Solution Manual For Introduction To Process Technology 4th Edition Thomas 9781305251472
Solution Manual For Introduction To Process Technology 4th Edition Thomas 9781305251472
OBJECTIVES
• Describe the process technology curriculum and Associate of Applied Science degree plan.
• List the key principles of safety, health, and environment
• Explain the principles of instrumentation and modern process control.
• Identify the different types of process equipment and the technology associated with
operating them.
• Solve math and science problems associated with the chemical processing industry.
• List the basic principles of quality control.
• Describe how the principles of chemistry and physics are applied in the chemical processing
industry.
• Describe the various systems found in the chemical processing industry.
• Explain how process operations is used to prepare a student for employment in the CPI.
• Solve simple process technology troubleshooting scenarios.
REVIEW QUESTIONS
1. List the basic concepts of statistical quality control.
Study of the background and application of quality concepts. Topics include team skills,
quality tools, statistics, economics and continuous improvement. The focus of the course
is on the application of statistics, statistical process control, math, and quality tools to
process systems and operations
2. List the basic concepts taught in safety, health, and environment.
page 18
Knowledge and skills to reinforce the attitudes and behaviors required for safe and
environmentally sound work habits. Emphasis on safety, health, and environmental
issues in the performance of all job tasks and regulatory compliance issues.
3. List three basic systems found in the chemical processing industry.
Pump and compressor systems, heat exchangers and cooling tower systems, boilers and
furnace systems, distillation systems, reaction systems, utility system, separation systems,
plastics systems, instrument systems, water treatment, and extraction systems.
page 19
7. Describe how science and chemistry are related to the other process classes.
Governmental guidelines require process technicians to understand the science and
chemistry of the processes they are operating, a solid foundation is required in applied
math, physics, and chemistry. Calculating product transfers, mixing raw materials to form
new products, and dealing with compositional, analytical, pressure, level, flow, and
temperature problems are all common areas to which the math/science foundation is
applied.
page 20
11. Describe the process technology curriculum and Associate of Applied Science degree
plan at your school.
See your college catalog.
12. Describe the primary purpose of the process instrumentation course.
The purpose of the process instrumentation course varies greatly from a traditional
instrumentation course. Process technicians are required to safely operate and
troubleshoot a vast array of pipes, pumps, valves, compressors, heat exchangers, cooling
towers, industrial drivers, boilers, furnaces, reactors, strippers, distillation columns,
plastics plant equipment, instruments, and control systems. The design of each process
system includes simple process flow diagrams (PFD’s) and complex piping and
instrumentation drawings (P&ID’s). The dictionary of equipment, control
instrumentation, and piping symbols associated with these processes are foundational in
the initial training of process technicians. Operators spend many hours tracing lines and
locating specific equipment. A process instrumentation class is designed to prepare
students to pick up existing drawings and quickly assimilate the information while
learning how to operate their process units. The purpose of a process instrumentation
course is to: (1) qualify students on a wide variety of process symbols and diagrams, (2)
draw process flow diagrams, (3)study the process variables and instruments used to
control; temperature, flow, level, pressure, analytical or composition, time, speed, etc.,
(4) draw the control loops used to control these variables including cascaded control, and
(5) draw a piping and instrumentation drawing (P&ID) that includes all of the above
mentioned items. In advanced courses technicians connect the concepts associated with
drawing a P & ID’s to operational set-points and conditions that exist with the equipment,
like tank levels, flow rates, temperatures, etc. Connecting the dots is a critical part of the
training process for any process technician.
13. List the key elements found in the definition of process technology.
page 21
chemical processing industry. The term process technology was first created in the
community college environment to describe a new program being designed to train
process technicians.
15. Draw a simple sketch of a shell and tube exchanger. Show all flows: tube-in, tube-out,
shell in, shell out, shell, channel-head, pass partition, tube-sheet, and all associated
valves. Explain principles of heat transfer, flow rate, and pressure and illustrate on your
drawing how they work.
page 22
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reference to this article our papers should observe: “Up to the present the
French have played the part of masters to the whole world, and Belgium,
Spain, and the King of Prussia have in turn experienced their arrogance.
Their behaviour was somewhat like that of the Sultan towards his
Khedive, it was a kind of megalomania based upon the bayonet. Their
presumption is now beginning to waver, so they court the assistance of
those good friends whom they pretend to have placed under obligations
to them.”
The Minister subsequently dictated the following, to be worked up
for the German newspapers outside Berlin, such as the Kölnische
Zeitung, and for the English and Belgium journals: “According to
confidential communications from loyal Hanoverian circles, amongst
other decisive factors which led the French to the declaration of war,
were the reports sent to Paris by Colonel Stoffel, the Military
Plenipotentiary in Berlin. Stoffel’s information was, it appears, less
accurate than abundant, as none of those who supplied him with it being
prepared to forego the payments they received from him merely because
they had nothing to say, they occasionally invented the news of which
they warranted the correctness. The Plenipotentiary had, it is said, been
informed that the arming of the Prussian infantry, both as regards rifles
and ammunition, was at present undergoing a thorough transformation,
and that consequently a moment so favourable as the present for
attacking Prussia would hardly occur again, inasmuch as on the
completion of this change the Prussian armaments would have been
unassailable.”[4]
2. “It now appears to be beyond all doubt that the French
Government was aware of the candidature of the Prince of Hohenzollern
for months past, that they carefully promoted it and foolishly imagined it
would serve as a means of isolating Prussia and creating a division in
Germany. No trustworthy information has been received as yet as to
whether and how far Marshal Prim had prepared the way for this
intrigue, in agreement with the Emperor Napoleon. But doubtless that
point will ultimately be cleared up by history. The sudden disappearance
of Spain from the political field as soon as the differences between
France and Prussia broke out gives matter for reflection and suspicion. It
cannot but be regarded as strange that after the zeal shown by the
Spanish Government in the matter of the Hohenzollern candidature had
been raised to boiling point it should have suddenly fallen below zero,
and that the relations of Marshal Prim to the French Cabinet should now
appear to be of the most friendly character, while the Spaniards seem no
longer to feel any irritation at the interference of France in their internal
affairs.”
3. “Rumours were circulated this afternoon to the effect that the
former French Military Plenipotentiary, Baron Stoffel, had been insulted
in the street. On closer inquiry it was ascertained that some individuals
who knew Stoffel followed him in the street, and on his reaching his
house struck the door with their sticks. The police intervened
energetically on the first report of this matter and have taken measures to
prevent a repetition of such conduct and to provide that Baron Stoffel
shall not be interfered with on his departure this evening. Excesses of
this description are, however, highly reprehensible, even when they are
confined to words. The former representatives of France are under the
protection of international law and of the honour of Germany until they
have crossed the frontier.”
July 21st.—Keudell asked me this morning if I knew Rasch, the
journalist, and if I could say where he was now to be found, in Berlin or
elsewhere. I replied that I had seen him in Schleswig in 1864, afterwards
at a table d’hôte at the Hotel Weissberg, in the Dessauer Strasse, where
he lodged at the end of February. I knew nothing more about him, but
had heard that he was extremely conceited, almost to the point of
madness—a political visionary who desired to convert the whole world
to republicanism. I was not aware of his whereabouts in Berlin, but
would make inquiries at Weissberg’s. Keudell told me to hunt him up
and ask him whether he would go to Garibaldi and urge him to undertake
an expedition against Rome, at the same time carrying him money from
us. I pointed out that Rasch was perhaps too vain to keep his own
counsel. Keudell consoled himself with the idea that he would doubtless
prove a good patriot. I declined to treat with Rasch in the matter, as I
could not speak to him in my own name but in that of the Foreign Office,
and that could be better done by some official of higher rank, who would
make a greater impression upon Rasch. Keudell seemed to recognise the
justice of this view. I made inquiries and was able to report on the same
evening that Rasch was staying at Weissberg’s.
Called to the Minister in the evening. He showed me an extract from
the National Zeitung, and observed: “They say here that the English
would not allow the French to attack Belgium. Well and good, but how
does that help the Belgians if the protection comes too late? If Germany
were once defeated (which God forbid!) the English would not be able to
assist the Belgians in the least, but might, on the contrary, be thankful if
they themselves remained safe in London.”
I am further to call attention to the “manner in which France is
begging for help on all sides—that great warlike nation which makes so
much parade of its victories, representing them as having always been
won solely by the force of its own arms. They go begging (use that
expression) to Italy, to Denmark, to Sweden, and above all to the
German States, to whom they promise the same brilliant destiny which
they have already prepared for Italy—political independence and
financial ruin.”
Called up to the Minister again later. I am to secure the insertion of
the following in the non-official German papers and in the Belgian and
English press: “The English Government observe their neutrality in
connection with the war that has now broken out in a liberal and
conscientious spirit. They impartially permit both sides to purchase
horses and munitions of war in England. It is unfortunate, however, that
France alone can avail herself of this liberality, as will appear from a
glance at the geographical position of the two countries and from the
superiority of the French at sea. Then quote what Heffter (the book must
be in the library) has to say on this kind of neutrality, and observe that
the English jurists describe it more tersely as ‘fraudulent neutrality.’”
July 23rd.—Called to the Minister five times to-day. The press
should urge the prosecution and seizure of Rothan, an Alsacian who
speaks German, hitherto French Chargé d’Affaires at Hamburg, who has
been a zealous spy and instrument of French intrigue in North Germany,
and who is now understood to be wandering along the coast between the
Elbe and Ems, as also that of the ex-Hanoverian officer, Adolf von
Kielmansegg, respecting whom further particulars are to be obtained
from the Ministry of the Interior. The Count further wants the press to
give a list of the names of the Bavarian members of Parliament who
voted for the neutrality of that State in the national war, mentioning their
professions but without any further remarks. “Give it first in Brass,” (i.e.,
Norddeutsche Allgemeine Zeitung,) he added. “You will find such a list
amongst the documents. The complaints as to the manner in which
England understands neutrality must be continually renewed. The
English Government does not forbid the export of horses, though only
France can avail herself of that facility. Colliers are allowed to load at
Newcastle and to supply fuel for the French men-of-war cruising in the
North Sea. English cartridge factories are working for the French army
under the eyes of the Government. In Germany the painful feeling has
become more and more widespread that, under Lord Granville, England,
while nominally maintaining neutrality, favours France in the manner in
which it is really observed.”
About 11 . . I was again called to the Minister. The reports
respecting the English coal ships to be at once sent by a Chancery
attendant to Wolf’s Telegraphic Agency for circulation to the
newspapers.
In this connection may be mentioned an Embassy report from
London, dated the 30th of July, to the following effect: Lord Granville
had asked the Ambassador if he had not stirred up the authorities in
Berlin against the English Government. The reply was in the negative.
The Ambassador had only carried out his instructions. Public opinion in
Germany influenced the Government, just as the German press
influenced public opinion. The manner in which neutrality was observed
on the part of England had excited the greatest indignation in Germany.
The action of the English Government, which indeed recognised that
France was in the wrong, but failed to give expression to that conviction,
was also bitterly resented there. Granville replied that once it had been
decided to remain neutral that neutrality must be maintained in every
respect. If the export of contraband of war were forbidden, the French
would regard it as an act of one-sided hostility, while at the same time it
would ruin English trade in the branches affected by such prohibition,
and favour American manufacturers. For the present, every one in
England approved of the maintenance of neutrality, and therefore in a
general way no change was possible in these matters. At the same time,
the English Government was ready, in case of complaints reaching them
in an official way respecting any acts of illegality, to institute an inquiry
into the facts and secure the punishment of the guilty parties. It did not
seem impossible to prevent the supply of English coal to French men-of-
war. Next Monday a Bill was to be submitted to Parliament for the
amendment of the laws regulating neutrality. The report concluded as
follows: “England is in many respects well disposed towards us, but will
for the present remain neutral. If we make further attacks upon English
public opinion through our official press in connection with these
grievances, it will serve no purpose but to conjure up future difficulties.
Granville is not what we might desire, but he is not prejudiced against
us. He may become so, however, if he is further provoked by us. We can
hardly succeed in overthrowing him, and if we did his probable
successor would in all likelihood be much worse than himself.”
July 24th.—I am instructed by the Count to send an article to the
Kölnische Zeitung respecting the Dutch coal question. He gave me the
following information on this subject: “Holland asked us to again permit
the passage of Prussian coal down the Rhine, and requested that a large
transport of Rhenish coal intended for Holland should be allowed to pass
the frontier. It was only to be used in factories, and the Government of
the Netherlands would prohibit its re-exportation. Prussia willingly
agreed to this, but shortly afterwards it was ascertained that foreign
vessels were being loaded with coal in Dutch ports, and the Government
of the Netherlands subsequently informed us that in promising to prevent
the re-exportation they had overlooked the circumstance that their treaty
with France did not permit this. Thereupon as a matter of course the
export of Prussian coal to Holland was prohibited. In the interval,
however, they seem to have secured a sufficient supply in Holland to
provide the French fleet for a considerable time. That is a very
suspicious method of observing the neutrality promised by the gentlemen
at the Hague.”
Bucher brings me the following paragraph from the Chief, which is
to be inserted in the Spenersche Zeitung, or some other non-official
organ, and afterwards in the North German Correspondence: “In 1851 a
literary gamin in Paris was commissioned to conjure up the Red Terror in
a pamphlet, which proved very useful to the President Louis Napoleon,
enabling him to escape from a debtors’ prison and ascend the Imperial
throne. The Duc de Grammont now tries to raise the Spanish Terror in
order to save the Emperor from the necessity of accounting for the
hundred millions which he diverted from the State Treasury into his
private purse. The literary gentleman in question was made a Prefect.
What reward can Grammont have had in view?”
Evening.—The Minister wishes an article to be prepared for
circulation in the German press describing the French and French policy
under the Emperor Napoleon. This is to be first sent to the Spenersche
Zeitung, while the Literary Bureau is to secure the insertion of the
principal points in a condensed form in the Magdeburg papers and a
number of the smaller journals to-morrow. The Count said (literally):
“The French are not so astute as people generally think. As a nation they
resemble certain individuals amongst our lower classes. They are
narrow-minded and brutal,—great physical force, boastful and insolent,
winning the admiration of men of their own stamp through their audacity
and violence. Here in Germany the French are also considered clever by
persons who do not think deeply, and their Ministers are regarded as
great statesmen because of their insolent interference in the affairs of the
whole world, and their desire to rule everywhere. Audacity is always
impressive. People think their success is due to shrewd political
calculation, but it is actually due to nothing else than the fact that they
always keep 300,000 soldiers ready to back up their policy. That alone,
and not their political intelligence, has enabled them to carry things with
such a high hand. We must get rid of this fiction.... In political affairs the
French are in the fullest sense of the word a narrow-minded nation. They
have no idea how things look outside of France, and learn nothing about
it in their schools. The French educational establishments, for the greater
glory of France, leave their pupils in the crassest ignorance as to
everything beyond her frontiers, and so they have not the slightest
knowledge of their neighbours; that is the case with the Emperor, or at
least he is not much better, to say nothing of Grammont, who is an ass
(Rindvieh). Napoleon is ignorant at bottom, although he has been
educated in German schools. His ‘Cæsar’ was intended to conceal that
fact. He has forgotten everything. His policy was always stupid. The
Crimean War was against the interests of France, which demanded an
alliance or at least a good understanding with Russia. It was the same
with the war in Italy. There he created a rival in the Mediterranean,
North Africa, Tunis, &c., who may one day prove dangerous. The Italian
people are much more gifted than the French, only less numerous. The
war in Mexico and the attitude adopted in 1866 were blunders, and
doubtless in storming about as they do at present the French feel
conscious that they have committed another blunder.”
July 25th.—At 11 o’clock this morning Count Bismarck and his
family took the Holy Communion at their residence. He asked whether
any one in our bureau desired to join them, but no one offered to do so. I
was for a moment tempted, but reconsidered the matter. It might look as
if I wished to recommend myself.
Copies of the Benedetti draft treaty are sent to Auber (the French
Press Agency) and Heide.
July 27th.—It is to be stated either in the Norddeutsche or the
Spenersche Zeitung that secrecy respecting confidential communications
between great States is, as a rule, more carefully observed and
maintained than the public imagines. Nevertheless, the French
misrepresentation of Prussia’s attitude in the affair of the candidature for
the Spanish throne (in Grammont’s despatch of the 21st of July) obliged
the authorities here to disregard these considerations of discretion.
Benedetti’s proposal has therefore been published and it may be followed
by other documents of the same description. The Count concluded his
directions as follows: “We are at least entitled to tell the truth with
discretion in presence of such indiscreet lies.”
Bucher brings me from the Minister the following sketch of a
paragraph for the press: “The despatch of the Duc de Grammont, the full
text of which now lies before us, is a desperate attempt to prove that the
origin of the situation which they have themselves created was the
Hohenzollern candidature, and to conceal the motive which they
confessed on many other occasions—namely, the conquest by France of
the left bank of the Rhine and of Belgium. The inconsistency of the
whole assertion is made clear by the circumstance that the offer of the
Spanish throne to the Hereditary Prince of Hohenzollern was first made
in a letter dated the 14th of February of the present year. Therefore, there
can be no connection between this offer and the conversations in March,
1869, between Benedetti and Von Thile, which were the outcome of
aspirations or proposals frequently ventilated in the press (also with
reference to Prince Frederick Charles). In 1851 the President Louis
Napoleon succeeded in obtaining credence both at home and abroad for
certain fictions, so long as that was necessary for the attainment of his
object. The fiction which is now circulated, at a somewhat late hour, to
the effect that the Prince of Hohenzollern was the candidate of Prussia is
refuted in advance by the fact, which has been well known for a long
time, that the Prussian Government as well as the officials of the
Confederation, had absolutely no knowledge of, or connection with, the
Spanish proposal. It was resolutely opposed by his Majesty the King, as
the head of the Hohenzollern family, until last June, when at Ems he
reluctantly withdrew his opposition when it was represented to him that
otherwise Spain would fall into the hands of the Republicans. We find it
difficult to understand what interest the French Government can have in
circulating such lies now that war has actually broken out. The attempt
of the Duc de Grammont to conjure up the spectre of a restoration of
Charles V.’s monarchy can only be explained by the complete isolation
of the French mind. That apparition had no sooner manifested itself than
it vanished before the angry contempt of public opinion, which resented
being supposed capable of such credulity.”
The Chancellor desires to see the following considerations
reproduced in the evening papers: “The Benedetti document is by no
means the only one dealing with the matter in question. Negotiations
were also carried on by others, as, for instance, by Prince Napoleon
during his stay in Berlin. Since French diplomacy was ignorant enough
to believe that a German Minister who followed a national policy could
for a moment think of entertaining such proposals, it had only itself to
thank if it was befooled with its own schemes so long as such fooling
appeared calculated to promote the maintenance of peace. Even those
who pursue the most ignorant and narrow-minded policy must ultimately
come to recognise that they have hoped for and demanded
impossibilities. The bellicose temper which now prevails in Paris dates
from such recognition. The hopes of German statesmen that they would
be able to befool the French until a peaceful régime was established in
France by some transformation of her despotic constitution have
unfortunately not been realised. Providence willed it otherwise. Since we
can no longer maintain peace it is not necessary now to preserve silence.
For we preserved silence solely in order to promote the continuance, and,
if possible, the permanency, of peaceful relations.”... The Minister
concluded: “You can add, too, that the question of French Switzerland
was also mentioned in the negotiations, and that it was hinted that in
Piedmont they knew quite well where the French districts begin and the
Italian districts leave off.”
July 28th.—I see the original of Benedetti’s draft treaty, and I am to
receive a photographic copy of it similar to that which has been prepared
for distribution amongst foreign Governments.
Bucher handed me the following sketch of an article, received by him
from the Minister, which is to be inserted in some organ not apparently
connected with the Government: “Those who now hold power in Spain
declare that they do not wish to interfere in the conflict between
Germany and France, because the latter might create internal difficulties
for them. They allow Bonaparte to prohibit their election of the King of
their own choice. They look on calmly with folded arms while other
nations go to war over a difference that has arisen out of a question of
Spanish domestic interest. We had formed quite another opinion of the
Castilian gentilhomme. The Spanish temper seems to resemble that of
Gil Blas, who wanted to fight a duel with the army surgeon but observed
that the latter had an unusually long rapier.”
July 30th, 10 p.m.—The Minister desires that attention should be
again called to the manner in which the French are looking about for
foreign assistance, and he once more gives a few points: “France is
begging in all directions, and wants in particular to take Italy into her
pay. Here, as everywhere, she speculates upon the worst elements, while
the better elements will have nothing to do with her. How does that
harmonise with the greatness of the nation which ‘stands at the head of
civilisation,’ and whose historians always point out that it was only
defeated at Leipzig because its opponents were four to one? At that time
they had half Germany, Italy, Holland, and the present Belgium on their
side. To-day, when they stand alone, they go round hat in hand to every
door, and seek mercenaries to reinforce their own army, in which they
can therefore have but very little confidence.”
July 31st.—This morning received from Roland one of the
photographic copies of the Benedetti draft.
CHAPTER II
DEPARTURE OF THE CHANCELLOR FOR THE SEAT OF WAR—I FOLLOW HIM, AT
FIRST TO SAARBRÜCKEN—JOURNEY FROM THERE TO THE FRENCH
FRONTIER—THE FOREIGN OFFICE FLYING COLUMN