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Thermo Prop

The document discusses thermodynamic property relations and useful equations. It presents: 1) A diagram depicting the properties of water as functions of temperature, pressure, and other variables. 2) General thermodynamic relations including equations for internal energy, enthalpy, and entropy as functions of temperature, pressure, and volume for ideal gases. 3) Useful relations for isentropic, reversible, and steady flow reversible processes, including equations relating pressure, temperature, and volume for isentropic processes and an expression for work done in steady flow reversible processes.

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Muskan Turaha
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14 views

Thermo Prop

The document discusses thermodynamic property relations and useful equations. It presents: 1) A diagram depicting the properties of water as functions of temperature, pressure, and other variables. 2) General thermodynamic relations including equations for internal energy, enthalpy, and entropy as functions of temperature, pressure, and volume for ideal gases. 3) Useful relations for isentropic, reversible, and steady flow reversible processes, including equations relating pressure, temperature, and volume for isentropic processes and an expression for work done in steady flow reversible processes.

Uploaded by

Muskan Turaha
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Thermodynamic Property Relations & Useful Equations

1 Water
The properties of water is depicted in Fig 1

h(T, p, x) h(T, p)

h(T )

Figure 1: properties of water

2 General relations

T ds = du + pdv
T ds = dh − vdp
∂p
· µ ¶ ¸
du = c v dT + T − p dv = c v dT for ideal gas
∂T v
" ¶ #
∂v
µ
dh = c p dT + v − T dp = c p dT for ideal gas
∂T p
cv ∂p cv R
µ ¶
ds = dT + dv = dT + dv for ideal gas
T ∂T v T v
cp ∂v c R
µ ¶
p
ds = dT + dp = dT + dp for ideal gas
T ∂T p T p
h fg
µ ¶
dp
= Clapeyron Eq.
dT sat T v fg
1
3 Useful relations
For isentropic process i .e., reversible and adiabatic process,

Tγ cp
pv γ = constant, = constant, T γ v γ−1 = constant where, γ =
p γ−1 cv

For Reversible process

T d S = δQ rev

For steady flow reversible process the work done per unit mass between inlet and outlet is
Z o Z o Z o
w i −o = v dp + d(ke) + d(pe)
i i i

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