
-Unit AH·questions CIU'T")-' e_qual marks.

Direct product of group:-: {E:-:-:emal nnd Jnt<"mn\). fso:norphism iht'·('rcm:>- D!:w1c•nd

i.~O:UOJ}"I!lbm theort:m, HutleTl1y LC'l1llll:t, Conjugate dasscs {E.':duding r·;.:~OU)JS.}.
C•)mmutawrs., Derived suhg,wu_ps. Nmmal :-;erics ;mrl Solt·ab!e group-s. Composi:.i.:.;:t
scrks. ReJim?Jnt.nt rhcan:m and .lordan-Hold-.:r ~h~tJn:m f0r !nitniit' gn~ups.

liuit2:

Eu:jide.m:rings. 'Moduks. Subm\Jciuks._ Qu<llic::n module~ Dirc:cl !>Ums und lvlodu!e

Hummno-rphism.s, Genel"ation qfmt)dwles. Cyclic nHY.:hlie..<:. Linc::.:.r tr.msinrmarim: of
\'CdN space-s. Dual spaces. l.'!u~d ha~is and Otcir proper:ies. Dwll mar,'). Am;il:ila!OL

F.idC thoory- E:-.:lcnsion Jk-ids.. A1g:t::bmlc and Transt:cmknial -C\!Gn$ions. gt:pnr<~t:k <mJ
ins""P~rnble e.;:tt".n:::ions. 1\1 mm~! e-Y.tensi{lns. Splilling fidrlt-. Ci-<Jl!)l!< ·111cory .. -Uv.:: dcrncnt·c
,,f G,aloi~•-th::-,ory. A_uwnwrphi<:0.1 of eK\cn:-.ion.s. Fund<:ment:\i 1hc-orem of Gu!ni;;; ;ht:nry.
:;;olutioo.s o[ polynomial equ<JtJons by radicals rmd ln;;olv<~bili1y nf t;ent.~ral equa\i1m o!'
dtpet· five by radical:-..

~-~~-~-·----------------------------
Unit 4:

Mmric.-e~ of a lincnr maps. :Odarricc~ oftornp(}sltiml n1aps. Matric.e~ ofdualmnp, Eiget>

\'illucs. Eigen \'(.".('.ll)rs. RanJ.·. and l>1ullity of linear mnrs •md m:llriccs. Jm'tTlib!c m::ltric.es~
Similar matrices, .Dctcrminams of m<~.trices and it$ compuwtions. Characleristic
polynomial and eigen t•alucs. ·

Unit 5:

Rt".Jl inner pmducl-spt~ce, Scbwarizs inequality. Orthogonality. Bessel's ·inequality.

Adjoint. Self adjoint linear U1:1nsfonnat.i(lhS and matrice.s, OU10gonal linear transfurmati:m1
1md ma:Irices. Principal Axis Theorem.

Pupe.r ~ fl: Real Analysis and Topology

Teaching: 6 Hour!' pc1· Week

EX11miuathm; Cmnrnon for Rcgnhn·/Non-colle~iai"C Candidalc~

3 Hrs. durnlion Mnx. Marks J 0(1

i\nte :

ll;is p:1per is divitled into-FIVE Units. TWO qucstinn.s tvill be scr from each Unit.
CandidAtes arc required 10 attempt Ff·'\'"£ questions in a·u tnking O)'JE question from e<tc!J
U;'i:.. AJI question~ carr.v equ3.1 marks.

fJnil I:

gcnc~ted by :1 c:lass of ~;ulJ.<;el~. Horel sets.

/I.Jgcbrn and algebras of sets. Algebras
Lebcsgut" measure of sen; of real numbers. Mcasurahility and Mca:-urc of<! sc.t Existenc-e
ofNon-mcasurablc sets... Mt:as:umbk fuJlCtions. l~ca.'!i~:flti(ln of Hfl11·ncgativ..~ mcnsur.~hle.
ftmdion as limit of an inc-rc:-t.<>ir.g sequence -of simpk functions, St111c1ure of mc.:~surablc
functions. Convergen;;r in JneJtsure. Egoroffs theorem.

Unif 2:
9/c:icrstras:;'g theorem Gn the ::~ppmxlmatirm ~Jf continuou!> functi0n by poly.rw:ni:.l.is.
L::hesg.ue in1Cf:,'T~i ofbotmded mcr~slmJh1e func-tions. Lche.sgu::- theorem on flu: pa:-;.->,1&~~ 1.;~
the timit under the .integral sign for bounzkd mzasurable func{i;_l\lS. Summahk fun~::~~m:r-.
Space of square surnmnb.!c funclions. Fourier ~.!ric-!' :md cocftk.ic-11\.s, Par.scvaf't: id:!JJj;;y,
Rie...,,:-Fi:;her T'heorc.m.

Uni1 :\;

1-r--hc~:,·;;lJc int•!{~':'~~J.it;;.• !-'r; ·nt,,t::lhini's ~lv:nrerr.. L:--tp<c~~t--s. i·rnldt:r~Minkowski incqualitie: .

Cvrnp;ctencss of U'-:<paces. Topt)loglcnl spacCs, Subspares. Oper, sets._ Clt>scci scl".
Neighbourhood system, R:se~: and suh-hnscs.

Cnit 4:

CN1tinuous mappine:. and Hol!'!t'O!llOrphism, Nets., Fi!~ers. Scpar:11ion axio:!l5 (1'<'. Tr. T::.
T_:. T 4 ), Product nnd Quotlem :;:pat".c.".

Unit 5:

Cnmpact anrllocaHy cnmpac1 spax~"- 7 ychonn-ff~ nne point' compaciification. Connct-lcd

and l..oc:lily connected spaces, Continulty and Cl)nnech.dn.ess and Compactness.

P:1pcr- J'f-1: HjffcreutiaJ £qu:lHons

T caC'hing ~ () Jlouno pr.r Wed;. 1l

Exa:nina1lnn: Comnwn f,>r HcguJ:tr!Non-c:oUe-giatt~ 0Hldid<th\"

3 Urs. tlurntion The.ory J 1 ~pc.r

Nol\":

This pr>;··t.~r is divide-..1 intn FI~·-'E 1 ;nil:-;. T\VO (!!lCstion'" .,.,.; l\ he sc< .fr0m c;Kh Unii.
c~ndid:::HC.S are require-d 1{,' UHl"-mpt F!VE quesllom in aU \~klng O'KE qJ..t(!!'<i<m fn•J'l: eac-h
L'nit. /\11 quest10ns t:.<Jrry C"qu~il m.:u-ks.
 NonMline<rr ordiJJary different i:1! equations of particular fom1s. Riccnti's equation ·Grncnll
SQlution and the sDiutiOil whe11 one. twp-or three p."L'1icub: solutions urc k:n0wr.. Total
Di1Tcrcntial equalion::;. Pan in/ differential equati~:.•n:; ofsccrtnd o:·dcnvith valiohlc c.o·
cfiidcni._c:- Monge's l!lethQd.

Uuil 2:

Clr1:<~~ifjcaiirm flflinear p.:!rtinl dilferc.iJ\i.'ll equation pfscc()nd ord~·r. C.1.ud1;<~ prohkm.

Me: hod ofscparaiino of vo;·\ablcs. l..aplr:!ce. Wa<'t:.TlJti {iiffu~:~ion e-quation->. Ca;lOilh::.J!
fon11.~. Linear homoge-neous b~mndury \'<J)u~: problems. Eigcn values and eigtn funditm:>.
S!rum-Lim:vilk·- h(rundm·y va!t1c problc:ms. Orthogonality of cigcn fun('ti(•ns. Reality of
eig_en values.

·unil 3:

Calculus of variation . Functionals, \' ari:ruicm of a fimctiona! nnd iL'- properties.

VnriaUon::t.! p:-vblcm~ with fn:t:d boundari-e~, Euler"!>- cgwuion. E~:·trcmals. hmdicnal
d::pcndcll! on scvcml unktl(!\.._.IJ function~ and their -fin:1 ordc:r dcrivntivt·.s, Ptlll~-tio-nals
dC'.pcndclll on higher order -tbrivntives. -Fwicciomils d~pendcn1 on the function of marl'
liHm one-independent \-;uiahlc-. V:.triational problems in pnrmm:::.tri(~ fonn. Series solution
of a second ordc:- Jjncar diffe.rcn!inl equation ncar u regnhJrisin&-rul~r rx1lni C\1t:i1wd of
Frobe-niu:c:) with special reference W Gnuss hypergeorndric·cquation and Lcgcndn:'s
r:quruion.

linir 4:

Gauss h~·pcrgc:-omt:i.ri<· fnn:;t;tm <md ils Jlrf:lf'"'..:J1ie!". lnl!?tzml n~prcscnl;.~tion. Un~ar

transfnnnation fonnuias, Coni1gUous: funrlioa relations. Diffcrr.ntiation formulae, Lille:lr
rebtion betwee-,n the solutions of Gaus.." hypt·rgoo:netric equntion. Kummer'~ confluent
h.'-fX"t£'X'll1Ctric functinn and i1s pr0perties. Jmegrni ;epresenr::~tion. K llnmJer':-.: i1rsi
;:mn.~fomrmion. J..egendrc ruhn(.lmia!!' and .functlotls P11(:x"J and Q 1,(x).

Unir5:

Bessel tUncti0n.<; Jt,(x), Hcm1i1e polynomials HnCx1. L.1guerre nnd Associ:Jted Laguerre
pol~·nnmiDis,

J 1 aJ>t~!·- IV: l)iflf>.renrial Gt•(Hlldry

m~---------------------------------------------------------
 Teaching:(, Hours per Wt-.cf;
Examinntion : Cummon fnr J{t..,!:U1ar/Nrm~.r<!llq~i;l'1l' Cundirlaie~

3 Hrs. duration M:n:. Mark" 100

h'otc:

This pap~r-is div-idd itno FIVE Units. T\liO qucs!ions wifl be set from e-ach Unit
Crutdidates are reqt1ircd tu attempt FIVE qlJeslions ir: a!l raking O~}j qucSlion frrm-: e:-J.cl'i
UniL ldl qucsliom cnrry ti:'-l.}ual murk;;;_

lJnH 1;

Thteory of {".urvc-s- Space cur~·cs. Tangetl.ei. c(lfllar"l·of-ctlrYC and. surface. Oswlaiir.g.

p-lane, Priril.:-ipal Jlonnal rmd BinorrmiL Cun·atun:. Torsion, St.'t"re!-Fre-n~t's fonnula.-.
Gsc.ulaiing_ circle and Osculating_spherc. Existence and Uniquenss theorems, Bcrtrr.:1td
2.11rn;•s, Involute, Evo-lu(cs.Conoids, 1nficxion::~1 t&'1£.C"llls. Singular point~.hldicalr~~:

f:swe:'lop, Edge of regression. Ruk-d :>urfac..e. Dc"elopabtc surfa<;e, T.u1.gent plane tn a

rule-d surfnce .. :Nece.•,sary and sufflcit~nt conditioa tha1·a surfwx~ ~=f OshouJd repn.:sern a
devdopable ::urface. Metric or-a su:Jace~Fi~-t!'>e~.:ond and third fundamc.nta!
fmm.•:;.fundamelital mag_nitud~ of some important snrfit-::es. (),ihog-onf!l rmje-ciorie.s.
normal c-urvmure. Meunier;~ ihcorc:m •.
Unit 3:

t'ricipa! direction$ and Principal curvature:s. Fit"$1 cmvmure. !\·le-an curvmure. G~\J~inn
curvature. UmhiHQO. P...:-1diu;; of c-urv<:~rure of W\"\i normal seciinr. m <111 wuh-di..:: on z "-
f[x.y). Radius of etlr'-'ature of a g)-veil-section ti1rough any poim en z."" ft:-.:.y). Lines{'{
curvature, Pr-incipal radii. Helation !){';\ween fundamentai fOrm$. /...symptolic lines.
Diffhcnilal equatinn of an a:;ymploiic "iiuc.-Curvah:rr and "TO:·sion of an asymptmic: lint":.
Geodesics. DiffcrelJ!ial c-.qua\lon of l.l geod•:sic, Sjn;;ic differt-Jlli:1! equation nfa gewle-&ic.
Gcode;;:c on<~ sur!ace of revolution, G~l):.icsk Cun·s.l\lft'. a."ld Torsion. fhws-s~Honw:~
ThC-(lX!Tj.

Vnit 4:

•
 Gauss's formulae. G.nJss's characledstic cquntic.'n, Weingarten equations. Mainnrdi·
o--.dav..i eqn::Jtions. Fundnnicnt::1l ('Xist..~ce tiicmcm for Sllrf:}GC.S. Parallel sur.fllt.X:'$".
Oaul';sia..:l tilld mean r.urwl!Ur'C' for<\ pm-.-dk!l surface, Bonm·f'.s the-.or:.'!rn on parallel
surfaces.
Tensor Analysis-- Kront·~.:ker delia. C.111travarinni and Covarimn tensors. ~:ymmcttic
tensors, QuCl1iel11 law of tc.rl~>Pn>. Rclati-\'e. tcnsoc 'Riemannian space. J\1etri('_ tcnsN.
Jndic.ator. Pennutation symhoJ:.; and Permutation tensors.

Unit 5:

Christo-ffel Fymbols and th-:!ir p1opt:nics. CoYm1nnt di/Tcnmtiation of ft.:ns:rrs. Ricci's

!.llcorc-rn. lnuinsic- dcrh'ati\'C. (lc:r!de:;ics. Differentiai cmmtion -of zcodesic. Gcodr.!lic
coordi;talcs, Field of pa.r.<~!lc! \'CCIQiS, Reimann·Christo.fitJ tensor--and iu propcnics.
Co\'ariant Cl,Jr\-'Uturc lcrL<~or, Einstein space. Bia-nc-hi'!' .identity. Einstci:11ensor. Flat~·
spacr. Isotropic poinL Schur':; theon.·-nL

V·.tpc:r- V: M<·dtanic~

'fl';H'.hing: 6 Houl's pc1· Week

Ex~mliuation ; Common for Rc-gular-J~on-cQIIcginie Candidates

Nntt':

This paper ls divided int0 FIVE UniL<;. TV/0 qu<~stio.us will be sc: from e:nch Uni1.
Candida.1es:-nre rcquiied ln <Jt!cmp! FIVE que-stions in aJ! ulklng ONE qucsl.inn from cnch
Unil. AH questions carry <"qual marks..

IJnil I:

D'Aiembert's principle. The gcnc.mJ equations or motion of a rigid body. Motion of c.cntrc-
ofioertia and motion relative to centre of inertia. t>.·lotion ahQui a fixed axis. llle
Cflmpound pendulum, Centre. of pe:rcu~sion. Motion of a rigid ll0dy in t\'-'0 dimt·.nsiom
under finite and impulsive f(·lrccs.

Unit 2:

./
 MoliN\ in thre<> di1m·:r:::i:m::- ~'-'ith t'l:'fet'~';tKt' 10 FAdc;-'s Cy!i~r:n_\~:\ and g"'"u:ne~··k·;;
\:qWJ:ti(}n;;., !v1o;in~1 'J!idc: >10 i ,;-:_'1.":':. Nbtior, umir:-;- intpuL"--1·,-~ f1)nx·~- Cc•;:~t:rv~:kn ,..
'-''StJentunJ (JinC;l; :;c1d ar!gL:b:·:1 ~tllG e;1e-rg:· fn:- i"':r<itr~ <18 wcl! ;!~ imjwbiv.~ ffwc~_-s

Unil ~:

Lng~~:lgc\ equation:; i(x ht>li):J{}J1liWS dynamic-al system, Energy C(jlWliO:l ro:·

COJJSt:rvll!ih;
1
fitld. Sm<dl {'::=~:illatwns, MotionLmdcr inuuisJve fO:ces. \-1otio:J ,-;fJ lop.
.-ktmifl<Jl;';:> Gq•mticm;, (l"!" ;:;,,-to!\ (";ftr:lS!'::Y::i.i{;;~ a;'::•~·::·gy. -jJ;.Unifton·s prl;it:i[>it: F!Dd
;.cincit•lt oflc&'i: acilun.

[nlt 4:

Kitll.'.nl.<~:-it:> ofidt>.uf tluid. [Jtgr<mt~e's and -Et:k:: 's m~~hods. Equatbu 0fC"<I!liJHlity !!1:
C:tmcsian. cylindrical -anr1 sph~ricd! polurcotlr-din:nes. R-ot:.'1dary :;~:d1v~~', Str~nai·htcs-<
rath-linD; and :<;!rc.a.m Iln0J, \'t'i·"K:ir~'"J'0!e~lfi;d irr0;cHi0::~aJ :nr::-icn

l)uii $:

Euk~r'~ l;ydro~yn:1ro:li.-: cgn:nio""- Bc;r!ou:Ji's th':.D:·ern. Helmi-Hlil?.: eql!::nin:l"'- C:md:.'/;:

ink-g.ruL Motlq, due ~v i ..,lpuisive :r-~r.:-es. i,1n~ion in twn-dimt"J~inm:. S~.r;_:.:Jm fimctb::
t',_,:·npi!".·; norc.::nni. ~-"U>('C:.:·· 5Cirrt:~'- D:;ubk-~5. ~" \''io ,;;;>:l:e:!
•
MAT 401: Functional Analysis II and Advanced Calculus

Unit- l

Adjoint of an operator on a Hilbert space. Self-adjoint, Positive, Normal and Unitary operators and
their. propertics.Projection on a Hilbert space. Invariance. Reducibility. Orthogonal projections.

Unit-2

Derivatives of a continuous map from an .open subset of Banach space to a Banach space. Rules of
derivation. Derivative of a composite, Directional derivative. Mean value theorem and its
applications.

Unit- 3

Partial derivatives and Jacobian Matrix. Continuously differentiable maps. Higher ~erivatives.

Taylor's formula.

Unit- 4

fnverse function theorem. Implicit function theorem. Step function, Regulated function, primitives
and integrals. Differentiation under the integral sign. Riemann integral of function of real variable

with values In norrned linear space.

 PAPE~-2-

!7~ 74?23
fm;G-;J

Unit -I

Viscosity , Analysis of stress and rate of strain, Stoke's law of friction, Thermal conductivity and
generalized law of heat conduction, Equations of state and continuity , Navier- Stokes equations of
motion.

Vnit-2

Vorticity and circulation, Dynamical similarity, Inspection and dimensional analysis, Buckingham
theorem and its application, Non-dimensional parameters and their physical importance : Reynolds
number, Froude number, Mach number, Prandtl number, Eckart number, Grashoff number,
Brinkmann number, Non- dimensional coefficients : Lift and drag coefficients, Skin friction , Nusselt
number, Recovery factor.

Vnit-3

Exact solutions of Navier - Stokes equations, Velocity distribution for plane couette flow, Plane
Poiseuille flow, Generalized plane Couette flow, Hagen- Poiseuille flow, Flow in rubes of uniform
cross-sections.

Unit- 4

Flow betv.reen tv.ro concentric rotating cylinders. Stagnation point flows : Hiemenz flow, Homann
flow. Flow due to a rotating disc.
 fM£1{,.- 3
MAT COl: Mathematical Programming -I
Unit -1

Separating and supporting hyperplane theorems. Revised simplex method to solve Unear
Programming problems, Bounded variable problems.

Unit -2

Integer programming: Gomory's algorithm for all and mixed integer programming problems, Branch
and Bound algorithm; Goal programming: Graphical goal arrainment method, Simplex method for
GPP.

Unit- 3

Separable programming: Piece-wise Linear approximations to non-linear functions, Reduction to

separable programming problem to l.p.p., separable programming algorithm, fractional programming:
computational procedure.

Unit- 4

Dynamic programming: Introduction, Bellman principle of optimality, solution of problems with

finite number stages, solution ofl.p.p. by dynamic programming.

~ - • 'T' rn-
 MAT EOl: Integral Transforms
Unit -1

Fourier transform - Defiition and properties of Fourier sine, cosine and complex transforms.
Convolution theorem. Inversion theorems. Fourier transform of derivatives.

Unit- 2

Mellin transform- Definition and elementary properties. Mellin transforms of derivatives and
integrals. Inversion theorem. Convolution theorem.

Unit- 3

Laplace transform- Definition and its properties. Rules of manipulation. Laplace transform of
derivatives and integrals. Properties of inverse Laplace transform. Convolution theorem.

Unit- 4

Complex inversion formula. Infinite Hankel transform- Definition and elementary properties. Hankel
transform of derivatives. Inversion theorem. Parse val Theorem.

MAT E02: Integral Equations

Unit -1

Linear integral equations- Definition and classification. Conversion of initiaJ and boundary value
problems to an integral equation. Eigen values and Eigen functions. Solution of homogeneous and
genera! Fredholm integral equations of second kind with separable kernels.

Unit- 2

Solution of F dh 1 d
re om an Volterra integral equations of second kind by m th ~- f .
SUb ftu( d e 0~ 0 SUCCeSSIVe
s I wns an successive approximations. Resolvent kernel and its results.
Conditions of unifonn
convergence and uniqueness of series solution.

Unit- 3

Integral equations with s t · k

ymme nc ern~ 1s- Orthogonal system of funct" · F d .
f . . 10ns. un amental properties
o eJgen_values and eJgen functions for symmetric kernels. Expansion in eigenfunctions and bilinear
f~nn. Hilbert-Schmidt theorem. Solution of Fredholm integral equations of s~cond kind b .
Htlbert~Schmidt theorem. Y us1ng

Unit- 4

Solution of V It ·
o erra mtegral equations of second kind with convolution
type kernels by Laplace
transform. Solution of singular integral equations by Fourier transfoml.

Classical Fredholm theory- Fredholm theorems.

Solution of Fredholm integral equation of second
kind by using Fredholm first theorem.
 34

MAT Jill: Numerical Analysis- I

Unit- I

Iterative methods- Theory of iteration method, Acceleration of the convergence, Chebyshev method,
Muler's method, Methods for multiple and complex roots.

Unit- 2

Newton-Raphson method for simultaneous equations, Convergence of iteration process in the case of
several unknowns. Solution of polynomial equations- Polynomial equation, Real and complex roots,
Synthetic division, the Birge-Vi eta, Bairstow and Graeffe's root squaring method.

Unit- 3

System of simultaneous Equations (Linear)- Direct method, Method of determinant, Gauss-Jordan,

LU-Factorizations-Doolitte's, Crout's and Cholesky's. Partition method. Relaxation methods.

Unit- 4

Eigenvalue problems- Basic properties of eigenvalues and eigen vector, Power methods, Method for
finding all eigenvalues of a matrix. Jacobi, Givens' and Rutishauser method. Complex eigenvalues.
 Singhania University
M.Phil (Mathematics)

Svllabus & Examination Rule

Paper Course 1 Max. Mark · Min.llfarks Times j

Code I
i -'
\ MPH Research Methodology 100 40 3hrs.
'' 801
MPH Generalized Hypergeometic IO~t' 40 3hrs. i
~- 802 Function & Fractional C.alculus I
MPH Relativistic Cosmology&- -JoO - 40 Jhrs. I
I
803 Differential Forms. L ____ ___--:-=----+-=:---1'
~~ Opernti on Research I' I 00 : 40 3hrs.
I
I
f--MP~~H;-+----~Dissertation 100 I 40 - '
i

805 I I ···--''
;

Note:-

L A student is required-to score 50 per cent marks in aggregate in order to pass the
themy examination. Pass mars in the 1ndividual course is 40 per cent as explained
above.
2. Thus, there will be 400 marks for theory examination of which a candidate is
required to score minimum of 200 marks in order to pass the theory examination.
3. Candidate has to opt any three paper.
4. In addition to the three paper, each candidate has to submit a dissertation (based
upon the papers ·opted by the candidates in M. Sc./ M.Phil. Course equal to a paper
earring !00 marks)
5. There will be eight question in each theory paper. Two question will be set from
each unit candidates are required to attempt five question in all taking one question
from each unit. All question carry equal marie

,,
/ Maximum Marks:IOO
Paper-! RESEARCH MATHODOLOGY
Time Allowed: 3Hrs.

Unit-1

Introduction: Concept.of research and its appliC3t.ion. Survey of literature Process of

research: Steps involved in research process, various methods of research design.

Unit-11

Data collection through experimental techniques and theoretical calculations. Types of data
and various methods of data collection and compilation.

Unit-Ill

Analysis and interpretation of data obtained: coding, editing and tabulation of data various
kinds of charts and diagnims use in data analysis. Application of statistical techniques for
analy;cing the data. Application of analysis -of variance (ANOVA). Uses of data analysis
tools like SPSS and Excel.

Unit-JV

]'reparation of Dissertation: Types and layout of research, precautions in preparing the

research Dissertations. Bibliography and annexure discussion of results, Drawing conclusion.
Giving suggestions and Recommendations to the concemed persons.
 Maximum Marks:l 00 Time Allowed:
31-lrs.

Unit-.1

Generali:a:d hypergeometric function- Definition, Convergence of the series for pFq,

Differential equation and its solution. Contiguous function relations. Saalschutz's theorem.
Whipple's theorem. Dixon's TI1corcm. Contour integral representation forpfq,. Eulerian
type involving pfq,. Integrdi representation for pFq,.

Unit-U

Meijer's G-function-Definition, Elementary properties. Multiplication formulas. Derivatives

Recurrence relations. Mellin and Laplace transforms oftl>e G-function.

Unit-HI

H-function of one variable-Definition. Identities. Special cases. Differentiation funnulas.

Recurrence and contiguous function relations. Finite and infinite series. Fourier sedcs for
the H-.ftmction. Simple finite and infinite integrals involving the H-function.

Unit-IV

Fractional Calculus -Definition and elementary prope1ties of Riemann- Liouville

fractional integrals and derivatives. Derivatives of the fractional integral and the fractional
integral of derivatives. Leibniz's formula for fractional integral and fractional derivatives.
Law of exponents. Images of elementary and generalized hypergometric function under
fractional integrals and derivatives.
/ Paper-III Relativistic Cosmology and Differential forms

Maximum Marks:! 00 Time Allowed: 3 Hrs.

Unit-!

Lie derivative of a Tensor field~ Scalar function, Contravariant and covariant vectors,

Covariant tensor of rd!lk two, Symmetry and killing equations, Integrability of killing
equation, Geodesic deviatio~ ConfonnaJ cun,ature tensor, its properties, Algebraic
classification ,;f conformal curvature tensor.

Unit-II

Basic equations of isotropic cosmo1ogy~ singularity and Singularities in isotropic models,

Red shift in non- static fonn of de-sitter universe, Einstein-space, Cosmological principal,
Godel universe and it properties.

Unit-III

Non-static cosmological models, Robertson- Walker model and its derivation and
Geometrical properties, Frcdmrum- Robert.<OJl- Walker model and its scale factor, Tbrcc
different forms of scale fnctor, Doppler effect in Robertson- walker model, Horizons (Event
and Particle), Big Bang Theory, Steady steady state theory.

Unit- IV

Brans- Dicke theory as an alternative theory of gravitation, Derivation of its field equation
and solution based on Brans- Dicke Theory. Differential forms: Exterior differentiation,
Connection 1-from. Ricci Rotation coefficients, Cartan's equation of structure, Calculation
of Riemann Cmvature Tensor using Differential forms, Curvature 2 from for Vaidya metric.

- - - - - -- -- ---------
 Papcr-IV: Operation Research

Maximum Marks:JOO Time Allowed :3 Hrs.

Unit-I

Transportation Models- Mathematical fonnulation, Initial basic feasible solution, Initial

basic feasible solution, Optimality test, Transportation algorithm for minimization problem,
Degeneracy in transportation problems, Unbalanced transportation problem.

Integer Linear Programming:- Definition, Gomory's cutting plane mcthed, Branch and
Bound method, Application ofintegt-r progrdJJlming

Unit-II
Theory of Games- Basic defmitions, Saddle point' Optimal stmtcgies and the value of
game. Fundamental theorem of game theory. 2x2 games without saddle point. Graphical
mcbod for 2xn and mx2 games. Dynamic Programming models -Definition, Bellman's
principle of optimaliry, Minimum path problem, Single additive constrain~

MuHiplicatively and additively separable return, sin_glc muWplicative constraint,

Additively separable return, System involving more than one constraint. Application in
production, inventory control, Linear programming and reliability.

Unit-ill

Inventory Models- Definition, elemen~1ry inventory models e.g. EOQ model without and
with shortages and EOQ with constraints.

Replacement and Reliability Models- Replacement of items that deteriorate,

Replacement of items that fail completely and other replacement problems.

Unit-IV

Queuing Theory- Definition, Queuing system. Arrival. Distribution theorem,

Dislribution of departures, P-robabilistic queuing- models 1 to IX; Mixed queuing models-

Model X; Deterministic queuing model- Xl.
 ENCINf.ERING CHE!VJ!STRY-J
......... 1
['106]

Clas.s s:·~fech. 1 Semester

51
Evaluation .
Schedule per week
-------
Examination Time - Three (3) Hour~;
Lectures 2 / Maxrrnum 1,1a·ks = 100
Tutorial _l ___________ i_[Mrd-rerrn (!0'• -& End-ler m (80)]
------------------------·----
Ic-ontents of the s~~----
'

tfrli!s
Water
1j

Corr1mC!n I mpuriti~~s of wai:er

i_ H.ardness c-f water: Determinaiion of hardness b_y Clark's test and cmnple:·;
l metric (EDTA) method, Degree of hardness
Numerical b.ised on hardness and EDTA m~thod

!
. I Municipal \Vater Supply: Requisites of drinking vvater, Steps involved 111
purification •)f warer, Sedimentation. coagulation, Filtration and Sterilization,
Break _point <:hlorination
1
·water Tre:.ttmeut
• ~:ofteniDg of water: Limt-Soda Method, Pemrutit (Zeolite) Method and

I - II . ,_
Deionization or Demineralization i\1ethod
Boiler troubles their causes, disadvantages and prevention: :Formation o~:·sr.::lid:;
8

(Scale and Sludge;, Carry O'ler (Priming :md Foaming), Corrosion and Causti:

[__ j
I ;
Fmbriltleme'lt
• 1--'umerical problerr.s based on Lime-Soda and Zeolite softening method>
=-~----

! Polyme·r~iff.~rent mer:hods )f classifi-cation and constituents c.f polymers

' .. PlasTic:;: Themosets and Thennopla;;;ts
• Preparation. Properties and uses ofpolyehylene, Bakelite, T-~!J-Iene <rnd N\ ·QI
El'"'torr.ers -- c'iatural rubber, \'Uicanizariou, Synthetic Rubber:; ; iz. J:;una-:<-
Buna-\J~ Butyl and neoprer11.:: rubbers
i
I Cement -------1
Definition, Cor_1position_ ba~.ic constituents and their significar. :::,
i
i Manu!'acturing of ?orrland eement by Ro'ary Kiln Technology
;
.. Chemistry of setting and hard·:ming of cement and role- of gypsum
IV ! Glass
I
·Definition, Properties, Manut:1cturing of glass
r
I
·Types of silicate glasses and the:ir commeccial uses
• Irnpl)rtance ofannt·aling in glass: making
I
Refractorilcs
" Detlnition. classification, pnJperries, .~equi:>ites of goc·d refractor) and
manufilduring o:f re fracto~/
• Det~ikd study of silica and fire clay retractcry and thc,ir u>es
• Seg,,r':' {Pyrometri.;) Cone Tesr and RUL Test
V Lubricants
~ Introd~lction, classifi~:atioJI ond uses c.f lubri(:.ants.
• Types of lubrication.
( •· Viscosity & vi~;eo:;ity index. flash and tire poiJTJ, cloud and pour poim, :;·-:earn
-~--l _____er:m~~-~:cat~·n nwr~~r, pre:~~':ltiOJ:-~::ber cu~~~~ neu~rali7~~on number·----~-- J
 ENGINEERING CHEMISTRY LAB-I [1 08]
5
Class B. Tech. 1 Semester 1 Evaluation
Schedule per week Maximum Marks- 50

----·
Practical 2 I [Sessional (30) & Practical (20)]

I S.No. I List of Ex~eriments

(Any 7 experiments are to be performed)

1. To determine the hardness of water by HCL method.

-
2. To determine the hardness of water by EDTA method.
'
~- Determination of C02 in a water sample.
4. To determine free chlorine in a gtven water sample.

5. I To determine the •;iscosity of a given lubricating oil by Redwood

VISCOmeter.
--
6. Measurement of residual chlorine in water.
7. To determine the tlash and fire point of a given lubricating oil.

'
8. / Measurement of dissolves oxygen in water.
J
L 9. To determine cloud and pour point of a given oil.

I 10.. Measuremeno of nitrate in water

.
j

-
•
ENGINEERING CHIEMISTRY-11

I Class B. Tech. 2"" Semes.ter I Evaluation ·

~~Examination i ime. = Three (3) HourS
::J [206]

L
eperweek
Lectures 2 Maximum Macks~ 100
Tutorial 1 I [Mid-term (20) & End-term (80)]
~~-,.~~~~~~~---------------------------------.
Units I Contents of the Sub'ect
Fuels (General Aspects)
.. Organic ?uels: Origin, classification and general aspec1:s of organic fuels
Solid fuels: CoaL carbonization of coal: manufacturing of coke. by Beehive oven and
Ely p:-oduct 0\·en method.
I Liquid fuels: Advantages and refining of pen·oleum. Cracking. refining. reforming,

·/-.· .
polymerization and isomeriza.1ion of refinery products
I Synrhe1ic perrol( Coal to Liquid. CTL. Tee/moJo&~'): Berguis and Fischer Tmpsch
.. j process

L
Knocki:lg, octane number and anti-knocking agents
•· Gaseous fuels: Advantages, manufacturing, (;omposition and calorific value :Jf coa~,
I eas and oil gas.
' Ftlels (Analyses)

I
1
II
I
I
~Ultimate and proximate analysis of coal.
• De1e:_-mmaDOJi o: sol,d and g_a~'f.'(IU; fuels by bomb and Junker"s Calonme:-er
re<pectlVel)'
• Calculatnns of calorific value based on Dulong s fom!Ll)a
• Combustion and requirement of oxygen/ air in combusrio.n process.
•· Flue f!a~~ anaLvsis bv Orsar's apparatus and its si~'Ilificance.
se Rule
• •· STatement. Definition and mecmlng ofthe rem1s involved

J
Ill • Application to one component ~.ysltm: V./ater and Sulphur :.ystems
• Reduced ?hase Rule and study (lf!'..vo components Ag-Pb, Bi-Cd systems also i~s-
indus-.:ria. application. ·
New Engineer-ing Materials
f
i FuJJere-nes: Introduction, properties. preparation and uses.
i Superconductors: ln:roduction, prcperties, preparation and uses
._. Organic Electronic Materials (ir:cluding cc·nducting polymers- poly(r•-pheJJyJene::,
polythiophent-:s . Polyphenylen~·. vinylenes, polypyroles, poJyanili:1e). ,__,H.. , ... _,, j
1
/ Optica: fires: .[ntrociuction, :roperjes, preparation, optieal fiber grade glass an~

I Corrosion j
l Definition and its si!!nificance
I •· Mechc..nisms of corrosion Ch(~mJcal(DryJ corros1on and ElectroclJemJc:tl(\~'elj
v
I
j
corrasio:r
Protection from conosion: Protcct1ve coanngs_ cath·JdJc protectJOn. sacJJficJa) anode
l and rnc1dificaxion in designs etc
__l ·----·--

-
•
ENGINEERING CHEMISTRY LAB-II [208]

Class B. Tech. 2" Semester l Evaruation

Schedule per week ,Maximum Maiks- 50
Practical 2 I [Sessional (30) & Practical (20)L
S.No. List of Experiments
(Any 7 experiments are to be pel"formed)

I. Proximate analysis ofscdid fuel.

2. IExperiments based on Bomb Calorimeter.
3. Measuremen' of pH of & given sample by pH-merer.

4. Measurement of conductivity of a given sample by conductivity meter.

5. Measurement of fluoride in water.

6. To determine the strength ofCuS04 solution with the help of hypo solution.
7. ··- To determine the strength of ferrous Ammonium sulphate solution with the
help of K2Cr20, solutio;!.
8. Determination ofNa/K/Ca by flame photometer in a given sample.

9. To determine the strength ofNaOH and Na2C03 in a given alkali mixture.

I 0. Detem1ination of barium as barium .sulphate ,gravimerricaJJy.

I

-
 r .ENGINEERING CHE'111STRY-I
--co\s:\.o1i~H .Ist "8"'
eaule per week
1• .Sem,.ster

Lectur€i\: ,_
Tulonal
2
~---
1 Evaluotior.
i Exar:-!inatic:'~ ---=-.~~T- :! = Three (3) Hours
) !·~axitnU:!l F.'la:kE:..: JOO
[1 06]

.. _____.LlMid-l,.rm (10'· & E~o:.o--"te'-'r"-m'-'(-"8"-0u_'-------..1

c-~- -
W!I!its.'-·_.,..~---:':C:':o"'n"te=cnccts=..oocfc..toohccec..S=uccbJc.e"c"t__
j ! Water
Cor:,mon Jrnpuriti\~S of water
1-!arom:ss of w<eler: Determina:JOn o;' ha.·dness bv Clark's rest and complex
lll".''"ic (EDTA) nc<thod, Degree ofharcwso
··;;rneri~al based -:n hardness and F.DTA method
fv1ur~ici,;al \Vater Supply: Re·~uis~,:es o-_~ drinking water~ Steps involved in
i puriric-atii)l: .Jf wa;:er, Sedirnentation., c.r:'.i_guJation, Filtration and Sterilization _
_____L__ bre;~roinr chlori;Jation
~>V::::ter T•·eatnH.~nt
• ~:m'lening of w2.1er: Lim<;-So:Jc, Merhod, Pennutil (Zeolite) Method and
fleion i;:ation 01 Deminen-:1 izc.1ion Method
•· E::iie:r :roubles rhe·,r causes, disc.dvcmtage.:; and prevention: Formation o·.:·soiids
(S-:·:·lL ::md Sludge;, Carry over ~~Priming and Foaming), Co:·~~osion and Ca.usti::
E.rnLrit1\eme:.1t
•· Numeri"al problen'5 based e-n Lime-Soda and Zeolite softening methods
L.-
~~ Poi;,'mers
II ·Different methods )fclas,iiication and constituents of polymers
•· Piasjco: Themosers and Thennoplasts
.. Preparation. Prc-perries and uses ofpolyet'Jylene, Bakelite, Terylene and Nvlon
Elastorr,ers -- 'la1Ural rubbn \'ulcanization, Synthetic Rubbers viz. E:una-S,
i buna-~~' Butyl ancl neoprene: rubbers
L
I 1 Cement
I
Definition, C.)Jtlposition, ba~ic constituents 2.nd their s1gnificanc:,
]\.1anuf3cturing of~:>c~rtland cement by Ro·~ary Kiln Technology
•· Chemi~:lTJ-' of sening and hard~ning 01~ (:ement and r·)k of gyps urn
1 IV : Glass
· •· Deflnir.ion, Properties, Manttfacturing of gla.ss

L
'''{''
. -~
.
---'-----:---·-
! Refractories
"Types u·f siiicate glasses and their commecial uses
··Jmportance ofanm:aling i~1 glas~ making

·· De:lnition, dassd~~-ation~ pnJpen:i.t~S: ·~equisltes nf good refracwry a.nd

a·:·: ehactor_:··
r:-JanuLi·~turing
•· Detc..iled s.rudy ofs lic:a and fire day refraGtcry and"/]"";.-~:~:· uses
.. Se.ge.i:C~ :Pyrome1ri,~) Com~ Test and RUL Test
V Lu ~;ric~mts
I " Ir:troduction, clc,.£.sifr.::a1io~·: <::nd uses c.f lubri1::ants:.
•· Types 0 f lubricalion .
i .. Viscostt:,: &.viscosity indc·x . flash .:.nd fire p;)int, c.ioud and pour point, .:;·:eam
I emu!sificaticn number, precipiratior! number and neutrali.z.a~1or ;lumber
L...... ______ ,____________ -----· _ _ _ _ .... __________ . _______________,__ .I
:

·:$~);·

··--·~~:
I'

ENGINEERING CHEMISTRY LAB-I [1 08]

. • 111 T.'SI St:IV'
Class 8. Tea h. 1s Semeste1· ' Evaluation
Schedule per week Maximum Marks = 50
I Practical 2 Sessional (30 & Practical (20)
--~-·

S.No. List of Experiments

(Any 7 experiments are to be performed)
1. To determine the hardness of water by HCL method.

2. To determine the hardness of water by EDTA method.

-
.0. Determination of C02 in a water sample.
4. To determine free chlorine in a gi·ven water sample.

5. To determine the viscosity of a given lubricating oil by Redwood

viscometer. _j
6. Measurement of residual chlorine in water.
7. To detennine the tlash and fire point of a given lubricating oiL
8. Measuremenr of dissolves ox:.rgen in \Vater.

I~ 9. j To determine cloud and pour point of a given oiL

I
10. - IMeasure~en• of nitrate in water

-
 Schedule per week
Lectures 2
-1 Evaluation
Examination Time = Three (3) Hours
Maximum Marks= 100
::J [206]

Tutorial 1 Mid-term (20'> & End-term (80))

~U~n~it~s~~c~·o~n~t~e~n~~~o~f~t~h~e~S~u~b~i·~,e~ct~---------------------------------------------------
Fuels (General Aspects)
•· Organic ~els: Origin, classification and general aspeciS of organic fuels
Solid fuels: Coal, carbonization of coal, manufacturing of coke by Beehive oven and
By p:-oduct O\'en method.
•· Liquid fuels: Advantages and refining of pen·oleum. Cracking, refining, ref.:mning.,
p-olymerization and isomerization of refinery producEs

I~ ---·
j
~
Synthedc petrol( Coal to Liquid, CTL, TechnJlog}'): Berguis .md Fisc.her Tropsci1
process
Knocking, octane number and anti-knocking agents
j ~
Gaseous fuels: Advantages, mamdacturing. o::omposition and calorific value
/ !BS and oil 2as
i Fuels (Analyses) ·"----.- - - -
/ .. Ultimat~ and proximate analysis of coaL
/ •· Dere:-mination of solid and e.asf.c•u:; fuels b1· bomb and Junker's Calorimeter
~ ~

II I respectively.
.. Calculat.i~ns of calorific value based on Dulong's formula.
, •· Combustion and requirement of o.xygen/ air in combustion process.
f.-------..J..i _____•._F._,lu:ce~gas"'·'-"ane.a,_,~sis by Orsat's apparatus and its si!!Dific.ance.
--
Phase Rule
•· Si.atement, Definition and m~aninf; oftht ten11s involved
ill • Applice;.tion to one component :::.ystem: \l/arer and Sulphur systems
• Rt:duced .?hase Rule and study of two cornpont:JES Ag-Pb, B1-Cd !-:ysterns aJso 11s
-·, ,i~~~~~i~n~d~u~srn"-·~·a~.~a~p~p:cl~ic~a~ti"o~n~.----------------------------------- -·----
1I !.·

I,.
New Engineering Materials
Fullerenes: Introduction, properties, preparatiou and uses.
Superc.onductors: ln:roduction, properties, preparation and uses
• IV
r·I
'' Organic Electronic Materials <)r:cluding cc-nducting polymers- pnly(p-rheJtyJene.~.,
polythiophenes. Po!yphen:ylen~: vinylenes, poJypyroles, poJyaniline).
Optica·. fires: lmroriuction., proper-;ies, preparation, optical fiber grade glass and uses.

/ Corrosion
I Definition and its si!!nificance
I · Mech~nisms of C(~rrosion: Chemicai(Dry) corrosion and Elecrro_chernic:~I(Wet)
v
corrosion ~
Prowction from conosion: Protective coarings, cath·:dic protection, sC~crificiaJ anode
and modification in je-signs el"c.
·----- ----------------· .
 ENGINEERING CH!j:l\11STRY LAB-II [208]
- \12i.vm/\..'l..l'Gj
Class l!t:&Gh. znd Semester
Schedule per week
Practical 2

S.No. List of Exoeriments

(Any 7 experiments are to be performed)

I. Proximate analysis of solid fuel.

0 Experiments based on Bomb Calorimeler.
3. Measuremen' of pH of" given sample by pH-merer.
I
4. Measuremem of conductivity of a given sample by conductivity merer.

5. Measurement of fluoride in water.

I
L6
- 7. .. -
To determine the strengi:h of C uS0 4 solutiOJJ with the help of hypo solution.

I To delennine the strengt.h of Ferrous Ammonium sulphate solution with the

help ofK 2 Cr2 0 7 solution.
8. Determination ofNa!K!Ca by flame photometer in a given sample.

9. To determine the strength ofNaOH and Na2 C03 in a given alkali mixtme.
I
10. Determination of barium as barium sulphate gravimetrically.
I
I

-
 B.Sc. Part-1, Syllabus I 1

B. Sc. PART-I UNIFIED SYLLABUS

CHEMISTRY
Paper I: Inorganic Chemistry M.M.:SO,
Unit -I : (I) Atomic Struture : Idea ofde-Broglie matter waves, Heiseliberg
uncertainty principle, atomic orbitals, Schrodinger wave equation; significance
of ljl and 1j12 , quantum numbers, radial and aqgular wave functions and
, probability distribution curves, shapes of s, p, d, orbitals, Aufbau and Pauli
exclusion, principles, Hund's multiplicity rule, Electronic configurations of die
elements effective nuclear charge. ·
(II) Periodic Properties : Atomic and ionic radii, ionization energy, electron
affinity and electronegativity-definition, methods of determination or evaluation ·
!rands in periodic table and applications in predicting and explaining the chemical
behaviour.
Unit- II: (III) Chemical Bonding: (A) Covalent Bond-Valence bond.
theory and its limitations directional characteristics of covalent bond, various
:1
types of hybridization and shapes of simple inorganic molecules ·and ions,
0 ~
valence shall electron pair repulsion (VSEPR) theory to NH,, H,o+, SF., CiF,,
ICI,- and H,O, MO theory, homonuclear and heteronuclear (Co and· NO)
diatomic molecules, multicenter bonding in electron deficient molecules, bond
strength and bond energy percentage ionic character from dipole moment and
electro-negativity difference.
{B)Ionic Solids-Ionic structures radius ratio effect and coordination
number, limitation of radius ratio rule, lattice defects semiconductorS, lattice
energy and Bron-haber cycle, salvation energy and solubility of ionic solids
polarizing power and polarisability of ions Fajan's rule, Metallic bondCfree
electron valence bond and band theories.
(C) Weak Interactions--Hydrogen bonding, Vander Waals forces.
Unit-III.: (IV) s-Biock·Elements : Comparative study, diagonal
relationship, salient features ofhydrides, solvation and complexation tendencies
including their function in biosystems, an intJ:oduction to alkyls and aryls.
(V) Chemistry of Noble Gasses: Chemical properties of the noble gases,
chemistry of xenon, structure and bonding in. "@.On 'compounds.
Unit-N: (VI) p-Biock Elements : Companuiv'estudy (including diagonal
relationship) of groups 13-17 elements, compounds like hydrides, oxides,
oryacids and halides ofgroup 13-16, hydrides ofboron"diborane and higher
boranes, borazine, borohydrides, fullerenc.es, .carbides, fluorocarbons, silicates
(structural principle), tetrasulphur tetra nitride basic properties of halgoens,
interhalogens and polyhalides.
 2 B.Sc. Part-1, Syllabus
Paper II: Organic Chemistry M. M.: so
Unit-I: (I) Structure and Bonding : Hybridization, bond lengths and
bond angles, energy, localized and delocalized chemical bonding, van der Waals
interactions, inclusion compounds, clatherates, charge transfer. complexes,
I resonances, hyperconjugation, aroillaticity, inductive and field effects,
hydrogen bonding.
(II) Mechanism of Organic Reactions: Curved arrow notation, drawing
I electron movements with· allows half-headed and double-headed arrows,
homolytic and heterolytic bond fission. Types of reagents- electrophiles ans

II nucleophiles. Types of organic reactions, Energy considerations.

Reactive int~mediates- Carbocations, carbanions; free iadicals, carbenes,
arynes and nitrenes (with exarnples).Assigning formal charges on intermediates
I' and other ionic species.
Methods of delermination of reaction mechanism (product analysis
intermediates, isotope effects, kinetic and stereochemical studies).
I (III) Alkanes and Cycloalkanes : IUPAC nomenclatute ofbranched and
unbranched alkanes, the alkyl group, classification of carbon atom in alkanes,
Isomerism in alkanes, soutces methods of formation (with special reference to
Wurtz reaction, Kolbe reaction, Corey-House reaction and decarboxylation of
carboxylic acids), physical properties and chemical reactions of alkanes,
Mechanism of free radical halogenation of alkanes : orientation, reactivity and
selectivity.
Cycl&alkanes- Nomenclatute, methods of formation, chemical reaction,
Baeyer 's strain theory and its limitations. Ring strain in small rings (eye lopropane
and cyclobutane), theory of stain less rings. The case of cyclopropane ring,
banana bonds.
Unit-II: (IV) Stereochemistry of Organic Compounds : Concept of
isomerism. Types of isomerism;
OPtical isomerism - elements of symmetry, molecular chirality,
enantiomers, stereogenic center, optical activity, properties of enant_iomers,
chiral and achiral molecules ":ith two stereogenic centers,disasteromers, thteo
and erythro diastereomers meso compounds, resolution of enantionmer,
inversion, retention and recemization.
Relative and absolute configutation, sequence rules, D & Land R &.S
ll.
systemS of nomenclatute.

i
l
Geometric isomerism - dete_rmination of configuration of geometric
isomers, E & Z system of noniencJature, geometric isomerism iri oximes and
alicyclic compounds.
Conformational isomerism- conformational analysis of ethane and n-
butane; Conformations of cyclohexane, axial and equatorial bonds,. conformation
ofmono substituted cyclohexane derivaiives, Newman projection and Sawhorse
 B.Sc. Part-1, SyJiabus J 3

fonnulae,
' .
Fischer and flving wedge formulae, Difference between configuration
and conformation.
\\ Unit-III: (V)Alkenes, Cycloalkenes, Dienes andAikynes: Nomenclature
of alkenes, methods offormation, mechanisms of dehydration of alcohols and
dehydrohalogenation of alkyl, halids, regioselectivity in alcohol dehydration.
The saytzeff rule, Hofinann elimination, physical properties aii'd rbtative .
stabilities of alkenes.
Chemical reactions of alkenes- mechanism involved in hydrogenation,
electrophilic and free radical additions\, MArkownikoffs rule,.hydroboration-
oxidation, oxymercuration-reduction. Epoxidation, ozoi10lysis, hydration,
hydroxylation and oxidation with KMno 4 Po!ymerization of alkenes, Subsitution
at the allylic and vinylic posi(ions of alkenes, Industrial applications of ethyle!le
and propene.
Methods of formation, conformation and clemical reactions of
cycloalkenes;
Nomeclature and classification of dienes : isolated, :conjugated and
cumulated dienes, Structure of allenes and butadiene, methods of formation,
polymerization, chemical reaction- I ,2 and I, 4, additions, Diels-Aiderreactibn.
Nomenclature, structure and bonding in alkynes, Methods. of forniation,
Chemical reactions of alkynes, acidity of alkynes, Mechanism o(electrophilic
and nucleophilic additimi reaction, hydroboration-oxidatlon, metal-ammonia
reductions, oxidation and polymerization.
Unit-IV : (VI) Arenes and Aromaticity : Nomenclature of benzene
derivatives. The aryl group, Aromatic nucleus and side chain structure. of
benzene; molecular formula and kekule structure, Stability.and:carbon,carbon
. ·-·
bond langths of benzene, resonance structure, Mo picture.
Aromaticity :The Huckle rule, aromatic ions.
Aromatic electrophilc substitution- general pattemofthe mechanism; ..
role or cr and 1t complexes, Mechanism of nitration, halogenation; .sulphonatioit,, .
mercuration ~'d Friedel -Crafts reaction.·Energy profile diagrams·. Activating·
and deactivating substituents, orientation and ortho/para ratio; Side chain
reaction of benzene derivatives, Birch reduction;
.I Methods of formation and chemical reactions of alkylbenzenes,
alkynylbenzenes and anthracene;
,.
j (VII) Alkyl and Aryl Halides: Nomenclature and·classes of alkyl halides,
methods offormation, chemical reactions Mechanisms ofnucleophilic substitution
reactions of alkyl halides, SN' and SN' reactions withene;gyprofile diagr~;
 4 1 B.Sc. Part-.!, Syllabus
Polyhalogen compounds: Chloroform, carbon telrachloride;
Methods of formation ofaryl halides, nuclear and side chain reactions;
The additio11-elirnination and the elimination-addition m€:chanisms of
nue-leophic aromatic substitution reactions;
Relative reactivities a alkyl halides vs allyl, vingl and aryl halides,
Synthesis and uses of DDT and BHC.

* ~'3tl<itrit~ i6J<ff.lq; ~
Paper-III :Physical Chemistry M.M.i50

Unit-!: (I) Mathematical concepts and Computers:

(A) Mathematical concepts : Logarithmic relations, curve, sketching
linear graphs and calculation of slopes, differentation of functions like Kx, e',
X', Sin X, log X; maxima and minima, partial differentitation and reciprocity
relations, Integration of some usefuVrelevant functions; permutations and
conbinations, Factorials, rrobability.
(B) Computers : General introduction to computers, different components
of a computer, hardware and software, input-output devices, binary numbers
and arithmetic's introduction to computer languages, programming, operating
systems.
Unit- II : (II) Gaseous States : Postulates of kinetic theory of gases,
deviation from ideal behavior, Vander Waals equation of state;
Critical Phenomena: PV isotherms of real gases, continuity of states, the
isotherms of Vander Waals equation, relationship between critical constants
and vander Waals constants, the law of corressponding states, reduced
equation of state.
Molecular velocities : Root mean square, average and most probable
velocities, Qualitative discussion of the Maxwell's distribution of molecular
velocities, collision number, mean free path and collision diameter, liquification
of gases (based on Joule- Thomson effect).
(III) Liquid State: Intermolecular forces, structure ofliquids (a qualitative
description). . .
Structural differences between solids, Liquids· and gases;
Liquid crystals : Difference between liquid crystal, solid and liquid,
classification, structure of nematic and cholestric phases, Thermography and
seven segment cells.
Unit-III: (IV) Solid States: Defmition of space lattice, unit cell;
Laws ofcrystallography-{i) Law of constancy ofinterfacial angles, (il,
Law of rationality of indices (iii) Law of symmetry, Symmetry_ elements in.
crystals.
 RSc. Part-1, Syllabus I 5 ·
X-raydilfraction by crystals, Derivation of Bragg equation, Determination
of crystal structure ofNacl, KCI and CsCI (Laue's method and power method).
· (V) Colloidal States : Definition of colloids; classification of colloids;
:' I Solids in liquids (sols): properties-Kinetic, optical and electrical; stability
of colloids protective action Hardy-Schulze law, gold number.
Liquids in liquids (emulsions): types ofemulsions preparation, Emu)sifier,
Liquids in solids (gels) : classification, preparation and properties,
inhibition, general application of colloids, colloidal electrolytes.
Unit-IV: (VI) Chemical Kinetics and Catalysis: Chemical kinetics and
· its scope, rate of a reaction,. factors influencing. the rate of a reaction.-
coilcentration, temperature, pressure, solvent, light catalyst, -concentration
dependence of rates, mathematical characteristics of simple chemical reactions
-zero order, first order, second.order, pseudo order, half life and mean life,
Determination of the order of reaction - differential method, method· of
integration, method ofhalf life period and isolation method.
Radioactive decay as a first order phenomenon;
Experimental methods of chemical kinetics; conductometic
potentiometric, optical methods, polarimetry and spectrophoto-meter.
Theories of chemical kinetics :effect of temperature on rateofreaction,
Arrhenius equations, concept of activation energy. • ·
Simple collision theory based on hard sphere model, transition -state
theory (equilibrium hypothesis), Expression for the rate constant based on
equilibrium constant and thermodynamic aspects.
Catalysis characteristics of catalysed reactions classification of catalysis .
homogeneous and· heterogeneous catalysis, enzytne catalysis, miscellanceous
examples.

Practical
Inorganic Chemistry: Semi micro Analysis -cationanalysisseparation
and identification of ions from Groops I, II, III, IV, V and VI Anion analysis. · i
Organic Chemistry: Laboratory techniques: '
Calibration of Thermometer : 80-82° (Naphthalene),ll3:5~114°
(Acetanilide)
!
132.5,133° (Urea), 1000 (Distilled Water)
Determination of melting point:
Naphthalene 80-82°· Benzoic acid 12 1.5-122° "!
(
Urea 132.5 -133°· Succinic acid 184.5-185°
j Cinnamic acid 132.5-133°, Sallicylicacid 157.5-158°
Acetanilide 113.5-114° m-Dinitrodenzene 90°
i p-Dichlorobenzene 52°, Aspiriill35°
''
i'
 6 I B.Sc. Part-!, Syllabus
Determination ofboiling point: Ethanol78°, Cyclohexane, 81.4°, Toluem
ll 0.6°, Benzene 80°
Mixed melting point determination : Urea-Cinnamic acid mixture o·
various compositions (I :4, L l, 4: l)
Distillation : Simple distillation of ethanol-water mixture using wateJ
condenser, Distillation of nitrobenzene and aniline using air condenser.
Crystallization: Concept of induction of crystallization,
Phthalic acid from hot water (using fluted filter paper and stemless funnel)
Acetanilide from boiling water
Naphth•lene from ethanol
Benzoic acid from water
Decolorisation and crystallization using charcoal : Decolorsation of
brown sugar (sucrose) with animal charcoal using gravity filtration.
Crystallization and decolorisation ofimpure naphthalene l OOg of napthalene
mixes with 0.3 g of Congo Red using I g decolorizing carbon) from ethanol.
Sublimation (Siple and Vacuum): Camphor, Naphta-Jene,Phthalic acid
and succinic acid.
Qualitative Analysis: Detection of extra elements (N, Sand halogc:IS)
and functions groups (phenolic, carboxylic, carbonyl, esters, carbohydrates,
amines, amides. nitro and anilide) in simPle. organic compounds.
Physical Chemistry
Chemical Kinetics:
I. To determine the specific reaction rate of the hydrolysis of methylacetate/
ethy acetate catalyzed by hydrogen ions at rooms temperature.
2 To study the effect of acid strenght on the hydrolysis of an ester.
3. To compare the strengths ofHCI and H2 S04 by studying the kinetice of
hydrolsis of ethyl acetate.
4. To study kinetically the reaction rate of decomposition of iodide by
H,O,.
Distribution Law:
l. To study the distribution of iodine between water and CCI 4•
2 To study the distribution of benzoic acid between benzene and water.
Colloids:
I. To prepare arsenious sulphide sol and compare the precipitating power
of mono-bi and crivalent anions.
Viscosity, surface Tension:
I. To determine the percentage composition of a given mixture (non
interacting systems) by viscosity method.
2 To determine the viscosity of amyl alcohol in water at different
concentratiOn,and calculate the excess viscosity of these sol uti<.
3. To determine the percentage composition of a given binary mixture by
surface tension method (acetone & ethyl methyl ketone). ·

/
 4 I ll. Sc. l'art-II (Syllabus)
respect of ionic radii, oxidation states, magnetic behavior, spectral properties
and stereochemistry.
UNIT-II- (iii) Coordination Compounds: Werner's coordination theory
and its experimental verification, effective atomic number concept, chelates,
nomenclature of coordinatiori compounds,
isomerism in coordination compounds, valence bond theory of 'transition
metal complexes.
UNIT-111-(iv) Chemistry of Lanthanide Elements: Electronic structure,
oxidation states and ionic radii and lanthanide contraction,
cornple·x fomwtion, occurrence and isolation, eerie ammonium sulphate and
its analytical uses.
(v) Chemistry of Actinides: Electronic confi(;uration, oxidation states and
magnetic properties, chemistJy of separation of Np, Pu and Am from U.
UNIT-JV---.-(vi) Oxidutloit and Reduction : Electrode potential,
electrochemical series and its applications, Principles involvefi in the extraction
of the elements.
(vii) Acids and Bases :Arrhenius, Bronsted-Lowry, the Lux-flood! solvent
i system and Lewis concept of acids and bases.
I (viii) Non-aqueous Solvents : Physical properties of a ~olvent, types of
l solvents and their general characteristics, Reactions in non-aqueous solvents
I witlt reference to liquid NH_, and Liquid so2.
Bsc Parf-JZ I PAPER II : ORGANIC CHEMISTRY
UNIT-1-(i) Electromagnetic Spectrum Absorption Spectra :Ultraviolet
I
I
(UV) absorption spectroscopy- absorption laws (Beer-Lambert law); molar
absroptivity, presentation and analysis of UV ·spectra, types of electronic
I transitions, effect of conjugation. Concept ofchromophore and auxochrome,
I Bathochromic, hypsochromic, hyperchromic and hypochromic shifts. U. V.
spectra of conjugated enes and en ones. Infrared (l.R.) absorption spectroscopy
-----/ !CHEMISTRY I -molecular vibratiOns, Hook~·s·law, .selection rules, intensity and position
ofl..R. bands, measurement ofi.R. spectrum, fingerprint region, characteristic
PAPER I : INORGANIC CHE;MISTRY absorptions of various functional groups and interpretation of I.R. spectra
UNIT-1-(i) Chemistry .of Elements of First Transition Series : of simple organic compounds.
Characteristic properties of d-block-elements. Binary compounds (hydrides, . UNIT-II-(ii) Alcohols : Classification and nomenclature, Monohydric
carbides and oxides) ofthe elements ofthe first transition series and complexes alcohols- nomenclature, methods of fonnation by reduction of Aldehydes,
· with respect to relative stability oftheir oxidation states, coordination number Ketones, Carbqxylic a~;ids and Ester~, Hydrogen bonding;. Acidic nature,
and geometry. ,
Reactions of alcohols. Dihydric alcohols-nomenclature, methods ofl'onnation,
(ii) Chemistry .of -Eiemen.ts of Second. ani! Third n·ansi!ion Series : ch.emical reactions of vicinal glycols, oxidative cleavage [Pb(0Ac)4 and
Oener91 characteristics, coqtparative treatment of Zr/Hf, Nb/Ta, Mo/W in Hl0 4] and pinacol- pinacolone rearrangement. Trihydric alcohols-
nomenclat.ure, niethods of formation, chemical reactions of glyceroL
(iii) Phenols : Nomenclature, structure and bonding, preparation of phenols,
physical properties and acidic character, Comparative acidic strengths..oJ
alcohols ,1·· ·1 phenols, .resonance stabilization of phenoxide ion. Reactions
 6, I B. Sc. l'art-Il (Syllauus)
!l. Sc. l'art-11 (Syllabus) I5
of phenols-electrophilic aromatic substitution, acylation and carboxylation. basicity ·Of amines. Amine salts as phase-transfer catalysts, Preparation of
Mechanisms of Fries rearrangement, C!aisen rearrangement, Gattem1an' alkyl and aryl amines (reduction of nitro compounds, nitrities), reductive
syntheis, Hauben-Hoesch reaction, Lederer-M.anasse reaction and Reimer- amination of aldehydic and ketonic compounds, Gabriel-phthalimide reaction,
Tiemann reaction. Hofmann bromamide reaction. Reactions of amines, electrophilic aromatic
UNIT-111-{iv) Ethers and Epoxides: Nomenclature of ethers and methods substituton in atyl amines, ~eactions of amines with nitrous.aci~. Synthetic
of their fonnation, physical prope.t1ies, Chemical reactions-cleavage and· transfonnations of a1yl diazonium salts, azo c.oupling.
autoxidation, Ziesel 's method. Synthesis of epoxides, Acid and base-catalyzed' PAPER JI1 : !'HYSICAL CHEMISTRY
ring opening of epoxides, orientation of epoxide ring opening, reactions of UN IT-I-{J"hermodynamics & ChemiCal Equilibrium)
Grignard and organolithium reagents with epoxides. (i) Thermodynamics - I
(v) Aldehydes and Ketones : Nomenclature and structure of the carbonyl Definitions of thermodynamic terms : System, surroundings etc. Types of
groups, synthesis of aldehydes and ketones with particular reference to the: systems, intensive and extensive properties·, State and path functions and
synthesis of aldehydes from acid chlorides, synthesis of aldehydes and. their diiTerentials, Thermodynamic processes, concept of heat and work.
ketones tJses I, 3-dithianes, synthesis of ketones from nitrites and from: First Law of Thermodynamics : Statement, definition of internal energy
carboxylic acids, Physical properties. Mechanism ofnucleophillic additions: and enthalpy, Heat capacity, heal capacities at constant volume and pressure
to carbonyl group with particular emphasis on benzoin, aldol, Perkin and i and their relationship, Joule's law- Joule-Thomson coefficient and inversion
Knoevenagel condensations, Condensation with ammonia and its derivatives. \ temperature. Calculation of w, q, dU &. dH for the expansion of ideal gases
\Vittig reaction, Mannich reacti.on. Us(> .)f aceta Is as protecting group, ; under isotheral and adiabatic conditions for reversible process.
Oxidation of aldehydes, Baeyer-Villiger oxidation of Ketones, Cannizzaro : Thermochemistry : Standard state, standard enthalpy of formation- Hess's
reaction, MPV, Clemmenscn, Wolff~Kishner, LiAIH 4 and NaBI-1 reductions.: Law of heat summation and its applications, Heat of reaction at <:onstant
4
Halogenation of enolit.able ketones An introduction to ±, 2 unsaturated ; pressure and at constant volume, Enthalpy of neutralization, Bond dissociation
aldehydes and Ketones. i energy and its calculation lfom thenno-chemical data, temperature dependence
UNIT-IV-{vi) Carboxylic Acids : Nomenclature, structure and bonding, : of enthalpy, Kirchhoff's equation
physical prope11ies, acidity of carboxylic acids, effects of substituents on; UNIT-11-{ii) Chemical Equilibrium: Equilibrium constant and free energy,
acid strength, Preparation of carboxylic acids, Reactions of carboxylic acids,; Thermodynamic derivation of law of mass action, Le Chatelier's principle
Hell-Volhard-Zelinsky reaction, Synthesis of acid chlorides, esters and amides, ; Rt'action isotherm and reaction isochore -Clapeyron~clausius equation and
Reduction of carboxylic acids, Mechanism of decarboxylation. Methods of: its applications.
fofmation and chemical reactions of halo acids, ~-lydroxy acids : malic, ·! (iii) Thcrmodynamics-11
trartaric and citric acids. Methods of forlllation and chemiCal reactions of·' Second Law of Thermodynamics : Need for the law, different statements
unsaturated monocarboxylic acids. Dicarboxylic acids: methods of formation ! of the law, Co mot's cycle and its efficiency, Camot's theorem. Thermodynamic .
and effect of heat and dehydrating agents. i scale of temperature.
(vii) Carboxylic Acid Derivatives : Structure and nomenclature of. acid i Concept of entropy : Entropy as a state function, entropy as a function
chlorides, esters, amides (urea) and acid anyhydrides. Relative stability of, ofV & T, entropy as a function ofP & T, entropy change in physical change,
acyl derivatives, Physical Properties, interconversion of acid derivatiyes by I clausius inequality, entropy as a criteria of spontaneity and equilibrium,
nucleophilic acyl substitution. Preparation of carboxylic acid derivatives, Equilibrium change in ideal gases and mixing of gases.
chemical reaction. Mechanisms of esterificaton and hydrolysis (acidic and ' Gibbs and Helmholtz functions: Gibbs function (G) and Helmhotz function
basic) (A) as thermodynamic quantities, A & G ~s criteria for thermodynamic
(viii) Organic Compounds of Nitrogen : Preparation of nitroalkanes and equilibrium and spontaneity, their advantage over entropy change, Variation
nitroarenes, Chemical reactions of nitroalkanes. Mechanisms of nuclephi'IC of·G imd."A with P, V and T.
substitution in nitroarenes and their reductions in acidic. neutral and alkaline Third Law of Thermodynamics : Nemst heal theorem, statement and
media, Picric acid. Halonitroarenes: reactivity, Structure and nomenclature concept of residual entropy. Nernst distribution law-thermodynamic
of amines, physical properties, Stereochemistry of amines, Separation of a derivation, applications.
mixture of primary, secondary and tertiary amines. Stmctural features effecting
 B. Sc. Part-II (Syllabus) I 7. 8 I B. Sc. Part-11 (Syllabus)

UNIT-UI-{Eiectrochemistry - I & Solutions) Quantitative Analysis :

Volumetric Analysis: (a) Detemtination of acetic acid in commercial vinegar
(iv) Electrochemistry-! :
using NaOB. (b) Determination of alkali content- antacid tablet using HCI.
Electrical transport : Conduction in metals and in electrolyte solutions,
(c) Estimation of calcium content in chalk as caldum oxalate by
specific conduCtance molar and equivalent conductance, measurement of.·
pcrmanganometry. (d) Estimation of hardness of water by EDTA. (c)
equivalent conductance, variation ofrno lar equivalent and specific conductance
with dilution. Migration of ions and Kohlrausch's Jaw, Arrhenius theory of Estimation of ferrdus and ferric by dichromate method. (f) Estimation of
electrolyte dissociation and its limitations, weak and strong electrolytes,: copper using thiosulphate.
Ostwald's dilution law its uses and limitations, Debyc-Huckei-Onsager's. Gravimetric Analysis : Analysis of Cu as CuSCN and Ni as Ni
equation for strong electrolytes (elementary treannent only), Transport number, (dimethylgioxime).
definition and determination by Hittorf's method and moving boundary ORGANIC CHEMISTRY
method. Applications of conductivity measurements: detennination of degree · Laboratory Techniques
of dissociation, detennination of Ka of acids, detennination of solubility A. Thin Layer Chromatography Detennination ofR/ values and identification
product of a sparingly soluble salt, conductometric titrations. of organic compounds; (a) Separation of greenleaf pigments (spinach leaves
(v) Solutions : Liquid - Liquid mixtures- Ideal liquid mixtures, Raoult's may be used). (b} Preparation of separation of2, 4-dinitrophenylhydrazones
and Henry's law, Nonideal system-azeotropes - HCI-1-1 2 0 and ethanol - · of acetone, 2- butanonc, hexan-2, and 3-one using toluene and light petroleum
water systems. Partially miscible liquids- Phenol- water, trimethylamine- (40:60) (c) Separation of a mixture of dyes using cyclohexane and ethyl
water, nicotine-water systems, Immiscible liquids, steam distillation.
acetate (8.5:1.5).
UNIT-IV-{Electrochemistry- II & Phase Equilibrium) B. Paper Chromatogrophy :Ascending and Circular Determination of R/
(vi) Electrochemistry -II :Types of reversible electrodes~ gns-mctal ion, valqes and identification of organic compounds: (a) Separation of a mixture
metal-ion, metal insoluble salt-anion and redox electrodes, Electrode reactions, ,,of phenylalanine and glycine, Alanine and aspartic acid, Leucine and glutamic
Nemst equation, cterivation of cell E.M.F. and single clectr0~e potential, acid. Spray reagent- ninhydrin. (b) Separation of a mixture ofD, L- alanine,
strandard hydrogen electrode-reference electrodes and their applications, glycine, and L-Leucine using nbutanol : acetic acid:water (4:! :5), Spray
standard electrode potential, sign conventions, electrochemical series and reagent- ninhydrin. (c) Separation of monosaccharide- a mixture of D·
·its significance. Electrolytic and Galvanic cells-reversible and irreversible galactose and Dfructose using n-butanol:acetone:water ( 4:5: i ), spray reagent
cells, conventional representation of electrochemical cells; EMF of a cell
and its measurements, Computation of cell EMF, Calculation of - an i!ine hydrogen .phthalate.
them10dynamic quantities of cell reactions ("G, "H and K) Concentration Qualitative Analysis :
ldentificat ion of an organic compound th.rough the functional group analysis,
cell with and without transport, liquid junction potential. application of
detcnninition of melting point and preparation of suitable derivatives.
concentration cells, valency ofions, solubility product and activity coefficient,
PHYSICAL CHEMISTRY
potentiometric titi-ations. Definition of pH and pKa, determination of pH
using hydrogen, quinhydrone and glass electrodes, by potentiometric methods; Transition Temperature
l. Detemtination of the transition temperature of the given substance by
Buffers -Mechanism ofbufferaction, Henderson-Hazel equation, application
of buffer solution, Hydrolysis of salts themtometric /dialometric method (e.g. MnC1 2 .4l·lpiSrBr2.2H 20).
(vii) Phase Equilibrium : Statement and meaning of the temts-phase, Phase Equilibrium
component and degree of freedom, derivation of Gibb's phase rule, phase 2. To study the effect of a solute (e.g. NaCI, succinic acid) on the critical
equilibria of one component system-water, 'C0 2 • and 'S' systems Phase solution temperature of two partially miscible liquids (e.g. phenol-water
equilibria of two component system- solid liquid equilibria simple eutectic system) and to detennine the concentration of that so\ute in the given phenol-
- Bi-Cd, Pb-Ag systems, desilverisation of lead. Solid solutions- compound water system. 3. To construct the phase diagram of two component (e.g.
formation with congruent melting point (Mg-Zn) and incongruent melting diphenylamine - benzophenone) system by cooling curve method.
point, (FeCirHPJ and (CuS0 4-H 20) system Thermochemistry
PRACTICALS I. To determine the solubility of benzoic acid at different temperatures and
INORGANIC CHEMISTRY to detcnnine "H of the dissolution process. 2. To detennine the enthalpy
Calibration of fractional weights, pipettes and burettes, Preparation of of neutralization of a weR :id/weflk base versus strong base/strong acid
standards solutions, Dilution·· 0.1 M to 0.001 M sc Jns.
 B.Sc. Part~fll. Syllabus. · 5.
t CHEMISTRY
r
r'
Paper I : Inorganic Chemistry ~
Unit·I: Hard and Soft Acids and Bases (ii:SAB) : Classification of acids and· bases

l ·i
as hard and soft. Pearson's 'HSAB concept acid-bOse strength and· hardness and -~
, _ softness. Symbiosis, theoretical basis_ Of hai"dness and softneSs,~ei~tron~gativi~Y.-~:IQd
·hardness and softness. -. .- __ . ·---~ .,- ·. ·. ~ "'"-
' . Metal~Jigand Bonding in 'Iran.Sitio~ Met.:il Complexes _:crJ-mitatiOOS_-Pf y~rerlCe
! 1:
!
\
!, bpnd theory, and elementary idea of cry;;tal~field tJieiJry,.erystal. te(a".:sjiliiivgjp
octahedral, tetrahedral and square planner complexes, factors affecting the-t'rystal-j'icid.
parameters. · ··. ·. · ·- -- · --, · - · -·:· · ·- ·- - :. ·._:
I (' - Unit-Ii _:MagnetiC Pr<!perties of.Tra.J;~Sition Me~- ~o~ple~_;_J~-of ~~&i-le-#c. -
behaviour, methods of. determining magnetic susceptibility; spin:Only· foOJ)irla;. L..S ·..
coupling, correlation Of Jts arid ftef! vaJUCs, orbiultc'ontribiitio~ la.n]agi}etic.riiiQ_iljeO·ts, .- .
application of. magnetic mpment data for 3d-¢etai (:Qmpr.,res...,,c;' .~., '.;: ·.:: ·.:~;: ,. . .
. Electro"' Spectra ofTrans1tion Metal Compi~.S':,_lfpe,S ofele<:tioiiic ~~tions,..·,.
i'
!
selection rules for d-d transitions~ spectro~scopic- &ro.und_~mi~~s~ s~~qchem~~-~rie;:­
Orgel-energy level diagram for d 1 and ci 9 states, disCUssion of the electroiuc .p;;;u-,;m ~f ..
I rn 3
(rhO )6] complexion. . .• - . .' . '' . . .
·J :. · Thermridyri.a_mic and Kinetic Aspe(;ts-bCMetal Complexes: A. brfc!f oilt_liJlC~~flb~ . · -· ..
thermodytiamic stability of metal ~omplexed and factors· affecting-.tbe>.s[abilify, "I
1 substitution reactions of square planer com pi~.· ·. ·. · . . . · · . .' ·.. :··'":.~··, , .
1. • Unit-III: Organometallic Chemistry :J)efinition,nomenclature arid'ctil~c3tion
'
~~- rganometalfic compounds. Preparation, properties, bonding.and applications._ of . .. ", 'I
Is and aryls of U, AI, Hg, ·sn and TI, a brief account of·metal..eth)'fenic complexes :· \
J . homogeneous hydrogenation, manoclear carbonyls and the· nature of bonmnfiri •
J
I Jf.a~~~~">;lsBio'<lrganic· Cbe~is~.; ~ntia~ ~~. tra:~ ...~~~~~ ln '~bib;~·
I I r>foCesse5, metalloporphyrins with special reference'ta haemoglobin ;arid' myoglobin;"
. , - BiolOgical role oflilkali arid alkalinO'earil!metalions witt('specialrefe~en~to:eaz~. '
Nitrogen fooition. · . · ·. . .· -' · . · . ,- • ·• ·· ··. -. ·.. _--. ·~
.Unit·V·: Sllieones and Phosphazenes: Silicones arid phosphazen.Sas examplc:S'ol ·
·.

:•··>: .
i
inorg::zr:; nature of bonding in tri~hosphazeites.. • . .... ,.., '. . -~ ~r·-., !
;'
I ;q,falR<Ji~ . . ~~~ .
J
I . i
l P3perll:.-Org3~~:kChemistry. __ _,~3:'-__ ~--,-~----~, __ :~_-~
· Unit-! :.(a) ,Spectroscopy: U.V.. Spectroscopy. and its appliCation iil .organic· . '
.. 1
.chc!rnisiry. !.R. ·Spe<;troscopy. and. its application in organic chemiStry: N:M:R..
r Spectroscopy and its·application in organic chemistry. , .. . . . · ~ .. · ,, . i
?rJ Synthetic Dyes: COlour and·constitution (electi:onitcconcept~. Cl3ssincatioi!Of '
r dyes• ChemiStry andsynthesiS-()f Methyf orange; Congo re~,l.{a_lachit~green,,C!JIS!")
!. vtolet; Phenophthalem; Hourescem,Ahzarm.and Indlg,9,:": . . · . .c:/ c.- ,. ,. .: ·.: -. :
' · Unit-Il : (a) Organimetallic Compounds : Organomagn'esium compounds ::the ..
Grigriard reagents-forinat.iori. structu~e-. and ·chemical .reaC1_ions:-· Organic compciu~~ ·: ~~ . .'. ~_.:~
r formation anctchemjcal reactions. Orgaoolithium compounds: formation and_~hemic31 ··> ,..
I reactions. _
(b) OrganOS~Jpbur Compounds_: NOmenclatur-e, structu-ral featur~;~~eU:i~.of: ~·
_ - -~-~--

formation .and ch,em.ical reaction of tbiols; lhietbers, sufpfi_~nJc- acids, sulphor.!'!'!llide$-. _.·
I a~d sulphaguanidine .. · .. · . . . · .·. . ' . . ·'. ·.~ _'.'
r · Unit'III : (a) Hatel'OC)'Iic Compound dntroductmn : Molecular orbital E'cture
and aromatic characteristics of pyrrole; furan thiophene· ana pyridine, Methods of·

I
 6 B.Sc. Part-Ill, Syllabus I
1
synthesis· and chemical react)ons wlth particular emph.1sis on the mechanisin of 1
electrophiJic substitution. Mechanism of Nucleophilic __substi£ution reactions in-pyridine
•!
derivatives. Comparison of basicity of pyridinf?, piperidine and pyrrole.
IntrOduction lO condensed five and six membered heterocycles. Preparation and
reactions_of indole1 quinoline and iscquinoline with special reference to F~sher indole !
synthesis, Skraup syhthesis and .Bischler-Napieraiski ·synthesis. Mechanism ~of· }j
cJectrophilic substitution reactions of indOle, quinoli~e nnd isoquinoline~ . _ .i
(b) Fats, Oils and Detergents: Natural fats, edible· ancj industrial oils of vegetable
origin, common farty acids, glycerides, hydrogenation of unsaturated ·oils. 1!·'
Saponification vLi.lue, iodine valu~, f.lcid value. Soap.:; syi1thetic detergents, alkyl and aryl !I
sulphonates. · . . 11
Unit-IV : Carbohydrates : Classification and nomenclatUre. Monosacch-arides, !!
mechanism of isazoQe fornla!ion, intcrconvcrsion of glucose and fructose, chain · 1
Ienthening and chain shortening of aldoses. ConJiguratlbn of mrinosacch3rides: Eryihro :.l:'
and rhea dias'tereomers. Conversion of glucose into mannose. Formation of Glycosides,
ethers and esters. Derermination_of ring size of mouosaccharidf:s. CycliC's~ructufe of :.·,'1
D( +) glucoSe. Mechanism' of mutarotation.
Structure-ofiibose and deoxyribose.·
An introduction to disaccharides (maltose,· sucrose· and 13ctose) and U
polysaccharides (Starch and ceJJLil9se without involving structure determination}. ;..)
Unit V : Amirio Aci~ Pe(>tides, ·Protein...:;: and Nudk Acids-: Classification, i I
structure and srcreOchemistry of amino aclds. Acid·base beh~viOur, isoelectric point H
and electrophorCsis. Preparation and reactions of a·amino acids. · . .· ~i
- Structure -and nomenclature of pep_tides ·and proteins. Classification of pro~7_s; . .)1"
Pept.ide structure determination,_ and grou. p analysis, selective_.hydrolysis of peptf pes. .
Oa'>.Sical peptide synthesis, solid-phase peptide synthesis. Structures of peptides; ~nd ·
proteins. Levels of protein structure. Protein.Penarurat~on/renaturation.
N~c/ein acids : introduction. Consdtuenls of nucl~ic acids. Ribon. ucleosides--. 00. ,;
: ' ;
:-.
\:i1
ribonucleotides. The double helical structure of DNA :~· ;·
. (b) Synthetic Polymers : Addition or cbain-groMh polymerization. Free radical
vinyl pofymerization, ionic vinyl polyme~ization, Ziegle~·Narta pO!ymeiisatiCJp. an.~ Vinyl ·~,
oolvmers. · . .l
· · Condens~!Lon or step .growlh polymerization, POlyesters, Polyamides, phenol, ~ !
i''
formaldchyde_resins, urea formaldehyde resir.s, eposy resigns and pOlyurethanes.
,_·--'N--·a--t--u_r.cal_a_n--d~sy'-n--t_h_et_ic---..ru_b_b'-e_rs_.'--~---------------------, . ·! ;

~~=~ ~~3lirnl H j
M.M. : 34 ..
·,.;
Paper III: Physical Chemistry
Unit-1 : Elementary Quantum 1\-fechanics :·Black-body radiation, PJanCWs
radia. tion Jaw, photoelectric effect, heat capacity of-solids.. Bohr's model of bydroge.n
~ l
mom (no derJYation) and its defects. Compton etiect. De Broglie hypothesis the · .1 ·1
; \

Heisenberg's uncertainty principle, Schrodinger wave equation, Hamiltonian oper(;!tOr.. l ·l

Schrodinger "'ave equation and ilS importance, physical interpretation of the ''I
function; postulates of quar_1tum mechanics, particle in one dimensional~
wave.

· f-.. 1
Schrodinger wave equation of H·atom. _separ~tion into three equation (\'J'ithout l i
derivation), quantum numb~rs ·ai:Jd their importance, hydrogen like wave .functions, j i
. radial wave fu~ctions, angular wave functions. · · \
UnH-II: (a)MoleCular orbital thec:>ry: Basis ideas-<:riteria for forming M.O. from
AO., construction of M.O.'s by LCAO-H2 + ion, calCulation of enetgy levels from wave
fuOc!ions, physical picture of bonding and ami bonding wave functions,.concept ofu,_ a•,

. '
I
 i s.sc. i>ari-m,.
- Syllabus
. . ,·
1
b of -n; ;r• _orbitalsand their charactefist!cS: Hybrid or~itals:SJf.sP 3~ sp3,. ci!J~Iatiod bt
~inc coefficients of AO.'s used in lbese--hybi'"id orbitals. ·. ·"".·_~,-~_. ~.- · - · -~
r. . Introduction to;,.,Jence bond model'ofHz, cOm]iari.sori·lJfM.O. and v.·Ji. models. ·
~~~ (b) _Spectroscopy _:_ .I~frodU~'tfa:n. ~-- _EI~omagncti~-~~di~ti~n,- --~egio~ ~bL ihe_
r·of. spectrum basic feature of ·_ different- _$pectrometeisj- -statem~nt · , of -Ahi
'I . I Born-Oppenheimer approximation; cieirees of freedom. ',:-· -~ · _____ : :-__,_ -·;' .. ·_ ·
{c). RotatioDaf Spedi-um ·: Pi3t_O~ic_ mf:J.~~Ies~···Enijgy--I~~~:a.~ri~id .rotor_'· _·.
!ble- I

bil<. I ('"mH:Iassical ptiriciples), selection _niles, _spectraL intensity, dlsri:ibuiion using -

ryl
I population distributiop (MaxzweU-Bol\ZffilmJl disttibutioil) deterininati9i1 Of bond -
length, qualitative description of n_On~iigi9 rotor, ~tqpe· effe¢t.·- . ··.·... ·. ·... ·...·. ~ : ·: · ·
es, I
ain . Unit-lll: (a) Vibrntiond! Specirum_; II!f~ared spectr~t.i: EiJe~gyl.;ye~ of~impJe,_ ' - ·
ro
es,
I
I
har~onic oscillator, selection fules,:-pure;vibr~tiC;lpa_l SJ*-U:i;im,J~f~D.S.it)';_:dettrQ:iiilri.tiQn ·
of force constant and quaH~tivt; relat\~.? Ciffurq: ccinstll_nf~~~:~n_e,,~es,idea of-
:
.
of vtbrat1onal frequencies•• of dJffer::ent:~~ll..'ff:.iO~J
' . ..
gro_ups..·..: :. ...<::.;_t4:.
. • . ·- ·-
~, ·; . -
,.-.-: ·· ;: ..·;~· ~~ -:·. :-· .. ' · ~;:· ·~. -·.
_.--r . . 1 .
, . Raman Spect-rum : concept ot:_pol_~bll~!y1 Q~.re ro_til~~al an':t pur~ Jli..bf:ati6hal
l
1nd
Raman spectra· of diatb~ic wolecuJes~.~~ti?~ _r:-ul~. :_ . .· :~::~./. ···:· :/>-:._ ·:,:"'i.L~-- -~;·~- ·. _.. .-•.. ·-
(ti)' Electronic Spectrum--: C9ncept· of potentiaLenergy~curvei 1\lt'olii:inding''and
anribonding molecular oibitals~:. qUajitativ~-- d~ptjo.!:J;l-rif .·:-sCiection-.:.rm.~. ·aizd.-.:· <
n,
r
Franck-Condon.pnnciple. · • - .· · · - ··- -.·· ·"-: '• -' - ·- ·- :·--:·~ < · . <,
Qualitative description ofO', "· anc{ii, M.ci:,'th~ir ener£':1.;,;~ and th~ r~~e ·:·- - .
transitions. · ~ · · ._ · ··· .,. _·:. . · .. ·-·: :.:_: -: · :· .• :-..;;_ ~--~-:.· 0:;~:-;,~- · ~-:- ·

es. I Unit-IV : . Photochemistry·: ;Inteiacti6n of _radi3ti0~---~--~att~~,-~ir;f!b~.erlce ·

__
nd
I between thermal and -photochemical prQ!:esses.. LaW._ oC photocliernjsitY,: ~< ~
Grothus-Drapper law, Sl;!rk-fiinstOin 'Jaw_, Qualitative di!scfiption· of flucirSpeilce, -: _.. · ·
. J'hOtsphorescence, non-radiative prcic~s (ioternal-conversfoq,.-intersystem<irn$.';_l_!lg);·;.~- . ·
I quantum yield, photosensitized reaction5-ener.gy transfer p~ (simp)~ exath~). :'-_' __.-.

n
chemiluminescence, kinetics of photochemicafcombinationp[H2-Cizanc>lf.l-~- ·'· '
Urut-V : (a) Physical Properties~iuid ,Moleculat .sfructure- :'-oj)iif.ijj~cl;'ttf.:·
Polaiization ·{aausis-Mossotti, eqtiittion); orjentatiori of..df~I~ ip..~an":'-e1_c£tlic;:;ti_61d;<_·
dipole ·moment, ".induced dipole. ~Onj~pt,_ .me~uremenfiif~dipote,rm~~t~:-~.Je--~
mOment and . structure of -~Oie~Ies, '-!Jla8J:let~c :-pl:opc:ttj~s~Rara~e·ti.Sni~ ·
diamagnetism and ferromagn~tis~J?~ -_. :_, : . .. . ·._._·-_.., : :~-~ ·_ · ·:_- ·-,_.;:·"<' .. :·~-~~;;;~~-~, ::,_.,

UI (b) Solutions~ Dilute Solutio~·.and ~ig3tiv~.Pro~~-~IdCat:-a;I~;n~:-~-~: ··

;f4 ·I :u~~::~t.~ethod of expressing ~ncentrations of S()ltJ!r,

- Dihiie solution, -coU~ative.-·properti~, RaoUJ~'s-Jaw;. :r~lativ¢ loweririg:;~r~pUr··.· -·

•_<tivity a_n~ --~ty _ _ •.l!i

rs~ ' pressure, molecular weight deterffi~atiorl. "Gsmasis;._Jaw:-m~9SmG-tic pres&~¢:""a_ifdjf.i. ~-:: . -.-_ ~
'- measurement, determination·of mdiei:Ular "Weight from :osmbti~· pressure.._.F.JeV'atiori·.Of"·' · I
~
"- r.
boiimg point and depression of freezing point, Thennildynamifderf"in!c?iiof'ii:t<itrdn; · , .-, . _'[
!
I. ::.-;;:..m-. ~....,.....,,"~'"""""""""""' : ~ r ::
between molecular W(:ight arid elevation iri lxiiling•poilit-~!ld· d~I;r~i~ In;'!feeti~g :_ , · , ~
e pomLExperiniental methods of detenntmngvanous colligatll(e propert'."': .'-' -,-,,._; · .-. · _1
II
~

l
-~~. ~mt~_--<
! Practical : ,
l
~-
The duiation of practical examinatjOil.Will be of six: ~ouri. . _. '. -. ·.• '·
I -
l
 8 B.Sc. Part-Ill, Syllabus
Unit J: Inorganic .'\nalysis and Preparation i
2 2
. (i) Paper Chromatographic Separation .of Metal ions Cu +, Pb +,
2
t
Co2+, Ni +, Cd2+ ions (binai)' mixt~res only) l
+;
(ii) EDTA titrations of ea 2 +, Mg 2 Zn 2 + and Cu 2 +. :l
(iii) Determination ofha,rdnesS of water. ·1
(iv.) PreparJlion of Simple Inorganic Complexes. --l
Unit II: Organic Analys"is oi lndustriallmporta:Dce 3
(i) Separation of a simple mixture of twO organic (solid) compou~ds Sef"li
by water and dil. acids and systematic identif-qtion of the compounds. 1
(ii) Paper chromaroiraphic separatiOn of arrtino acids an_d sugarS (only -b~
mixtures) 1
Unit III: Physical Chemistry Experiments _ I
(i) Hydrolysis of methyl acetate catalysed by an acid i
(ii) Hydrolysisof ethyl acetate catalysed by an acid -~'
(iii) Absorption Of acetic acid on charcoal. · :
a
·
(iv) Heat of Solution of a substance (oxalic acid) by solubility method.
(v) Transition Temperature of Glauber•s S3lt by Thermometric methCJ:d.
(vi) Heat a( Neutralization ofNaOH and HC!. ·
.
j
Students shall be given three experiments each of two -hour duration (Inoi
experiment of 10 marks, orga_pic experiment of 15 marks, and physical experimeri'
marks, 5 marks for viva and 5 marks for records(= Total 50 marks) in the·_.,
practi~al examination. . ~ , ·. ~
1
 [2]
[ 3]

· CHEMISTRY ' Asymmctnc

· · · synt hes1s,
· · · ·1n a· bsen~e· o.f ch.tra 1.carbon
· 1 activity
. . !"'· Sc.-·:· ~Prevtous)
.. • '
.. ·
oplica
(Bipilcnyls), stereo chemist!); of corn pound containing Nitrogen.
Paper 1-Inorgamc Chemistry . . . . Unit 11-Reaction mechanism : Types 6f mechanism, types·
Un~t !-Reaction Mechanism of Transition Metal Corhp·, of reaction, methods of determining mechanism structure, Stability
!exes: Energy,profile·of,a reaction, reactivity of metal complexes, and reaction of Carbocation carbanions free radicals Carbene's, - ·
mscrt and labile complexc~:., kinetic application of valence bond Nitrenc, effect of structure on reactivity~ resonances & field effect
and cryst~l field theories, kinetics of octahedral substitution, acid Steric effect. · 1 .
hydrolySis,- factor affecting aCid hydrolysis, base hydrolysis, Unit III~Nz, SN 1 mecha~iSJn classical and nonclassical
conjugate base med1amsm, direct and indirect evidences in favour Carbo cation, Phcnoumiom, Nucleophilic·substi!Ution at an allylic,
of Conjugate Tnechanism, anation reactions, reactions without vinyllic Carbon. SF 2 , SE 1, Electwphilic Substitution accompanied
metal ligand bond dcawage, subtitUtiO_"n reactions in Square planer hy double- bqnd shift. The arcnium on mechani-sm, orientatioh
complexes,_ the trans effect, mechanism of the substitution reactivity ortho pariiratio Sn,Ar, Sn 1 Bcnzy.ne E 2 , E.
reactions. . Unit JV-Mcchanistic arid Streco chemical aspect of addition
Unit II -Metal-Ligand Bonding : Linlitation of crystal field r, •ction, involving elcctrophilcs, nucleophiles and free radicals.
theory, molecular ofbital theory, oct~hcdral, tetrahedral and square H! "'rogCnation of double bo~d _&.trip!~ bond, aromatering, Hydro
planar complexes, rr-bonding and moic.cular orhital theory. . foLiation. Mechanism of theta!· hytlrides reduction of saturated
Unit Ill-Metaln-Complexes : Meta} carbonyle, 'structure, and_ unsaturated carbonyl compounds, acid, Addition of Grignard
and bonding, vibr~ti?~al spectrri.of metal' carbonyls for bonqing reagent aCid to ~arbonyl c?!TIP~urids ~echaniSt!l o~ Al~ol,
and struc.tural elucJ~latJOn,'mlportant reactions of metal carbonyls; Knocvcn:gel Cla1ses, Manmch Ocnz01n, Pcrk1n reactiOn:
preparatiOn, bondltlg, structure and important reactions, of· HydrolySIS of est~r. .. . . _ . _ _. .
tra~sition metal nitrosyl, dinitrogen and dioxygcn complexes; Uni~ V- Type~ o_f free radicals : Fr~e radical SubstliUti~n
tert1ary phosphine as ligand. .· mcchams~; mechamsm of. an. aromatic. substrate allyl_llc
Unit IV -Met 1 Cl t • · · '- halogenation (NBS), auto bx1datwn, couphng of alkynes and
a us ers . Higher boranes, car_boran.es, anylation of aromatic cOmpound by diazonium salt. Sandmyer's
metalloboranes and m~tallocarborancs me.tal carbonyl and halide reaction. Molecular orbital Symmetry, trompier orbital of ethylene
clusters, compounds \\flth metal-metal multiple bonds. 1.3 butadiene classification of. Peri cyclic reaction Wood ward.
Unit V -Isopoly and Heteropoly Acids and salts. Hoffmann correlation diagram Fi-10 PMO approach anlerafacial
l_)aper 11-0rganic Chemistry and super facial ;;idtlition: ·
Unit !-Nature of Bondi no : Paper III-Physical Chemistry
. (a) .Delocalized Chemi~al bonding-Conjugation, cross/ Unit 1-Quan.tum Cherhi<ttry_: _ . .
conjugallon resonance, Hyber-conjugation, tautomcrson. Aromatic (a) Intr~duchon. to ~xac_t Quantum Mechamcal Results •
in benzenoid and non beriZenoid COmpounds a!t t d - The Schrodmger equatiOn ~nd the postulates of quan_tum
, ernan an non . . . . f . f h h d. · t
. ahcrnant hydrocarbOn, huckle rule, ailnulenes. mcchan~cs, D1scussto~ o sol~tlo~s o · t esc ro t~g_er. equn~IOn a
(b) Conformational analysis of cyclo alkanes dicaliries, sam~ t~odel systems vtz., particle m a box, the hamlOnJC osc!llator,
confo·rmat 1·0 n of sugars Ele n nts f S , h' 1; the ng1d rotor, the hydrogen atom.
. . ... . 1 e . o ymmetry, c tra~y . · . .- · 1 1·
molecules, with 111 Are
~,
· 1 cen 1er, Tlueo & cryt
th en one c-h nra . · ro . (b)
. Approxtmate
-. . Method. : The vanat10n
. · t1eorcm, mear
isomers metllods of resolutt' on enan 110 . . & d.tastercotoptc
· t rop1c . vanat10n pnnciple, . PerturbatiOn
. . .theory (f1rst order and non ·
:1toms Groups sterc<> spe·c··,r· & 1
. , . 1c
. · .· .
s ereo se 1ect1ve synt 11es1s · h.
degenerate). ApplicatiOn
H - t
of vanat10n method and perturbation
1 eory to 11e
1 e 1Jum a om.
 [ 5]
[ 4]
1 of Jroplets (Kelvin Equatio:1), Gibbs ·adsorption isothems,.
(c) Angular l\'lomenlum · Ord 1.,u 1y Ull"ular 1 estimation of surfaCe area (BET equation), surface films on liquids
· " c nomcntum ·· . . . . . ·
generalized a_ngular momentum, ~~ gcn functions 'for angula 1(ElectrokJ~etJc Phenornepon), ~<JtalytJC aciJvJty _at su~faces.
1
~omerll~m. etgcn v~l~es of an .gular 111 omem 4 m, Operator usint . (b) Micelles_:_ sur:ac~ actJve agents, <:Ias_?Jficau~n of su_r~ace
~adder o~erators~ at.ldt~IOJ~ of angubr momenta spin, an_tisyrnmetrfc_tlvc agents, mtce~ltzatwn, hydrophobic Jnt~ractJOn, en tical_
unu Pauh e~cluswn pnnc1ple. micellar ConcentratiOn (CMC), factors uffecung the CMC of
Unit II-Thermodynarilics: surfactants.
(a) Classical thern~o<;iyn~mics: Brief resume of concepts ol (c}'·M<l:c.lomolecules·: Polymer-definition, types of polymers,
laws ~f therm~dynanjics, free energy, chemical potential an~e~ectr.i~al1/. conductio~, f:re resistant, .liquid cryst~l po.lym.ers,
entr?p1es. Parl!al molar propert_ies, Partial mol or fret! ent!rg kme_t1cs ot. polymer.JZ<illon, .mcc~~msm of· polymensatwn.
P.an~a-~ molar volume and p~rtial mrill;lr ht:~t content and thel;scdmle~l\ali~n, cham_ con.hg:Hatw~ of n~acromoleculcs,
stg,tu_!.Jcances, De~efl~lination of their quantities. Concept oJCalculauon of a~verage <hme?swns of vanous cha~n struc:ures ..
fug~c.Jty &, detenm.natton of f.ugacily. Non ideal systems : Execs~ Unit V'-----Eiectrochenustry : Ele~trochen11~try ?f. solutwn.
funclions tor non-Jde<tl sohJttons. Activity, activity coefficients.Debye-Hucklc-Qusajer treatment & Hs extensiOn, JO:t solvent
~eb~e-~ucklc ~he~ry f~r a~t~\ity coefficient of electrOiyticintera.c~h?n: Debye-Huckl.e-Jerum mode. 'Thermodynamics of
..soluttons, detennJnallon of activlty and pctivity coefficients ionicelectnfJed mterfacc cC)uatwns. Ov_er potentw.l exchange current
strength. ' density. Semiconductor interhces-Theory of double layer at
. (b) Statistical thennod}'namics: Panition functions T a ,·_semiconductor electrolyte so1ution interface, Structure of double
tiona!, rotational, v~bnHional & clectr~nic partition fu ~· nsi. layer interface. Effect of light at semiconductor solution interface.
.,· Calc~lation of lhermodynamic properties in terms of pnactiOt_ns, PolarQgraphy theory, 11 kovic equaiion. half wave potcminl & its
. .
fu n Ct '.on, A pp I~catwns r 1 1011 . . .. . . · H '1
o~ paf(itjo 11 functions. Heat capacit s1glll 11cance. 1?troduct1o~· to cn~ros.wn, amoge.ncous/t 1eory,
?~havJour of soiJds : ·Chenucal equilibria and tLJL.iilibriunl co t y forms of corros10n, Corros10n momtonng & preventiOn methods.
111 t CJ_·ms/o f p~rt1t.wn
·· .. · nsam
tunctwn, Fermi-Dirac statistics, distdbutions Paper IV -Spectroscopy cmd diffraction methods
law and appl.wauon fomatal, B{;sc·-Einstcia Statistics-distribution Unit I -Vibrational Spectrosco-py:
law an?_ application to Helium.', ' . (A) Infrared spectroscopy : Review ·of linear harmonic
Umt .I~I~Ch~mical. Dyfl:&mics : ~ethods of determiniilo rate oscillator, vibrational eilcrgies of diatomic molecules, zero point
laws, CoJ!J.SIOn theory .o! _re~c.t~,~n _.r~tt:s, steri_c factor, acti~ated energy, force constant and bond strengths~ antiannonicity, Morse
compte~ l~:or~, ..~~r-hen~~s.:~u~tj9n_ 3nd the activated complex potential energy diagram, Vihratio_n-rctation sp.ectr~scopy: P, R 9·
~~eor~, JOllie reucuon, Km.eqc ·s~h,_effec~s. steady state kinetics, branches, lJreakdJ?wn ?f oppenheuner app~oxJmatJon, V1brauons
l~etics & thenno~ynun_Hc. C:~~l.t_rql of reactiori, treatment of of poly atomic molecules selection rules, normal modes of
um~n_olccular re~ctwn~. Dy_namic chain (hydrogen-bromine vihi'ation, group frequencic:.s, overtones, hoi' bonds, factors
reaction, P~rolys1s of actald~hyd.e decomposition of ethane), affecting the band position and intensities, for IR region, met.:!
Phot?chemJCal (hyd~q?en·~brvnune. and · hydroge_n-chloriJlc ligand vibrations, normal coordinatt; analysis.
reactwn)~ Homog~~eoUs·:·cataly~is, kinetics \if-·· enzyme reaction (B) Uaman Spectroscop:{: Classical anJ quantum theories of
general~ fe~turcs ot fast reac;:tioJl.;. I-Jach Photolysis and the nuclea; Raman effect Pure rotational vibrational and vibrational-r,)tational
magnell.c res_onance method. · ., Raman £pt:clra, sele.uion rule.s., mutual exclusion princ'tple,
Umt IV =-Surface Chemistry: · . Resonance Raman speclroscopy, Coherent anti stokes Raman
(a) Adsorp~ion -:_ S~~_facc- tensiou, capill:iry i;i.Ction, pressure -Ji sp~ctroscopy (CARS). . .. ;~ .-:
h_erence across curved surf<fe (Laplace cquatio':) vapour press•·
 ·-·---·-··· . --~ ·-·-- --··

[ 6] 171
Unit II-Eiectrunic Spectroscopy : [\ M. Sc. (Previous) Chemistry
(A) Ator:nic Spectroscopy: Energies of atomic orbitals, vecto~ Practical
represe_ntation qf momenta and vectOr cat,Jpling, spectra of: Iilorganic Chemistry: ·. .
hydrogef1 atom anQ alka~i i:}toms. · · . :A Qualitative and Quantiladvc Analy-sis:
(B) Molecular Spectroscopy.: Energy levels, molccuia/ (a) Less common ,,,etal ions-TI.IJ.1o, W, Ti, Zr, Th, Y, U
1
orbitals, vibronic· transitiOns,_ vibrational progressions and; (two metal ions in CaUoi:HCia~IOnJC fonn~)- · _
geometry of the e~citeP stateS ·Fra·nk-Coridory prin_ciple;_ electr~mic\ {b) Separation rind dctennination of two m_etal io,ns ~u-N_l,
spectrz of poly atomic ~olecules, E~ission spectra, radiative and~ Ni-Zn, Cu-Fe, etc:, involving volumetnc & gravnnctnc
non-radiatiVe decay, intCrn~l conversi?n spectra of transition r:netal 1

methods. ·
1
complexes, charge, transfer spectra. ! B. Chramatography :
Unit Ill-Magnetic Resonance Spcctro.scopy: \ Separation of Cations and· Anions by Paper
, (A) Nucl~ar MDgnetic resonance sp"ectroscopy : Nuclear: . chromatography.
spin, nuclc~r re.Sbi1aJ~~e. S_lil~_r_ation; S_hielding of magnetic nuclei~ C. Preparations . : .
chemical shifl and .its meas':lre.ments, factor· influencing chemical: Preparation of Selected· inorganic Compounds hke :
shift, deshielding, spin-spin !inte'ra<;tions, factors influencing; 1. K [Fe(C,04 )6 j 2. [Ni(NH 3 ),]CJ,
coupling cons~ant 'J' classification (ABX, AMX, ABC, A 2 B 2_. etc.)!
.~r·

3 _ N: (dmg), 4. [Cu(NH 1 )4 ]S04 .H 2 0

Spm dccouphng, baSic 1.dcas about mstrument, NMR studtcs of' [C0 (NH ) I [CO(NO ) 1 6. ·rr~ssian Blue
5 3 6 2 6
nuclei other than proton 13 c. 19F .and 31 p, Fl' NMR advantages of ·. • ,
FT NMR use of MNR in h1Cdical diaonostics 0
' Orgamc Chemistry : · fi-
. • •. · . · • . • A. Qualitative Analysis : · · ··' · . ·
(B) Electron ·'PI" Resonance spectroscopy : Baste . P 'fi · · · d ·d t'fication of compounds of
. . r· I .I 0

pnnc1plcs, zero 1e d sp ettmg f!.rL

'd K 0 d f
ramer s egeneracy, actors
Sl'paratJOn UTI !CaliOn an I en I
b" . ' · (T s· -d )
.
·· • .~ · 1 '"· · · d : · mary mixture wo o 11 s
a ffecttng the g va ue. Isotropic an · anisotropic hyper fine . ..
coupling constan!s<Sp_in Hainlltonian spin "densitieS and Me B. Orgamc .syntheSIS:
1
. r r ··d "th a ctyl
Caunell relationship 1 me.·~suremcnt icchnique, .. application. Acct~latiO~ : A~etylauon ~f. Sa ICY~ 1 ~ act '. wit .· cf p
• . . ·. · . . • . • . • • • : chlonde, Aromat 1c Electrophthc substJtutton-Synt 1es1s o -
Umt IV -X-ray D!ffractJ~:m.: Bragg condttlon, Mtllermd1ccs, '. nitro~ni"line and P-bromoaniline from aniline.
Lane method, Bragg method, Dehye-Scherrer method of X-ray, Aldol Condensation : Dibcnzal acetone from benzaldehyde.
str~ctural analysiS of cry~t~l,s tn~c~ _refl~ctl0.11, Ide~tdicaoun of: sandmeyer. reaction : P-chlorotolucne from. P-~?ludtne.
unll cells frm_n systematic· absences ·tn d1ffractwn. pattern.. Cannizzaro reaction : Benzyl alcohol &_.Denzotc acJd, from
Structl:Jre of simple lattices and x~r~y i"ntensitics structure factor Benzaldehyde. . . . .
and its relation ·w)ntensity and elec~ron.deitsity, phaSe probl~m. Friedel Crafts recation : p-Benzoyl propionic acid from
Description of the procedure for an,· X~ray strucllire analysis, succinic anhydride and benzene. ··'; ·
absotUte configuration of molecule~·! Ramchti~dran diagram.. "Qrign3rd reaction : Synthesis of triphenyl methanol from
Unit Y_.-Eiect.ron Diffractioil :· · Sc~ttering intensity vs. 1 ben.z9i~ acid. . . .
Scauering angie •. Wi¢rl .euati"on · mcas'Ufemerft techniqUes,.\ .c. Quantitative Anall:'sis: .
elucidati.on of" strutturc of simple gas· Phase 1'nol·e·cules, Low 1' (a) Detennination of ~he percentage or numb~r of hy~roxyl
· · · · ·· l ps ·,n art organic compound by acetylatiOn method .
.-\'crgy elect rOil ~~~fractiOn and stJ~UCht_re of surface~. gro 1 .
 [ 8] [91

(b) Estimation of aminestrlh:.a£'.ts using b'romate bromide , Unit IU-(i) Metal ions in Riologica) Systems Essential and
solution/or ·acetylation method. trice m'etals ·
· Physical Chemistry : (ii) N~+/K"'" Pump Role of metal ions in biological process.
Each experiment will be of 3-4 hours duration. (iii). Transport and Storage of Dioxygen. Heme Proteins and
I. To Study surface 'cnsion-~once.ntration re_lationship for oxygen. uptake, structure and. fur.Ction of i-Iaemoglohin,
solution (Gibbs equation) myoglobins, _Hemocyanins and hemeryihrin, model synthetic
2. Determination of the effect of (a) change of temperature (b) ' complexes of irons Coball Copper.
change of concentration·of reactant & c'atalyst on the velocity Unit- (i) Bioenergetics and ATP cycle : DNA
constant of hydrol'ysis of an .ester/ionic reaction. Polymerisation, Glucose storage, metal compleXes in transmission
· 3. DetCrrry.ination of the velocity constant of hydrol)'sis. of an of energy chlorophylls. Photosystem I and Photosystem II in
ester/iOnic reaction in micellar media. cle<ivage of water. Model system.
4. Dct!!rmination of molecular weight of non-variable and. non- (ii) Electron transfer in Biology' : Structure and function in
electrolyte/electrolyte by. cryscopic method ~ to d~tennine the metalloproteins in electron transport procr;::sscs-cytochromes and
activity coefficients of an electrolyte. ion-sulphur proteins, synthetic models.
5. Determinati011 of Solubility & Solubility product of sparing (iii) Nitrogenase : Biological nitrogen fixation, molybdenum
soluble sails (~.g. PbS0 4 , BaS0 4 ) conductometrically. infrogenase, spectroscopic and other evidence, other nitrogenases
6. Detennination of the strength of strong and weak .acids in a 1

model systems.
given mixture conductometdcully. Unit V -(i} Soils : Composition, mjcro and macro nutrients
7.. Determination of the strength of stroQg. and weak aciJ In a P,1\lution-Fertilizcrs, pesticides, plastics and metals. Waste
given mixture using a potentiometer/pH meter. Treatment.
8. Determiuation of rate constant 'for hydrolysis/inversion of (ii) Hydrosphere : Chemical composition of water hodies.-
sugar using a polarimeter. Jakes, streams, rivers and wet land etc. Hydrological cycle Aquatic
9. Acid· base Titration in a non· aqueous media using a pH meter. pollution-inorganic, orgnnic Pesticide, agricultural, industrial and
sewage detergents, oil spills and oil pollutants. Water quality
CHEMISTRY parameters-dissolved oxygen, biochemical Oxygen demand,
M. Sc. (Final) solids, metals, content of chloride, sulphate, Phosphate, intrate and
Paper I -Inorganic General micro organisms, water quality standards. Purification anll
Unit I -Vibrational Spectroscopy: Symmetry_·and shapes of treatment of water.
AB 2 , AB 3 , AB 4 , AB 5 and AB 6 mode of bonding of ambidentate P~per 11-0rganic General

.. ligands, ethylenediamine and diketonato complexes, application of Unif 1---,0pticnl Rotatory Dispersion (ORD) and circular
resonance Raman Spc~.:troscopy partricularly for the study of active Dichroism (CD) Definition, dcducation of abso_lutc configuration
sit~s of metalloproteinf!. octal rule for "ketOne. Mass Spectr('rnetry-lntroduction-
Unit II- Nuclear l\1~gnetic. Resonance of Paramegnctic. Fragmentation, Molecular ion peak, metastnble peak, Nitrogen
Sub.Stanccs in Solution .: The contact and pseudo contact shifts. rule. High resolution mass Spectral fragmentation of organic
factors ~ffecting nuclear rclnxation, some applicatiom including compound with respect to their structure determination.
hichcrnical systems, an overview of NMR of metal nudides with Unit II-N.rvt.R. : Introduction, definition; Chemical Shift,
emphasis on Pt 19 .'i and Sn l.'i9 NMR. Spin-Spin Interaction. Shielding Mechanism. Mechanism _of
 [ 10 l
I [11)

measurement Chemical Shift .value and .correlation 'for proton ! structure of metals, bat'11· theory, intrinsic ~nd extrinsic
bonded to Carbon (Aiphntic, Aromatic) and other nuclear (Alcohol semicOnductors, doping. semiconductor, p-n junction, super
PhCnol), Carbolic acid, amine, effect of deuferation complex spin~ conct~'etors Optical properties. Optical rcflectftnce.
spin interaction between two three nuclei. Carbon 13 NMR Photocon.duction-photoelcctric· effects,· Magnetic Properties-
Spectroscopy'lntroduction, cosy, Nocsy- Technique chemical s·hift Classification of materials, Qu~ntum thc.ory of ·Paramagnetics-
. aliphatic, obfinic, alkyne, Aromatic, Carbonyl Carbon. Coopcrative;Phcnomena. MagnetiC domains: hyst~risins.
Unit Ill-Photo Chemistry :· Type of excitation, fate of Unit III-,- Thermodynamics of ·Biopolymer Solutions : .
excited mole, types of Photo Chemical reaction Photo dission gas Thermodynamics of. biopolymer solutions, osmotic pressure,
Photolysis, Intramolecular reactions of ·OJifinic bond intra membrane equilibrium·, muscular contraction and energy
molecular •Nction of Carbonyl Compounds-Saturated Cyclic, .a~ generation in meciianochernical system.
Unsaturat compounds. intra mOlecular cyclo addition reaction- Biopolymer's and their Molecular Weights : Evaluation of
dinerisahan Isomerisation addition and Substitution. size, shape, molecular wilght. and extent of hydration of
Unit IV-::::::-- Enzyene : Introduction : Noinenclaluse & biopolymer.s by various experimental techniques, sedimentation
Classification. Fischer lock and key; Kosi and and Induced equilibrium, hydrodyryamic methods; diffusiOn, sedimentation
hypothesis; Trari.sitio,n State theOry, acid bllse catalysis, covalent velocity, Viscosity, electrophoresis and rotational motions.
catalysis,- Nucleo-philic displacement on Phosphorus atom, Diffraction Methods Light Scattering, low angle X-ray
n~ultiplc di_splacernent reaction and the coupling of ATP, cleave to scattering, X-ray deffraction and photo corclation spectrosCopy,
endergonic Proc.csses, Addition and Elimination reaction Enzyme ORD ..
Catalyzed Carboxylation & Decarboxylation. Unit IV-Bioenergetics : Standard tree energy change in
Unit V-Coenzymes, Apoenzyne, Structure & BiologiCal biochemical reactions, cxcrgonic endergonic, Hydrolysis·of ATP;
Function o.f coenzymes, production, Purification of e.nzyme, Synthesis of ATP from ADP. Statistical Mechanics in
method of Immobilization of enzyme effect of immobilizatiml' on Biopolymers : Chain configunt\ion of macromofecules, statistical
enzyme activity. Application of Immobilized Engyrne, Clinical use distribution end ·to . end dimension, calodation of average
of Enzyme, Disposal of Wastes ·and their management, .. dimension for various chain structures, Polypeptide and protein
Biodegradability, Chemical Solution to environmental Problem. structureS, introduction to protein folding problein.
Paper III-Physical General Cell Membrane and Transport of Ions : Structure and
Unit 1-Solid Slate Reaclions: General Principles, cxperi- functions of cell mernbrrine, ion transport ·through cell membrane,
.rnental procedures. co-precipitatio1,1 as a precu.Ssor to solid state irreversible thermOdynamic treatment of lnembrane .transport,
reactions, kinetics of solid state reactions. Crystal defects an_d Non-
Nerve conduction.
Stoichiometry. Perfect and imperfect crystals, Intrinsic and
Unit V ~Organic Solids : Electrically conducting solids,
extrinsic defects-point defects, line and plante ·defects, vac3ncics~
Schollky defects and Frenked defects, Thermodynamics of . organic charge ··transfer complex, organic metals, new super
Schottky & Frenkel defect formation, colour centres, non coductors.·
stoichiometry and defects. Biological Cell and its constituents : Biopolymer Interactions : Forces involved in biopolymer
Biological cells structure and functions of proteins; enz.ymes, DNA interactions, electrostatic charges and molecular expqnsion,
and RNA in living systems, Helix·coil Transitions. h)'drOphobiC forces, Jispeision force interaction. Multiple
Unit II -Electronic Properties and Band Theory : Metals, ~·-1uilibrias and .va.rious types of building processes in biologic;:ll
insulators and semicon..Juctors, electronic structure of solids, band .yste\ms·, Hydrogen ion titfnrion cur\'CS.
 ( 12]

Paper IV (i)-Inorganic Chemistry (Special) ( 13]

Unit l-(i) Transiti(m metul n:-compJexes: Transition rn~1al
n-complexes with unsata,JrateJ·organic molecules, alkenes, illkynes, Unit .III-St<,•oids : Occurence, nomonclature, diels
allyl, dienc, dienyl, arene and trienyl complexes, preparations, hydrocarbon siructlm.. determination of cholesterol, Androsterone.
properti~s. nature of bonding and structural features. Important Testosterone, Progest )ne,'Biosymhesis of steroid.
reactions relaring to nucleoPhilic and cle'ctrophilic attack on UnJt IV:P1ant :.<~igment: Occurence nomenclature. Isolation
ligands and to organic synthesis. · strucwre determin-ttion of· querc_etin, Cyanidil'!. Hirsutidin,
(i_i) Transitipn me1al compounds with Bqnt.ls to Hydrogen. Auceusin, Dio synthesis of flavonoid. Structure of Hflemoglobin
Uqit Jl-(i) ·Metal storage Transport anJ lliomincralis:.•rion and ('ltiorophyll.
Ferritin, Transferrin and siderophores. tl!,it' V-AntiLiotics ~ P-lactamring, st~ucture & syrithesis of
(ii) Calcium in Biology : Ca!.:ium in living celis, Tr:-msport Peni~iliin' G. Penicillin V, Ampicillin, amoxycillin Chloram-
. itnd regula'tion! molecu.Jar aspects of intramolcculbr processes, pher.i(:IJid, Tetracyclin and Streptomycin.
extJ:acellular binding prOieins. Paper IV (iii}--Physical Chemistry (Special)
llnit 111-MetaJioenzJme,s : ZinC enzymes-Carboxypq?ti~­ Unit 1- Thin Films and Langmuir-Blodgett Films : ·
dase and carbonic Lillhyllruse, Iron enzyme.s--c'at<~lase, .pcn)xiJasc" Preparatibn tech1_1iques, e_vaporation/sputtering, chemical··
and cytochrome P-450. Copper cnzymes-superoxide JiSJilutasc processes, MOCVD, Sol-gel, etc. Langmuir-Biodgell (LB) films,
molybdenum oxatransferase enzymes-xanthine oxidase. Coenzyme growth techniques, Photolithography, properties and application of·
vitar~1in B 12 . , thin .1:· LB films.
Unit IV-(i) Meal Nucleic Acid liit~ractions ; Mctn/ 1ons Liquid CrystaJs ·: Mesmorphic behaviour, thermotropic liquid
and metal ~omplex interaction metal complexes-nucleic acids. crysrals, positional order, bond orientational order, nematic and
(ii) lVIetal in L\1edicine : Metal deficiency and diseas~. ~oxic smetic me.sophates, smetic-nematic, transition and clearing
effects of metals, metals used for diagnosis and chemotherapy with temJ)t;rature, homeotropic, planar and schlieren tex.iufes, twiste'd
panicular reference to anticancer drug~. nematics·, c:hiral nematics, molt:cular arrangement in smctic A and
Unit V -Excited states of Metal Complexes : Excited sr;:Hes SI;Jletk C phases, Optical properties of li(Juid ci-ystals, Dielectric
of metal cOmplexes : comparisori with organjc compounds, susceptibility and dielectric constants. Lyotropic Phases and their
electronically excited states of nwtal complexes, dmrge-trar,sfer description of orderit:t£ in liquid crystiils. ·
spectra, change transt(:r exci!_ations, methods for obtaining charge- Unit 11-Pol)'meric Materials·: Molecular shupe, structure
tra·nsfer spectra. anl~ configuration, crystalinity, stress-strain behaviour~ thermal

Unit IV (H)-Organic Chemistry (Special) : Terpcnuid & behaviour, polymer types and their application, conducting and
Carotenoid : feno-clcctric polymers.
Unit 1-Chis·sificat-ion, nomenclature occurance., IsohHio!l, . Ionic Conductors : Types of ionic conductors, mechanism of
Isoprene rule structure ,dtffen_nination of citra!, a-tepeneol, ?.ingi ionic, .conduction, iriterstitial jumps (Frel)kel); Vacancy,.
berene,. P-carotene, Biosynthesis of terpene. mechanism, diffusion superionic·conductf,lr, phase tr<:insitions and
1
mechan ism of conduclion in super ionic conductors, examples and
Unit II-Alkaloid : Definition, nomerwlaiu.:~e- nnd physio-
applkation of Ionic -conductors. · .
logical action-;· ocCurrence· Isolation; clas;-;ification b~1s~d 011
Nitrogen hetrotyclic ring stn,lcture of Nicotine, Atropine, Quinine Uitit Iil-llleor~tical arid computational treatrrlen.t of atoms
and Morphine. Biosynthesis of Albdoid. and molecules, Hartree-Fock theory. Review of the principles of
quantum mechanics., Born-oppen-heimer approximation, Staler.
Condon rules. Hartree Fock equation, Koopmans and Brilloning
\
theorie:;, Roothan equatiO!l, Gaussian bu,sis sets.
 r t4J i.
r1sJ
·,
Unit IV -General Properties of Liquids : (v) Reduction of Ethyl ACetoacetate using Baker yeast to
(a) Liquids as dense gases, liquids as disordered solids, some Yield enantiomeri~ cxcen of e~hyl-3 hydroxy butanoate.
thermodynamic relation, internal pressures ami its significance in 3. Extraction.·of organic ~ompounds, from natural sources:
liquids. Equation of state, critical constants. Different types of (i) Isolation of caffeine fror.n tea·leaves.
intermolecular forces in liqUids, different potential function for (ii) Isolation of casein from milk.
liquids, additivity of pair potential approximation. (iii) Isolation of Lactose from milk.
(b) A classical paftitiqn function for liquids, correspondence (iv) Isolation of Nicotinc-Di-Picrate from Tobacco.
principle, configi1rati9n integral, Configuration properties. (v) Isolation of Lycopene fromotomatoes.
Unit V --.Polymer l,rocessing: Plastic, elastomers and fibres, (vi) Isolation of Bcarotene from carrot.
compounding. Processing techniques. Calendering dil! casting, 4. Paper Chromatography : Separation and identification of·
rotational caSting, filri1 casting, inj!!ction moulding, Blow sugars Present in mixture of glucose, Fructose, Sucrose by
moulding, ex·trusion moulding, thermoforming, foaming, Paper chromatography and determination of RF values.
reinforci~g and fibre spinning.
5. Spectra PhOto!Tietric estimation :
M.Sc. (Final) Inorganic Chemistry Practic.al
(i) Amino acid (ii) Carbohydrale (iii) Ascorbic Acid (iv)
I. Flame Photometric Determinations. Aspirin (v) Caffeine.
(a) Sodium and Potassium when present together.
M.>!ic. (Final) Physical Chemistry
(b) Li/Ca!Ba/Sr
(c) Cd and Mg in tap water. PRACTICAL
2. Spectrophotometric Dctenninations. Number of hours for each exper)ment 3-4 hours.
(a) Fluoride/Nitrite/Phosphate A list of experiment under different heildings nrc given below.
. (b) Copper-Ethylenediamine complex; slope ration rnethod. Typcinl experiments are to be selected from ench type .
3. Chroma~ographic Separations. · Thermodynamics
. (a) Cd and Zn (i) Determination of partial molar volume of solute {t.c·•
(b) Zn and Mg KCI) and solvent inn binary mixture.
(c) Thin-layer chromatography (ii) Determination of the tempcr<!.ture dependence of the
Separation of Ni, Mn, Co & Zn Determination of Rf solubility of a compound m two solvents having similar
values. intermclecular interaction (henzoic acid in water & in·
M.Sc. (Final) Organic Cluimistry DMSO water mixture) and calculate the partial molar heat
PRACTICAL of solution.
1. Separation and indentification of Components of mixture of Spectroscopy :
three organic compounds. (i) Detemiination of vka vf an indicah.. r (e.g. Methyl red)' in
~- Multi step Synthesis of organic compounds. (a) aqueous and(b) micellar media. I
· (i) Benzene-Buzophenone-Benzopheri one o.xi·mc Benzilide. (ii) Determination of stoichiometr'y anci Stability_ constant.of
(ii) Benzaldehyde-·Benzoin-Benzil-Bcnzili~ Acid.· inorganic (e.g. ferric-salicylin acid) and organic ceg.
(iii) Skramp Sy.nthcsis-Bepar~tion of quinoline from anilenc. amine i_odine) complexes.
(iv) Fischer-Indole Synthesis-Preparation of 2 Phenylindolc {iii) Characterisation of the complexes· by electronic and IR
! f~nrn Phenylhydrozine. Spectral Da~a. · !
 [ 16]

Polarography.: . · . . ...
· (i) Estimation o(Pb 2 +-~nd .C~f2+iZn 2 + and-Ni~+ ions in a
mixture· of P.b 2+ a!Jd Cd 2+fZn 2+ and Ni 2+ bY Polarography.·
(ii) Detennination o(dissolved oxygen in aqueous sqlutiori of
organic solvents:-_;,-:·
Eh!ct.-Onics : · ·
(i) Measurements of resistance with muJtimetcr.
(ii) To measure the resistance of the given ammeter.. . . . .
(iii) Use of a wheatstone bridge for accuraiemeasuremcnt of· ·
resistance.
(iv) Capacito~ as a ~harge storage device. ·
(v) Verification of Kirchoff's Laws.
(vi) Measuremen-t of c.in.f. with thermocouples.
(vii) To plot the characteristic curve of a· diode.
(viii) Sctti1~g up Of a th~rmostat : c·onStaPt'terTip-erature both. ·
Op~"'tional Amplifiers : · . . .. ·
Ideal · characteristicS, inverter, ·sLimmer, integrator·,
II
differentiator Volu~ge follo'wreS' illust~~lliVc Usc of operational I i
. amplifiets. 'Introduction to' fourier tr_ansfoim in instrumentatimL
Active C_omponents· : . .. . . i i
· Introduction to ordinary diodes & Zener ..diodes _with some·
empha~is on p-n junction as a solid state.property_, use. .of diodes as .i
rectifiers, clipping and clamping circuits, power s·uPPties .\I,
Transistors. An extension of p~n junction . to p-n-p and n-p-n
Transistors. Charcteri_sti~s ·of tr_ansistors, hybfid par~mcter,
transistor ·circuits as amplifiers, J:tigh impedance (pre amplifier)
circuits, Darlinction pairs, differential amplifiers. .
Basic Electronics :
Notation used in an electric circ~it, study of electronic
cOmponents & co\o!Jr coqes, conversion of chemical quantities I
I
I
'
into electrical q·uantities, .Transdu¢cr, illustration with ·eleCtrodes, I
them10Couples & thennistors. · ·
Passive components,· Resistors·, Capacitors & inductors yvith I
some emphaSis on solid s~ate prOpertieS-of materials. Net works of
resistors. The venin's theorem, ·sup7rposit!on theoreJD, IO<;JP
anlaysis, R.C. circuits, L.R. circuits, UCR circllits .. IIIustration of I
i
I
the use· -of the c-ircuits, in NQR :..spectr9s·~opy, Mosbauer .;
spectroscopy, cyclic Voltametry and in power sup·plies·.as filter I
circuits. i'
....
. ------ .. --·--l
 SYLLABUS

B.TECH.- FIRST SEMESTER

physics(common to all branches}

UNIT-1

Energy bands in solids, Semiconductors- insulators and conductors on the basis of energy bands,
types of semiconductors, Doping, P type and N type semiconductors, P-N junction, Characteristics of
a P-N junction diodes.

UNIT-2

-7 Heat transfer- conduction, convection and radiation, Pressure, viscosity, surface tension.

-7Eiements of communication system, Band width, different type of propagation of e.m. waves.

UNIT-3

Electric current, Flow of electric charge in metallic conductor, OHM'S law,Eiectrical resistance, V-1
Characteristics, Resistors,lnductors, Capacitor, Conductor-semiconductor and insulator, Electric
potential and e.m.f., capacitance of a parallel plate capacitor,energy stored in a capacitor, carbon
resistors with colour code,series and parallel combinations of resistors and capacitors, power.

UNIT-4

Need of measurement, Fundamental and derived units,System of units, S.l. Units, Abbreviations in
powers of ten, Errors in measurement, Significant figures, Dimensions of physical quantities.

UNIT-S

Newton's first law of motion(inertia), Newton's second law of motion and momentum, Friction,
Circular motion, Motion of vehicle on levelled circular road and banked road, centripetal and
centrifugal forces.
 SYLLABUS

DIPLOMA- FIRST SEMESTER

physics( common to all branches)

UNIT-1

Need of measurement, Fundamental and derived units,System of units, 5.1. Units, Abbreviations in powers of
ten, Errors in measurement, Significant figures, Dimensions of physical quantities.

UNIT-2

Electric current, Flow of electric charge in metallic conductor, OHM'S law, Electrical resistance, V-1
Characteristics, Resistors, Inductors, Capacitor, Conductor-semiconductor and insulator, Electric potential and
e.m.f., capacitance of a parallel plate capacitor, energy stored in a capacitor, carbon resistors with colour
code,series and parallel combinations of resistors and capacitors, power.

UNIT-3

Newton's first law of motion( inertia), Newton's second law of motion and momentum, Frictiori, Circular
motion, Motion of vehicle on levelled circular road and banked road, centripetal and centrifugal forces.

UNIT-4

Energy bands in solids, Semiconductors- insulators and conductors on the basis of energy bands, types of
semiconductors, Doping, P type and N type semiconductors, P-N junction, Characteristics of a P-N junction
diodes.

UNIT-S

-7 Heat transfer- conduction, convection and radiation. Pressure, viscosity, surface tension.

-?Elements of communication system, Band width, different type of propagation of e.m. waves.
,.

S. No. Chflpters Pages

1.01 Introduction 1.0]

1.02 Particle Confined in One-Dimensional Box 1:02
1.03 Particle Confined in Three-Dimensional Box 1.03
1.04 Energy Eigen Values 1.06
1.05 Quantum Mechanical Tunneling 1.08
1.06 a-Decay: Confirmation of Quantum Mechanical Tunneling "I .13
i .07 Sommerfield's Free Electron Gas Model 1.14
1.08 Fermi Energy of a Metal 1.17
1.09 Band Theory of Solids 1.19
1.10 Kronig-Penney Model 1.20
1.11 Band Theory Predictions of Conductor,
Insulators and Semiconductor 1.23
1.12 Effective Mass 1.24
• Solved Examples 1.26
• Questions and Numerical Problems 1.35

2.01 Emission of Light 2.01

2.02 . Spontaneous and Stimulated Emission 2.02
2.03 Theory of Laser : Einstein's Coefficients 2.03
2.04 Essential Components of a Laser 2.07
 I
( ii )·

2.05 Properties of Laser 2.08

2.06 Threshold Conditim\ for Laser Action 208 ··-:
"'
2.07 Helium-Neon Laser 2.10
2.08 Semi-Conductor Laser 2.LI
I
2.09 Q-Switching 2.12
2.10 Mode-Locking 2.13
2.11 Application of Laser 2.14
2.12 Difference between Photography and Holography 2.15
2.13 Theory of Holography: 2.15
2.14 Holographic Laboratory 2.18
2.15 Applications of Holography 2.18
o Solved Examples 2.19
o Questions and Numerical Problems 2.20

'·
.• _f'
: '~ "; _- - ;
•
3.0 I Introduction
. 3.02 Coherence
3.03 Interference as a Measure of Coherence
• 3.04 Temporal Coi;crence as a Spectral Purity
3.05 Spatial Coherence and Size of the Source
3.06 Optical Fibre
3.07 fypes of Optical Fibre
3.08 Numerical Aperture and Maximum Angle of Acceptance
3.09 Applications of Optical Fibres
o Solved Examples

o· • Questions and Numerical Problems

4.01 Nuclear Radiation

4.02 Gas Filled Detectors: General Consideration
 (iii)

4.03 Construction, Working and Properties oflonization Chamber 4.05

4.04 Construction, Working and Properties of Proportional Counter 4.06
4.05 Construction, Working and P~opertics ofG.M .. Counter 4.07
4.06 Construction, Working and Properties of Scintillation Counter 4.09
4.07 Dielectrics Versus Conductors 4.12
4.08 Dielectric Polarization and Breakdown 4.13
2.14 4.09 Measurement of Dielectric Constant 4.16

2.15 4. I 0 Application ofDielectrics 4.19

2. I 5 • Solved Examples 4.19

2.18 • Questions and Numerical Problems 4.27

5.01 Scalar and Vector Fields 5.01

H 5.02 Gradient of Scalar Field 5.02
5.03 Divergence of Vector Field 5.03
5.04 Curl of Vector Field 5.03
. 5.05 Gauss's and Stoke's Theorems ofVectorc 5.04
5.06 Maxwell's Equations 5.04
5.07 Gauss's Law in Electricity 5.04
5.08 Gauss's Law in Magnetism 5.05
5.09 Faraday-Lenz's Laws of Electromagnetism 5.05
5.10 Ampere's Law and Maxwell's Moditication 5.06
5.11 Wave Equations andTheir Solutions 5.08
n
5.12 Plane Electromagnetic Waves 5.10
5.13 Poynting Vector and Energy Flow 5.12
5.14 The Boundary Conditions 5.14
ems
• Solved Examples 5.15
• Questions and Numerical Problems 5.23
(• Experiments [- 10 ............................................................ 1-68
··:- Glossary............................................................................. i- vi
•!• Appendix........................ ........................ ......................... i- v
 SYLLABUS
f4PEI(-J_

(PHYSICS) B.SC.-1

UNIT-1

Mechanics of single and systems of particles, conservation laws of

linearmomentum, angular momentum and mechanical energy, centre of mass
and equation of motion, degree of freedom.

UNIT-2

Generalised coordinates, displacement, velocity, acceleration, momentum,

force and potential. Hamilton's variation principle, Lagrange's equation of
motion from Hamilton principle,Linear harmonic oscillator, simple pendulum,
atwood's machine.

UNIT-3

Rotation of rigid body. Moment of inertia, torque, angular momentum, kinetic

energy of rotation, theorems of moment of inertia( qualitative idea),moment
of inertia of- solid sphere,hollow sphere, spherical shell, solid cylinder, hollow
cylinder, and solid bar of rectangular cross section. Acceleration of a body
rollingdown on an inclined plane.

UNIT-4 Motion and rest,

Frame of reference( inertial and non inertiai),Galilion transformations and
invariations of newtons laws,centripetal and centrifugal forces,
transformations of displacement, velocity and acceleration bet. Different frame
of refrences.

UNIT-S

Zeroth law of thermodynamics,First law of thermodynamics, work done by and

on the system,carnot cycle and its efficiency,carnot theorem and second law of
thermodynamics, practical cycles used in interna combustion engines, third
law of thermodynamics.
r

I
!
J·
I
i
..
PAPER II (THEORY)
I
1
I t •
It I /
i \I• I1I '.l11 1\}~.'•il
l
{J
•. ~
~IJ
1
l
J.l l I
1
l

UNITJ .·
Electrostatic Fieid. Vector Caieulus-gradient, divergence and Curl of
a Vector (Cartesian co-ordinates) and their physical significance, Gauss's
Theorem, Stoke's Theorem, derivation of field Jrom I
potential as gradient,.
derivation of Laplace and Poisson equations. EH:ctric flux density, Gauss's
law and its application to a sphericaJ shell, unifonnly charged infinite plane
and unfonnly straight wire, mechanicalforce of charged surface, Energy per
unit Volume.
UNIT II ....... ,.
Electric Field in Dielectrics
I ...., ....,
I Three Electric Vector, Polarisation Vector P, Displacement Vector D and
__,
Electric intensity Vector E, and their srelation, .
-7 -; ~

D =e E + P.
0
=
Electric susceptibility and relaiton K 1 +X· Gauss's Law for dielectric,
energy stored in dre!ectrics.
i Steady Current. Electric current and current density, equation of
I
I . __, .
I
continuity Div. J + dp!dt =0, Resistivity and electrical conductivity, Micro-
1
__,
. . .

scopic form of Ohm Law J =Ecr, magnetic induction, magnetic flux, solenoidal
II
nature of Vector field of induction. Properties of B,
__, __, ......
! (i) lJ. .B :: p (i i) Ll X B =11/·

'
I
UNIT ill
l'
Magnetic Properties of Matter. Behaviour of various substances in
l:
'· J_
l
magnetic field. Magnetic permeability (11) Susceptibility (X), Intensity of
magnetisation (I) andtheir relations. Magnetic shell; its strength, potential of
a magnetic shell (infinite planes spherical) at a point. Electronic theory of dia
and para magnetisation curve, Hysteresis loss, Magnetic circuits, comparison
of magnetic and electrical circuits.
UNIT IV
I Electromagnetic Ind!Jction. Calculation of self-inductance of a long·
• solenoid. Calculation of mutual inductance of two solenoids, Energy stored in
4 . •
i
I
I

.i
I
 Unit! : Fowier Series and FourierTransfonns: Fourier analysis of com-
plex wave and its application for the ~olution of triangular, and
rectangular waves, half and full wave rectifier outputs, Fourier
transforms, Fourier u-ansforms of
2
(i)f(x) =e-x /2 (ii)j(x) 1,1 xI< a
0,/xl>a
Unit II : Matrix MethOds in l'aQxial optics :. Effect of translation and
refraction. Derivation of tltin lens and rttick lens fminulae. uiut
plane, nodal planes, system of tltin lenses. Aberrations: Cluomatic,
sphe1ica I, coma, astigmatism and distonion and their removal
Unit Ill : lnte1ference by Division of Wavefront : Fresnel bipristn and its
applications to detrmination ·of 1.. of sodium light and thickness of
a mica sheet. Lloyd rrlirror, phase dunge on retlectiotJ.
Interference by Division of Amplitude : Colour of tltin films,
wedge shaped fihn, Newton· s rings.
lntelfcrrometers: Michelson's interferometer and its applications ·
to (i) standardisation of a meter Iii) detcnnination of 14.
Unit IV: Flesnel Diffraction : Fresnel's half period zones, zone plate,
diffraction at a straight edge, rectangular slit and circular apc1ature.
Friwnhofferdiffraction: Singleslitdifti-Jction, Two slit diffraction,
N-slit diffraction, plane transmission grating spectrum, Dispersive
power ofgrating. Limit of resolution, Rayleigh 'scriterion, Resolv-
ing power of teleSj:Ope and a grating.
Unit V: Polarisation and Double Refraction : Polari?.lltion by reflection,
pola!ization·by scanering, Malus, Law, Phenomenon of.doublc
ref! action (nom1al and oblique:incidencc), Analysis of polarized
light, Nicol pristn, Quarter wave plate and halfwave plate, Produc-
tion and detection of (i) plane pola!·ized light (ii) circularly
polarized light and elliptically pola!izcd light, optical activity,
Flesnel's themy of rotation, specific rotation, pola!imeters (Half
shade and Biquartz).
·.
,.

SYLLABUS FOR B.Sc. PART II (Theory)

Electronics and Nuclear Physics

,'•'
PAPER SECOND
Unit I : Elementary ideas of Semi-conductors : Zener diode char-
acteristics, Zener diode as voltage regulators, Mech.:nism of
LED, Half and full wave rectifier-efficiency and ripple fac-
tor, filter circtrits (L, C, lt), low pass and high pass RC filter
analysis - amplitooe and phase response, PNP and NPN
muisistor amplifier characteristics in common base; com-
mon emitter and.aimmon collector configurJtions (exclud-
ing h parJmeter analysis) ·
Unit I: Classification of Amplifiers, concept of feed back and ad-
vatage of negative feed back, circwt diagram and woricing
princple ofRC-coupled amp lifer-concept of band width (No
derivation), feed back in oscillaoor, tuned tranSistor oscillator
& Hartley oscillatDr (basic principle only), Amplitude &
Frequency modulatin, characteristics and applications.
l! Unit III: Strucutre of Nuclear : Structure of nuclei, properties of
! · nucleiandtl1eir detemnination,chargeby Moseley's law, size
by a-particle scattering, mass by Bein Bridge mass
spectrometer, magnetic moment by atomic beam resonance
·experiment, electric quadrupole roomcnt by Coulomb ex-
citation.
Forms of nuclear· potential (sbapes and relation between
nuclear potential depth and nuclear range).
·Unit IV: Interaction and Detection of Nuclear Radiations: Inter-
. action of charged particles with maner, energy loss (No
derivation) and range concept, Interaction of gamma-rays
with matter (qualitative description ofphotD.electric, Com-
pton scattering and pair production), absorption cpefficient ·
of ganuna-rays and its applications. Detection of nuclear
radiations using gas filled counters : Ionization, proportional
I and GM counlers.
Unit V: Radioactivity & Accelerators: Laws of radioactive decay,
half-life and meanlife, successive decay, radioactive equi-
librium conditions, age of earth using radioactive dating,
basic principle of nuclear ~ccelerators :Tandem accclcratDr,
Linear accelerator & cyclotron. Radiation hazard.

' -·,.
 ' .
' j

SYLLABUS
Pages ~
f
B.Sc. ParHll :I

181 Paper-1 (Theory)

184 I
186
Unit-1 : . Basic Idea of Statistical Physics : Scope if statistical Physics,
-327 Basic ideas of probability, distribution of four distinguishable
216 panicles in two compartments of. equal size, Coneept of mac-
217 rostates, microstates, thermodyn;unic probability, effect of con- .
220
straints on the system, deviation fr¢m the state of maximum
234 probability, equilibrium staie of dynamic system, distribution:of
15 indistinguishable particles in two compartments bfinon-equal
. - :1

:l49 sizes. · ·
252
'54 Classical Statistics : Phase space and its division intO elementary
·)' cells, three kinds of statistics, the basic approach to three
.l55
statistics, M-B statistics and its application to an' ideal gas in
256 equilibrium.
257 l,. Unit-IT : Quantum Statistics : Need for quantum statistics, B"E statistics
261 & derivation of Planck's law of radiation, F-D statistics, Fermi
265 . energy, comparison of M-B, B-E and F-D statistic~,
266 .,i Stati~tical interpretation of Entropy : Statistical .definition ~f
275 • I
entropy, change of entropy of a system, additive' nature of
280 entropy, law of increase of entropy, reversible and irreversible
281 processes, examples of reversible processes, work done in a
2R4 reversible process, eXl!ffiple of increase of entropy in natural
processes, entropy and disorder.
Unit-ill : Classical mechanics : Mechanics of a particle, mechanics •of
system of panicles, generalised co-ordinatates, ··Constraints,
288
Hamilton's principle, Derivation br Lagran~e's equations from
291
294 Hamilton's principle. Applications of Lagrange's'e(juation (a)
.j Simple Pendulum (b) qnear Harmonic Oscillator (c) ~twood's
'
297 "i Machine (d) Double penduiUip.
. '
298 i Unit-IV : Wave Mechanics : Inadequacy of old quantum iheory, wave
iI panicle dualism, Davisson and Germer experiment, Compton
-358 !
i scattering, wave packets,(Development of Schrodinger equation,
328 ! Significance of uncertainty principle, uncertainty of position' and ·
335 (' momentum, Energy-time uncertainty, Illustration df lind:rtliinty
343 principle (Diffraction of electrons and Gamma ·• Ray Micro.·
352
363 .I
scope)) · . . • .·...
•Viii) I
I 1 ~ :.·-

I \ ..

i
I, . ~·

'
 (viii)

Unit- V : Applicatibnsof Quantum Mechanics: Applications ofSchrodin-

•
ger equation! to one dimensionaL problems -
(l) Particle in a box
(il) Potential step
(iii) Potential barrier
(iv) Simple Harmonic oscillator with special emphasis to the
concept of ground s~te energy, oscillator eigen functions.
(v) Rectangular potential well.
1.1.

usee
r '-
. not
eith
insl
mol
tim'
mo1
the
and
par
the
sut
:~.
ell
res
ir
the
CO!
pre
Th
po
sui
be
ve
pr'
to
he
ca

'· -
···- -~---··
 g.Sc.JI[
SYLLABUS
?aper • II (Theory)

Un•t-I : Vec!or M:xlel aud Spectra of Alkali Metals : Ve::r.or &tom

modei (concept of the spiuning .electr:>n and spatial Quami:u.-
tion, Quantum numbe;-s associated with the ;-e.ctor 2tr>rn mode').
peoetratir.g and non-penetratin:; orbits (QualitNive descciption)
spectral lines in different series of alkali spectra, spin orbit
ime:acti<>n md doublet terre separation, :..s or Russel-saunder
coupli~g. coupling, Is coupling, jj coupling (Expressions foe
interact;on eucrgies (r Factors) for Is and jj coupling required).
Unit-JJ _ A!cm ;_nan Extemal Force Fielc:l.·: Z~emen effe~t (Normal an<!
Anomalous and Paschen Back ~ffecc of one valence electron
system tosing vector etom model, S:an -effect of hyamgcn ato!ll
(Mat:1ematical treatment not required), Hyperfine structure of
spectra a:Jd its origiil (simpie Qualitative ideas only).
Uni~-Ill : SoEd Sta:e Physics : Crystallir.e state, Bravais 1at:ices in two
and :hre<. dimer.sions, Miller indice,;, X-ray diffraction (Bragg's
law) Reciprocal Lattice, and its physical s;gnificance, Recipro.
cal Latti~e vectors, (Anclysi~ of diffraction onditions in terms
of Recip;ocallattic.e vectors not reqmred), Recipwc;;J lattice ro
a simple cubic iat!ice spec:fic heat of soEds, Einstein's thtory
of specific heat, Debye model of specific neat of solids.
Unit."tV : EJemer.ts of Laser : Main features of P Laser, direct'onlility,
high in<ensity, monochromaticity, high det:ree oc ~oherenc~.
," ,."';' ,. .
,.·.,.".AI
.: ' SpatiJ.I and temporal coherence, Einst~in coefficients and pos·
.. ' sibJ~ity or amplification, Momeutum tnmsfer. lJfe lime of a
level, Ki~etics of opticJ.! absorption.
B'ISic P r;nciples of Lasers : Threshold :conditkn and f1urr.ping,
He-Ne and r.UBY Laser {Plinciple, CO%lrU("tion and working),
Somicor.ductor La>ers : Main teaturos a;rd C<'nG.itions of laser
action.
i.Jnii-V : Nuclear Phy.,icc : Energetics of alpha decay, e).)l"rimental
' informations on alpha de-;ay- Node;~r stabili:)', Decay mecha-
msm and fine strucutre. Type oi beta energetics, neutri~o
hypothesis, :2nergetics of gamo::. decey and recc il effects.
Nuclero.· reactions, conservation Jaws, Q-value and reaction
threshold, Nuclear fission and fusion reactor" (Basic ;>rincipie,

0 construction, working a.'ld uses}.

·""'
•

•
•
•
 PAPER-I: CLASSICAL MECHANICS

Max. Marks: 30 Duration 3 Hrs.

Note: In all jive questions are to be sel. Four quesrions will be our oft he four unir taking one
queslionfrom eve!Ji unir with 100% imerna/ choice. One queslion will be of short answer type
covering en/ire course wilh no choice. The candidales will be required to a!/empt aliihe five
questions.

l. Holonomic and non-holonomic constraints: D- Alembert's Principle, Generalized

coordinates, lagrangian, lagrange's equation and its applications, velocity dependent
potential in lagrangian formulation. Generalized momentum, legendre tr andformation,
Hamiltonian, Hamiltonian's canonical Equation.
2. Calculus of variational principal, derivation of lagrange's and Hamilton,. Canonical
equation from Hamilton's variational principal. Extension of Hamilton's Principle for
nonconservative and nonholonomic systems, Method of lagrange's multipliers,
conservation principle and Noether's theorem. Conservation of energy, linear momentum
and angular momentum as a consequence ofhomogencity of time and scope and isotropy
of space respectively.
3. Canonical transformation, integral invariant of poincare: Lagrange's and Poisson brackets
as canonical invariants, equation of motion in Poisson bracket formulation. Infinitesimal
contact transformation and generators of symmetry, Louvilee's theorem, Hamilton-Jacobi
equation and its application.
4. Action angle variable adiabatic invariance of action variable: The Kepler problem in
action angle variables, theory of small oscillation in Lagrangian formulation, normal
coordinates and its applications. Orthogonal transformation, Euler's theorem, Eigenvalues
of the ine11ia tensor, Euler equations, force free motion of a rigid body.

Reference Books:

I. Goldstein- Classical Mechanics

2. Landau and Lifshitz- Classical Mechanics
3. A. Raychoudhary- Classical Mechanics
 PAPER-II: MATHEMATICAL PHYSICS

Max. Marks: 3 Duration 3 Hrs .

Note: In all five questions are to be set. Four question will be our ofthe four unit taking one
ques!ionfrom every unit with 100% internal choice. One question will be ofshort answer type
covering em ire course with no choice. The candidates will be required to a/lempt all the five
questions.

l. Coordinates Transformation inN - dimensional space: Contravariant and covariant

tensor, Jacobian. Relative tensor, pseudo tensors (Example: charge density, angular
momentum) Algebra of tensors, Metric tensor, Associated tensors, Riemann space
(Example: Euclidean space and 4D Mankowski space), Christoffel S)~nbols,
transformation of Christoffel symbols, covariant differentiation, Ricci's theorem,
divergence, Curl and Laplacian tensor form, Stress and strain tensors, Hook's law in
tensor form. lorentz covariance of Maxwell equation, Klein Gordon and Dirac Equation,
Test of covariance of schroodinger equation.
2. Group of Transformation: (Example: S:mmetry transfonnation of square) Generators of
a finite group, Normal subgroup, Direct product of groups, Isomorphism and
Homomorphism. Representation theorem of finite groups, Invariants subspace and
reducible representations, irreducible representation, crystallo-graphic point groups·,
Irreducible representati-on ofC,v. Translation group and the reciprocal lattice.
3. Fourier Transforms: Development of the Fourier integral from the Fourier Series, Fourier
and inverse Fourier transform: Simple Applications: Finite wave train, Wave train with
gaussian amplitude, Fourier transfonn of derivatives, solution of wave equation as an
application. Convolution theorem. Intensity in terms of spectral density for quasi
monochromic EM Waves, Momentum representation, Application of Fourier transform
to diffraction theory: diffraction pattern of one and rwo slits.
4. Laplace transforms and their properties, Laplace transform of derivatives and integrals,
derivatives and integral of Laplace transfonn. Convolution theorem. Impulsive function,
Application of Laplace transform in solving linear, differential equations with constant
coefficient with variable coefficient and linear partial differential equation.

Reference books:

1. Mathematical Methods for Physicists: George Arfken (Academic Press)

2. Applied Mathematics for Engineers and Physicists: L.A. Pipe (McGraw Hill)
3. Mathematical Methods- Potter and Goldberg (Prentice Hall of India)
4. Elements of Group Theory for Physicists: A.W. Joshi (Wiley Eastern Ltd.)
5. Vector Analysis (Schaum Series) (McGraw Hill)
 PAPER III: QUANTUM MECHANICS
Max. Marks: 30 Duration 3 Hrs.

Note: In all jive questions are 10 be set. Four question will be out of the four unit taking one
question from eve1:v unit wi1h 100% imernal choice. One question will be ofshort answer type
covering entire course with no choice. The candidates wi/1 be required to a/lempt all the jive
questions.

l. (a) States, Amplitude and Operators: States of a quantum mechanical system,

representation of quantum-mechanical states, properties of quantum mechanical
amplitude, operators and change of a state, a complete set of basis states, products of
linear operators, language of quantum mechanics, postulates, essential definitions and
commutation relations.
(b J Observables and Description of Quantum system: Process of measurement ,
expectation values, time dependence of quantum mechanical amplitude, observable with
no classical analogue, spin dependence of quantum mechanical amplitude on position, the
wave function, super position of amplitudes, identical particles.
2. Hamiltonian matrix and the time evolution of Quantum mechanical States: Permittivity of
the Hamiltonian matrix, time independent perturbation of an arbitrary system, simple
matrix examples of time independent perturbation, energy given states of a two state
system, diagonalizing of energy matrix, time independent perturbation of two state
system the perturbative solution: Weak field and Strong field cases, general description
of two state system,Pauli matrices, Ammonia molecule as an example of two state
system.
3. Transition between stationary States: Transitions in a two state system, time dependent
perturbations - The Golden Rule, Phase space, emission and absorption of radiation,
induced dipole transition and spontaneous emission of radiation energy width of a quasi
stationary state.
The co-ordinate Representation: Compatible observables, quantum conditions and
uncertainty relation, Coord in ate representation of operators, position, momentum and
angular momentum, time dependence of expectation values, The Ehernfest Theorem, the
time evolution of wave function, the schroedinger equation, energy quantization, periodic
potential as an example.
4. Symmetries and Angular Momentum:
a. Compatible observables and constants of motion, symmetry transformation and
conservation laws, in variance under spaceand time translations and space rotation
and conservation of momentum, energy and angular momentum.
b. Angular momentum operators and their Eigenvalues, matrix representations of the
angular momentum operators and their eigenstates, coordinate representations of
the orbital angular momentum operators and their eigen state (Spherical
Harmonics), composition of angular momenta, Clebsch-Gordon Coefficients
tensor operators and Wigner Expait theorem, c commutation relations, of J ,. J y,J,
with reduced tensor operator, matrix elements of vector operators, time reversal
invariance and vanishing of static electric dipole moment of stationary state.
 Reference Books:

I. Ashok Das and A. C. Mel issions: Quantum Mechanics -A modern approach (Gordon and
Breach Science Publishers).
2. P.A.M. Dirac, Quantum Mechanics.
3. E. Merzbecher: Quantum Mechanics, Second Edition (John Wiley and sons)
4. L.P. Landau and E.M. Lifshitz, Quantum Mechanics- Relativistic theory (Pergamon
Press)
5. A. Ghatak and S. Lokanathan: Quantum Mechanics- Theory and Applications, Third
Edition (Mac. Millan, India Ltd.

PAPERIV:ELECTRONICS
Max. Marks: 30 Duration 3 Hrs.

Note: In all five ques!ions are to be set. Four question will be au/ ofthe four uniltaking one
question ji-om evety unil with 100% internal choice. One question will be ofshort answer type
covering en/ire course with no choice. The candidates will be required to a/tempt all the five
questions.

1. Operational Amplifiers:
Differential amplifier- circuit configurations- dual input, balanced output differential
amplifier, DC analysis- AC analysis,inverting and non inverting inputs, CMRR-
constant current bias level translator.
Block diagram of typical OP-Amp analysis. Open loop configuration, inverting and
noninverting amplifiers, Op-Amp with .negative feedback, voltage series feedback, effect
of feed back on closed loop gain, input resistance, band with and output offset voltage-
voltage follower.
Practical Op-Amp input offset voltage~input bias current-input offset current, total output
offset voltage, CMRR frequency response. DC and AC amplifier. integrator and
different iator.
2. Oscillators and wave shaping Circuits:
Oscillator Principle- Oscillator types, Frequency stability response, the phase shift
oscillator, We in bridge oscillator. LC tunable oscillators, Multivibrators-Monostable and
 Astable, Comparators, Square wave and triangle wave generation, clamping and clipping.
Voltage regulators- fixed regulators, adjustable voltage regulators, switching regulators.
3. Digital Electronics: Combinational logic:
The transistor as a switching, circuit realisation of OR, AND, OR, NOR, NAND gates,
Exclusive OR gate, Boolean algebra- De-morgan Theorenis, Adder, subtracter,
comparator, decoder/Demultiplexer Data selector/multiplexer, encoder.
Sequential Logic: Flip-Flops: one- bit memory, the RS flip-flop, J flip flop, JK master
slave flip-flops, T flip-flop, D flipflop, shift resisters- synchronous and asynchronous
counters, cascade counters, Binary counter, Decade counter.
Basic concepts about fabrication and characteristics of integrated circuits.
4. Microprocessors:
. Introduction to microcomputers: memory- input/output- interfacing device 8085, CPU-
Architecture- BUS timings- Demultiplexing the address bus generating control signals-
Instruction set- addressing modes- Illustrative programmes- writing Assembly language
programmes looping, counting and indexing - counters and timing delays - stack and
subroutine.

Text and Reference Books:

I. "Electronic Devices and Circuit Theory" by Robert Boylested and Louis Nashdsky, PHI,
New Delhi -110001,1991.
2. "OP-AMP and Linear Integrated Circuits" by Ramakanth, A. Gayakwad, PHI, Second
Edition I 991.
3. "Digital Principle and Applications" by A.P. Malvino and Donald P. Leach, Tata
McGraw Hill Company, New Delhi, 1993.
4. "Microprocesso'rs Architecture, Programming and Applications with 8085/8086" by
Ramesh S Gaonkar, Wiley- Eastern Ltd., 1987.
 PAPER V: CLASSICAL ELECTRODYNAMICS

Max. Marks: 30 Duration 3 Hrs.

Note: in all five queslions are 10 be set. Four question will be out of the four unil taking one
questionji-om eve1y unit with 100% internal choice. One question will be ofshort answer type
covering em ire course with no choice. The candidates will be required to allempl a lithe five
queslions.

I. Electrostatics: Electric field, Gauss Law, Differential form of Gaussian Jaw. Another
equation of electrostatics and the scalar potential, surface distribution of charges and
dipoles and discontinuities in the electric field and potential, Poisson and Laplace
equations, Green's Theorem, Uniqueness of the solution with the Dirchlet or Neumann
boundary Conditions, Fonnal Solutions of electrostatic Boundary value problem wit
Green's function, Electrostatic potential energy and energy density, capacitance.

Boundary Value Problems in Electrostatics: Methods of Images, Point charge in the

presence of a grounded comducting sphere, point charge in the presence of a charged
insu Ia ted conducting sphere, point charge near a conducting sphere at a fixed potential,
conducting sphere in a uniform electric field by method of images, Green function for the
sphere, General solution for the potential, conducting sphere wit hemispheres at a
different potentials, orthogonal functions and expansion.

2. Multipoles, electrostatics of Macroscopic Media Dielectric:Multipole expansion,

multipole expansion of the energy of a charge distribution in an external field,
Elementary treatment of electrostatics with permeable media. Boundary value problems
with dielectrics. Molar polarizability and electric susceptibility. Models for molecular
polarizability, electrostatic energy in dielectric media.
3. Magnetostatics: Introduction and defi11ition, Biot and Savart Law, the differential
equations ofmagnetostatics and Ampere's Jaw, Vector potential and magnetic induction
for a current loop, Magnetic fields of a localized current distribution, Magnetic moment,
Force and torque on and energy of a localized current distribution in an external
induction, Macroscopic equations, Boundary conditions on Band H Methods of solving
Boundary value Problems in magnetostatics, Uniformly magnetized sphere, magnetized
sphere in an external fields, permanent magnets, magnetic sheilding, spherical shell of
permeable material in an uniform field.

• Time varying fields, Maxwell's equations conservation Jaws:Energy in a magnetic field, vector
and scalar potentials, Gauge transformations, Lorentz gauge, coloumb gauge, Green function for
the wave equation, Derivation of the equations of Macroscopic Electromagnetism,Poynting's
Theorem and conservation of energy and mom~ntum for a system of charged particles and-EM
fields. Conservation Jaws for macroscopic media. Electromagnetic field tensor, transformation of
four potentials and four currents, tensor dissipation of Maxwell's equations.
 Reference Books:

l. J.D. Jackson: Classical Electrodynamics

2. Panofsky & Phillip: Classical electrodynamics and magnetism
3. Griffith: Introduction to Electrodynamics
4. Landau & Lifshitz: Classical Theory of Electrodynamics
5. Landau & Lifshitz: Electrodynamics of continuous media
6.

Msc Physics Final

PAPER. VI: NUMERICAL METHOD AND COMPUTER PROGRAMMING

Max.Marks : l 00 Duration : 3hrs.

Five question are to be set taking one from each unit (each question will have an·internal choice).
Student will attempt all the five question. 40% weightage will be given to problem and
numericals.

UNIT- I

l. Operational Amplifiers: .Differential amplifier- circuit configurations-dual inpu~ balanced

output differential amplifier. DC analysis- AC analysis, inverting and nonninverting inputs,
CMRR- constant current bias level translator.
Block diagram of a typical Op-Amp-analysis.Open loop configuration,inverting and non-
inverting amplifiers.Op-amp with negative feedback- voltage series feed back -effect of feed
back on closed loop gain, input rersistence, output resistance, bandwidth and output offset
voltage- voltage follower.
Practical op-arnp-input offset voltage -input bias current -input offset current, total output offset
voltage, CMRR frequetency response. DC and AC amplifier, summing, scaling and averaging
amplifiers, instrumentation amplifier, integrator and differentiator.

Ul'I'IT- ll
Oscillators and Wave Shaping Circuits: Oscillator Principle- Oscillator types, Frequency
stability, response, The Phase shifi oscillator, Wein bridge OScillator,LC tunable oscillators,
Multivibrators-Monostable and Astable, Comparators, Square wave and Triangle wave
generation, Clamping and Clipping.
Voltage regulators- fixed regulators, Adjustable voltage regulators, Switching regulators.
UNIT- III
Digital Electronics: Combinational Logic :The transistor as a.switch;circuit Realisation of
OR,AND,NOT, NOR and NAND gates, Exclusive OR gate, Boolean algebra- Demorgan's
theorems Adder, Subtractor, Comperator. Decoder I Demultiplexer ,Data selector/ multiplexer-
Encoder.
Sequential Logic: Flip -Flops: one-bit memory; The RS Flipflop, JK Flip- Flop, JK master slave
Flip -Flops, T Flip -Flop, D Flip- Flop, Shifi resisters- syncronous and asynchronous counters-
 cascade counters)Binary counter, Decade counter.
Basic concepts about fabrication and characteristics of integrated circuits.Fortran 77: Variable,
Expression, jumping. Bracching an looping statement ,Input I Output statement Statement for
handling Input I Output Files, Subroutine, External, Function ,Special statements
,COMMON,ENTR Y FORMA T,PA USE,Equvalence . Programming of simple problems
involving use of interpolation differentiation, Integration, matrix inversion and least square
analysis.

UNIT-IV

Errors in numerical analysis: Source of error, Round off error, Computer Arithmetic, Error
Analysis, Condition and stability,Approximation, Functional and Error analysis, the method
of, Undetermined Coefficients. Use of interpolation formula, Iterated interpolation. Inverse
interpolation,Hannite interpolation and Spline interpolation, Solution of Linear equations, Direct
and Iterative methods, Calculation of eigenvalue and eigenvectors for sysmmetric matrices.
Solution ofNonliner equation: Bisection method, Newton's method,.modified Newton's
method, method of Iteration, Newton's method and method of iteration for a system of cosuation
Newton's method for the case of complex roots.

UNIT-·V
Integration of a function: Trapezoidal and Simpson's rules. Gaussian quadrature formula,
Singular integrals, Double integration.
Integration of Ordinary differential equation: Predictor- corrector methods, Runga-Kutta
method, Simultaneous and Higher order equations
Numerical Integration and Differentiation of Data, Least-Squares Approximations, Fast
FourierTransfonn ..
Some elementary information about Computer: CPU, Memory, Input/ Output devices, Super,
Mini and Micro systems, MS-DOS operating system, High Level Languages, Interpreter and
Compiler. Programming: Algorithm and Flowchart.

Reference Book
I. Ryder-Electronic Fundamentals and applications.
2. Millman and Thub-Pulse, Digital and Switching waveforms.
3. Millman and Helkias-lntegrated Electronics.
4. Ryder-network Lines and Fields.
5 Bapat-Eiectronics Devices and Circuitrs.
6. A Ralston and P. Rabinowitz, A First Course in Numberical analysis Me Graw Hill (1985)
7. S.S. Sastry, Introductory Methods ofNumerical Analysis. Prentice hall of India (1979).
8. Ram Kumar, Programming with Fortran 77, McGraw-Hill (1986).
9. "Eiectronic'Devicesand circuit theory by Robert Boylested and Louis Nashdsky PHI, New
Delhi. 1100001,1991.
JO."OPAmps& Linear integratedcircuits, by Ramakanth A. Gayakwad PHI, Second Edition,
1991.
II. Digital principles and Applications by A.P. Malvino and Donald P.Leach, Tata Megraw-
Hill company, New Delhi, 1993.
 12. Microprocessor Architecture, Programming and applications with 8085/8086 by Ramesh S.
Gaonkar, Wiley- Eastern Ltd., I 987.

PAPER -VII: ATOMIC AND MOLECULAR PHYSICS

Max.Marks :I 00 Duration : 31m.

Note: Five qustion are to be set taking one from each unit (each question will have an internal
choice).Student will attempt all the five question 40% weightage will be given to problems and
numericals.
UNIT-I

States, Amplitudes and Operators: States of a quantum mechanical system, representation of

quantum,- mechanical states, properties. of quantum mechanical amplitude;operators and change
of state, a complete set of basis states,.products of linear operators, language of
quantummechanics, postulates, essential definitions and commulation relations.
Obsen·able and description of system: Process of measurement,expectation values,time
. dependence of quantum mechanical amplitude, observables with no classical anal.ogue, spin.
dependence of quantum-mechanical amplitude on position. the v>•ave fimction, super-position of
amplitudes, identical particles.
The Co-ordinate Representation: Compatible observables, quantum conditions and uncertainty
relation, Co-ordinate representation,of operator&; position,momentum and angularmomentum,.
time dependence[ of expectation values, the Ehrenfest's theorem: the time evolution of wave.
function, the Schrodinger equation, energy quantization, ,periodic potential as an example.

UNIT -II

Symmetries and-Angular momentum: (a) Compatible observables and constants of motion,

symmetry' transfonnation and conservation laws, invariance,under space and time translations
and space rotation and conservations of momentum, energy and angular momentum.
Angular momentum operators and, their eigen values, matrix representations of the angular
momentum operators and their eigenstates, co-ordinate representations of the orbital angular
momentum operators and their eigenstate (spherical harmonics), composition of angular
momentum, Clebsch- Gordon coefficients tensor operators anq Winger Ex part theorem,
commutation relations, of Jx, Jy, Jz with reduced spherical tensor operator, matrix elements of
vector operators, time reversal invariance and vanishing of static electric dipole moment of a
stationary state.
UNIT- III

Hamiltonian matrix and the time evolution of Quantum mechanical States: Hemriticity of
the Hamilionian matrix, Time independent perturbation of an arbitrary system, simple matrix
examples of time-, independent perturbation, energy given states of a two state system,
diagonalizing of energy matrix, time independent perturbation of two state system the
perturbative solution: Weak field and strong field cases, general description of two state system.
 Pauli matrices. Ammonia molecule as an example of two state system.
Interaction with External Fields: Non degenerate first order stationary perturbation method,
atom in a weak uniform external electric field and first and second order Stark effect, calculation
of the polarizabi lity of the ground state of H-atom and of an isotropic harmonic osciJiator,
Degenerate stationary perturbation theory. Linear Stark effect for H-atom levels, inclusion of
spin-orbit and weak magnetic, field, Zeeman effect, strong magnetic field and calculation of
interaction energy.
UNIT-IV
Transition Between Stationary States: Transitions in a two state system, Time independent
perturbations-The Golden rule, phase space, emission and absorption ofradiation,induced dipole
transition and Spontaneous emission. of radiation. energy width of a quasi stationary state.
Systems with Identical Particles: lndistinguish ability and, exchange symmetry, many particle
wave functions and Pauli's exclusion principle, spectroscopic terms for atoms. The Helimn atom,
Variational method and its use in the calculation of ground state and excited state energy, Helimn
atom. The Hydrogen molecule, Heitler-London method for molecule, WKB method for one
. dimensional problem, application to bound states (Bohr-Sommerfield quantization) and the
barrier penetration (alpha decay, problems.
UNIT- V
Hyd rogenAtom : Gross structure energy spectnuil, probability distribution of radial and angular
(I=J ,2) wave .functions (no derivation), effect of spin, relativistic correction to energy levels and
fine structure,magnetic dipole interaction and hyperfine structure, the Lamb shift (only an
qualitative description)
Spectroscopy(qualitative) : General features of the spectra of one and two electron system-
sin.gletdoublet and triplet characters of emission spectra,general features of Alkali
spectra, rotation and vibration band spectrum of a molecule, PQ and R branches, Raman spectra
for rotational and vibrational transitions,comparison with infra red spectra. general features of
electronic spectra. Frank and Condon's principle.

ReferenceBooks:

I. Ashok Das and A. C. Melissionos. Quantum Mechanics-A modern Approach (Gordon and
Breach Science Publishers).
2. P.A.M.Dirac, Quantum Mechanics.
3. E. Merzbaker. Quantum Mechanics, Second Edition (John Wiiley and Sons).
4. L.P.Landau aridH.I\1. Lifshitz, Quantum Mechanics-Non relativistic theory (pergamon Press)
5. A .. Ghatak and S. Lobnathan.- Quantum Mechanics: Theory and, Applications, Third
Edition(Mac Millan India Ltd.),
6. G. K. Woodgate,EiementaryAtomic Structure, Second Edition Clarendon Press, Oxford.
7. T.A. Littlefield- Atomic and Molecular Physics.
8. Eistanberg and Rasmik-QuantumPhysicsof Atoms. Mo.lecules, Solids and Nuclear Particles.
9. White- Atomic Spectra.
I 0 .Herzberg- Molecular Spectra.
 PAPER- VIII: STATISTICAL AND SOLID STATE PHYSICS
Max.Marks.: 100 Duration : 3hrs.
Note: Five question are to be set taking one from each unit(each question will have an internal
choice).Student will attempt all the five questions. 40% weightage will be given to problems and
numericals.
UNIT-I

Basic Principles, Canonical and Grand Canonical ensembles: Concept of statistical

distribution, phase space, density of states, Liouville's theorem, systems and ensemble, entropy
in statistical mechanics Connection between thermodyanic and statistical quantities micro
canonical ensemble, equation of state, specific heat and entropy of a perfect gas, using micro
canonical ensemble.
Canonical ensemble, thermodynamic functions for the canonical ensemble, calculation of
mean values, energy fluctuation in a gas, grand Canonical ensemble, thermodynamic functions
for the grand canonical ensemble, density fluctuations.

UNIT- II

Partition functions and Statistics: Partition functions and Properties, partition function for an
ideal gas and calculation of thermodynamic quantities, Gibbs Paradox, validity of classical
approximation, determination of translational, rotational and vibrational contributions to the
partition fimction of an ideal diatomic gas. Specific beat of a diatomic gas, ortho and para
hydrogen.
Identical particles and symmetry .requirement, difficulties with Maxwell-Boltzmann
statistics,quamum distribution functions, Bose-Einstein and Fermi-Dirac statistics, Boson
statistics and Planck's fonnula, Bose Einstein condensation, liquid He as a Boson system,
quantization ofhannonic oscillator and creation and annihilation of Phonon operators,
quantizarion of fermion operators.
Ul'HT-lll

Band Theory: Block theorem, Kronig Penny model, effective mass of electrons, Wigner-Seitz
approximation, NFE model, tight binding method and calculation of density for a band in simple
cubic Janice, pseudo potential method.

Semiconductors: Jaw of mass action, calculation of impurity conductivity,ellipsoidaJ energy

surfaces in Si and Ge, HaJJ effect, recombination mechanism, optical transitions and Schockely-
Read theory excitons, photoconductivity, photo-Luminescence.Points line, planar and bulk
defects, colour centres, F-centre and aggregate centresin alkali halides.

UNIT- IV

Theory of Metals: Fermi- Dirac distribution function, density of states, temperature dependence
of Fermi energy, specific heat, use of Fermi.
Dirac statistics in the calculation ofthennal conductivity and electrical conductivity,
.. Widemann -Franz ratio, susceptibility, width of conduction band, Orude theory of light,
absorption in metals.
 Lattice Vibratuibs and Thermal Properties: Interrelations between elastic constants Cl 1, Cl2
and C44 wave propagation and exparimental determination of elastic constant of cubic crystal,
vibrations of linearmono and diatomic lattices, Detennipation of phonon dispersion by inelastic
scattering of neutrons.
UNIT- V

Magnetism: Larmor diamagnetism.Paramagnetism,Curie Langevin and Quantum theories.

Susceptibility of rare earth and transition metals. Ferromagnetism: Domain theory, Veiss
molecular field and exchange,spin waves: dispersion relation and its experimental determination
by inelastic neutrons scattering, heat capacity. Nuclear Magnetic resonance: Conditions of
resonance, Black equations. NMR-experiment and characteristics of an absorption line.
Superconductivity: (a) Experimental results: Meissner effect, heat capacity, microwave and
infrared properties, isotope effect, flux quantization, ultrasonic attenuation, density of states,
nuclear spin relaxation, Giver and AC and DC Josephson tunnelings.
(b) Cooper pairs and derivation ofBCS Hamiltonian, results ofBCS theory (no derivation).

Reference Books:
l.Huag : Statistical Mechanics
2. Reif: Fundamentals of Statistical and Thermodynamical Physics
3. Rice: Statistical mechanics and Thermal Physics
4. Kittle: Elementary statistical Mechanics
5. Kittle: Introduction to Solid State Physics
6. Patterson:'Solid State Physics
7. Levy: Solid State Physics
8. Mckelvy: Solid State and Semi-conductor Physics.

Max. Marks : J 00 Duration : 3hrs.

Note: Five question are to be set taki one from each unit( each question will have an internal
choice).Student will attempt all the fiv questions. 40% weightage will be given to problems and
numericals.
UNIT-I

I. Introduction to microwaves and its fr quency spectrum, Application of microwaves.

Wave guides: (a) Rectangular wave gui es: Wave Equation & its solutions,TE&TM
modes.Dominan tmode and choice ofw ve guide Dimensions Methods of excitation of wave
guide.
(b) Circular ,;,ave guide-wave equation its solutions, TE, TM & TEM modes.
(c) Attenuation - Cause of attenuation in 1 .ave
I
guides. wall current & derivation of attenuation.
- .
constant, Q of the wave guide. 1
2. Resonators: Resonant Modes of rectangular and cylindrical cavity resonators, Q of the cavity
resonators, Excitation techniques, Introduction to Microstrip and Dielectric resonators,
Frequency meter.
UNIT- II
 3. Farrites: Microwave propagation inferrites, Far~~. rotation, Devices employing Faraday
rotation (isolator. Gyrator, Circulator). Introduction to ~ngle crystal ferromagnetic resonators,
YIG tuned solid state resonators. , ·
4. Microwave Measurement: \
(a) Microwave Detectors: Power, Frequency, Attenuatio$, Impedance Using smith chart, VSWR.
Reflectometer. Directivity, coupling using direction coupler. .
(b) Complex pennittivity of material & its measurement:idefinition of complex of Solids, liquids
and powders using shift of minima method. ·
UNIT- III
3. Microwave tubes: Spacecharge spreadingofan electronbeam, Beam focussings.
Klystrons: Velocity Modulation, Two Cavity Klystron, Reflex Klystron Efficiency of Klystrons.
Magnetrons: types & description, Theoretical relations •between Electric & Magnetic field of
oscillations. Modes of oscillation & operating characteristics.
Gyrotrons: Constructions of different ,Gyrotrons, Field. -Particle Interaction in Gyrotron.
UNIT- IV i

6. (a) Avalanche Transit Time Device:Read Diode, N ~ative resistance of an avalanching p-n
Junction diode JMPA TT and TRAP A TT Oscillator.
(b) Transferred Electron Device: Gunn effect, two vel ey, model, High field Dotrutins, Different
Modes for Microwave generation.
(c) Passive Devices: Termination (Short circuit and tched tenninations) Attenuator, phase
changers, E&H plane Tees, Hybrid Junctions. Directi nal coupler.
?.Parametric Amplifier: Varactor, Equation of Cap citance in Linearly graded & abrupt p-
njun.ction, Man ely Rowe relations, parametric upcoll/"ertor and Negative resistance parametric
amplifier,-use of circulator, Noise in parametric amplifiers.
· UNIT-"\!'
8. Microwave Antennas: Introduction to antenna pa~ameters, Magnetic Currents, Electric and
magne* current sheet, Field ofHuygen's source, Radiation from a slot antenna, open end of a
wave f!Uide and Electromaf'Jletic Horns. PraboJic refl~ctors. Lens antennas. .

calculations, Microstrip design formulas.

9. Microwave Communication:
I
Radiation fields of Microstrip wave guide, Microstri* wave gUJde, M1crostnp antenna

(a) LOS microwave systems, Derivation of LOS communication range, OTH microwave
systems, DeriVation of field strength of tropospheric ~aves,. Transmission interference and
signal damping, Ductpropagation. /
(b) SateJJite Communication: Satellite frequencies aliocation, Synchronous satellites,Satellite
orbits, Satellite location with respect to earth and look angle, earth coverage and slant range,
Eclipse effect, Link calculation, Noise consideration, Factors affecting satellite communication.
Reference Books: I. Electromagnetic waves & Radiating Systems: Jorden & Balmain.
2. Theory and application of microwaves by A.B. Brownwell & RE. Beam (McGraw Hill).
3. Introduction to microwave theory by Atwater (McGraw Hill).
4. Principles of microwave circuit by G.C. Montgomery (Me Graw HiJJ)
5. Microwave Circuits & Passive Devices by M.L. Sisodia and G.S. Raghuvanshi (New Age
lnteniational, New Delhi) ·
6. Foundations of microwave engineering by RE. Collin. (McGraw Hill).
7. Microwave Semiconductor Devices and their Circuit applications by H.A. Watson
 I
8. Microwave by M.L. Sisodia and Vija~ Laxmi Gupta. New Age, New Delhi.
9. Antenna Theory, Part-) by RE. Collin\& EJ. Zucker (McGraw Hill, New York)
I O.Microstrip Antennas by Bah I & Bharliya (Artech House, Messachausetts)
I I. Antenna Theory Analysis by C. A. B~Ianis Harper & Row. Pub. & Jnc. New York.
12. Antenna Theory Analysis by E.A. vJo1 '"'(J. Willey & Sons)
13. Antenna Theory & Desie:n by RS Elliott ' (LPHJ Ltd. New Delhi)
I 4. Microwave electronics b)• RE Sooh,bo (Addisen Westey pubblic company,).
I 5.Microwave Active Devices, VacuoJms by M.L Sisodia new Age lntemational New Delhi.
I 6. Semiconductors & Electronics dev(ce by A. Barle vs (PHI, India).
I 7. Solid State physical electronics by t>..Vanderziel, (PHI, India).
I 8. Hand book of microwave measurefent Vol-ll by M. Sucher & J.Fox (pol}1echnic Press,
New York). f
19. Microwave devices& circuits by .Y.Liao(PHI, India).
20. Microwave Principles by H.J. Rei h (CBS).

r
21. Simple microwave technique for feasuring the dielectric parameters of solids & their
powder by J.M. Gandhi, J.S. Yadav, of pure & applied physics Vol. 30, pp-427431, 1992.

PAPER -IX: CLASSICAL ELECTRODYNAMICS

Max.Marks :I 00 Duration : 3hrs.

Note: Five question are to be set taking one from each unit (each question will have an internal
choice). Student will attempt all the five question. 40% weightage will be given to problem and
numericals.

Unit- I

1. Electrostatics: Electric field; Gauss Jaw, Differential form of Gauss Jaw. Another equation of
electrostatics and the scalar potential, surface distribution of charges and dipoles and
discontinuties in the electric field and potential, Poisson and-Laplace equations, Green's
Theorem, Uniqueness of the solution with Dirichlet or Neumann Boundary conditions, Fomal
solution of Electrostatic Boundary value problem with Green's Function. Electrostatic potential
energy and energy density, capacitance.
Boundary- Value'Problems in Electrostatics: Methods of Images, Point charge in the presence
of a grounded conducting sphere point charge in the preseqce of a charge insulated conducting
sphere, Point charge near a conducting sphere at fixed potential, conducting sphere in a unifonn
electric field by method of images, Green function for the sphere, General solution for the
potential, Conducting sphere with Hemispheres at different potential, orthogonal functions and
expanswn.

Unit- II
 2. Magnetostatics: Introduction and defmition, Biot, and Savart law, the differential equation of
magnetostatics and Ampere's law, Vector potential and Magnetic induction for a circular current
loop, Magnetic fields of a localized current distribution, Magnetic moment, Force and torque on
and energy of a localized current distribution in an external magnetic induction, Macroscopic
equations. Boundary conditions_ on Band H. Methods of solving Boundary-value problems in
magnetostatics, Unifonnly magnetized sphere, Magnetized sphere in an external field, Permanent
magnets, Magnetic shielding, spherical shell of permeable material in an unifonn field.
Unit- III

3. Multipoles, Electrostatics of Macroscopic Media Dielectrics: Multiple expansion, multipole

expansion of the energy of a charge distribution in an external field, Elementary treatment of
electrostatics with permeable media, Boundary value problems with dielectrics. Molar
polarizability, and electric susceptibility. Models for molecular polarizability, Electro-static
energy in dielectric media ..
4. Time varying fields, Maxwell's eqllations Conservation Laws:Energy in a magnetic field,
Vector and Scalar potentials. Gauge transformations, Lorentz gauge, Coulomb gauge, Green
functions for the wave equation, Derivation of the equations of Macroscopic Electromagnetism,
Poyntings theorem and conservations of energy and momentum for asystem ofcharged
particles. and EM fields. Conservation Jaws for macroscopic media. Electromagnetic field tensor.
Transformation of .four ,potentials.and four currents. Tensor description of Maxwell's equation.
Unit- IV

5. Plane Electromagnetic Waves and Wa\'e Equation :Plane wave in a nonconducting

medium. Frequency dispersion characteristics ofdielecttics, conductors and plasmas, waves in a
conducting or dissipative medium, superposition of waves in one dimension,group
velocity,casualty connection between D and E. Kramers-Kroning relation ..
7. Covariant Form of Electrodynamic Equations :Mathematical properties of the space-time
special relativity,Jnvariance of electric charge covariance of electrodynamics, Transformation of
electromagnetic fields.
Radiation by moving.charges: Lienard-wiechert Potentials for a point charge, Total power
radiated by an accelerated charge ,Larmour's formula and its relativistic generalization, Angular
distribution of radiation emitted by an accelerated charge, Radiation emitted by a charge in
arbitrary extremely relativistic motion. Distribution in frequency and angle-of energy radiated by
accelerated charges, Thomson scattering and radiation, Scattering by quasi free charges, coherent
and incoherent scattering, Cherenkov radiation.
7. Magnetohydrodynamics and Plasma Physics: Introduction and definitions, MHD equations
Magnetic diffusion viscosity and pressure; Pinch effect instabilities in a pinched plasma column.
Magnetohydrodynamic waves; Plasma oscillations, short wave length limit of plasma
oscillations and De bye shielding distance.
8. Radiation damping, self fields. of a particle, scattering and absorption of radiation by a
bound system: Introductory considerations, Radiative reaction force from conservation of
energy, Abraham Lorentz evaluation of the self force, difficulties with abraham Lorentz
model;lntegro-differential equation of motion including radiation damping,. Line Breadth
and level shift of an oscillator, Scattering and absorption of radiation. by an oscillator, Energy
transfer to a harmonically bound charge.
 Reference Books :

1. J.D. Jackson-.-Classica/ Electrodynamics

2. Panofsky andPhiiips Classical Electricity and Magnetism'
3. introduction to Electrodynamics-Gritfrths
4. Landau and Lifshitz--C/assica/ Theory of Field
5. Landau and Lifshitz.:.Electrodynamics of Continuous Media

PAPER-X: MICROWAVE ELECTRONICS

Max.Marks :100 Duration : 3hrs.
Note: Five question are to be set taking one from each unit( each question will have an internal
choice).Student will attempt all the five questions. 40% weightage will be given to problems and
numericals.
UNIT- I

1.Introduction to microwaves and its frequency spectrum, Application of microwaves.

Wave guides: (a) Rectangular wave guides: Wave Equation & its solutions, TE&TM
modes.Dominan tmode and choice of wave guide Dimensions Methods of excitation of wave
guide.
(b) Circular wave guide-wave equation & its solutions, TE, TM & TEM modes.
(c) Atlenuation- Cause of attenuation in wave guides, wall current & derivation of atlenuation
constant. Q of the wave guide.
2. Resonators: Resonant Modes of rectangular and cylindrical cavity resonators, Q of the cavity
resonators, Excitation techniques, introduction to Microstrip and Dielectric resonators,
Frequency meter.
UNIT- II
3. Far rites: Microwave propagation in ferrites, Faraday rotation, Devices employing Faraday
rotation (isolator, Gyrator, Circulator). Introduction to single crystal ferromagnetic resonators,
YIG tuned solid state resonators.
4. Microwave Measurement:
(a) Microwave Detectors: Power, Frequency, Anenuation, Impedance Using smith chart, VSWR,
Retlectomerer. Directivity, coupling using direction coupler.
(b) Complex permittivity of material & its measurement: definition of complex of Solids, liquids
and powders using shift of minima method.
UNJT- III
3. Microwave tubes: Spacecharge spreadingof an electron beam, Beam focussings.
Klystrons: Velocity Modulation, Two Cavity Klystron, Reflex Klystron Efficiency of Klystrons.
Magnetrons: types & description, Theoretical relations between Electric & Magretic field of
oscillations. Modes of oscillation & operating characteristics.
Gyrotrons: Constructions of different ,Gyrotrons, Field. -Particle Interaction in Gyrotron.
UNIT- IV

6. (a) Avalanche Transit Time Device:Read Diode, Negative resistance of an avalanching p-n
Junction diode IMPA TT and TRAPATT Oscillator.
(b) Transferred Electron Device: Gunn effect, two velley, model, High field Dotrutins, Different
Modes for Microwave generation.
(c) Passive Devices: Termination (Short circuit and matched terminations) Attenuator, phase
changers, E&H plane Tees, Hybrid Junctions. Directional coupler.
7.Parametric Amplifier: Varactor, Equation of Capacitance in Linearly graded & abrupt p-
njun.ction, Man ely Rowe relations, parametric upconvertor and Negative resistance parametric
amplifier,-use of circulator, Noise in parametric amplifiers.
UNIT- V
7. Microwave Antennas: Introduction to antenna paranieters, Magnetic Currents, Electric
and magne* current sheet, Field of Huygen's source, Radiation from a slot antenna, open
end of a wave guide and Electromagnetic Horns. Prabolic reflectors, Lens antennas.
Radiation fields ofMicrostrip wave guide, Microstrip wave guide, Microstrip antenna
calculations, Microstrip design formulas.
9. Microwave Communication:
(a) LOS microwave systems, Derivation of LOS communication range, OTH microwave
systems, Derivation of field strength of tropospheric waves,. Transmission interference
and signal damping, Ductpropagation.
(b) Satellite Communication: SateJJite frequencies aJJocation, Synchronous
sateJJites,SateJJ ite orbits, SateJJite location with respect to earth and look angle, earth
coverage and slant range, Eclipse effect, Link calculation, Noise consideration, Factors
affecting sateJJite communication.

Reference Books: J. Electromagnetic waves & Radiating Systems: Jorden & Balmain.
2. Theory and application of microwaves by A.B. BrownweJJ & RE. Beam (McGraw
HiJJ).
3. Introduction to microwave theory by Atwater (McGraw Hill).
4. Principles of microwave circuit by G.C. Montgomery (Me Graw Hill)
5. Microwave Circuits & Passive Devices by M.L. Sisodia and G.S. Raghuvanshi (New
Age International, New DeltJi)
6. Foundations of microwave engineering by RE. Collin. (McGraw Hill).
7. Microwave Semiconductor Devices and their Circuit applications by H.A. Watson
8. Microwave by M.L. Sisodia and Vijay Laxmi Gupta. New Age, New Delhi.
9. Antenna Theory, Part-! by RE. CoJJin & EJ. Zucker (McGraw Hill, New York)
I O.Microstrip Antennas by Bah I & Bhartiya (Artech House, Messachausetts)
J J. Antenna Theory Analysis by C. A. Balan is Harper & Row. Pub. & Inc. New York.
12. Antenna Theory Analysis by E.A. WOJ ""(J. Willey & Sons)
13. Antenna Theory & Design by RS EJJiott (LPHI Ltd. New Delhi)
14. Microwave electronics by RE Soohoo (Addisen Wesley pubblic company,).
IS.Microwave Active Devices, Vacuoums by M.L. Sisodia new Age International New
Delhi.
16. Semiconductors & Electronics device by A. Barle vs (PHI, India).
17. Solid State physical electronics by A.Vanderziel, (PH1, India).
18. Hand book of microwave measurement Vol-II by M. Sucher & J.Fox (polytechnic
Press, New York).
19. Microwave devices & circuits by S. Y.Liao(PHI, India).
20. Microwave Principles by H.J. Reich (CBS).
21. Simple microwave technique for measuring the dielectric parameters of solids & their
powder by J.M. Gandhi, J.S. Yadav, .1. of pure & applied physics Vol. 30, pp-427431,
1992.