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Qualitative Notes

Chemistry olevel notes
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Qualitative Notes

Chemistry olevel notes
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© © All Rights Reserved
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Notes for use in qualitative analysis Tests for anions anion carbonate, CO,” test add dilute acid then test for carbon dioxide gas test result effervescence, carbon dioxide produced chloride, CZ acidify with dilute nitric acid, then add white ppt. {in solution] aqueous silver nitrate bromide, Br- acidify with dilute nitric acid, then add cream ppt. {in solution] aqueous silver nitrate iodide, acidity with dilute nitric acid, then add yellow ppt. [in solution] aqueous silver nitrate nitrate, NO, add aqueous sodium hydroxide, then ammonia produced {in solution] aluminium foil; warm carefully sulfate, SO,?- acidity with dilute nitric acid, then add white ppt fin solution] aqueous barium nitrate sulfite, SO, adda small volume of acidified aqueous the acidified aqueous potassium manganate(VII) Tests for aqueous cations cation aluminium, AC effect of aqueous sodium hydroxide white ppt, soluble in excess, giving a colourless solution potassium manganate(VII) changes colour from purple to colourless effect of aqueous ammonia white ppt, insoluble in excess ammonium, NH,* ammonia produced on warming calcium, Ca’* white ppt, insoluble in excess ro ppt. or very slight white ppt. chromium(III), C?* green ppt., soluble in excess ‘green ppt,, insoluble in excess copper(II), Cu** light blue ppt, insoluble in excess light blue ppt, soluble in excess, giving a dark blue solution iron(II), Fe iron(II), Fe** ine, Zn* green ppt, insoluble in excess, ppt. turns brown near surface on standing red-brown ppt, insoluble in excess white ppt, soluble in excess, giving a colourless solution ‘green ppt, insoluble in excess, ppt. turns brown near surface on standing red-brown ppt, insoluble in excess white ppt., soluble in excess, giving a colourless solution Tests for gases gas ammonia, NH, carbon dioxide, CO, chlorine, Cl, hydrogen, H, test and test result turns damp red litmus paper blue turns limewater milky bleaches damp litmus paper ‘pops’ with a lighted splint oxygen, 0, relights a glowing splint sulfur dioxide, SO, turns acidified aqueous potassium manganate( VII) from purple to colourless Flame tests for metal ions metal ion lithium, Li? sodium, Na* potassium, K* calcium, Ca* barium, Ba”* copper(II), Cu* flame colour red yellow titae orange-red light green blue-green

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